NANOTECHNOLOGY
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2024
·Vol. 36
·期 9
·095203
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IF 2.9
Xiaozong Huang,Wen Li,Linghang Kong,Xiaoyan Lu,Chengzhi Yang,Bingsuo Zou
Due to the easy transformation to the non-luminous yellow δ-CsPbI3 phase in air, α-CsPbI3 nanocrystalline materials with red light emission find limited applications. Lifting its structural stability is a challenge in its quantum dot (QD) lighting field. Here we studied the doping of Mn2+ ions (5.0%) and processing by a small amount (0.315 ml) of TOP molecules on the OA-capped CsPbI3 nanocrystals. It is found that after the successful introduction of Mn2+ into the CsPbI3 nanocrystal, the grain size reduces, which leads to a stronger quantum confinement effect than the undoped QDs, which leads to the blue shift of PL and absorption spectra. The incorporation of Mn2+ simultaneously reduced defects and lifted the luminescence efficiency and lifetimes of QDs, the cause for the above optical behavior is due to the formation of excitonic magnetic polaron (EMP) excitons near the bandedge. On the other hand, the treated TOP molecule on the OA-capped NCs did not significantly affect their room-temperature luminescence. However, it improved the low-temperature emission performances of QDs significantly. Moreover, the TOP-treated QDs fixed in the PMMA film can transform into rod-like shapes in acidic environments, giving strong stability for emission, especially for the Mn-doped CsPbI3 QDs. This work has been done to improve the stability and emission efficiency of related QDs through the EMP formation near band-edge and surface modification of CsPbI3 NCs, favoring their potential applications in display and low-temperature light-emitting devices.
研究领域:
材料科学
·
光学
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PubMed
高影响因子
JOURNAL OF BIOMATERIALS SCIENCE-POLYMER EDITION
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2024
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IF 3.6
Siqi Li,Di Wang,Meng Zhang,Ying Yang,Xiangyu Zhang,Jinlian Li,Dongmei Wu
Biocompatible fatty acids are natural biological materials which exhibit widespread biomedical applications. Nevertheless, their application in vesicle forms is hampered by strong pH sensitivity and poor stability to changes in ionic strength, temperature, and storage. In the investigation, the incorporation of alkyl glycoside (APG), a surfactant with non-ionic properties, into the oleic acid (OA) vesicles was undertaken as a means to address this issue. The newly formed OA/APG composite vesicles form in a pH range of between 5.4 and 7.4, which is close to the pH range of the physiological environment. The stability studies results showed that the OA/APG composite vesicles have excellent stability in terms of ionic strengths, temperature and storage. The formation of NAR-loaded OA/APG composite vesicles was demonstrated through FT-IR, DSC and XRD. In vitro topical delivery and skin retention studies confirmed that the composite vesicles improve skin permeation rate and have better skin permeation behavior. Antioxidant activity experiments confirmed that the antioxidant effect composite vesicles were significantly increased as compared to the naringenin (NAR). This finding has theoretical implications for the use of drug-loaded fatty acid vesicles in cosmetics industries and topical delivery systems.
研究领域:
化妆品科学
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药剂学
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生物材料科学
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PubMed
高影响因子
ENERGY & FUELS
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2025
·
IF 5.3
Haoyu Liu,Wei Liu,Yanlin Wang,Hong Yuan
The incorporation of mesopores into zeolite catalysts improves both reactant diffusion and the catalyst lifespan. In this study, a bolaform surfactant, C6H13–N+(CH3)2–C6H12–N+(CH3)2–C6H12–O–C6H4–O–C6H12–N+(CH3)2–C6H12–N+(CH3)2–C6H13 (BAM–6–6–6), was used to guide the synthesis of hierarchical MFI zeolite nanosheets (HMNs). The HMN pore structure and acidic sites were altered by varying the ratio of the K2SO4-derived K+ and Al sources in the initial gel. The X-ray diffraction, Fourier transform infrared spectroscopy, scanning electronic microscopy, and N2 adsorption/desorption were used to characterize these materials. The HMNs each had an interconnected hierarchical pore structure which consisted of MFI and mesoporous structures and mesopore-specific surface areas as high as 353.8 m2 g–1, indicating that the BAM–6–6–6 formed lamellar micelles based on π–π stacking. Temperature-programmed NH3 desorption and 27Al magic angle spinning nuclear magnetic resonance spectroscopy revealed that the intersection cavity of the HMN structure was enriched with acidic sites. Because of the layered HMN structure, which promoted diffusion and increased resistance to carbon deposition and buildup, the catalysts possessed good catalytic activity in cracking oleic acid. For the HMN zeolite, the light-olefin yield reached 50.02% at 500 °C, outweighing that of conventional ZSM-5 (39.80%), and the initial catalytic activity was retained for up to 50 h. Furthermore, for HMN, the hard coke loss (3.8%) was less than that for CZSM-5 (9.7%).
研究领域:
化学工程
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材料科学
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高影响因子
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY
·
2024
·Vol. 99
·期 12
·2693-2702
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IF 2.8
Yandong Lu,Jiaxu Ning,Yue Zong,Fu Ding,Gaige Liu,Ruijun Zhang
BACKGROUND Tailored design of high-performance nanofiltration membranes is desirable. The physicochemical properties of the organic phaseare essential for the preparation of nanofiltration membranes. Therefore, byfine-tuning the organic phase, it is possible to achieve nanofiltrationmembranes with enhanced performance. RESULTS In this work, oleic acid, a naturally extracted fatty acid, wasintroduced into three different organic solvents (n-heptane, n-octane andisopar G) to construct special oil phases for interfacial polymerization. Testingresults showed that proper dosage of oleic acid addition can effectivelydecrease the nanofiltration membrane pore size and enhance the salt rejectionregardless of the solvent type. Taking n-octane as example, 5% oleic acidaddition in it can decrease the mean pore size from 0.500 nm to 0.341 nm and improve the MgSO 4 rejection from 52.4% to 95.5%. Further characterizationindicated that the introduction of oleic acid into organic solvent cansignificantly reduce the interfacial tension and promote the diffusion of piperazinefrom aqueous phase to the oil phase. In addition, oleic acid could react with piperazineand produce some white particles that could be embed into the polyamide layer, thus altering the surface morphology. CONCLUSION In this work, a novel modified thin film composite nanofiltration membrane was prepared by a simple and controllable oleic acid assisted interfacial polymerization strategy, which exhibits good water permeability, solute selectivity and antifouling property. Without changing the existing process, our strategy opens up a simple, environmentally friendly and operable route for the synthesis of thin film composite nanofiltration membranes. © 2024 Society of Chemical Industry (SCI).
研究领域:
材料科学
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环境工程
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高影响因子
Sustainable Energy & Fuels
·
2024
·Vol. 9
·期 1
·152-171
·
IF 5
Haoyu Liu,Wenbo Luo,Ke Wang,Yanlin Wang,Hong Yuan
The bolaform surfactant C6H13-N+(CH3)2-C6H12-N+(CH3)2-C6H12-O-C6H4-C6H4-O-C6H12-N+(CH3)2-C6H12-N+(CH3)2-C6H13 (BCPH-6-6-6) was synthesized and used to guide the synthesis of hierarchical ZSM-5 nanosheets (HZN) for use as zeolite catalysts. The number of acidic sites and the Al distribution in the zeolite pores were varied by changing the amounts of sodium sulfate and Al in the initial gel. The X-ray diffraction, Fourier transform infrared spectroscopy, scanning electronic microscopy, NH3 temperature programmed desorption, 27Al magic angle spinning nuclear magnetic resonance spectroscopy and N2 adsorption/desorption were used to characterize these materials. These zeolites each had a well-developed hierarchical system and specific surface areas as high as 631 m2 g−1, indicating that the BCPH-6-6-6 formed lamellar micelles based on π–π stacking. Interconnected hierarchical pore structures were retained after the templating agent was removed. The HZN sample exhibited a 90° rotational intergrowth structure and retained a large number of lamellae. The same material had a high concentration of acidic sites and contained Al in a tetrahedral coordination framework. The catalytic cracking of oleic acid using this zeolite gave light olefin yields up to 52.2% at 500 °C, exceeding the performance of conventional ZSM-5 (38.9%), and the catalyst remained active for up to 60 h. At 450 °C, the BTX selectivity of 6.72% obtained with this material also exceeded that from the conventional ZSM-5. These results were attributed to the connected hierarchical pores of the HZN, which promoted diffusion and provided higher carbon resistance.
研究领域:
材料科学
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催化化学
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高影响因子
TRIBOLOGY INTERNATIONAL
·
2024
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IF 6.1
Qingyao Li,Qiang Gao,Wenhao Chen,Wenpeng Wang,Zixiang Wu,Zhuopei Zhang,Youqiang Wang,Yange Feng,Daoai Wang,Feng Zhou
Currently, the conductive grease has problems such as unstable conductivity and large wear volume. This article used an in-situ synthesis method to synthesize a base conductive grease with PAO 10 as base oil, oleic acid and melamine as thickener. The complex conductive grease was further prepared by doping MWCNTs-OH into the base conductive grease. The experiment found that the complex conductive grease's anti-wear and anti-friction properties improved by 72.23% and 27.16%, respectively, with respect to the current-carrying condition. The contact resistance is 27.12% lower than commercially available conductive grease. This method of reducing the contact resistance (ECR) and friction coefficient (COF) of conductive grease through hydrogen bonding shows excellent application prospects in the current-carrying friction direction.
研究领域:
材料科学
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摩擦学
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化学工程
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高影响因子
MICROPOROUS AND MESOPOROUS MATERIALS
·
2026
·
IF 4.5
Yan Jin,Hui Zhang,Tengfei Li,Shaojie Lei,Meier Jiaerheng,Dezhang Ren,Zhibao Huo
Biodiesel has emerged as a promising alternative to conventional diesel due to its renewability and environmental friendliness. In this study, a MIL-101(Cr) featuring synergistic acid sites was developed through a combined defect engineering and post-sulfonation strategy, enabling efficient esterification of oleic acid under mild conditions. Defects were introduced in the MIL-101(Cr) through a mixed-ligand approach. The existence of abundant oxygen vacancies in the defect-engineered MIL-101(Cr) was confirmed by electron paramagnetic resonance (EPR), which could provide adequate grafting sites for the subsequent sulfonation. The sulfonic acid-functionalized MIL-101(Cr) catalyst (MRBSX) was then synthesized by post-sulfonation with chlorosulfonic acid as the sulfonation agent. The chemical structure and sulfonic acid density of MRBSX were systematically investigated by X-ray diffraction (XRD), scanning electron microscope (SEM), brunauer-emmett-teller (BET), and Fourier-transform infrared spectra (FT-IR), and other characterization techniques. Acid-base titration combined with elemental analysis (EA) demonstrated the successful loading of sulfonic acid groups in MRBSX, highlighting the promotional role of oxygen vacancies in enhancing acid site density and catalytic efficiency. Under optimized reaction conditions (100 °C, 6 wt%, 3 h, and M/O = 8:1), the MRBSX with 10 mol% benzoic acid achieved a high oleic acid conversion of 96.7 % and a corresponding biodiesel yield of 91.5 %. Therefore, the proposed synergistic strategy of defect engineering and post-sulfonation is effective in constructing high-performance solid acid catalysts, demonstrating promising potential in green energy conversion applications.
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高影响因子
APPLIED SURFACE SCIENCE
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2026
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IF 6.6
Yixin Chen,Yisimayili Tuersun,Pingjun Luo,Tong Wu,Zexi Chen,Yubin Ke,Sheng Chu
Water-based lubrication systems are increasingly attractive due to their environmental friendliness, cost-effectiveness, and safety merits. While oleic acid-modified magnetite nanoparticles (Fe 3 O 4 -OA) have demonstrated promising properties as lubricant additives in oil-based systems, their performance in water-based lubrication systems remains largely unexplored, as the Fe 3 O 4 -OA nanoparticles exhibit limited dispersion stability and tribological performance in aqueous environments. In this study, Fe 3 O 4 -OA was combined with amine-functionalized silica (SiO 2 -NH 2 ) nanoparticles to enhance the anti-friction and anti-wear properties in water-based lubrication. Comparative tribological tests showed that adding 1 wt% Fe 3 O 4 -OA and 1 wt% SiO 2 -NH 2 reduced the coefficient of friction by 72.4% and the wear volume by 81.7% under a 100 N load compared with pure water. Small-angle neutron scattering (SANS) analysis reveals that increasing Fe 3 O 4 -OA concentration led to a more extended configuration of oleic acid molecular chains, facilitating interactions with surface amine groups on SiO 2 -NH 2 . These interactions promote the formation of a stable and compact tribofilm through combined Lewis acid–base coordination, hydrogen bonding, and electrostatic attraction. The improved frictional performance provides insights into the rational design of high-performance, water-based lubrication systems via nanoparticle additives.
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APPLIED CATALYSIS B-ENVIRONMENTAL
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2026
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IF 19.7
Chunya Wang,Zhentao Liu,Shanbin Gao,Jiyuan Fan,Zhaoqing wang,Chunyang Han,Zhidan Huang,Zhengkai Cao,Chunming Xu,Xilong Wang
A core-shell ZSM-22@meso-SiO 2 support alleviates diffusion constraints for fatty acid hydrogenation. • NiCo alloy formation induces electron transfer from Co to Ni, optimizing the electronic properties. • Enhanced H 2 dissociation and H⁎ spillover over NiCo alloy boost the hydrogenation activity. • The 9Ni6Co/Z@MS catalyst achieves a superior bio-jet fuel yield of 57.2% from oleic acid. Reducing carbon emissions from the aviation sector represented a pressing environmental challenge, and the hydrogenation of vegetable oils to produce high‑value bio-jet fuel offered one of the most promising and economically viable pathways. Herein, we reported a novel bimetallic alloy catalyst with a tunable Ni/Co ratio, specifically designed for the selective hydrogenation of oleic acid to bio-jet fuel. This system delivered 100% conversion of oleic acid and a higher bio-jet fuel yield of 57.2%, while maintaining high iso-alkanes selectivity, which demonstrated superior performance compared to previously reported dazzling heterogeneous catalysts. The introduction of Co promoted the formation of a NiCo alloy phase and facilitated electron transfer from Co to Ni species. The resulting electronic and geometric synergies collectively enhance the dissociation and activation of H 2 , as well as the hydrogenation activity of substrates. Moreover, the Ni/Co ratio directly modulated the catalyst acidity, and the optimized acid properties played a critical role in the subsequent cracking and isomerization of deoxygenated intermediates. Collectively, these findings established a foundation for the rational design of efficient catalysts for bio-jet fuel production derived from oils. Download: Download high-res image (280KB) Download: Download full-size image
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高影响因子
CATALYSIS LETTERS
·
2025
·Vol. 155
·期 12
·1-12
·
IF 2.4
Ge Pengyu,Liu Xiyu,Li Xincheng,Fan Mingming,Zhang Pingbo
In this study, highly crystalline ZSM-22 zeolite with a TON topology was synthesized via a seed–template co-assisted hydrothermal method and subsequently modified with low-concentration NH₄Cl to introduce Brønsted acid sites. The characterization of the catalyst revealed its well-defined rod-like crystals (2–5 μm), one-dimensional straight channels (0.46 × 0.57 nm), microporous surface area of 210 m 2 ·g −1 , Brønsted-to-Lewis (B/L) acid ratio of 0.45, and excellent thermal stability. Under optimized reaction conditions (270 °C, 3 h, 6 wt% catalyst), the catalyst achieved a 95.01% conversion of oleic acid and a 77.72% yield of isostearic acid. The confinement effect of the 1D channels effectively suppressed undesired side reactions, offering significantly enhanced selectivity compared to commercial zeolites such as ZSM-5. Thermogravimetric analysis demonstrated that calcination at 550 °C successfully removed coke deposits and restored catalyst activity. After five regeneration cycles, the conversion and yield remained at 89.50% and 72.80%, respectively, with less than 6% loss. These findings provide theoretical and technical guidance for the high-value catalytic transformation of biomass-derived fatty acids. Graphical H-ZSM-22 catalyst with good reusability
研究领域:
催化化学
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材料科学
·
绿色化学
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生物质转化
·
石油化工工程
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高影响因子
Journal of Animal Science and Biotechnology
·
2022
·Vol. 13
·期 1
·1-13
·
IF 6.175
Zhou Xiaoge,Mo Zhaoyi,Li Yankun,Huang Liang,Yu Sihai,Ge Lan,Hu Yamei,Shi Shengjie,Zhang Lutong,Wang Liguang,Gao Lei,Yang Gongshe,Chu Guiyan
Background Oleic acid is an abundant free fatty acid present in livestock that are in a negative energy-balance state, and it may have detrimental effects on female reproduction and fertility. Oleic acid induces lipid accumulation in bovine granulosa cells, which leads to a foam cell-like morphology and reduced steroidogenesis. However, why oleic acid increases lipid accumulation but decreases steroidogenesis remains unclear. This study focused on oleic acid’s effects on lipid type and steroidogenesis. Results Oleic acid increased the lipid accumulation in a concentration-dependent manner and mainly increased the triglyceride level and decreased the cholesterol ester level. Oleic acid also led to a decline in estradiol and progesterone production in porcine granulosa cells in vitro. In addition, oleic acid up-regulated the expression of CD36 and diacylglycerol acyltransferase 2, but down-regulated the expression of 3-hydroxy-3-methylglutaryl-coenzyme A reductase, scavenger receptor class B member 1 and acetyl-Coenzyme A acetyltransferase 2, as well as steroidogenesis-related genes, including cytochrome P450 family 11 subfamily A member 1, cytochrome P450 family 19 subfamily A member 1 and 3 as well as steroidogenic acute regulatory protein at the mRNA and protein levels. An oleic acid-rich diet also enhanced the triglyceride levels and reduced the cholesterol levels in ovarian tissues of female mice, which resulted in lower estradiol levels than in control-fed mice. Compared with the control, decreases in estrus days and the numbers of antral follicles and corpora lutea, as well as an increase in the numbers of the atretic follicles, were found in the oleic acid-fed female mice. Conclusions Oleic acid changed the lipid type stored in lipid droplets of ovarian granulosa cells, and led to a decrease in steroidogenesis. These results improve our understanding of fertility decline in livestock that are in a negative energy-balance state.
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高影响因子
JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY
·
2023
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IF 3.2
Bing Qian,Yonghua Hu,Minggao Xu,Jiuzhong Yang,Chengyuan Liu,Yang Pan
Cooking oil fumes are an intricate and dynamic mixture containing a variety of poisonous and hazardous substances, and their real-time study remains challenging. Based on tunable synchrotron radiation photoionization mass spectrometry (SR-PIMS), isomeric/isobaric compounds in the gaseous oil fumes from oleic acid thermal oxidation were determined in real time and distinguished by photoionization efficiency (PIE) curve simulation combined with multiple linear regression (MLR) analysis. A series of common carcinogens such as formaldehyde, acetaldehyde, acrolein, and several unreported chemicals including diethyl ether and formylcyclohexane were successfully characterized. Moreover, time-resolved profiles of certain components in gaseous oil fumes were monitored for 55 h. Distinct evolutionary processes were observed, indicating the consumption and formation of parent molecules, intermediates, and final products.
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高影响因子
危险品化学品经营许可证（带存储）