CARBON
·
2025
·
IF 11.6
Hongfeng Yu,Junru Yao,Jinlong Lv,Ruirui Zhang,Zi Wang,Xiangjia Song,Xiangfei Wei,Jintang Zhou
Developing lightweight, high-performance microwave absorbing materials with multiple functions has become a major challenge in the field of electromagnetic protection. In this study, ZIF-67/cellulose nanofiber (CNF)-derived Co–C/C aerogel with an integrated design for microwave absorption and thermal camouflage functions was prepared. The hierarchical pore structure with coexisting micron-scale skeletal pores and MOF-derived nanopores was constructed through in-situ growth of ZIF-67 on CNF and low-temperature carbonization regulation. Simultaneously, uniformly distributed Co nanoparticles (20–30 nm) and defect-rich graphitized carbon heterointerfaces were obtained. The Co–C/C aerogel exhibited an ultra-low density (16.21–17.35 mg/cm 3 ). In terms of microwave absorption, it achieved an effective absorption bandwidth of 6.87 GHz (covering the Ku band) at a thickness of 2.4 mm. This was attributed to the synergistic mechanisms of multiple scattering from hierarchical pores, enhanced interfacial polarization induced by low-temperature carbonization, and magnetic loss from Co nanoparticles. In addition, the material demonstrated a low thermal conductivity of 0.0492 W m −1 K −1 , and infrared imaging revealed its significant thermal signal shielding capability. This study addressed the issues of structural collapse and functional singleness in traditional MOF-derived materials through in-situ growth and low-temperature carbonization strategies, providing new insights for the design of lightweight, broadband, and multifunctional stealth materials.
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高影响因子
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
·
2025
·
IF 4.6
Yinjia Zhao,Xufang Hu,Chengyu Li,Jing Hu,Tianran Yuan,Yanxiong Liu,Qiue Cao,Shiyu Feng,Liyan Zheng
17β-estradiol (E2) is a crucial estrogen that significantly influences reproductive biological processes and the development of associated diseases, highlighting the need for effective detection methods. Here, we propose a magnetic hierarchical porous material (Mag MOF@COF-Apt) through the in situ growth of a TAPB-DMTP-COF layer on a magnetic Fe-MOF core for the selective recognition and surface-enhanced Raman scattering (SERS) analysis of E2. The Mag MOF@COF-Apt features the inherent SERS-enhancing properties of Mag MOFs. Furthermore, the COF layer establishes a gap between E2 and the Mag MOF, enhancing SERS activity through the on-shell-isolated effect. Additionally, the topological structure of the COF on the MOF provides a high surface area platform for more affinity sites, and its expanded porous structure facilitates size-exclusion of interferents. Finally, E2 aptamer functionalization equips this heterojunction with the capability for the selective capture of E2. Through these multiple synergistic effects, the Mag MOF@COF-Apt assisted E2 profiling features good sensitivity (detection limit of 110.14 nmol L −1 ), strong tolerance to protein (40 mg mL −1 BSA, 40 mg mL −1 HSA) and salt (40 mg mL −1 NaCl) interference, high signal reproducibility (RSD = 7.29 %) and reusability over four cycles. The effectiveness of Mag MOF@COF-Apt based profiling was validated by successful E2 detection in human serum. This work is anticipated to advance MOF/COF hybrid substrates for SERS, providing an effective tool for E2 analysis.
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高影响因子
INORGANIC CHEMISTRY
·
2025
·
IF 4.7
Saiyu Yang,Zicheng Yin,Xianchun Chen,Zhide Geng,Bo Wang,Junwen Zhou,Lu Wang
Conventional methods for synthesizing nano-sized metal-organic frameworks (nano-MOFs) often rely on additives or extra conditions, overlooking the critical role of solvents. Here, we highlight tetramethylene sulfone (TMS, or sulfolane) as a versatile solvent for nano-MOF synthesis. TMS forms strong solvation structures with metal ions and inhibits ligand deprotonation, enabling control over particle size. Using TMS, we synthesized ZIF-65 [Zn(2-nIm)2, 2-nIm = 2-nitroimidazole], ZIF-8 [Zn(2-mIm)2, 2-mIm = 2-methylimidazole], UiO-66 [Zr6O4(OH)4(BDC)6, BDC = 1,4-dicarboxybenzene acid], and MOF-199 [Cu3(BTC)2, BTC = 1,3,5-benzenetricarboxylic acid] with significantly smaller particle sizes compared to traditional solvents like ethanol (EtOH). Systematic analysis on the growth of ZIF-65 revealed distinct growth behaviors: in TMS, slower kinetics allowed the coexistence of nucleation and growth over an extended period, leading to an increase in particle number while maintaining relatively constant size; in contrast, EtOH promoted rapid growth followed by Ostwald ripening, resulting in larger particles and reduced particle number over time. By adjusting reactant concentration, metal-to-ligand ratio, and reaction temperature, we achieved facile size modulation of ZIF-65 nanoparticles. This work underscores the importance of solvents in nano-MOF synthesis and offers a robust strategy for tailoring MOF particle size, advancing applications in catalysis, biomedicine, and beyond.
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JOURNAL OF SOLID STATE CHEMISTRY
·
2025
·
IF 3.5
Xun Li,Xuanying Lu,Bingtao Gui,Cheng Wang,Jun Liu,Liang Lu
Seawater uranium extraction is a key technology for environmental sustainability with significant potential applications. For the first time, this work synthesized a CTAB/Bent-MOF808 with strong stability, abundant coordination functional groups, and low cost, and assessed its adsorption effectiveness for U (VI) in carbonate solutions. The study explores how pH, contact time, uranium concentration, temperature, carbonate, halide salts, phosphorus, and Ca/Mg ions influence uranium adsorption, with a focus on mechanistic insights through characterization and modeling. Under optimal conditions (temperature of 25 °C, pH 8.0, with a sodium bicarbonate concentration of 2 mmol L −1 and a U(VI) concentration of 50 mg L −1 ), which are similar to the real seawater environment, CTAB/Bent-MOF808 demonstrated superior uranium adsorption performance compared to MOF808 and CTAB/Bent in U(VI)–CO 3 solutions. Under high initial pH, NaHCO 3 , Ca/Mg ions, and halide ion concentrations, the complex's uranium adsorption capacity and removal rate are reduced due to competitive adsorption between ions, as well as increased electrostatic repulsion on the surface. The sorption process was identified as monolayer homogeneous chemical adsorption process by analyzing it with quasi second order kinetic models and Langmuir isotherm models. The inhibitory effect of halide ions is as follows: I − > F − > Br − > Cl − . XPS suggested that the complexation of bromide anion with –COOH and electrostatic attraction could be crucial processes for uranium adsorption. This study offers theoretical insights into uranium extraction from natural uranium-bearing waters and highlights the expanded potential of MOF-based adsorbents in this process, enhancing both efficiency and application scope.
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GREEN CHEMISTRY
·
2024
·
IF 9.3
Xin-Ran Shi,Meng Qiao,Yan Wei,Ling-Xia Yun,Jie-Xin Wang,Jian-Feng Chen
MOF-74 or M2(dhtp) (M = metal ions, dhtp = 2,5-dihydroxyterephthalic acid), as a typical class of metal–organic frameworks (MOF), have garnered considerable interest due to their abundant unsaturated metal sites. However, environmental and economic limitations caused by the extensive use of organic solvents in traditional syntheses hinder their industrial applications. Although water as a green solvent is considered to be the best candidate solvent, water-based MOFs often have poor crystallinity and long synthesis time, and controlling the particle size is difficult. Herein, a water-based strategy is proposed to synthesize high-quality MOF-74–Co with controllable particle sizes in a rotating packed bed (RPB) reactor using high-gravity technology. MOF-74–Co could be rapidly prepared in the RPB, and shows a smaller and more uniform particle size, higher crystallinity, and larger specific surface area, as compared to the counterpart prepared in a traditional stirred tank reactor. Further adopting acetic acid as a modulator, the as-prepared MOF-74–Co has the highest BET surface area (1599 m2 g−1) in the reported literature so far and simultaneously possesses a high space–time yield (293 kg m−3 day−1). High-quality MOF-74–Zn and MOF-74–Ni can also be prepared, proving the generality of this strategy. Furthermore, the small-sized MOF-74–Co-78 nm exhibits a faster adsorption rate and a larger saturation adsorption capacity (298 mg g−1) for CO2 compared with large-sized samples. This study not only advances the field of green synthesis of MOFs but also paves the way for efficient manufacturing processes in MOF-74 synthesis for CO2 adsorption.
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JOURNAL OF MEMBRANE SCIENCE
·
2025
·
IF 9
Xinyue Shang,Ruoman Ji,Lijuan Gao,Shuyi Li,Riji Qiu,Ting Wang
After modification of MOF-919 by bovine serum albumin (BSA) and further membrane formation, a novel metal-organic framework (MOF) chiral membrane based on protein functionalization was prepared. In the process, the stability of biomacromolecules under harsh conditions could be enormously raised on account of the combination MOF and BSA, while imparting chirality to the modified MOF. The influence of conditions such as reaction time, pH, initial concentration and salt concentration on the efficiency of MOF immobilized BSA were discussed. The outcomes indicated that the binding between MOF-919 and BSA was due to the synergistic interplay of pore diffusion and surface adsorption mechanisms. Meanwhile, after the immobilization, the composite material (MOF-919@BSA) was developed as a new kind of chiral splitter that combined with polyethersulfone to form the MMM. As well as the concentration of feed solution, thickness of membrane, proportion of biocomposite materials in membrane, the penetration time, cycle index and the micro environment of BSA on the separation of chiral enantiomers from the MMMs were investigated. The chiral membrane had excellent selectivity and high flux in the process of transporting chiral enantiomers. After that, the reliability of the mechanism for chiral separation was demonstrated through molecular docking simulations. At the same time, MOF@BSA-PES mixed matrix membrane manifested superior performance compared with the majority of state-of-the-art chiral membranes.
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Materials Today Bio
·
2025
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IF 10.2
San-yang Yu,Ting Wu,Kai-hao Xu,Ru-yue Liu,Tian-hao Yu,Zhen-hua Wang,Zhong-ti Zhang
Critical-size bone defects remain a significant clinical challenge. The lack of endogenous stem cells with osteogenic differentiation potential in the defect area, combined with the inflammatory responses induced by scaffold implantation, highlights the need for biomaterials that can deliver stem cells and possess inflammatory regulation properties. In this study, we developed a 3D bioprinted gelatin methacrylate (GelMA) hydrogel scaffold modified with luteolin-loaded ZIF-8 (LUT@ZIF-8) nanoparticles, designed to deliver bone marrow mesenchymal stem cells (BMSCs) to the defect site and release bioactive components that promote osteogenesis and modulate the immune microenvironment. The LUT@ZIF-8/GelMA hydrogel scaffolds demonstrated excellent physical properties and biocompatibility. The sustained release of luteolin and zinc ions from the LUT@ZIF-8 nanoparticles conferred antibacterial, osteoinductive, and inflammatory regulation effects. The immune microenvironment modulated by LUT@ZIF-8/GelMA hydrogel scaffolds facilitated osteogenic differentiation of BMSCs. Furthermore, in vivo experiments confirmed the osteogenic and inflammatory regulation capabilities of the LUT@ZIF-8/GelMA hydrogel scaffolds. In conclusion, the 3D bioprinted LUT@ZIF-8/GelMA hydrogel scaffolds exhibit osteoimmunomodulatory properties, presenting a promising strategy for the treatment of bone defects.
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Journal of Inorganic and Organometallic Polymers and Materials
·
2025
·
IF 4.9
Zhang Qiuyun,He Maozhen,He Shijian,Lei Yanhui,Zou Huixin,Zhang Xiaojuan,Hu Yulin,Zhang Yutao
Photocatalytic organic pollutant degradation offers new perspectives for sustainable sunlight utilization and wastewater purification. In this study, the flower-like Bi 2 O 2 CO 3 (BOC) nanosheets were incorporated into zirconium-based MOFs (MOF-801) for the construction of BOC@MOF-801 heterojunction nanocomposites, through a simple one-pot hydrothermal route to remove persistent rhodamine B (RhB) dye efficiently. The as-synthesized photocatalysts were systematically characterized by XRD, FTIR, SEM, EDS, N 2 physisorption, TG, XPS, UV-Vis DRS, PL, transient photocurrent, and EIS techniques. The results of all characterization studies confirmed that the incorporation of BOC into MOF-801 improved the textural properties, visible light response-ability, and the formation of heterojunctions with better charge transport. All BOC@MOF-801 photocatalysts show high activity, with the BOC@MOF-801-0.2 nanocomposite reaching 98.8% RhB (50 mg/L) degradation after 120 min under visible radiation, superior to individual BOC and MOF-801. This improvement possibly due to the relatively high specific surface area (316.2 m 2 /g), suitable pore volume (0.17 cm 3 /g), mesoscale pore size (3.2 nm), narrowed band gap (3.22 eV), and higher photocurrent. Importantly, the free radical scavenging experiment exhibited that holes and · O 2 − radicals are the main species responsible during photodegradation. Moreover, a potential mechanism for the breakdown of RhB dye is also discussed. This research highlighted an efficient way to develop MOFs-based heterojunction hybrid materials for environmental remediation applications. Graphical Zirconium-based MOFs (MOF-801) supported Bi 2 O 2 CO 3 nanocomposites (BOC@MOF-801) were successfully synthesized via a simple one-pot hydrothermal route, which was subsequently applied to photocatalytic degradation of organic dye.
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ANALYTICAL CHEMISTRY
·
2025
·
IF 6.7
Yuan Qin,Huimei Liang,Jia Wu,Zheyang Chi,Shulin Zhao,Fanggui Ye
Natural enzyme cascades, including the same and different kinds of enzymes, have been widely used in biosensing. However, it is still a challenge for nanozymes, the mimics of natural enzymes, to achieve biosensing with different types of enzyme-like activities based on cascade reactions, such as hydrolase and oxidoreductase. Considering the characteristics of the multienzyme-like activity of some nanozymes, as a proof of concept, this study demonstrates a Cu/Ce-MOF-808 nanozyme as a self-cascade catalyst with hydrolase-like and catechol oxidase-like activities. Taking organophosphorus pesticides as an example, we constructed a self-cascade catalytic reaction for the one-step colorimetric detection of isocarbophos. Specifically, the hydrolase-like activity of Cu/Ce-MOF-808 can hydrolyze isocarbophos to produce colorless isopropyl salicylate, which is further oxidized by the catechol oxidase-like activity of Cu/Ce-MOF-808 and complexed with 4-aminoantipyrine (4-AAP) to produce red quinoneimine under neutral conditions with illumination. Thus, a colorimetric strategy for sensitive isocarbophos analysis is developed, with a linear range of 0.90–400.00 μg·mL–1 and a detection limit of 0.42 μg·mL–1. This research presents a new approach to the design and synthesis of nanozymes and has great application potential in the field of nanozyme cascade biosensing.
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高影响因子
APPLIED ORGANOMETALLIC CHEMISTRY
·
2025
·Vol. 40
·期 1
·e70473
·
IF 0
Fuhua Wei,Anhui Huang,Qinhui Ren,Min Li,Wei Shang,Diaodiao Zhang,Zhao Liang
In this research, GO/Cu/Cr-MOF composites were fabricated via a dissolution-heat method. The GO/Cu/Cr-MOF composite was characterized using FT-IR, SEM, XRD, and EDS techniques. The characterization results confirmed the presence of Cu and Cr metallic elements in the composite, and FT-IR analysis demonstrated that the organic ligands were successfully coordinated with the metal centers. The characterized GO/Cu/Cr-MOF composite was employed in the removal study of fleroxacin and levofloxacin. The results demonstrate that the addition of 40 mg of the composite to a 40-ppm levofloxacin solution achieved a removal efficiency of 95.9% within 5 h. Likewise, adding the same amount of composite to a 20-ppm fleroxacin solution resulted in a maximum removal efficiency of 98.2% over the same time period. The experimental data were examined using both the kinetic model and the isotherm models. The results revealed that the adsorption of both antibiotics onto the GO/Cu/Cr-MOF composite followed the pseudo-second-order kinetic model and was most accurately represented by the Langmuir isotherm. The experimental results indicate that the adsorption capacity of the GO/Cu/Cr-MOF composite for fleroxacin and levofloxacin reaches its maximum within the pH range of 6 and 8.
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JOURNAL OF MEMBRANE SCIENCE
·
2025
·
IF 9
Hongxu Tao,Haiqian Lian,Jingxian Hua,Shengui Ju,Yichang Pan
The MOF membrane has shown great promise for the gases or organic solvent mixtures separation. However, the implementation of MOF membranes remains challenged by defect formation during membrane fabrication. Herein, we reveal that the activation solvent plays a critical role in governing the degree of defect and separation performance in secondary-growth-derived ZIF-8 membranes. The isopropanol activation process exerts excellent membrane structure protection through a synergistic dual mechanism to limit the generation of ZIF-8 membrane defects during drying: (a) The isopropanol inhibits the ZIF-8 seed layer recrystallization and maintains its porous architecture to mitigate interfacial stress during drying through its elastic deformation. (b) The low surface tension of isopropanol minimizes the capillary force during solvent removal to reduce the risk of structural damage. While methanol activation and n-propanol activation have no such structure control. The optimized isopropanol-activated membrane achieves a C 3 H 6 /C 3 H 8 selectivity of 141 to show a 4.8-fold and a 4.4-fold compared to n-propanol- and methanol-activated membranes at room temperature and 1 bar. This study highlights low-surface-tension as an effective strategy for defect suppression in MOF membranes, advancing their potential for industrial hydrocarbon separations.
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ENERGY CONVERSION AND MANAGEMENT
·
2025
·
IF 10.9
Xinyu Zhou,Yaohui Feng,Lurong Ge,Zixuan Su,Tianshu Ge
Desiccant coated heat exchanger (DCHE) is a promising and energy-efficient dehumidification unit, which uses cooling source to overcome sorption heat effect. Recently, metal–organic framework (MOF) is emerging in this filed due to its S-shaped isotherms, leading to reduced requirements for regeneration temperature differences. However, this unique characteristic of MOF also means that each adsorbent can only function under conditions where the relative humidity (RH) is limited, and adsorbents with high stepwise relative humidity are difficult to function under low humidity conditions. This work proposes a two-stage MOF-coated heat exchanger (MCHE), where the first stage utilizes MOFs that operate under high RH, while the second stage employs adsorbents capable of functioning at low RH, aiming to achieve efficient cascade dehumidification over a wide humidity range. MIL-101(Cr) and Al-fumarate were respectively selected for the first and second stages for experimental verification. The influence mechanisms of key parameters such as switching period, cooling/hot water temperatures, and air conditions were investigated. Compared with the single stage configuration, the two-stage MCHE in this work exhibits better heat and mass transfer performance, achieving a lower supply air temperature (2–3 °C lower) and a higher dehumidification efficiency (10 % higher). This study verifies the feasibility and applicability of the proposed system, providing a new approach for efficient dehumidification under wide humidity range.
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