Nanoscale
·
2019
·Vol. 11
·期 18
·9115-9124
·
IF 6.97
Yunfei Tang,Xiaoqiang Liu,Hejie Zheng,Liwei Yang,Lele Li,Si Zhang,Yanmei Zhou,Subbiah Alwarappan
In this work, a novel photoelectrochemical (PEC) aptasensor was developed for the sensitive detection of aflatoxin B1 (AFB1) based on a resonance energy transfer strategy between the Ce-TiO2@MoSe2 heterostructure and Au nanoparticles (AuNPs). The Ce-TiO2@MoSe2 composite was obtained by growing MoSe2 nanosheets on a TiO2 nanocube doped by the Ce element with a facile hydrothermal method. The composite effectively extended the absorption of TiO2 to the visible region and avoided the self-aggregation of MoSe2 nanosheets, leading to the excellent photocurrent response under visible light excitation. The PEC aptasensor was then fabricated by immobilizing the Ce-TiO2@MoSe2 composite on an ITO electrode, followed by the modification of the aminated AFB1 aptamer. An AuNP-labeled DNA sequence was subsequently hybridized with the aptamer to fabricate a sandwich structure, which was destroyed after the introduction of AFB1, decreasing the amount of the energy acceptor (AuNPs) at the electrode surface. Accordingly, the photocurrent was increased with the increase of AFB1 concentration. Under the optimal conditions, the PEC aptasensor showed a wide linear range of 0.03–200 ng mL−1 and a low detection limit of 0.01 ng mL−1 for AFB1 determination.
研究领域:
分析化学
·
食品安全
·
纳米技术
✓ 已验证
产品关联
DOI
PubMed
高影响因子
ADVANCED FUNCTIONAL MATERIALS
·
2017
·Vol. 27
·期 48
·1703864
·
IF 12.124
Jing Yang,Chunde Wang,Huanxin Ju,Yuan Sun,Shiqi Xing,Junfa Zhu,Qing Yang
MoSe 2 as a typical transition metal dichalcogenide holds great potential for energy storage and catalysis but its performance is largely limited by its poor conductivity. Bi 2 Se 3 nanosheets, a kind of topological insulators, possess gapless edges on boundary and show metallic character on surface. According to the principle of complementary, a novel integrated quasiplane structure of MoSe 2 /Bi 2 Se 3 hybrids is designed with artistic heteronanostructures via a hot injection in colloidal system. Interestingly, the heteronanostructures are typically constituted by single-layer Bi 2 Se 3 hexagonal nanoplates evenly enclosed by small ultrathin hierarchical MoSe 2 nanosheets on the whole surfaces. X-ray photoelectron spectroscopy investigations suggest obvious electron transfer from Bi 2 Se 3 to MoSe 2 , which can help to enhance the conductivity of the hybrid electrode. Especially, schematic energy band diagrams derived from ultraviolet photoelectron spectroscopy studies indicate that Bi 2 Se 3 has higher E F and smaller Φ than MoSe 2 , further confirming the electronic modulation between Bi 2 Se 3 and MoSe 2 , where Bi 2 Se 3 serves as an excellent substrate to provide electrons and acts as channels for high-rate transition. The MoSe 2 /Bi 2 Se 3 hybrids demonstrating a low onset potential, small Tafel slope, high current density, and long-term stability suggest excellent hydrogen evolution reaction activity, whereas a high specific capacitance, satisfactory rate capability, and rapid ions diffusion indicate enhanced supercapacitor performance.
研究领域:
材料科学
·
电化学
·
纳米技术
·
能源存储与转换
✓ 已验证
产品关联
DOI
高影响因子
Solar RRL
·
2023
·Vol. 7
·期 24
·2300711
·
IF 7.9
Chunkai Wang,Ding Ma,Mengge Li,Yue Liu,Xiaofei Sun,Yuting Sun,Yan Zhu,Zhanhui Ding,Yongfeng Li,Bin Yao
One of the key issues impeding the enhancement of power conversion efficiency (PCE) of Cu 2 ZnSn(S,Se) 4 (CZTSSe) solar cells is the severe carrier recombination at CZTSSe/MoSe 2 back interface, primarily arising from the reverse electric field formed between CZTSSe and n-type MoSe 2 produced after selenization. To inhibit recombination at back interface, herein, the MoSe 2 layer is converted from n-type to p-type by V doping in site through reaction of V-alloyed Mo (Mo:V) back electrode with Se during selenization, and CZTSSe solar cells with p + -type V-doped MoSe 2 (MoSe 2 :V) interface layer are fabricated. It is found that the PCE of the device rises from 8.34% to 9.63% as back contact changes from soda lime glass (SLG)/Mo/n-MoSe 2 to SLG/Mo:V/p + -MoSe 2 :V. The quantitative analysis demonstrates that the increased PCE predominantly originated from the decreased reverse saturated current density ( J 0 ), followed by the decreased series resistance ( R S ), and lastly by the increased photogenerated current density ( J L ). The influence mechanism of the SLG/Mo:V/MoSe 2 :V back contact on device performance is suggested by studying the properties of Mo:V and MoSe 2 :V films and CZTSSe/MoSe 2 :V heterojunction. This work emphasizes the vital significance of the back surface passivation field induced by p + -MoSe 2 :V/p-CZTSSe heterojunction, which is enlightening for optimizing the back contact in kesterite photovoltaics.
研究领域:
材料科学
·
光伏技术
✓ 已验证
DOI
高影响因子
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
·
2025
·
IF 8.3
Jingting Sun,Shangshang Wang,Xingyu Liu,Huan Yu,Jiaming Li,Chao Liu,Qinfang Zhang,Zhigang Zou
Photocatalytic hydrogen production (PHE) technology has emerged as a sustainable approach to convert solar energy into hydrogen energy, exhibiting significant potential for clean energy applications. In this study, an ultrasonic-assisted method was adopted to fabricate S-scheme MoSe 2 /Mn 0.5 Cd 0.5 S (MoSe 2 /MCS) composites, where intimate heterostructures are formed through interfacial Mo–S bonds between MCS and MoSe 2 . The atomic-level Mo–S bonds establish charge transport pathways and enable directional control of charge transfer. The as-constructed S-scheme MoSe 2 /MCS photocatalysts exhibit two critical advantages: enhanced charge carrier separation rate and improved overall redox capacity. Under visible-light irradiation, the MoSe 2 /MCS composites significantly outperform pure MCS in PHE performance. The optimal 5-MoSe 2 /MCS composite demonstrates the superior PHE activity, achieving an apparent quantum yield value of 71.16 % at 400 nm and remarkable photocatalytic stability. Key characterization techniques, including (solution-based) time-resolved photoluminescence technique, theoretical calculation, photoelectrochemical measurements, were employed to elucidate the positive correlation between ion-carrier interaction and charge separation efficiency, thereby enhancing the PHE performance. Based on experimental analysis and theoretical calculation, a plausible PHE mechanism for the S-scheme MCS composites is revealed and discussed in detail. These findings provide valuable insights for designing high-efficiency S-scheme heterostructured composites with interfacial chemical bonds.
研究领域:
材料科学
·
物理化学
·
纳米催化
·
能源材料
·
光催化
✓ 已验证
产品关联
DOI
高影响因子
SENSORS AND ACTUATORS B-CHEMICAL
·
2021
·
IF 7.46
Wenjing Pan,Yong Zhang,Sujing Yu,Xiaohua Liu,Dongzhi Zhang
The metal-organic framework (MOF)-derived alpha-iron oxide hollow nanosphere/molybdenum diselenide nanoflower (α-Fe 2 O 3 /MoSe 2 ) composite is fabricated via simple hydrothermal route. Multiple characterization methods have proved the successful synthesis of α-Fe 2 O 3 /MoSe 2 composites. The nanocomposite with a mass ratio of α-Fe 2 O 3 and MoSe 2 of 4:1 shows high response to H 2 S gas sensing. Moreover, the gas sensitivity test of the system shows that the α-Fe 2 O 3 /MoSe 2 composite sensor exhibits a faster response/recovery rate, outstanding repeatability and anti-humidity interference toward H 2 S sensing at room temperature, which also shows excellent selectivity for H 2 S compared to various potentially interfering gases. Further studies have shown that α-Fe 2 O 3 /MoSe 2 nanocomposites have improved H 2 S gas sensing performance due to the increased active sites and specific surface area, and the formation of n-n heterojunctions at the interface between α-Fe 2 O 3 hollow nanospheres and MoSe 2 nanoflowers.
研究领域:
材料科学
·
化学传感器
·
纳米技术
✓ 已验证
DOI
高影响因子
JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS
·
2020
·
IF 3.209
Xu Hun,Xiaohui Kong
Alzheimer’s disease is a worldwide health problem and it has attracted extensive attention. Tau protein is an important biomarker in the pathogenesis of Alzheimer’s disease. Herein, we devise a in situ enzyme catalysis generating electron donor photoelectrochemical (PEC) biosensor for Tau-381 protein. Tau-381 protein aptamer is immobilized onto the surface of AuNPs/MoSe 2 nanosheets modified electrode. In the presence of Tau-381 protein, an aptamer-protein duplex is formed. Meanwhile, the Tau-381 antibody and the protein G/AP (protein G labeled with alkaline phosphatase) are captured with the affinity interaction between Tau-381 protein and Tau-381 antibody, Tau-381 antibody and protein G/AP. The electron donor, ascorbic acid, is in situ produced by the catalyzing of ascorbic acid 2-phosphate in the PEC detection solution. As a result, low blank noise and strong photocurrent response are engendered. The photocurrent response is related to the concentration of Tau-381 protein. The detection range of Tau-381 protein is from 0.5 fM to 1.0 nM with detection limit of 0.3 fM. This in situ generating electron donor PEC biosensor can detect various targets by simply alternating antibody, antigen, or aptamer commercially. Thus, this work represents a simple and general sensing protocol.
研究领域:
生物传感器
·
神经退行性疾病
·
分析化学
·
纳米技术
·
光电化学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
ChemistrySelect
·
2022
·Vol. 7
·期 33
·e202201722
·
IF 2.307
Jiameng Wang,Baohua Chen,Wuyi Zhang,Yifeng Wu,Lanlan Chen,Jia Wen,Hongyuan Yan
Graphical The properties of MoS 2 , MoSe 2 and MoTe 2 on the glucose sensing were systemically explored and compared. The three kinds of exfoliated TMDs modified electrodes possessed a low detection limit, an outstanding specificity and acceptable specificity. Two-dimensional transition-metal dichalcogenides (TMDs) have attracted widespread interests owing to their attractive physical and chemical properties. In particular, they are especially attractive in the field of electrochemical biosensors. In this study, the properties of TMDs ((molybdenum sulfide (MoS 2 ), molybdenum diselenide (MoSe 2 ) and molybdenum telluride (MoTe 2 )) on the glucose sensing were explored and compared. Exfoliated MoS 2 , MoSe 2 and MoTe 2 nanosheets with basically the same size were fabricated through controlling the ultrasonic power. The structure and morphological characteristics of MoS 2 , MoSe 2 and MoTe 2 were examined through scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy and powder X-ray diffractometer. Electrochemical properties were analyzed through cyclic voltammetry and differential pulse voltammetry. Results showed that all the three kinds of TMDs can enhance the electroconductibility of the electrodes. When incorporated into the construction of electrochemical biosensors for glucose detection, all of the three kinds of exfoliated TMDs modified electrodes possessed achieved analytical requirements of selectivity, wide linear ranges, as well as low limits of detection and quantification. In particular, MoS 2 -based biosensor generated a higher specificity and lower detection limit than that of MoSe 2 and MoTe 2 . This is imperative to showcase the real potential of TMDs in electrochemical biosensors.
研究领域:
材料科学
·
纳米技术
·
分析化学
·
生物传感器
✓ 已验证
产品关联
DOI
高影响因子
Journal of Materials Chemistry A
·
2025
·
IF 9.5
Guangqi Zhang,Congcong Dang,Yiping Liu,Rouyan Guo,Lingti Kong,Liancheng Zhao,liming Gao
Li-O2 batteries have emerged as promising contenders for advanced energy storage systems, leveraging their exceptionally high theoretical energy density. Nevertheless, their practical deployment is substantially hindered by rapid capacity degradation and restricted operational durability, primarily attributed to sluggish oxygen reaction kinetics. Here, to modulate kinetic barriers, we propose an approach synergizing structural and electronic advantages by integrating heterointerface engineering and hierarchical nano structuring. A hollow nanobox MoSe2@CuS core-shell heterostructure is developed as a bifunctional oxygen electrode. Such heterostructure could induce a built-in electric field to modulate charge transfer dynamics and the hollow architecture could optimize triple-phase interfacial reactions. Leveraging the synergistic attributes of its components, the MoSe2@CuS-based Li-O2 battery achieves an excellent specific capacity of 16,000 mAh g-1 at 100 mA g-1. Moreover, it demonstrates remarkable cycling durability, sustaining high performance for over 190 cycles at 200 mA g-1 with a restricted capacity of 600 mAh g-1. Density functional theory (DFT) calculations further illustrate the lowered energy kinetic barrier for Li2O2 formation/decomposition induced by MoSe2@CuS core-shell heterostructure. This work pioneers a universal heterointerface engineering strategy through rational design of hierarchical hollow architectures, providing new insights for developing high-performance Li-O2 battery cathodes.
研究领域:
储能
·
纳米材料
·
电化学
·
电池技术
·
材料科学
·
理论化学
✓ 已验证
DOI
高影响因子
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING
·
2022
·
IF 9.463
Xiu-Zhi Tang,Zijian Liao,Haolong Shi,Rong Wang,Jianling Yue,Xuelong Chen
Electromagnetic wave (EMW) absorption materials have recently received considerable attention due to the increasingly severe EMW pollution. It remains challenging to fabricate a lightweight absorber with high absorption performance and low matching thickness via structure design and composition tuning. Herein, one type of fibrous composite EMW absorber with two-dimensional (2D) nanosheets coating was synthesized by electrospinning, pyrolysis and hydrothermal. The combination of cobalt nanoparticle and carbon nanofiber with decoration of 2D MoSe 2 nanosheets on the surface significantly promote the EMW absorption through dielectric/magnetic loss, impedance matching, diverse polarizations and porous structure induced multiple scattering. Owing to the coupling effect of proper combination of multiple components and hierarchical structure, a strong EMW absorption with minimum reflection loss (RL) −62.30 dB at 10.70 GHz, effective absorption bandwidth (EAB) 5.10 GHz (9.30–14.40 GHz) covering most of the X-band was achieved with absorber thickness of 2.05 mm. By adjusting the thickness to 1.60 mm, the EAB can reach 6.00 GHz (12.00–18.00 GHz), covering the whole Ku bands. This composite fibrous absorber with excellent EMW absorption performance is promising to be used in many EMW attenuation applications.
研究领域:
材料科学
·
电磁工程
·
纳米技术
✓ 已验证
产品关联
DOI
高影响因子
Materials Today Nano
·
2022
·
IF 13.364
X. Cui,Y. Zhou,Y. Zheng,L. Cao,L. Gao,J. Duan,H. Yin,S. Ai
N 6 -methyladenosine (m 6 A) is the most abundant and dynamic reversible modification of mRNA in eukaryotes discovered in the mid-1970s, which is widely involved in various physiological processes. Fat mass and obesity-associated protein (FTO protein) is not only a demethylase for m 6 A, but also a carcinogenic factor for many human cancers. Therefore, it is very important to build a simple and sensitive platform for simultaneous detection of m 6 A and FTO protein. To achieve this aim, a novel photoelectrochemical biosensor was constructed with the antibody-free detection strategy of DTT mediated –SH functionalization of m 6 A triggered by FTO protein catalyzed m 6 A oxidation . To achieve high detection sensitivity, CdS/Bi 2 MoO 6 /MoSe 2 system with matched energy gap was employed as photoactive material. To achieve high detection selectivity , the –CH 3 of m 6 A in the captured RNA sequence (m 6 A RNA) on the electrode surface was oxidized by FTO protein to form hydroxymethyl, followed with the covalent reaction of DTT with hydroxymethyl, making the labeling of m 6 A with –SH. Finally, a CdS nanoparticle was modified on the electrode through the specific covalent reaction between –SH and Cd, achieving the improvement of the photocurrent with the matched energy band . Under the optimal experimental conditions, the biosensor showed linear range from 0.001 to 50 nM and 0.0005–500 μg/L with the detection limit of 0.37 pM and 0.034 ng/L (S/N = 3) for m 6 A RNA and FTO protein, respectively. The applicability of the developed method was assessed by investigating the effect of entacapone on FTO protein activity.
研究领域:
生物化学
·
分析化学
·
生物技术
·
癌症研究
✓ 已验证
产品关联
DOI
高影响因子
CHEMICAL ENGINEERING JOURNAL
·
2022
·
IF 16.744
Liying Zhang,Pei Xie,Hang Wu,Jiulong Zhao,Shige Wang
Acute pancreatitis (AP) is a disease with high mortality which could cause an inflammatory responses such as edema and necrosis of the pancreatic tissue. Studies have proved that the excessive produced reactive oxygen species (ROS) and reactive nitrogen species (RNS) play an important role in the pathogenesis of AP. Although progresses have been made for ROS and RNS elimination using artificial enzymes, biocompatible nanomaterials with advanced multi-enzymatic activities have been rarely studied. In this study, we constructed a simple and efficient method to fabricate a two-dimensional (2D) MoSe 2 @PVP nanosheets (NSs) as an artificial enzyme to treat oxidative stress-related diseases. Both in vitro and in vivo experiments proved that MoSe 2 @PVP NSs have good biocompatibility. Interestingly, the MoSe 2 @PVP NSs simultaneously showed the thermal durable peroxidase, catalase, superoxide dismutase, and glutathione peroxidase mimicking capacities, which endowed the material with good ROS and RNS scavenging abilities. The MoSe 2 @PVP NSs were engaged in treating the AP in an animal model, which led to a significant down-regulation of serum levels of amylase, IL-6, IL-1β, and TNF-α. Further H&E staining of pancreatic tissue validated the AP therapeutic effect of MoSe 2 @PVP NSs. We hope that our research will facilitate the development of multifunctional artificial enzymes for the treating of oxidative stress-related diseases.
研究领域:
纳米技术
·
生物医学工程
·
药理学
·
病理学
✓ 已验证
产品关联
DOI
高影响因子
Carbon Energy
·
2022
·Vol. 5
·期 2
·e255
·
IF 21.556
Yunke Wang,Yige Zhao,Kangli Liu,Shaobin Wang,Neng Li,Guosheng Shao,Feng Wang,Peng Zhang
Sophisticated efficient electrocatalysts are essential to rectifying the shuttle effect and realizing the high performance of flexible lithium-sulfur batteries (LSBs). Phase transformation of MoSe 2 from the 2H phase to the 1T phase has been proven to be a significant method to improve the catalytic activity. However, precisely controllable phase engineering of MoSe 2 has rarely been reported. Herein, by in situ Li ions intercalation in MoSe 2 , a precisely controllable phase evolution from 2H-MoSe 2 to 1T-MoSe 2 was realized. More importantly, the definite functional relationship between cut-off voltage and phase structure was first identified for phase engineering through in situ observation and modulation methods. The sulfur host (CNFs/1T-MoSe 2 ) presents high charge density, strong polysulfides adsorption, and catalytic kinetics. Moreover, Li-S cells based on it display capacity retention of 875.3 mAh g −1 after 500 cycles at 1 C and an areal capacity of 8.71 mAh cm −2 even at a high sulfur loading of 8.47 mg cm −2 . Furthermore, the flexible pouch cell exhibiting decent performance will endow a promising potential in the wearable energy storage field. This study proposes an effective strategy to precisely control the phase structure of MoSe 2 , which may provide the reference to fabricate the highly efficient electrocatalysts for LSBs and other energy systems.
研究领域:
材料科学
·
电化学
·
储能技术
·
纳米技术
·
电池技术
✓ 已验证
DOI
高影响因子
危险品化学品经营许可证（带存储）