JOURNAL OF THE ENERGY INSTITUTE
·
2018
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IF 4.217
Shuai-wei Liu,Rui-tang Guo,Xiao Sun,Jian Liu,Wei-guo Pan,Zhi-ling Xin,Xu Shi,Zhong-yi Wang,Xing-yu Liu,Hao Qin
In present study, the poisoning mechanism of Cl on V/TiO 2 catalyst for SCR removal of NOx using NH 3 as the reductant was explored by in situ DRIFT technique. The experimental results revealed that the existence of Cl did not change the SCR reaction mechanism over V/TiO 2 catalyst, which was mainly under the control of both E-R and L-H mechanisms. The deactivation of V/TiO 2 catalyst by Cl was mainly resulted from the inhibited adsorption of NH 3 and NOx species, accompanied by the decrease of the reactivity of adsorbed NH 3 species.
研究领域:
环境科学
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催化化学
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产品关联
DOI
高影响因子
JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION
·
2021
·Vol. 36
·期 3
·338-346
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IF 0.957
Shan Hailin,Du Yue,Du Xiaodi,Lei Jiaheng
In order to reduce the emission of SO x in the environment, sulfur compounds must be removed efficiently from fuels. Three-dimensional highly ordered meso-macroporous HPW/TiO 2 (3DO m/M HPW/TiO 2 ) materials were synthesized successfully by sol-gel method and applied as oxidative desulfurization catalyst for the model fuel. The characterization results displayed the existence of highly ordered meso-macroporous structures and the Keggin type of HPW was highly dispersed in TiO 2 framework. The effect of catalyst on desulfurization under different reaction conditions was studied systematically. The results showed that the catalyst exhibited excellent desulfurization performance in the hydrogen peroxide oxidation system, which could be explained by the unique meso-macroporous structure of catalyst. In addition, the catalyst showed good cycling performance and the removal rate of DBT still reached 96.1% even after 6 cycles, providing a feasible method for the development and application of fuel deep desulfurization catalysts.
研究领域:
催化材料
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环境科学
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能源化工
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF NANOPARTICLE RESEARCH
·
2022
·Vol. 24
·期 3
·1-22
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IF 2.533
Yang Chunyan,Xue Ziwei,Yin Hao,Lu Ke,Liu Wei
In this work, the photodegradation of methylene blue was investigated by constructing a novel photocatalysis reactor, which was filled with aqueous foam. Nanoscale TiO 2 particles were used as photocatalyst. In order to obtain stable foam phase, cetyl trimethyl ammonium bromide (CTAB) was used as the frother, and its suitable initial concentration in the feeding solution was 0.20 g/L. Under the suitable conditions of loading liquid volume 200 mL, initial concentration of TiO 2 nano-catalysts in the feeding solution 5.0 g/L, inner diameter of foam column 18 mm, aperture diameter of gas distributor 125 μm, and circulating velocity of bulk solution 500 mL/h, the maximum degradation percentage of methylene blue was 97.6 ± 1.2%. Atomic force microscopy (AFM) analysis suggested that the entrainment effect of rising bubbles and the circulation flow of bulk solution inside the aqueous foam did not cause the conspicuous aggregation of TiO 2 nano-catalysts under the suitable conditions, but their surface roughness decreased. Meanwhile, foam entrainment had not a significant impact on the polydispersity of TiO 2 nano-catalysts. In contrast to the photodegradation of methylene blue in aqueous solution, the photocatalysis process using aqueous foam is the intensity of light received by TiO 2 nano-catalyst increases, and irradiation period is less. This work is expected to provide new insight into the rational design of photocatalysis reactor, to facilitate the harmless treatment of dyestuff wastewater. Graphical abstract
研究领域:
环境科学
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材料科学
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产品关联
DOI
高影响因子
Catalysis Science & Technology
·
2022
·Vol. 12
·期 4
·1245-1256
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IF 6.177
Jie Yang,Shan Ren,Mingming Wang,Zhichao Chen,Lin Chen,Lian Liu
Ce–Ti catalysts were considered as a promising replacement for V–Ti based catalysts for selective catalytic reduction (SCR) of nitrogen oxides (NO and NO2) with NH3. In this work, a CeO2/TiO2 catalyst was prepared by the impregnation method and studied by a series of in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) experiments. The results showed that CeO2 particles grew along TiO2 faces and amorphous cerium in the lattice of TiO2, both of which are present on the CeO2/TiO2 catalyst. NH4+ might adsorb on the Ti–O–Ce structures or TiO2–CeO2 interface as Brønsted acid sites, while two types of NH4+ species were distinguished by the time-resolved spectroscopic method due to the different increasing trends. Based on the temporal evolution transient in situ DRIFTS spectra, L-NH3 had higher activity than coordinated NH3 species, which suggested that gas phase NO reacted preferentially with L-NH3. The NH4NO3 intermediate dominated the SCR reactions over the CeO2/TiO2 catalyst, which followed the Eley–Rideal mechanism.
研究领域:
催化化学
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环境科学
✓ 已验证
产品关联
DOI
高影响因子
CHEMICAL ENGINEERING JOURNAL
·
2023
·
IF 15.1
Xiang Li,Xueqian Wang,Li Yuan,Langlang Wang,Yixing Ma,You Wu,Yibing Xie,Rui Cao,Yiran Xiong,Ping Ning
The lengthy processes and cumbersome operations for the separate removal of COS and H 2 S have severely limited the development of blast furnace gas recycling process. CuO exhibits excellent H 2 S oxidation performance, but weak COS hydrolysis performance; in contrast, ZrO 2 shows the opposite trend. However, the functional combination of CuO and ZrO 2 has never been used for simultaneous removal of COS and H 2 S. In this study, a Cu/Zr co-doped K@TiO 2 bifunctional catalyst was tailored to simultaneously remove COS and H 2 S. The combined COS and H 2 S capacity of this catalyst reaches 340.5 mg/g at a low temperature of 60 °C, which is much higher than those of other reported bifunctional catalysts. The microcrystal structure formed by Cu/Zr co-doping increases the specific surface area of the catalyst and promotes the adsorption of COS/H 2 S. Specifically, Zr doping increases the content of moderate basic sites and significantly improves the hydrolysis efficiency of COS. Moreover, Cu doping induces lattice distortion of TiO 2 , while CuO captures 4 s valence electrons of K to form Cu 2 O. These two processes lead to the release of lattice oxygen from TiO 2 and CuO, generating oxygen vacancies and ·O 2 − , which promotes H 2 S oxidation. By proposing a simple route for the bifunctionalization of a desulfurization catalyst, this study drives innovation in both the theory and application of simultaneous removal of COS and H 2 S.
研究领域:
环境科学
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催化化学
✓ 已验证
产品关联
DOI
高影响因子
Journal of the Taiwan Institute of Chemical Engineers
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2022
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IF 5.477
Kaiwen Ni,Yuewang Peng,Geyu Dai,Huawang Zhao,Zhiwei Huang,Xiaomin Wu,Guohua Jing,Wei Feng,Ye Yuan
Background Ammonia bisulfate (ABS) deposition on the active sites of the catalyst surface is the main reason for SO 2 poisoning in low-temperature NH3-selective catalytic reduction (SCR). Accelerated ABS decomposition efficiently enhances the SO 2 resistance. Methods In this work, ceria was specifically chosen to decorate V 2 O 5 -WO 3 /TiO 2 catalyst (Ce-VW/Ti) to activate ABS decomposition in low-temperature NH 3 -SCR. Significant findings The optimal 7Ce-VW/Ti catalyst accelerated the decomposition of ABS and had superior SO 2 tolerance at 250°C. The additive CeO 2 improved the specific surface area and surface acidity, favoring the NH 3 -SCR catalytic activity. ABS was preferentially deposited on the additive CeO 2 on the surface of the 7Ce-VW/Ti catalyst and generated cerium sulfate, eventually protecting the active V 2 O 5 sites and TiO 2 support. Moreover, high quantity of V 5+ and charge transfer between active species V 2 O 5 and support TiO 2 could be maintained due to CeO 2 protection, subsequently maintaining the high NH 3 -SCR performance and enhancing the SO 2 tolerance.
研究领域:
催化
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环境科学
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化学工程
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产品关联
DOI
高影响因子
FUEL
·
2023
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IF 7.4
Peng Li,Senlin Zhang,Zhourong Xiao,Hui Zhang,Fei Ye,Jianmin Gu,Jidong Wang,Guozhu Li,Desong Wang
Catalytic reduction of CO 2 to high value-added chemicals such as methane is crucial in the development of renewable energy and waste disposal. Photo-thermal CO 2 methanation has been received great attention, because the synergistic effect of photo and thermal lead to efficient CO 2 reduction at low temperature. Herein, we reported the synthesis of Ni nanoparticles (NPs) supported on TiO 2 (Ni-TiO 2 ) derived from MIL-125 (Ti-MOFs) for photo-thermal CO 2 methanation. The nanoparticle sizes and electron densities of metallic Ni, defects and chemical properties, photo-thermal and photo-electric characteristics of the catalysts have been systematically characterized by XRD, TEM, CO 2 /H 2 -TPD, XPS, photoluminescence and photocurrent. For the Ni-TiO 2 , the conversion of CO 2 was 56 % under the full spectrum irradiation (1200 mW/cm 2 ) at 325 °C, which was about 1.8 times of that without light irradiation. The selectivity of methane nearly 99 % with a production rate was 95.7 mmol/(g cat ∙h), which was about 2.7 times of that without light irradiation. Meanwhile, the catalysts showed excellent stability without any activity decay during the four cycles testing (32 h). The main reasons for the high catalytic performance for photo-thermal CO 2 methanation were attributed to the uniform distribution of Ni NPs with synergistic effect of large specific surface area of TiO 2 with abundant moderate strength alkaline sites. In addition, good photo-thermal and photo-electric conversion ability make the catalysts possess more photo-generated charge carriers and reduce its recombination.
研究领域:
化学工程
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材料科学
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环境科学
✓ 已验证
产品关联
DOI
高影响因子
Frontiers of Chemical Science and Engineering
·
2024
·Vol. 18
·期 11
·1-11
·
IF 4.3
Gao Huimin,Zhang Jinpeng,Zhang Fangyuan,Jing Jieying,Li Wen-Ying
The photocatalytic reduction of CO 2 into formic acid is a feasible approach to alleviate the effects of global climate change and achieve chemical energy storage. It is important to design highly active photocatalysts to improve the selectivity and yield of formic acid. In this study, TiO 2 -based catalysts were prepared and loaded with Pd nanoparticles via an impregnation process. The Pd/H-TiO 2 catalyst demonstrated superior CO 2 reduction activity and a high formic acid production rate of 14.14 mmol cat ·g −1 ·h −1 . The excellent catalytic performance observed in the presence of a Pd/H-TiO 2 catalyst is ascribed to the synergy between O v and Pd. The presence of O v led to increase in CO 2 adsorption while Pd loading enhanced the photogenerated electron-hole pair separation. Electron transfer from H-TiO 2 to Pd also contributed to CO 2 activation.
研究领域:
环境科学
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材料科学
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DOI
高影响因子
CHEMICAL ENGINEERING JOURNAL
·
2017
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IF 6.216
Chong Xie,Shenghui Yang,Jianwen Shi,Beibei Li,Chen Gao,Chunming Niu
The stability of MnO x based low temperature SCR catalysts remained to be a serious issue. This report explored use of multi-walled carbon nanotubes (MWCNTs) network with uniform structure as a “rigid” pore template for synthesis of mesoporous MnO x -TiO 2 SCR catalyst with high surface area and high stability. The results showed that MWCNT network imposed MnO x -TiO 2 catalyst a mesoporous porosity with a narrow pore size distribution centered on ∼13.2 nm and a surface area of 131.6 m 2 g −1 stabilized at 500 °C. The mesoporous structure was formed by interconnected nanoparticles, comprised of crystallized rutile TiO 2 core surrounded by amorphous MnOx , with an average diameter of ∼8 nm. The catalyst exhibited an excellent low temperature SCR activity and selectivity as well as high resistance to deactivation and poison by H 2 O and SO 2 . SnO 2 modification led to degradation of catalytic performance in low temperature (60–180 °C) side, but improvement at high temperature side (240–360 °C), especially at high gas velocity, which can be attributed to change in structure, reactivity of MnO x and surface acidity induced by SnO 2 addition.
研究领域:
材料科学
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环境科学
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催化化学
✓ 已验证
DOI
高影响因子
ACS Catalysis
·
2025
·
IF 13.1
Tingting Xiao,Jingrong Li,Jian Li,Qihang Gong,Peikai Luo,Xinluona Su,Haiyang Cheng,Chao Zhang,Fengyu Zhao
The hydrogenolysis of cellulose-derived 5-hydroxymethylfurfural is essential for the production of fuels and chemicals from biomass. Herein, we fabricated a phosphorus-doped Pd/P-TiO2 catalyst for the hydrodeoxygenation of 5-hydroxymethylfurfural to 2,5-dimethylfuran. A large number of defects and electron-deficient Ti4+ sites (dTi4+) were formed by doping phosphorus into the TiO2 support, which could promote hydrogen spillover and reactant adsorption. Moreover, the spilled active hydrogen induced the formation of P–O(H)-dTi4+, which acted as a “Brønsted acidic site” to promote the activation of C–O bonds. Consequently, the Pd/P-TiO2 catalyst exhibited superb activity for the hydrodeoxygenation of 5-hydroxymethylfurfural to 2,5-dimethylfuran at mild conditions of 150 °C under 1 MPa H2.
研究领域:
催化化学
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生物质转化
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材料科学
✓ 已验证
产品关联
DOI
高影响因子
ACS Catalysis
·
2025
·
IF 13.1
Zilin Wang,Dongbo Shu,Haijie Chen,Chuanmin Ding,Junwen Wang,Yan Lv,Qingqing Gu,Aiqin Wang,Bing Yang
The regulation of selectivity in CO2 hydrogenation is of great importance and has been intensively studied for the utilization of CO2. The particle size and metal–support interaction are proven to be key factors influencing the selectivity of CO2 hydrogenation. However, the dynamic structure evolution during real reaction conditions and their impact on the selectivity are still poorly understood. Here in this work, we reported the crystal-phase-mediated dynamic restructuring of the Rh/TiO2 catalyst during reaction that strongly modulates the mutual interaction of dynamic size stability and strong metal–support interaction (SMSI) encapsulation of the Rh catalyst and thus the selectivity of CO2 hydrogenation toward CO/CH4. By utilizing state-of-the-art characterizations, the interplay between dynamic size distribution and SMSI of the Rh catalyst on TiO2 was clearly elucidated. The selectivity of CO2 hydrogenation was prone to the particle size in the low reaction temperature range (225–275 °C) while highly depending on SMSI at high reaction temperatures (350–400 °C). Remarkably, anatase TiO2 promotes small Rh particles and strong SMSI at the low-temperature range, rutile TiO2 facilitates large particles but high-temperature SMSI encapsulation, while the P25 phase favors large Rh particles without encapsulation. The in situ DRIFTS experiments further reveal that all Rh/TiO2 catalysts follow the hydrogenation path via *HCOO as an intermediate, where the large Rh particle size facilitates deep hydrogenation of *HCOO to CH4, whereas the TiOx encapsulation favors the *HCOO decomposition to CO due to the suppressed H2 activation. Our results provide dynamic insight for the restructuring of the active sites in the Rh/TiO2 catalyst that tunes the selectivity of CO2 hydrogenation and opens up a route for the rational design of supported metal catalysts based on their dynamic structures.
研究领域:
催化化学
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材料科学
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环境科学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY
·
2023
·Vol. 98
·期 9
·2136-2145
·
IF 3.4
Long Wang,Liu-Lin Zhao,Qin-Yuan He,Dan-Dan Shao,Shi-Peng Sun,Xue-Li Cao
BACKGROUND Desalination membranes have been widely in demand for separating dyes and salts. However, dyes are easily adsorbed on/in the membranes, deteriorating membrane performance. Coupling photocatalysis and membrane separation might be a promising strategy for efficiently alleviating membrane fouling. Aiming at the defects of single catalyst, this work constructed photocatalytic membranes based on heterostructured Fe 3 O 4 -doped g-C 3 N 4 (FeCN)/TiO 2 catalysts by successively filtrating FeCN aqueous dispersion and titanium butoxide/isopropanol solution on the hydrolyzed polyacrylonitrile substrate. RESULTS The H-bonds among TiO 2 , FeCN and substrate lead to excellent load stability of the photoresponsive layer. Due to the low-potential conduction band and high conductivity of Fe 3 O 4 and the low-potential conduction band of TiO 2 in FeCN/TiO 2 , electrons can be more easily transferred to guarantee the high separation efficiency of electrons and holes. Hence the membrane not only exhibited superior permeability (104 L m −2 h −1 bar −1 ) and dye desalting performance (Coomassie brilliant blue R250 rejection of >98.80% and NaCl rejection of <7.00%), but also displayed highly efficient and stable dye photodegradation. CONCLUSION The degradation efficiency surpassed that reported in the literature in comparable circumstances, and the recovery rate of permeability still reached 89.12% after three fouling–photodegradation cycles. This work provides new opportunities for designing high-efficiency self-cleaning membranes to solve membrane fouling based on low-cost materials. © 2023 Society of Chemical Industry (SCI).
研究领域:
材料科学
·
环境工程
✓ 已验证
DOI
高影响因子
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