JOURNAL OF ELECTROANALYTICAL CHEMISTRY
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2023
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IF 4.5
Ying Ma,Ping Wei,Mengjie Chen,Xianhua Shi,Xiange Lu,Xuanxuan Zhang,Duanping Sun
A variety of two-dimensional (2D) metal–organic framework (MOF) nanosheets have been discovered with excellent peroxidase-like activity due to their merits of accessible active sites and large surface area. However, few methods can be used for the large-amount production of 2D MOF nanosheets. Herein, we report a simple room temperature solution phase method for the high-yield synthesis of 2D trimetallic MOF nanosheets with three kinds of metal ions as ligands. The as-synthesized NiCoM (M = Cu, Fe, and Zn) nanosheets showed markedly enhanced electrochemical activity due to the synergistic effect. Among these obtained nanosheets, NiCoFe showed the highest electrocatalytic activity, demonstrating that Fe played a dominant role in determining the activities of nanozymes. As a proof-of-concept application, 2D NiCoFe nanosheets are used as modified materials for the electrochemical detection of H 2 O 2 . The results showed that the fabricated sensor can detect hydrogen peroxide (H 2 O 2 ) with a detection range of 5.0 μM − 15 mM, a detection limit of 2.1 μM, excellent selectivity and stability. Moreover, the fabricated NiCoFe nanosheet-based electrochemical sensor can be used for the detection of H 2 O 2 in serum samples. Our work provides a scalable method for the large-scale synthesis of 2D trimetallic MOF nanosheets as enhanced nanozymes for various applications.
研究领域:
材料科学
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分析化学
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生物医学工程
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DOI
高影响因子
Journal of the Taiwan Institute of Chemical Engineers
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2021
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IF 5.876
Yanfang Chen,Xuemei Yan,Haifeng Lin,Chao Wang,Jixiang Xu
Background Fe 2+ /H 2 O 2 -based photo-Fenton process is often used in pollutions removal. But, Fe-species related low activity at neutral condition hinders their practical applications. Activation of in situ generated H 2 O 2 for Fenton-like degradation of pollutions through catalysts absences of Fe species is expected. Methods A strip-like benzene and K + co-doped g-C 3 N 4 (KBCN) was constructed by the thermal polymerization of assembly of melamine and 2-aminoterephthalic acid, then post-calcination in LiCl–KCl molten salt, which was then used to degrade Rhodamine B (RhB) and Congo red (CR) via in situ generated H 2 O 2 . Significant findings Benzene and K + co-doping were critical both in increasing charge separation and enhancing the H 2 O 2 production. The yield of H 2 O 2 for KBCN was 57.5 μM in pure water after 60 min irradiation. In the absence of Fe 2+ , the in situ generated H 2 O 2 could subsequently degrade RhB and CR with the formed ·OH. The apparent rate constants of KBCN for RhB and CR degradation were 0.0446 and 0.0497 min −1 , respectively. The advantages of degradation with in situ generated H 2 O 2 in the absence of Fe 2+ can provide a new prospective to the environmental friendly Fenton-like reaction.
研究领域:
环境科学
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化学工程
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材料科学
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DOI
高影响因子
Inorganic Chemistry Frontiers
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2019
·Vol. 6
·期 6
·1490-1500
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IF 5.934
Yuanguo Xu,Jie Liu,Meng Xie,Wei Wei,Ting Zhou,Jia Yan,Hui Xu,Haiyan Ji,Huaming Li,Jimin Xie
In this study, NixFeyO4–BiOBr (NFB) composites with different etching degrees were successfully synthesized via a simple hydrothermal method. The etching degree was regulated by adjusting the pH during the synthesis process. The superiorities of the obtained materials can be outlined as follows: (i) BiOBr has the property of generating H2O2in situ; and (ii) NixFeyO4 nanoparticles in the composite could effectively promote the decomposition of H2O2, which proceeded via the two-electron reduction of O2 on the surface of BiOBr. The excellent properties of the prepared materials were confirmed through the photocatalytic degradation of bisphenol A under visible light irradiation, which is denoted as a solid–liquid-interfacial Fenton system. This work may pave the way for in situ H2O2 generation and decomposition; thus, the defects of traditional Fenton reaction systems, such as strict reaction conditions, high costs and secondary contamination after reactions, can be intelligently overcome.
研究领域:
环境科学
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材料科学
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产品关联
DOI
高影响因子
Desalination and Water Treatment
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2024
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IF 1
Lichun Fu,Tao Jin,Ruixuan Hu,Yuwei Pan,Yingjie Zhao
In recent years, dye wastewater caused serious effects on environmental ecology and human health. Thus, in the present study, hydroxylamine (HA) was used to improve the Fe 3 O 4 /H 2 O 2 process for removing the typical dye pollutant (tartrazine). Only 2.8% tartrazine could be removed in Fe 3 O 4 /H 2 O 2 system within 60 min at the reaction of 1 g/L Fe 3 O 4 , 1 mM H 2 O 2 , and pH 4 while 97.5% tartrazine could be removed within 20 min after adding 1 mM HA into the Fe 3 O 4 /H 2 O 2 system. Compared with Fe 3 O 4 /H 2 O 2 system, the removal rate for removing tartrazine in Fe 3 O 4 -HA/H 2 O 2 system could enhance more than 100 times. Electron paramagnetic resonance tests (EPR), radical quenching experiments and quantitative determination demonstrated that • OH was the major reactive species for removing tartrazine in Fe 3 O 4 -HA/H 2 O 2 system and • OH produced concentration in Fe 3 O 4 -HA/H 2 O 2 system was also much higher than that in Fe 3 O 4 /H 2 O 2 system. The key factors affecting tartrazine removal in Fe 3 O 4 -HA/H 2 O 2 system were also conducted. The optimal HA dosage, Fe 3 O 4 dosage, and H 2 O 2 dosage was 1 mM, 1 g/L and 1 mM. The optimal initial pH in Fe 3 O 4 -HA/H 2 O 2 system was 3, but compared with Fe 3 O 4 /H 2 O 2 system, the tatrazine removal efficiency could significantly improve under any initial pH condition. Fe 3 O 4 -HA/H 2 O 2 process had strong adaptability to inorganic ions and good applicability to different pollutants. Fe 3 O 4 -HA/H 2 O 2 process also exhibited good recycle ability for tartrazine removal. Overall, Fe 3 O 4 -HA/H 2 O 2 process is an effective and good practical applicability approach for dye wastewater treatment.
研究领域:
环境科学
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化学工程
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水处理
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DOI
高影响因子
MOLECULAR PHARMACEUTICS
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2023
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IF 4.9
Zhaomin Tang,Shuting Jiang,Wanlan Tang,Qian He,Huangzhao Wei,Chengyu Jin,Shuai Wang,Hui Zhang
Chemodynamic therapy (CDT) that involves the use of Fenton catalysts to convert endogenous hydrogen peroxide (H2O2) to hydroxyl radicals (·OH) constitutes a promising strategy for cancer therapy; however, insufficient endogenous H2O2 and glutathione (GSH) overexpression render its efficiency unsatisfactory. Herein, we present an intelligent nanocatalyst that comprises copper peroxide nanodots and DOX-loaded mesoporous silica nanoparticles (MSNs) (DOX@MSN@CuO2) and can self-supply exogenous H2O2 and respond to specific tumor microenvironments (TME). Following endocytosis into tumor cells, DOX@MSN@CuO2 initially decomposes into Cu2+ and exogenous H2O2 in the weakly acidic TME. Subsequently, Cu2+ reacts with high GSH concentrations, thereby inducing GSH depletion and reducing Cu2+ to Cu+ Next, the generated Cu+ undergoes Fenton-like reactions with exogenous H2O2 to accelerate toxic ·OH production, which exhibits a rapid reaction rate and is responsible for tumor cell apoptosis, thereby enhancing CDT. Furthermore, the successful delivery of DOX from the MSNs achieves chemotherapy and CDT integration. Thus, this excellent strategy can resolve the problem of insufficient CDT efficacy due to limited H2O2 and GSH overexpression. Integrating H2O2 self-supply and GSH deletion enhances CDT, and DOX-induced chemotherapy endows DOX@MSN@CuO2 with effective tumor growth-inhibiting properties alongside minimal side effects in vivo.
研究领域:
肿瘤学
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生物医学工程
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药理学
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产品关联
DOI
PubMed
高影响因子
CHEMICAL ENGINEERING JOURNAL
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2023
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IF 15.1
Jiahang Liu,Xiaoyang Li,Yingying Chu,Ling Yuan,Ruolin Lv,Weiming Zhang
The conventional Fe(III)/H 2 O 2 system is of low efficiency on the removal of most organic pollutants. However, we discovered that the Fe(III)/H 2 O 2 system was robust on remediating tetracycline (TC) in water (0.109 min −1 for the pseudo-first kinetic constant), and the reaction was even slightly faster than that in the conventional Fe(II)/H 2 O 2 system (0.105 min −1 ). The addition of TC could also initiate the degradation of other refractory pollutants in the Fe(III)/H 2 O 2 system. Complexation between Fe(III) and TC with the stoichiometric ratio of 1:1 was observed. Electron transfer from TC to Fe(III) gave rise to the slight production of Fe(II), which served as the initiator of the following Fenton reaction. •OH was ascertained as the main reactive species through quenching experiments, EPR tests and the probe method, while O 2 • − /HO 2 • was also a subsidiary contributor. Hydroquinone intermediates were proved to be generated through the hydroxylation of the benzene ring of the TC molecule by •OH and thus facilitate the reductive transformation of Fe(III) to Fe(II). This study analyzes the relationship between molecular structural features of TC and the catalytic efficiency of ferric Fenton-like reactions. We expect to shed light on new mechanistic insights on autocatalysis in the Fenton-like catalytic processes.
研究领域:
环境科学
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化学
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产品关联
DOI
高影响因子
Molecular Catalysis
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2023
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IF 4.6
Jing Li,Suxia Ma,Ke Ren,Nuo Xu
SSZ-13 zeolite was synthesized from fly ash using a combined alkali fusion hydrothermal method. The optimal synthesis parameters are as follows: NaOH/FA=1.4, SiO 2 /Al 2 O 3 =50, H 2 O/SiO 2 =1800, TMAda-OH/Al 2 O 3 =7, the amount of SSZ-13-seed=10%, and crystallization time and temperature were 160 °C and 40 h. Based on this, a series of fly ash-based Fe-SSZ-13 catalysts were prepared using three different methods and tested in catalytic oxidation with H 2 O 2 for NO removal. The experiment results showed that the NO removal efficiency catalyzed by Fe-SSZ-13-SSIE, Fe-SSZ-13-LIE and Fe-SSZ-13-IM were 78%, 87% and 84%, respectively. ESR was used to detect hydroxyl radicals, UV-vis, XPS and H 2 -TPR were applied to test the composition, state and distribution of iron species, while NH 3 -TPD and Py-FTIR were performed to analyze the intensity and type of acidic sites, and finally to determine the relationship between catalyst structure, active species and catalytic performance in combination with NO removal experiments. The catalytic oxidation mechanism analysis revealed that the excellent catalytic performance can be attributed to the dual function of strong Brønsted acidity on the surface and isolated Fe 3+ with high dispersion, which can rapidly decompose H 2 O 2 into ·OH and efficiently achieve NO oxidation. In conclusion, the preparation of fly ash catalysts has great potential for achieving the dual function of waste utilization and pollutant removal.
研究领域:
环境科学
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催化化学
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产品关联
DOI
高影响因子
JOURNAL OF ALLOYS AND COMPOUNDS
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2024
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IF 5.8
Yue Liu,Chunkai Wang,Ding Ma,Mengge Li,Yuting Sun,Xiaofei Sun,Yan Zhu,Bin Yao,Yongfeng Li,Zhanhui Ding
It is proved that secondary phases, such as Cu 2 Se, and ZnSe etc., and MoSe 2 layer can form at Cu 2 ZnSn(S,Se) 4 (CZTSSe)/Mo electrode interface, due to that Mo electrode reacts with CZTSSe and Se vapor during selenization process. The secondary phases and MoSe 2 with inappropriate thickness can decrease power conversion efficiency (PCE) of CZTSSe solar cell. In this work, a simple method was proposed to suppress the reaction between CZTSSe and Mo, and to optimize the thickness of MoSe 2 . This was achieved by growing a layer of Mo oxide in situ on the Mo electrode surface through soaking the Mo electrode in H 2 O 2 . The Mo oxide layer consisted of MoO 3 , MoO x and MoO 2 . It could suppress the reaction between Mo and CZTSSe, thus preventing the formation of secondary phases in CZTSSe. By further tuning the soaking time, the thickness and density of the Mo oxide layer were optimized, resulting in an optimized thickness of the MoSe 2 layer and a significant improvement in the contact quality at both the front and back interfaces. This improvement is beneficial for suppressing carrier recombination and reducing contact resistance. Furthermore, the Cu/(Zn+Sn) ratio in CZTSSe was optimized, leading to an expansion of the depletion region width. As a result, the reverse saturation current density and series resistance decrease, while the photogenerated current density increases. This ultimately led to a rise in PCE from 7.66% for CZTSSe solar cells with Mo electrodes that were not soaked to 8.95% for those with Mo electrodes soaked for 20 s.
研究领域:
材料科学
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能源技术
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产品关联
DOI
高影响因子
BIOSENSORS & BIOELECTRONICS
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2018
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IF 8.173
Xue Hu,Xidong Liu,Xiaodan Zhang,Hongxiang Chai,Yuming Huang
The fluorescent CuNCs/ZIF-8 nanocomposites were facilely prepared by mixing the PEI protected CuNCs with the precursors of ZIF-8, and characterized by UV–vis absorption, fluorescence, FT-IR, TEM , XRD and XPS . The quantum yield of the CuNCs/ZIF-8 is 15 times that of the PEI-CuNCs. Furthermore, the CuNCs/ZIF-8 possesses better stability and higher fluorescence response due to protective and confinement effects of MOFs . It was found that H 2 O 2 could cause much more quenching of fluorescent CuNCs/ZIF-8 than that of PEI-CuNCs, which might result from enriching H 2 O 2 by ZIF-8. The CuNCs/ZIF-8 can be designed as a fluorescence probe to selectively and sensitively detect H 2 O 2 with a linear range from 0.01 to 1.5 µM and a LOD of 0.01 µM, while those with PEI-CuNCs are 0.5–30 µM and 0.50 µM, respectively. Through formation of CuNCs/ZIF-8 hybrid, the sensitivity for the detection of H 2 O 2 increases by nearly 50-fold, which makes CuNCs/ZIF-8 a desirable probe to detect H 2 O 2 content in human serum samples. Also, we successfully demonstrated the potential application of the CuNCs/ZIF-8 for screening and evaluating activities of oxidase using glucose oxidase as a model. The glucose oxidase activity can be detected in a range of 0.1–10 mU/L with a LOD of 0.1 mU/L.
研究领域:
生物化学
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分析化学
✓ 已验证
DOI
PubMed
高影响因子
DYES AND PIGMENTS
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2022
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IF 5.122
Jian Wang,Haoyang Li,Weibo Xu,Bo Zhang,Yu Wang,Nan Chen,Qinghai Zhou,Tianrui Ren
A reversible colorimetric and ratiometric fluorescent probe ( QG-Py ) was developed for HSO 3 − detection. The probe showed large changes in absorbance and emission wavelength shift both with 155 nm when reacted with NaHSO 3 . Furthermore, probe QG-Py exhibited high selectivity and sensitivity to NaHSO 3 with quantitative analysis in real water samples through colorimetric and ratiometric methods. Interestingly, the reaction product ( QG-Py-SO 3 H ) displayed structural recovery to QG-Py induced by H 2 O 2 , accompanied with reversible optical properties . Probe QG-Py was established to visualize HSO 3 − /H 2 O 2 in MCF-7 cells. Importantly, QG-Py was also successfully applied for HSO 3 − /H 2 O 2 detection and imaging in rice roots and leaves, providing better understanding of the influence of SO 2 derivatives to crops, as well as a new and simple method for evaluating environmental pollution of SO 2 .
研究领域:
生物化学
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环境科学
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细胞生物学
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产品关联
DOI
高影响因子
Journal of Environmental Chemical Engineering
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2024
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IF 7.4
Yuzhu Xue,Weinan Wang,Yanhong Zhang,Qinhua Fan,Ying Zhang,Chen Ling,Yuwei Pan
This study proposes a green purification strategy in which mild decomplexation of Ni-EDTA into other Ni complexes facilitates the efficient removal and recovery of nickel through resin adsorption. Decomplexation of Ni-EDTA by boron/Fe 2+ /H 2 O 2 (B/Fe 2+ /H 2 O 2 ) followed by resins adsorption was conducted for Ni(II) removal in Ni-EDTA. The Ni(II) removal efficiency could only achieve 1.3 % and 6.2 % while Ni(II) coexisted with EDTA but more than 10 times of higher when Ni(II) coexisted with EDTA-relatives via the single adsorption of commercial heavy metal-affined resins (D001 and D463), which attributed to the increased binding energies of these Ni-EDTA’s degradation products complexes than Ni-EDTA based on density functional theory (DFT) calculation. In comparing to precipitation, the resin adsorption required much less mineralization of EDTA to have a better removal efficiency of Ni(II). B improved the efficiency of Ni-EDTA decompexation by accelerating the recycle of Fe 3+ /Fe 2+ . The EDTA (and TOC) removal enhanced from 48.7 % (4.7 %) to 94.7 % (11.9 %) by B/Fe 2+ /H 2 O 2 process comparing to Fe 2+ /H 2 O 2 process. With the high EDTA but low TOC removal efficiency after B/Fe 2+ /H 2 O 2 treatment, Ni(II) removal efficiency via resins adsorption could maximum achieve 80.5 %, 2–3 times of that via regular precipitation method. In addition, B and resins exhibited good reusability in five cycles, and B/Fe 2+ /H 2 O 2 -resins process had excellent adaptability to different heavy metal complexes. B/Fe 2+ /H 2 O 2 -D463 system not only could reduce 78.4 % reagents cost compared with that of Fe 2+ /H 2 O 2 -precipitation process, but also could save much cost than other processes. The results provide new insights for the cost-effective treatment of EDTA-complexed heavy metal wastewater.
研究领域:
环境科学
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化学工程
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产品关联
DOI
高影响因子
ENERGY & FUELS
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2022
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IF 4.654
Jing Li,Suxia Ma,Rongji Cui,Nuo Xu,Ting Pei
Solid waste fly ash can encroach on land, contaminate the environment, and jeopardize human health. An alkali fusion method combined with a hydrothermal method was adopted to prepare fly ash-derived ZSM-5 molecular sieves, and a series of Fe/ZSM-5 catalysts were also prepared to test their catalytic performance in NO oxidation with H2O2. Moreover, the characteristics of catalysts synthesized by fly ash, as well as the relationship between the structure and the catalytic activity, were analyzed in detail through multiple characterization approaches. The results gave important insights into the active sites of catalytic oxidation. They concluded that 10% Fe/ZSM-5 had the best catalytic activity in which Fe sites and Brønsted acid sites collectively provided the catalytic functionality, and 92% NO removal efficiency was obtained achieved under optimal experimental conditions. This work provided a new way for recycling fly ash and developing low-cost catalysts for NO removal.
研究领域:
环境科学
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催化化学
✓ 已验证
DOI
高影响因子
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