TALANTA
·
2025
·
IF 6.1
Xueyun Wei,Baorong Zhang,Zhuomin Zhang,Gongke Li
Haloacetic acid (HAA) disinfection by-products (DBPs) with high polarity, low concentration and significant health hazard are widely present during disinfection processes, particularly iodinated and brominated acetic acids. Due to the lack of selective enrichment media, current sample preparation methods are insufficient for efficient enrichment of low concentrations of HAA DBPs in complex samples, which usually influences the analytical sensitivity and accuracy. In this study, a modulator-induced defect formation strategy was employed to prepare defective UiO-66-NH 2 (D-UiO) as a selective enrichment medium which was further fabricated as membrane solid-phase extraction (M-SPE) to efficiently enrich HAA DBPs. The structure and enrichment performance of the D-UiO medium was studied in detail. D-UiO exhibited good extraction selectivity for the five target DBPs in the presence of structural analogs as interfering compounds. Then, a sensitive quantification method by D-UiO based M-SPE was developed for trace brominated and iodinated acetic acid DBPs in tea drinks coupled with ultra-performance liquid chromatography-tandem mass spectrometry. The limits of detection of the method were in the range of 5.0-15.0 ng/L, and the recoveries were in the range of 78.3%-124%. By combining a ten-pass syringe pump with M-SPE technology, this method enabled batch sample processing and significantly reduced pre-treatment time. The method developed was efficient, selective, sensitive, and accurate for the analysis of hazardous HAA DBPs in complex tea drinks.
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PubMed
高影响因子
JOURNAL OF CHROMATOGRAPHY A
·
2016
·
IF 3.926
Saichai Lin,Ning Gan,Yuting Cao,Yinji Chen,Qianli Jiang
In this paper, a novel dispersive solid phase extraction (dSPE) adsorbent based on aptamer-functionalized magnetic metal-organic framework material was developed for selective enrichment of the trace polychlorinated biphenyls (PCBs) from soil sample. Firstly, we developed a simple, versatile synthetic strategy to prepare highly reproducible magnetic amino-functionalized UiO-66 (Fe 3 O 4 @PDA@UiO-66-NH 2 ) by using polydopamine (PDA) as covalent linker. Then amino-functionalized aptamers which can recognize 2,3′,5,5′-tetrachlorobiphenyl (PCB72), 2′,3′,4′,5,5′-pentachlorobiphenyl (PCB106) were covalent immobilized on UiO-66-NH 2 through coupling reagent of glutaraldehyde. Aptamer-functionalized adsorbent (Fe 3 O 4 @PDA@UiO-66-Apt) can specifically capture PCBs from complex matrix with high adsorption capacity based on the specific affinity of aptamer towards target. Moreover, the adsorbent can be easily isolated from the solution through magnetic separation after extraction. Afterwards, the detection was carried out with gas chromatography tandem mass spectrometry (GC–MS). The selective dSPE pretreatment coupled with GC–MS possessed high selectivity, good binding capacity, stability, repeatability and reproducibility for the extraction of PCBs. Furthermore, the adsorbent possessed good mechanical stability which can be applied in replicate at least for 60 extraction cycles with recovery over 80%. It provided a linear range of 0.02–400 ng mL −1 with a good correlation coefficient (R 2 = 0.9994–0.9996), and the limit of detection was found to be 0.010–0.015 ng mL −1 . The method was successfully utilized for the determination of PCBs in soil samples.
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高影响因子
JOURNAL OF SEPARATION SCIENCE
·
2018
·Vol. 41
·期 22
·4149-4158
·
IF 2.415
Huixiao Duo,Yuhuan Wang,Licheng Wang,Xiaofeng Lu,Xiaojing Liang
A zirconium(IV)-based metal organic framework, composed of 4,4′-biphenyldicarboxylic acid ligands and Zr 6 O 4 (OH) 4 clusters, was successfully fabricated. Characterizations were performed on fourier transform infrared spectroscopy, scanning electron microscopy, X-ray diffraction, Brunauer-Emmett-Teller, and thermogravimetric analysis, which confirmed that it possessed large specific surface area, high pore volume, and strong acid resistant stability. Furthermore, the prepared material containing biphenyl skeleton and a large number of Zr-O bonds, can grasp acid herbicides especially phenoxyacetic acid herbicide s with aromatic structures through π-π interaction, hydrophobic interaction and Zr-O-H + bonds. Based on these advantages, a method was developed for the determination of four phenoxyacetic acid herbicide s from vegetable samples. Under the optimal conditions, wide linearities from 0.3 to 250 μg/L and low limits of detection from 0.1 to 0.5 μg/L were obtained. The intra- and interday relative standard deviations were 1.56-3.92 and 5.01-7.65%, respectively. The proposed method was applied to analyze phenoxyacetic acid herbicide s residues in the tomato, cucumber, and white gourd samples. The satisfactory recoveries (86.12–103.44%) for the spiked samples in vegetable samples were achieved which demonstrated the method was an efficient pretreatment procedure and has a potential application for the trace determination of phenoxyacetic acids from a complex matrix.
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高影响因子
Foods
·
2025
·Vol. 14
·期 18
·3264
·
IF 5.1
Yimeng Pang,Zehao Yang,Xiaohua Liu,Xing Shen,Hongtao Lei,Xiangmei Li
Gentamicin (GEN) is a broad-spectrum antibiotic widely used in livestock production, and its excessive residues in animal-derived foods pose potential health risks to consumers. However, conventional colloidal gold immunochromatographic assays (AuNPs-ICA) often suffer from low sensitivity and poor tolerance to sample matrices. Herein, a UiO-66-NH2framework decorated with gold nanoparticle (UiO-66-NH2@Au)-based ICA was employed to construct an ICA platform for GEN detection, combining the optical advantages of AuNPs with the protective and stable octahedral framework of the Metal-organic framework (MOF) to enhance antibody stability under extreme conditions. The method achieved limits of detection for GEN of 0.1 µg/kg in four tested matrices, with recoveries of 80.1–112.0% and coefficients of variation below 11.7%. Compared to traditional AuNPs-ICA, the sensitivity was improved by up to 30-fold, the pH tolerance range was expanded from 6–8 to 4–10, and the organic solvent tolerance to organic solvents expanded up to 40%. Verification with 40 real samples demonstrated excellent correlation (R2> 0.99) with results from commercial ELISA kits. This UiO-66-NH2@Au-ICA platform offers a new technical solution with high sensitivity, strong good anti-interference performance, and robustness for rapid field detection of GEN residues in products of animal origin and holds significant practical importance for advancing rapid food safety detection technologies.
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高影响因子
CHEMOSPHERE
·
2022
·
IF 8.943
Yuhan Wang,Chang Liu,Chao Wang,Qing Hu,Longzhen Ding
Developing synergistic systems and taking environmental risks into account are two necessary aspects of being considered to remove persistent organic pollutants efficiently. Thus, a combined catalytic system uniting the Fenton-like process and simulated solar-light photocatalysis has been constructed. Moreover, a series of NiCo 2 O 4 /HP-UiO-66 catalysts (yNiCo-DUx) were also fabricated to improve tetracycline (TC) removal efficiency. The NiCo 2 O 4 nanoparticles (NPs) and hierarchically porous metal-organic frameworks (HP-MOFs) were synthesised using one-step calcination. The Z-scheme structure of the catalysts was confirmed by ESR, XPS, DRS, time-resolved PL (TR-PL) spectra and the quenching experiments. The NiCo 2 O 4 nanoparticles could be embedded and fixed into the defects of the MOF structure, and the leaching of toxic metals was also significantly suppressed. In the optimal reaction condition with 15NiCo-DU50, sunlight, and peroxymonosulfate (PMS), the total removal efficiency of TC could reach 98.5% within 8 min of irradiation, and the highest % RSE could reach 11.2%. Moreover, the corresponding reaction rate was 28.7, 3.6 and 1.3–10.2 times higher than photocatalysis, Fenton-like processes and other catalysts. Furthermore, the possible degradation mechanism, generation of reactive species and PMS excitation pathways were also investigated in depth. The present study sheds light on the fabrication of HP-MOFs based catalysts and the combination of various methods to eliminate organic pollutants.
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高影响因子
NEW JOURNAL OF CHEMISTRY
·
2022
·Vol. 46
·期 27
·13047-13053
·
IF 3.925
Feng Xu,Chao Liu,Jia-Xin Li,Cai-Zhen Zhan,Qi-Ning Xun,Wen-Shen Zhang,Wen-Fang Xing,Gang-Gang Chang
γ-Valerolactone (GVL) is an important lignocellulosic platform molecule with huge potential for various industrial and chemical applications, which is usually produced using levulinic acid (LA) or its esters as raw materials. However, a two-step reaction process in which hydrogenation of the carbonyl groups on metal sites and subsequent lactonization catalyzed by acidic sites over multiple catalysts has generally been needed to realize this synthesis. In this work, a hierarchically multifunctional single catalyst of Ru/phosphotungstic acid/hierarchically porous UiO-66 (Ru/HPW/HP-UiO-66), simultaneously integrated with acidic and metal sites, has been fabricated via a simple strategy and successfully applied in the one-pot synthesis of GVL using methyl levulinate (ML) as the raw material. The hierarchically porous and nanosized (∼15 nm) HP-UiO-66 can not only provide sufficient space for the mass transfer of substrates but also favors the loading of bulk HPW molecules, which can effectively mediate the catalytic activities and stability of Ru NPs using the confined pore effect of UiO-66 and the strong interaction between HPW and Ru. When applied in the one-pot synthesis of GVL, the hierarchical Ru/HPW/HP-UiO-66 catalyst showed excellent catalytic activity (>97% yield) and stability (maintained after 7 successive cycles) for GVL. More importantly, the hierarchical catalyst also exhibited an extraordinary performance in the hydrogenation of different unsaturated hydrocarbons in aqueous solution. It is expected that our study offers a novel route to biomass upgrades involving metal/acid bifunctional synergistic catalysts.
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高影响因子
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
·
2024
·Vol. 171
·期 3
·037526
·
IF 3.1
Deyong Kang,Shanbao Ma,Qiaoling Zheng
Squamous cell carcinoma antigen (SCCA) is an important biomarker in the diagnose of cancer, so developing effective methods for its detection is of great significance. In the present work, a novel sandwich-like electrochemical immunosensing assay (STEM) of SCCA was constructed by preparing gold nanoparticle/reduced graphene-oxide (Au NPs/rGO) to immobilize primary antibody (PAb) of SCCA and UIO-66-NH2 MOFs structure to immobilize second antibody (SAb) and electroactive toluidine blue (Tb) probe. In this designed STEM assay, the prepared Au NPs/rGO nanohybrid offers the advantages in large surface area and conductivity as carrier, and UIO-66-NH2 provided an ideal platform to accommodate SAb and a large number of Tb molecules as signal amplifier. In the existence of SCCA, the current peaks of Tb from the formed STEM structure increase with the increase of SCCA level. After optimizing the related control factors, a wide linear range (0.01 pg ml−1 and 15.0 ng ml−1) and very low detection limit (0.003 pg ml−1) of SCCA was achieved, it's thus expected the designed STEM strategy has important applications for the detection of SCCA.
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高影响因子
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
·
2024
·Vol. 171
·期 4
·047503
·
IF 3.1
Zhengjie Zhang,Yiheng Zhang,Yangchun Li,Yurong Wang
An electrochemical sensor for the simultaneous detection of magnolol (MAG) and honokiol (HON) was constructed based on the metal-organic framework, UIO-66-NH2, and electroreduced carboxylated graphene oxide (ErGO-GOOH). The UIO-66-NH2@ErGO-COOH coating was characterized by scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and electrochemical impedance spectroscopy. Cyclic voltammetry was applied to investigate the electrochemical behavior of MAG and HON on UIO-66-NH2@ErGO-COOH/GCE. The electroanalytical method for the simultaneous determination of MAG and HON was established using linear sweep voltammetry. Under optimal experimental conditions, a linear range of 0.05 ∼ 8 μM and limits of detection of 16 and 7.0 nm for MAG and HON, respectively, were obtained. The sensor exhibited good repeatability, reproducibility, stability and anti-interference ability. The sensor was successfully applied to the simultaneous detection of MAG and HON in urine and serum samples with good recovery.
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高影响因子
RENEWABLE ENERGY
·
2024
·
IF 9
Wenli Zhang,Jifei Liu,Hongwei Gu,Cheng Pan,Yifei Long,Qunpeng Cheng,Guozhi Fan
The metal-organic framework materials ZIF-8 and UiO-66-NH 2 , synthesized by hydrothermal methods, were characterized in detail and combined to catalyze the transfer hydrogenation of 5-hydroxymethylfurfural (5-HMF) to 2,5-di(hydroxymethyl)furan (2,5-DHMF) using isopropanol as the hydrogen source. The ZIF-8/UiO-66-NH 2 catalyst mixture exhibited abundant Lewis acid-base sites and a hierarchical multiporous structure with a large specific surface area (564.0 m 2 /g). The conversion of 5-HMF reached 98.2 %, and the selectivity and yield of 2,5-DHMF were 96.2 % and 94.5 %, respectively. The recycling performance of ZIF-8/UiO-66-NH 2 was also investigated, and the conversion of 5-HMF and selectivity of 2,5-DHMF significantly decreased to 78.4 % and 79.1 % in the second run, respectively. The loss of −NH 2 groups was found to be the main reason for the decrease in activity. However, the catalytic activity of the recovered catalyst can be almost completely restored by the addition of a small amount of fresh UiO-66-NH 2 and ZIF-8, and the conversion of 5-HMF and selectivity of 2,5-DHMF were increased to 89.4 % and 95.5 %, respectively. In the proposed reaction mechanism, Lewis acid-base sites play important roles and exhibit a synergistic catalytic effect in the selective conversion of 5-HMF to 2,5-DHMF.
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高影响因子
ACS Applied Materials & Interfaces
·
2024
·
IF 8.3
Ying Gao,Qinqin Chen,Xinhao Shen,Shuang Yao,Zhiwen Jiang,Sanjian Ma,Hailiang Yang,Juanhong Li,Zixia Lin,Xin Liu
Both the sluggish kinetics of Fe(II) regeneration and usage restriction of H2O2 have severely hindered the scientific progress of the Fenton reaction toward practical applications. Herein, a reduction strategy of activated hydrogen, which was used to simultaneously generate H2O2 and accelerate the regeneration of ferrous in a Fenton-like reaction based on the reduction of activated hydrogen derived from H2, was proposed. Two types of composite catalysts, namely, Pd/UiO-66(Zr)-2OH and Pd@UiO-66(Zr)-2OH, were successfully prepared by loading nano-Pd particles onto the outer and inner pores of UiO-66(Zr)-2OH in different loading modes, respectively. They were used to enhance the reduction of activated hydrogen. The characterization results based on the analysis of scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy, X-ray diffraction, and X-ray photoelectron spectroscopy revealed that the materials were successfully prepared. By using a trace amount of ferrous iron and without adding H2O2, trimethoprim (C0 = 20 mg·L–1), as a target pollutant, could be nearly 100% degraded within 180 min in the reaction system composed of these two materials. The cycle of iron and the self-generation of H2O2 were verified by the detection of ferrous H2O2 in the system. Density functional theory calculation results further confirmed that the pore-filled Pd0 NPs, as the main catalytic site for Pd@UiO-66(Zr)-2OH, could produce H2O2 under the combined action of hydrogen and oxygen. The Pd@UiO-66(Zr)-2OH system had excellent stability after multiple applications (at least 6 cycles), all of which resulted in 100% removal of trimethoprim. The degradation efficiency of the Pd/UiO-66(Zr)-2OH system for TMP gradually decreased from 97 to 80% after six cycles. The results of electron paramagnetic resonance combined with classical radical burst experiments revealed the degradation pathways in the reaction system with hydroxyl radicals and singlet oxygen as the main reactive oxygen particles.
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高影响因子
JOURNAL OF MEMBRANE SCIENCE
·
2025
·
IF 9
Ziheng Li,Fengting Yao,Yan Dai,Xuehua Ruan,Xiaobin Jiang,Xuemei Wu,Wenji Zheng,Gaohong He
Metal-organic frameworks (MOFs) offer exceptional pore tunability for targeted separations. Moving beyond conventional defect engineering which often sacrifices selectivity for permeability, we propose to construct functionalized defects that synergistically integrate hierarchical low-resistance gas transfer pathways with tailored ultra-CO 2 -philic molecular domains. This strategy is achieved by in-situ embedding β-cyclodextrin (β-CD) as a multifunctional modulator during the crystallization of NH 2 -UiO-66 (NUiO). The macrocyclic cavities of β-CD induced structural defects cooperatively optimize the pore architecture of NH 2 -UiO-66, significantly enhancing gas permeability. Concurrently, exposed Zr 6 clusters and hydroxyl groups from β-CD enhance CO 2 adsorption capacity. Furthermore, defect-induced incomplete coordination promotes hydrogen bonding between the β-CD@NUiO and Pebax, improving interfacial compatibility for MMMs. The prepared β-CD 20 @NUiO MMM at 5 wt.% filler loading exhibits a CO 2 permeability of 125.5 Barrer and a CO 2 /N 2 selectivity of 112.4, exceeding the 2019 McKeown upper bound. The in-situ construction of defects via functional molecules transcends the limitations of single-parameter optimization for mass transfer pathways and active sites in porous materials, establishing a universal design principle for multifunctional coupled separation materials.
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高影响因子
FOOD CHEMISTRY
·
2025
·
IF 9.8
Yehong Han,Ruiyang Ma,Juntao Wang,Hongyuan Yan,Yufei Shan,Zihan Liu,Zhi Wang
In this study, for the effective determination of fipronil and ethiprole residues in milk, a new analytical approach, which was based on a tip solid-phase extraction (TSPE) by using a newly prepared ternary deep eutectic solvent-functionalized UiO-66 (TDES@UiO-66) as the adsorbent and HPLC-UV detection, was developed. The method integrated the advantages of both the high adsorption capability of the TDES@UiO-66 and the high efficiency of the TSPE, and enabled a rapid extraction of fipronil and ethiprole from milk samples within 8 min by utilizing only 3.0 mg of TDES@UiO-66 adsorbent. The developed method demonstrated an excellent analytical performance, including good linearity (linear rang: 0.02–10 μg/mL; r : 0.9990–0.9997), high precision (relative standard deviations: ≤ 9.9 %), good accuracy (recoveries: 91.1 %–109.8 %), and good sensitivity (limits of quantification: 0.011–0.018 μg/mL). This study provides a rapid and practical approach for the detection of fipronil and ethiprole in different milk samples.
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高影响因子
危险品化学品经营许可证（带存储）