JOURNAL OF CHEMICAL RESEARCH
·
2024
·
IF 1
Liyuan Zhang,Xuewen Bai,Kai Zou,Linlin Zhu
Magnetic polymer microspheres have attracted a great deal of attention due to their magnetic properties and good biocompatibility. In this study, novel magnetic cross-linked poly(divinylbenzene-co-acrylic acid) microspheres were successfully prepared via improved emulsion polymerization. The microstructures of nanocomposites were characterized using scanning electron microscopy, transmission electron microscope, energy-dispersive X-ray spectrometry, X-ray diffraction, and saturation magnetization measurements. It was noteworthy that the nanocomposites displayed good water dispersibility, a rapid absorption rate, a high absorption capacity, and high magnetic separability, results that are promising in terms of these nanocomposites’ future application in biomedical fields.
研究领域:
材料科学
·
生物医学工程
✓ 已验证
DOI
高影响因子
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
·
2024
·
IF 7.7
Yuhang Wei,Weiwei Xie,Xinyue Wang,Qingyang Chong,Song Li,Zhiming Chen
The degradation of synthetic dye wastewater is important for green chemistry and cost-effectiveness. In this study, we developed Fe 3 O 4 @C-laccase (laccase immobilized on Fe 3 O 4 @C nanoparticles) for photothermal degradation of high concentration of triphenylmethane dye wastewater. The Fe 3 O 4 @C-laccase possessed superior pH and thermal stabilities, as well as excellent tolerance to organic solvents, inhibitors, and metal ions. Laccase activity assays revealed that the activity recovery was approximately 118.2 %. Furthermore, the Fe 3 O 4 @C-laccase presented rapid and sustainable photothermal degradation capabilities to triphenylmethane dye wastewater. The initial removal efficiencies of 400 mg/L malachite green (MG), 400 mg/L brilliant green (BG), 100 mg/L crystal violet (CV), and 600 mg/L mixed dye (MG:BG:CV = 1:1:1) wastewater were approximately 99.8 %, 99.9 %, 96.4 % and 99.2 % by 60 min treatment, respectively. After undergoing 10 batches of reuse, the photothermal degradation efficiencies of the triphenylmethane dye wastewater remained consistently high, at about 99.3 %, 97.4 %, 94.0 %, and 95.1 %, respectively. The excellent photothermal degradation properties indicate that the Fe 3 O 4 @C-laccase holds promise for addressing high concentration of textile wastewater in various applications.
研究领域:
环境科学
·
生物技术
✓ 已验证
DOI
PubMed
高影响因子
Journal of Materiomics
·
2022
·
IF 8.589
Li Wang,Zhang Chen,Xue Wang,Liying Zhang,Zongtao Zhang,Qi Zhao,Yanfeng Gao
Low-frequency microwave absorbing materials have been challenging for many years. Three-dimensional dielectric/magnetic porous materials are beneficial for improving the low-frequency microwave absorbing performance because of natural resonance and improved impedance matching. In this study, Fe 3 O 4 @C 3D foam was prepared by carbothermal reduction method and the microwave attenuation performances and mechanisms were studied. By adjusting the content of Fe 3 O 4 @C 3D foam in paraffin composites, the low-frequency microwave attenuation capacity could be effectively optimized. The minimum reflection loss (RL min ) of paraffin composite with 40% (in mass fraction) loading exhibits −54.7 dB at 4.1 GHz for a thickness of 4.0 mm. Surprisingly, the paraffin composite with 50% (in mass fraction) loading could almost cover 2–4 GHz (S-band) in the thickness range of 3.5–5.5 mm. The strong low-frequency microwave attenuation property of Fe 3 O 4 @C 3D foam is mainly attributed to excellent low-frequency impedance matching, natural resonance, interfacial/dipole polarization, multiple reflection and scattering. This method provides a new perspective for preparing lightweight and high performance low-frequency microwave absorbing materials.
研究领域:
材料科学
·
电磁学
✓ 已验证
产品关联
DOI
高影响因子
BULLETIN OF ENVIRONMENTAL CONTAMINATION AND TOXICOLOGY
·
2020
·Vol. 106
·期 1
·165-174
·
IF 1.657
Feng Jinghua,Cai Yawen,Wang Xiangxue,Wang Xin,Zhu Mingyu,Fang Ming,Liu Zehua,Tan Xiaoli
Adsorbents with the combination of magnetic separation and removal performance are expected for reducing the adverse impact of nuclear pollution. In this study, the core–shell Fe 3 O 4 @polydopamine (Fe 3 O 4 @PDA) was successfully synthesized and used for removal of uranium (U(VI)) ion from aqueous solution. The abundant N-containing groups derived from PDA exist as the chelate sites for U(VI) and contribute greatly for U(VI) removal. Experimental results show that Fe 3 O 4 @PDA (56.39 mg g –1 ) exhibits greater sorption capacity for U(VI) removal compared with the pure Fe 3 O 4 (9.17 mg g –1 ). The sorption isotherm can be well fitted with Freundlich model and the sorption process is endothermic and spontaneous. The removal of U(VI) can be explained by the complexation of U(VI) with –NH–, –NH 2 and C–O in the surface of Fe 3 O 4 @PDA by X-ray photoelectron spectroscopy (XPS) analysis.
研究领域:
环境科学
·
材料科学
✓ 已验证
DOI
高影响因子
ENERGY & FUELS
·
2022
·
IF 4.654
Guodong Zhang,Weiqiang Cao,Haixia Zhang,Ying Hou,Junjie Guo
Polypyrrole (PPy) has great potential for applications as a supercapacitor electrode owing to its excellent pseudocapacitance. However, the large volume changes during the rapid charge and discharge process lead to damage to the structure, which is the main obstacle to practical applications. Here, the core–shell structure composite composed of magnetic ferroferric oxide (Fe3O4) nanoparticles and PPy was prepared by solution polymerization. In the Fe3O4/PPy composite, Fe3O4 nanoparticles play the role of reaction template, which can be arranged in a line under a magnetic field, thereby starting the adhesion polymerization of PPy to form a stable core–shell structure with excellent capacitance. The as-synthesized Fe3O4/PPy electrode presents a significantly enhanced specific capacitance of 697 F g–1 at 1.0 A g–1. In particular, the as-synthesized Fe3O4/PPy composite achieved a high energy density of 96.8 Wh kg–1 at 500 W kg–1. This study paves a way to develop materials with high electrochemical performance and may promote the practical application of high-capacity energy storage materials.
研究领域:
材料科学
·
电化学
✓ 已验证
DOI
高影响因子
SEPARATION AND PURIFICATION TECHNOLOGY
·
2021
·
IF 7.312
Yongfei Zhu,Yonggang Du,Junming Su,Yanchao Mo,Shujuan Yu,Zhi Wang
Oil/water separation through superhydrophobic sponges is an important method for oily wastewater and organic solvents pollution treatments, and developing a simple and eco-friendly approach to fabricate superhydrophobic sponge is still very urgent and valuable. In this work, Fe 3 O 4 and bio-benzoxazine based on cardanol and long-chain aliphatic amine were successively loaded on melamine sponge (MS) through a simple dip-coating method, which was thermally cured to obtain superhydrophobic MS. The as-prepared superhydrophobic MS (P15C-O/Fe 3 O 4 /MS) not only exhibited high oil absorption capacity from 65.8 to 136.2 times its own weight for various oils and organic solvents, but also showed excellent recyclability with a water contact angle (WCA) of about 149° after 50 absorbing-squeezing cycles and an absorption retention of more than 92% after 100 cycles. Moreover, P15C-O/Fe 3 O 4 /MS also possessed outstanding chemical stability, whose WCA almost kept unchanged after touching with strong acid (pH = 1) and alkali (pH = 13) as well as NaCl solutions for 48 h. The outstanding recyclability and stability of P15C-O/Fe 3 O 4 /MS were from the stability of polybenzoxazine and strong adhesion between the coating and sponge, due to the formation of coordination interactions between Fe 3+ and N, O atoms as well as hydrogen bonds between polybenzoxazine and sponge. In addition, P15C-O/Fe 3 O 4 /MS could be used for continuous oil-water separation and driven remotely by a magnetic force. These advantages make P15C-O/Fe 3 O 4 /MS a potential candidate for large-area oil-spill cleanup and oily wastewater treatment, especially under some dangerous conditions.
研究领域:
材料科学
·
环境科学
✓ 已验证
DOI
高影响因子
LANGMUIR
·
2018
·
IF 3.789
Jianfeng Zhang,Qunling Fang,Jinyu Duan,Hongmei Xu,Huajian Xu,Shouhu Xuan
This work reports a novel Fe3O4@polydopamine/Au/polydopamine core/shell nanocomposite toward a magnetically separable nanocatalyst. Because the polydopamine (PDA) layer-sandwiched Au nanocrystals were prepared by a layer-by-layer method, the content of Au could be controlled by varying the Au shell number (such as burger-like Fe3O4@PDA/Au/PDA/Au/PDA). Fe3O4@PDA/Au/PDA exhibited excellent catalytic activity in reducing p-nitrophenol because the substrate could penetrate the PDA shell. Owing to the protection of the PDA shell, Fe3O4@PDA/Au/PDA presented higher cyclability than Fe3O4@PDA/Au. The activity of Fe3O4@PDA/Au/PDA maintained 95% after 7 cycles, while that of Fe3O4@PDA/Au was only 61%. The detailed cycling catalytic mechanism was investigated, and it was found that the catalytic rate of Fe3O4@PDA/Au/PDA/Au/PDA was faster than that of Fe3O4@PDA/Au/PDA because of the higher Au content. Interestingly, this method could be extended for other magnetic nanocomposites with two different kinds of noble metal nanocrystals integrated within one particle, such as Fe3O4@PDA/Au/PDA/Ag/PDA and Fe3O4@PDA/Au/PDA/Pd/PDA.
研究领域:
材料科学
·
化学工程
·
纳米技术
✓ 已验证
产品关联
DOI
PubMed
高影响因子
ACS Applied Materials & Interfaces
·
2022
·
IF 10.383
Zhu Xiong,Yongshi Huang,Zehui Huang,Yiwen Shi,Fangshu Qu,Gaosheng Zhang,Jingxin Yang,Shuaifei Zhao
Membrane surface fouling is often reversible as it can be mitigated by enhancing the crossflow shear force. However, membrane internal fouling is often irreversible and thus more challenging. In this study, we developed a new superhydrophilic poly(vinylidene fluoride) (P-PVDF) membrane confined with nano-Fe3O4 in the top skin layer via reverse filtration to reduce internal fouling. The surface of the P-PVDF membrane confined with nano-Fe3O4 had superwetting properties (water contact angle reaching 0° within 1 s), increased roughness (from 182 to 239 nm), and enhanced water affinity. The Fe3O4@P-PVDF membrane surface showed a thicker and enhanced hydration layer, which prevented foulants from approaching membrane surfaces and pores, thereby improving the rejection. For example, when 50 ppm humic acid (HA) solution was used as the feed, the removal efficiency of the Fe3O4@P-PVDF membrane was ∼67%, while the HA removal of the P-PVDF membrane was only ∼20%. The results from the resistance-in-series model showed that nanoconfinement of Fe3O4 in the top skin layer of the membrane allowed foulants to accumulate on the membrane surface (i.e., surface fouling) rather than within the internal pores (i.e., internal fouling). The filtration results under crossflow fouling and cleaning confirmed that the Fe3O4@P-PVDF membrane had higher surface fouling but it was much more reversible and much lower internal fouling compared with the control membrane. Our fouling analysis offers new insights into mass transfer mechanisms of the membrane with a nanoconfinement-enhanced hydration layer. This study provides an effective strategy to develop membranes with low internal fouling propensities.
研究领域:
环境科学
·
材料科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
CERAMICS INTERNATIONAL
·
2020
·
IF 3.83
Li Li,Yanjun Cui,Zhixia Zhang,Peng Tu,Haipeng Gong,Ping Li
In this work, a novel 3D graphene/Fe 3 O 4 (G-Fe 3 O 4 ) nanocomposite was prepared by a facile one-pot hydrothermal process used to be adulterated into the varnish as an anticorrosive and electromagnetic shielding paint. It is confirmed that the skeleton structure of graphene can effectively inhibit Fe 3 O 4 agglomeration by Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) technique, and the G-Fe 3 O 4 nanocomposites can be well dispersed in the varnish for a longtime without settling. The graphene/Fe 3 O 4 composite varnish shows excellent corrosion resistance both in city water and seawater , besides its corrosion resistance is also superior to that of ordinary anti-rust paint. Moreover, the electromagnetic shielding test confirms that the as-prepared composite varnish shows well electromagnetic shielding performance. This new type of composite varnish has a broad application prospect to be used as urban exterior wall and ships paint.
研究领域:
材料科学
·
化学工程
✓ 已验证
DOI
高影响因子
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
·
2017
·Vol. 25
·期 4
·3922-3932
·
IF 2.741
Yi Xiaofeng,Yang Meixia,Mo Liuda,Xu Wenkai,Wang Shuai,He Jiarui,Gu Junjie,Ou Minrui,Xu Xiaoping
Copper in drinking water causes a significant environmental problem. Composite material based on alginate hydrogel has been gaining attention in the field of Cu(II) adsorption. However, alginate-based hydrogel exhibits poor mechanical property and relative low adsorption capacity which limit their application. The present study is devoted to the modification of chitosan/calcium alginate/Fe 3 O 4 (CAF) hydrogel microsphere by NaOH solution for enhancement of Cu(II) adsorption. Results reveal that modification of CAF via NaOH solution significantly improves the mechanical strength and Cu 2+ adsorption capacity of pristine materials. FTIR and XRD analysis confirms that CAF and newly prepared materials (NACAF) are successfully prepared. SEM and EDX are employed to analyze the surface morphology and elemental composition, respectively, both before and after their loading with Cu 2+ . XPS study demonstrates adsorption mechanism is based on chelation and ion-exchange. Compressive stress-strain curves demonstrate NACAF has better mechanical performance than CAF. The adsorption kinetics of the two adsorbents follow a pseudo-second-order model. The equilibrium data were best described by Langmuir isotherm model, and the estimated maximum equilibrium sorption capacity, q
m ,is 261.31 mg/g for the NACAF, which is larger than that of CAF (145.39 mg/g). Hence, NACAF shows excellent mechanical strength and high sorption capacity for Cu 2+ . It has great potential for Cu(II) removal in aqueous solutions.
研究领域:
环境科学
·
材料科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
Materials Science & Engineering C-Materials for Biological Applications
·
2019
·
IF 4.959
Wanling Cai,Mengyu Guo,Xiulan Weng,Wei Zhang,Zuliang Chen
Since Fe 3 O 4 nanoparticles synthesized by plant extracts possess good bio-compatibility and superparamagnetic properties, the possibility of these could be used as a carrier in drug delivery. In this work, doxorubicin hydrochloride (DOX), an anti-cancer drug, loaded on glutaric anhydride-functionalized magnetic nanoparticles (Fe 3 O 4 @SiO 2 -Glu) was investigated at varying pH values for effective drug delivery. Various factors affecting the adsorption of DOX onto the Fe 3 O 4 @SiO 2 -Glu were examined, where the adsorption efficiency of DOX reached 92% at a concentration of 20 mg/L employing 10 mg of Fe 3 O 4 @SiO 2 -Glu at 303 K in pH 7.4. However, the adsorption efficiency of DOX was decreased to 18% at acidic pH value down to 3.0, implicating that the drug releasing process was controlled by pH. Adsorption kinetics was fitting to pseudo-second-order and the isothermal adsorption conformed to Freundlich isotherm. The morphology and surface composition of the synthesized Fe 3 O 4 @SiO 2 -Glu were characterized by SEM, TEM , and N 2 adsorption/desorption isotherms, revealing that the specific surface area being 62.6 m 2 /g and the size ranging from ~30 to 50 nm. The zeta potential results indicated that Fe 3 O 4 @SiO 2 -Glu were negatively charged in various pH from 3 to 8.5. Characterizations by FTIR and UV–Vis techniques suggested that the DOX was absorbed and it can be delivered by Fe 3 O 4 @SiO 2 -Glu.
研究领域:
生物医学工程
·
药剂学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
JOURNAL OF MATERIALS SCIENCE
·
2022
·Vol. 57
·期 7
·4528-4540
·
IF 4.682
Chen Mingyan,Zhang Yao,Chen Jie,Liu Yucheng,Li Lingli,Du Guoyong
The porous material MOF-199 with a large specific surface area is widely used in the field of adsorption, but the single MOF material is not stable enough and the adsorption performance needs to be improved, so MOFs materials are often modified by combining with other materials. The composite material Fe 3 O 4 -ATP/MOF-199 (FAM) was prepared by solvothermal method combined with MOF-199, attapulgite (ATP) and Fe 3 O 4 . It was used in the static adsorption experiment of model oil to study the desulfurization performance, including the influence of external conditions such as adsorption time, temperature and the mass ratio of model oil to adsorbent on adsorption capacity. The structure and morphology of the adsorbent were characterized by XRD, FT-IR, SEM, VSM and BET. The experimental results show that the doping of attapulgite reduces the particle size of magnetic MOF-199 and makes the adsorbate closer to the active center of the adsorbent so as to improve the adsorption efficiency.
研究领域:
材料科学
·
环境科学
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）