INTERNATIONAL JOURNAL OF POLYMER ANALYSIS AND CHARACTERIZATION
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2017
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IF 0
Jiale Cui,Zhihua Zhou,Yun Yang,Wenjuan Liu,Yunfei Zhao,Cheng Peng,Tianlong Huang,Hu Zhou,Lihua Liu,Qiao Zhang
In order to improve hydrophilicity and settle the acidity in hydrolysis, a novel ethanediamine (EDA) and maleic anhydride (MAH) modified poly(D,L-lactide-co-glycolide) (PLGA) polymer (EMPLGA) was synthesized. Fourier Transform Infrared Spectrometer (FTIR), Gel Permeation Chromatography (GPC), Nuclear Magnetic Resonance (1HNMR), titration and the water contact angles were employed to characterize the synthesized polymer. The effects of various polymerization conditions on weight average molecular mass (Mw), polydispersity index (PDI) and anhydride content of MPLGA were investigated. The degradation behaviors of PLGA, MPLA and EMPLGA were also studied by observation of the changes of the pH value of incubation medium, molecular weight and weight loss ratio for a time interval of 25 days in-vitro, respectively. The results showed that MPLGA with high anhydride content was successfully obtained by directly ring-opening polymerization and ethanediamine was further grafted onto MPLGA, and there is almost unchanged in Mw between MPLGA and EMPLGA polymers. The introduction of anhydride and amino groups improved the hydrophilicity of PLGA. A uniform degradation of EMPLGA was observed in comparison with an acidity-induced auto-accelerating degradation featured by PLGA and MPLGA. The results revealed that the introduction of ethanediamine into PLGA has weakened or neutralized the acidity of PLGA degradation products.
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RESEARCH ON CHEMICAL INTERMEDIATES
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2017
·Vol. 44
·期 1
·491-502
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IF 1.369
Li Shaoxin,Zhao Bing,Kan Wei,Wang Liyan,Song Bo,Chen Shuwen
A novel pH fluorescence probe (PIF), derived from phenanthro[9,10- d ]imidazole bound to the fluorescein, is designed and synthesized based on the intramolecular hydrogen bond and then its spectra properties are investigated. Probe PIF exhibits negligible fluorescence intensity at acidic pH condition due to ESIPT quenching caused by the formation of the intramolecular hydrogen bonds, and a significant fluorescence enhancement in neutral and weak alkaline environments because of the strengthened ICT process arose from the fracture of the intramolecular hydrogen bonds. The studies of UV–Vis and fluorescence spectra mean that probe PIF is able to respond linearly and reversibly over pH from 6.5 to 9.0 with p K
a of 7.0. Moreover, the pH responses of probe PIF are stable and not disturbed by the common cations and anions. The possible response mechanism has been proposed according to the analysis of 1 H NMR and DFT calculations.
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APPLIED SURFACE SCIENCE
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2017
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IF 3.387
Xiao Shang,Kai-Li Yan,Zi-Zhang Liu,Shan-Shan Lu,Bin Dong,Jing-Qi Chi,Xiao Li,Yan-Ru Liu,Yong-Ming Chai,Chen-Guang Liu
Oxidized carbon fiber (oCF) as support successfully realizes the vertical growth of uniform WS 2 nanosheets arrays for efficient hydrogen evolution reaction (HER) via a facile hydrothermal process. Thanks to oxygen functional groups on oCF, vertical WS 2 nanosheets structures have grown more easily on oCF, which can provide better dispersion, short charge transfer distance and more exposed active sites for HER in comparison with bulk WS 2 and WS 2 nanosheets on bare carbon fiber (CF) fabricated at the same condition. The electrochemical measurements confirmed that WS 2 /oCF possesses better HER activity than bulk WS 2 and WS 2 /CF. Especially, the 10-h stability with unchanged vertical WS 2 nanosheets morphology further demonstrate the positive effect of oxygen functional groups on the enhanced vertical structure and close combination between WS 2 and oCF. It may offer a facile way to realize more exposed active sites from stable electrocatalyst hybrids of transition metal sulfides by surface oxidization of carbon supports.
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SEPARATION AND PURIFICATION TECHNOLOGY
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2016
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IF 3.299
Xi Zhang,Jiawei Wang,Shaofeng Chen,Zongbi Bao,Huabin Xing,Zhiguo Zhang,Baogen Su,Qiwei Yang,Yiwen Yang,Qilong Ren
Preparation of a novel hybrid boron-selective adsorbent with N- methyl- d -glucamine functional groups was reported. The adsorbent was synthesized by inverse suspension polymerization method based on chemistry of sol-gel reaction. The structure and morphology of the hybrid adsorbent were characterized by MS, FTIR, XPS, BET analysis and PXRD , etc. The perfectly spherical hybrid adsorbent exhibits exceptionally efficient adsorption of boric acid from the aqueous solution. The boron adsorption behavior on the adsorbent was investigated by varying the dosages of the adsorbent, pH, and competitive ions. The adsorption isotherm was in better accordance with the Langmuir model, exhibiting a theoretical maximum adsorption capacity of 2.02 mmol/g. The adsorption capacity peaks at pH ∼ 9 due to the vast formation of stable tetrahedral structure between dominant B(OH) 4 − and the adsorbent. The presence of Na + ions has slight effect on boron adsorption while Mg 2+ cations significantly enhanced the adsorption capacity because of the simultaneous adsorption attributed by Mg(OH) 2 .
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ChemCatChem
·
2016
·Vol. 9
·期 3
·458-464
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IF 4.724
Ting Yang,Lan-Lan Lou,Wenjun Yu,Yajun Feng,Hao Li,Kai Yu,Shuangxi Liu
Graphical Porous but extraordinarily durable : 3 D ordered macroporous alumina–carbon composite supported Pt nanocatalysts are applied in the asymmetric hydrogenation of ethyl pyruvate. They exhibit high catalytic activity and extraordinary durability. The three-dimensionally ordered macroporous alumina-carbon composite materials were firstly prepared through a surfactant-assisted colloidal crystal template method and applied to support Pt nanoparticles. The results of SEM, XRD, TEM, and N 2 sorption analyses revealed that these composite materials possessed highly ordered macroporous structures with meso- and micropores within the skeletons of macropores and that the Pt nanoparticles were well dispersed on these materials with a very narrow size distribution. These prepared Pt nanocatalysts were evaluated in the asymmetric hydrogenation of ethyl pyruvate after chiral modification with cinchonidine. Excellent catalytic activity and enantioselectivity were achieved. More importantly, these catalysts exhibited extraordinary stability and reusability during the reaction and could be reused at least 26 times without significant loss in catalytic activity and enantioselectivity.
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FOOD RESEARCH INTERNATIONAL
·
2025
·
IF 8
Zirou Xiao,Shuang Wu,Hongshan Liang,Bin Li,Jing Li
The reduction of sucrose in dough formulations disrupts mechanical properties, fermentation performance, and structural organization, leading to rigidity and impaired gas retention. This study investigated how composite improvers—oligosaccharides (XOS/KOS), CMCNa, and D-allulose—mitigate these challenges by restoring viscoelastic balance, enhancing fermentation, and stabilizing protein and starch interactions. Correlation analysis was further conducted to explore the complex relationships between these parameters. Results revealed that D-allulose optimized gas retention by contributing to a denser gluten network, achieving the highest retention rate of 90.92 %. Oligosaccharides improved water availability, promoting gluten development and enhancing starch gelatinization, while CMCNa strengthened the gluten network through its binding and film-forming properties, collectively increasing fermentation height by 79.78 % compared to sugar-reduced dough. These structural improvements were further confirmed by SEM images, which revealed a more uniform microstructure with continuous gluten films encapsulating starch granules. These findings elucidate the mechanisms underlying the deterioration of sugar-reduced dough and highlight the potential of composite improvers in mitigating the adverse effects of sucrose reduction, paving the way for the development of high-quality sugar-reduced products.
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PubMed
高影响因子
Small
·
2024
·
IF 13
Yaqi Li,Sijie Wan,Weichen Liang,Bei Cheng,Wang Wang,Yao Xiang,Jiaguo Yu,Shaowen Cao
Owing to the improved charge separation and maximized redox capability of the system, Step-scheme (S-scheme) heterojunctions have garnered significant research attention for efficient photocatalysis of H 2 evolution. In this work, an innovative linear donor–acceptor (D–A) conjugated polymer fluorene-alt-(benzo-thiophene-dione) (PFBTD) is coupled with the CdS nanosheets, forming the organic–inorganic S-scheme heterojunction. The CdS/PFBTD (CP) composite exhibits an impressed hydrogen production rate of 7.62 mmol g −1 h −1 without any co-catalysts, which is ≈14 times higher than pristine CdS. It is revealed that the outstanding photocatalytic performance is attributed to the formation of rapid electron transfer channels through the interfacial Cd─O bonding as evidenced by the density functional theory (DFT) calculations and in situ X-ray photoelectron spectroscopy (XPS) analysis. The charge transfer mechanism involved in S-scheme heterojunctions is further investigated through the photo-irradiated Kelvin probe force microscopy (KPFM) analysis. This work provides a new point of view on the mechanism of interfacial charge transfer and points out the direction of designing superior organic–inorganic S-scheme heterojunction photocatalysts.
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JOURNAL OF COLLOID AND INTERFACE SCIENCE
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2024
·
IF 9.4
Yuci Xin,Yong Wu,Xingan Dong,Yuhan Li,Zhenxiang Cheng,Jianli Wang,Xiaolong Guo,Peng Yu
Amorphous electrocatalysts display several unique advantages in electricity-driven water splitting compared to their crystalline analogs, but understanding their structure–activity relationships remains a major challenge. Herein, we show that the d- and p-electronic states of amorphous Ni-Fe-B can be subtly manipulated by varying the Ni and Fe contents. The optimal Ni-Fe-B alloy exhibits a high performance in the oxygen evolution reaction (OER), as supported by its impressive stability (no clear degradation after 100 h) and considerably lower overpotential compared to those of its crystalline analogs. Based on theoretical calculations, different Ni and Fe contents can cause significant shifts in the d-band levels of Ni and Fe and the p-band level of B, thus altering the OER activity. Additionally, the energy difference between the d- and p-band centers (ΔE ad-p ) may be an effective index for use in reflecting the structure–activity relationship of an amorphous Ni-Fe-B alloy in the OER. An amorphous Ni-Fe-B alloy with a smaller ΔE ad-p displays a higher intrinsic activity. This study supplies a unique direction for use in constructing the structure–activity relationships of amorphous electrocatalysts by revealing the role of ΔE ad-p , which promotes fundamental research and the practical application of amorphous electrocatalysts.
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INTERNATIONAL IMMUNOPHARMACOLOGY
·
2025
·
IF 4.7
Zhen He,Xiangyun Tan,Ming Yuan,Liang Chen,Yan Meng,Qi Wang,Junjie Hu,Zhenpeng Qiu,Yuan Yang
Acute liver injury (ALI) is a prevalent form of hepatic disease associated with significant morbidity and mortality due to medical treatments, exposure to toxins or viral infections. Anethole trithione (ATT) is a heterocyclic sulfur compound recognized for its chemoprotective properties against cancer and drug-induced toxicity. This study aimed to evaluate the effectiveness of ATT in the treatment of ALI. The therapeutic effects of ATT on hepatic injury were evaluated in vivo by inducing ALI in mice through the administration of lipopolysaccharide (LPS) and D-galactosamine (D-Gal). Additionally, HepG2 and Huh7 cells exposed to LPS were utilized to investigate the underlying mechanisms in vitro. The results indicated that ATT significantly reduced the production of reactive oxygen species (ROS), mitigated oxidative stress-related biochemical markers, and inhibited hepatocyte apoptosis in vivo, resulting in marked improvement in ALI in the murine model. Mechanistic studies conducted both in vivo and in vitro demonstrated that ATT alleviates LPS/D-Gal-induced ALI by inhibiting ROS production and the activity of nuclear factor-kappa B (NF-κB). Collectively, these findings underscore the potential therapeutic benefits of ATT in the management of ALI.
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SEPARATION AND PURIFICATION TECHNOLOGY
·
2024
·
IF 8.1
Boliang Li,Binfei Li,Liping Du,Teng Lu,Guolin Shao,Zhaomin Li,Mengyuan Zhang,Junhao Zhang
High carbon emissions and low efficiency in thermal utilization are pivotal challenges in heavy oil development. Addressing the urgent need to enhance heavy oil production, this paper introduces an innovative approach in which aerogel and flue gas serve as supplementary additives in steam thermal recovery. To investigate the mechanisms behind the improved heat transfer and oil recovery facilitated by the combination of aerogel and flue gas, condensation heat transfer experiments and 2-D visual oil displacement experiments were carried out. The condensation heat transfer coefficient, oil displacement performance, and heat utilization efficiency were analyzed and compared. The results showed the porous structure of the aerogel enhances its thermal insulation properties by adsorbing flue gas, thereby reducing the steam-to-cold object condensation heat transfer coefficient by 60.6%. The cementation between aerogel nanoparticles (NPs) retained in the formation and rock particles formed an insulating layer that impedes the upward propagation of steam heat. Combined with efficacy of flue gas foam in improving fluid flow, this promoted the horizontal expansion of the steam chamber, resulting in an 8.2% and 3.4% increase in the steam chamber’s extent compared to using steam and a combination of steam with aerogels, respectively. Moreover, the profile control and thermal insulation impacted following the NPs, lowering the water cut in the produced fluid and enhancing the oil recovery by 7.9%. Upon the application of flue gas, this enhancement in recovery extended to 9.3%.
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PESTICIDE BIOCHEMISTRY AND PHYSIOLOGY
·
2024
·
IF 4.2
Yao Yu,Xinru Li,Yiping Hou,Min Wei,Yiyun Qian,Yuxin Zhou,Min Yin,Yanqin Jiang,Pingping Song
Gray mold , caused by Botrytis cinerea is an intractable fungal disease that causes extensive damage to agricultural products. In the search for novel antifungal active ingredients, we discovered a linear pyranocoumarin Pd-D-V was effective against B. cinerea in both in vitro and in vivo assays. Furthermore, this study investigated the effects of Ca 2+ and the Ca 2+ -calcineurin signaling pathway on its antifungal activity against B. cinerea . The results indicated that Pd-D-V reduced the concentration of Ca 2+ in the mycelia of B. cinerea ; CaCl 2 , the Ca 2+ channel blocker verapamil , or the calcineurin inhibitor cyclosporin A could affect the sensitivity of Pd-D-V against B. cinerea ; the expression of genes ( Bccch1, Bcmid1, BccnA, Bccnb1, Bcpmc1, and Bcpmr1 ) of the Ca 2+ -calcineurin signaling pathway decreased after Pd-D-V treatment. In summary, Pd-D-V is compound for developing fungicides against B. cinerea . Pd-D-V can reduce intracellular Ca 2+ concentration and disturb Ca 2+ homeostasis . The Ca 2+ -calcineurin signaling pathway is important in the antifungal activity of Pd-D-V against B. cinerea .
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JOURNAL OF MOLECULAR LIQUIDS
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2024
·
IF 5.3
Zhouzhou Li,Zheng Li,Feng He,Wen He,Qixu Chen,Hongqing Wang
Recently, how to improve the photocatalytic uranium removal performance of Graphite-phase carbon nitride (GCN) has always been a hot research topic. In this paper, a new strategy based on p-n junction and D-A structure is proposed to improve the photocatalytic performance. And as a result, a novel cyano modified photocatalytic material NC-GCN/Ag 2 O was designed and prepared for the reduction of U(VI). Interestingly, the material shows better adsorption performance for U(VI) in the dark treatment stage, and its removal of U(VI) is close to 70 % under the initial U(VI) concentration of 20 ppm and the solid–liquid ratio of 0.2 g/L. And the adsorption is in accordance with the Langmuir model and Pseudo second order model. After 30 min of illumination, the removal rate of U(VI) can reach 93.2 %, significantly higher than that of GCN (13.6 %) and NC-GCN 10 (37.7 %). It’s worth mentioning that photocatalytic reduction dominated the adsorption-reduction process for U(VI) removal after light exposure. In addition, after four cycles, the removal of U(VI) from the composite material decreased by only 5 % with no change in the crystal structure, i.e., it has good reusability and stability. Meanwhile, there was no significant interference with other ions except for Cu 2+ and V 5+ , which had a weak interference. Finally, a new mechanism for U(Ⅵ) reduction was proposed.
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