JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
·
2018
·Vol. 29
·期 16
·13925-13930
·
IF 2.324
Li Tianjing,Shi Qingle
In this paper, explain a new relationships between Bi 3+ content, the phase crystal, microstructure and conductivity for Sm and Bi co-doped Ce 0.8− x Sm 0.2 Bi x O 1.9−1/2 x ( x = 0, 0.05, 0.1, 0.15, 0.2) electrolytes prepared by co-precipitation method. The XRD patterns showed that this compounds exhibit a fluorite-type cubic structure after the samples calcined at 700 °C for 4 h and the cell volumes of increased when the Bi content increased. In addition, for the samples sintered at 1400 °C for 4 h, the Bi doping improves the relative density, the grain size and the average thermal expansion coefficient (TEC). More in details, the relative density and TEC increase with the Bi content. Form the AC impedance spectroscopy measurements, the conductivity of the sintered samples is found to improve with the increasing of Bi content (for x ≤ 0.15), which is ascribed to the increasing of the number of oxygen ion vacancies and the increase in the unit cell volume. However, the conductivity decreases when the Bi content is further increased (0.15 < x ≤ 0.2), which is ascribed the reduction of the number of free oxygen vacancies. The highest conductivity at 800 °C is 5.6 × 10 −2 S/cm and the activation energy is 0.83 eV for Ce 0.65 Sm 0.2 Bi 0.15 O 1.825 , indicating that this would be a promising electrolyte for the intermediate temperature-solid oxide fuel cell applications.
研究领域:
材料科学
·
无机非金属材料
·
固态离子学
·
能源材料
·
燃料电池
✓ 已验证
DOI
高影响因子
JOURNAL OF ALLOYS AND COMPOUNDS
·
2021
·
IF 5.316
Tianhang Zhang,Timothy D. Christopher,Saifang Huang,Tilo Söhnel,Yan'gai Liu,Peng Cao
In this work, we co-doped barium (Ba) and zirconium (Zr) in a lithium garnet oxide , to improve its electrochemical properties . In the doping range of y = 0–1.0, the Li 6+y La 3−y Ba y NbZrO 12 (LLBNZO) oxides maintain a cubic crystal structure. A secondary phase of BaZrO 3 emerges when y ≥ 0.75. The ionic conductivity of the developed garnet oxides first increases with Ba-doping in the low doping range and then decreases in the high doping range. It reaches the maximum value in Li 6.5 La 2.5 Ba 0.5 NbZrO 12 when y = 0.5. Cyclic voltammetry shows that the garnet oxides have a wide electrochemical voltage window up to 6 V. The constant-current polarization results on the symmetric cells assembled from Li 6.5 La 2.5 Ba 0.5 NbZrO 12 reveal that this garnet oxide is chemically stable against metallic lithium and has stable cycling performance.
研究领域:
材料科学
·
电化学
·
固态离子学
·
能源材料
·
无机非金属材料
✓ 已验证
DOI
高影响因子
CATALYSIS TODAY
·
2017
·
IF 4.636
Nianjun Hou,Ping Li,Tianmu Lv,Tongtong Yao,Xueli Yao,Tian Gan,Lijun Fan,Pengzhi Mao,Yicheng Zhao,Yongdan Li
Sm 0.5 Ba 0.5 MnO 3-δ (SBMO) has been synthesized with the Pechini method and investigated as an anode material of solid oxide fuel cells with H 2 and methanol as fuels. A cubic perovskite structure is formed after reduction. The reduction process of SBMO is studied with X-ray photoelectron spectroscopy and temperature programmed reduction techniques. The electrical conductivities of an SBMO sample sintered at 950 °C are 1.15 and 0.10 S cm −1 at 850 °C in air and H 2 , respectively. A single cell with an SBMO anode layer and a 300-μm La 0.8 Sr 0.2 Ga 0.8 Mg 0.2 O 3-δ electrolyte layer exhibits a maximum power density ( P max ) of about 150 mW cm −2 at 850 °C with H 2 as fuel. The electrical conductivity of the anode layer with methanol as fuel is improved by the moderate carbon deposition, and the P max increases to about 415 mW cm −2 . The cell fed with methanol also shows a promising stability.
研究领域:
材料科学
·
能源化学
·
电化学
·
无机非金属材料
·
燃料电池技术
✓ 已验证
DOI
高影响因子
RSC Advances
·
2016
·Vol. 6
·期 79
·75359-75364
·
IF 3.289
Chunmei Li,Furen Zhang
A series of pyrrolo[2,3,4-kl]acridin-1-one derivatives were successfully synthesized from facile materials (enaminone and isatin) using a reusable solid acid as catalyst in water. A variety of structurally diverse enaminones and various isatins bearing different functional groups tolerated the reaction and gave the corresponding goal products with good to excellent yields. Advantages of this strategy include the mild conditions, operational simplicity, being convenient and environmentally benign, and the reusability of the heterogeneous catalyst. A mechanism was proposed to explain the formation of different substituted pyrrolo[2,3,4-kl]acridin-1-one derivatives.
研究领域:
有机化学
·
药物化学
·
绿色化学
·
杂环合成
·
催化化学
✓ 已验证
DOI
高影响因子
CERAMICS INTERNATIONAL
·
2019
·Vol. 46
·期 4
·4720-4729
·
IF 3.45
Guojiao Ding,Rujie He,Keqiang Zhang,Min Xia,Chengwei Feng,Daining Fang
Stereolithography based additive manufacturing provides an effective method to fabricate complex-shaped SiC ceramic components. The dispersion and stability of the ceramic slurry are very important for stereolithography. In this study, the dispersion and stability of SiC ceramic slurries were investigated systematically. The effects of resin monomers , dispersants , particle size, solid loading and ball milling time on the dispersion, rheological behavior and stability of SiC ceramic slurries were studied in detail. Finally, an optimal SiC ceramic slurry for stereolithography based additive manufacturing was obtained, and complex-shaped SiC ceramic architectures were fabricated.
研究领域:
材料科学
·
先进制造
·
陶瓷工程
·
高分子材料
·
复合材料
✓ 已验证
DOI
高影响因子
CHEMICAL ENGINEERING JOURNAL
·
2024
·
IF 13.3
Chenyu Lin,Tianqi Yang,Haiyuan Zhang,Donghuang Wang,Wenkui Zhang,Yao Wang,Yang Xia,Hui Huang,Xinhui Xia,Yongping Gan,Xinping He,Xinyong Tao,Jun Zhang
Solid-state lithium metal batteries with high energy density and safety have gained increasing attention due to their potential applications. However, the practical use of solid electrolytes is hindered by several challenges. These include poor compatibility at the electrode–electrolyte interface, low ionic conductivity at room temperature, and fast capacity degradation. To address these issues, here we propose ternary strategies by in-situ cross-linked plastic crystal electrolyte (in-situ PCE) based on succinonitrile (SN). Through the in-situ polymerization of SN with polyacrylonitrile/poly(vinylidene difluoride) (PAN/PVDF) nanofibers separator, excellent mechanical strength and compatibility at the electrode–electrolyte interface are achieved. The cross-linked structure of thermally polymerized ethoxylated trimethylolpropane triacrylate (ETPTA) immobilizes the SN molecule, preventing its contact with the lithium metal and inhibiting irreversible side reactions. Additionally, a LiF-rich passivation layer is employed to further protect the SN at the electrolyte-lithium metal interface. The dual protection from ETPTA and LiF offers excellent stability to lithium. Hence, the in-situ PCE exhibits high ionic conductivity (0.79 mS cm −1 at 30 °C) and wide electrochemical window (4.56 V, vs Li + /Li). The cells exhibit excellent cycling stability and high-rate performance. LiFePO 4 //Li cells retain 96.6 % capacity after 1000 cycles at 10C rate. This study provides valuable insights into the development of high-performance solid-state electrolytes.
研究领域:
材料科学
·
电化学
·
能源存储
·
高分子化学
·
固态离子学
✓ 已验证
DOI
高影响因子
Asia-Pacific Journal of Chemical Engineering
·
2022
·Vol. 17
·期 4
·e2769
·
IF 1.777
Hao Qiu,Shanshan Jiang,Yingjie Niu,Qi Zhang,Yingping Pang,Chao Su
The electrochemical performance of solid oxide fuel cells (SOFCs) is highly reliant upon the properties of cathodes, including crystal structure, electrical conductivity, electrode thickness, and so on. Here, Ba 0.5 Sr 0.5 Co 0.8 Fe 0.2 O 3-δ (BSCF) is synthesized and served as the electrode for enabling high-performance SOFCs. The effect of electrode thickness on the electrocatalytic activity is systematically investigated. The electrode thickness is adjusted in two ways. One is spray-coating and then calcining once, and the other is performing the above process twice. On the basis of symmetrical cells configuration, the oxygen reduction reaction (ORR) activity of BSCF electrode with different thickness is evaluated and analyzed by the electrochemical impedance spectroscopy (EIS) technique and distribution of relaxation time (DRT). The obtained area-specific resistances (ASRs) of electrodes on the oxygen ion conducting electrolyte Sm 0.2 Ce 0.9 O 1.90 (SDC) demonstrate the thickness-dependent electrochemical activity in ORR of BSCF electrode. With an electrode thickness of 24 μm that controlled by conducting “spray-coating and calcining” twice, the BSCF electrode displays the optimal electrochemical performance with an ASR of 0.072 Ω cm 2 in ambient air at 600°C. This strategy has allowed us to produce an electrode layer with optimal thickness, paving a new path for the design of high-performance SOFCs.
研究领域:
材料科学
·
电化学
·
能源材料
·
固体离子学
·
燃料电池技术
✓ 已验证
DOI
高影响因子
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
·
2022
·Vol. 47
·期 79
·33861-33871
·
IF 7.139
Zhizhong Leng,Zuzhi Huang,Xu Zhou,Bo Zhang,Hu Bai,Juan Zhou,Shaorong Wang
Proton-conducting solid oxide electrolysis cells (H-SOECs) are attracting attentions of researchers due to their unique advantages. The proton-conducting material BaCe 0·7 Zr 0·1 Y 0.1 Yb 0.1 O 3-δ (BZCYYb) has both the advantages of barium ceria-based and barium zirconate-based materials. BZCYYb material usually is synthesized by solid-state reaction (SSR) method, hence the densification of this electrolyte material is the key to restrict the application of H-SOECs. In this paper, effects of adding 1 wt% of different sintering aids (NiO, CuO, ZnO) to BZCYYb on the grain size and the conductivity are investigated. After adding 1 wt% of NiO and CuO sintering aids, BZCYYb electrolyte achieves ideal density. The electrical conductivity of four samples (BZCYYb without adding sintering aid, BZCYYb with 1 wt% NiO, CuO, ZnO, respectively) is tested under different steam concentrations of air, nitrogen, hydrogen, and nitrogen-hydrogen mixture. The conductivity increased after the sintering aid is added. With the increase of steam concentration, the conductivity decreased slightly and then increased due to electron holes under oxygen atmosphere with steam at high temperature. In other atmospheres, the conductivity increases with the steam concentration. In the atmosphere of 20 vol% H 2 O-Air and H 2 , the conductivity of the BZCYYb samples with 1 wt% CuO is about 1.087 × 10 −2 S cm −1 and 9.02 × 10 −3 S cm −1 at 650 °C, and the conductivity of the BZCYYb samples with 1 wt% NiO is 1.277 × 10 −2 S cm −1 and 8.24 × 10 −3 S cm −1 , respectively. However, compared with NiO, CuO has advantages in promoting hydration reaction and proton conduction of BZCYYb electrolyte.
研究领域:
材料科学
·
电化学
·
能源材料
·
固态离子学
·
陶瓷材料
✓ 已验证
DOI
高影响因子
JOURNAL OF POWER SOURCES
·
2021
·
IF 9.127
Jingxiong Gao,Songyi Han,Haiming Hua,Jie Wu,Jing Zeng,Yuanyu Sun,Weiping Tang,Shuling Liu,Jinbao Zhao
To optimize the electrochemical behavior of NCM-based high-energy lithium-ion batteries (LIBs) in wide temperature ranges, Phenyl trifluoromethane sulfonate (PTM) is demonstrated as the novel electrolyte additive to enhance the electrochemical behavior of LiNi 0·6 Co 0·2 Mn 0·2 O 2 /graphite cells at 25 °C, −20 °C and 45 °C. The cells with 1.0 wt% PTM-containing electrolyte deliver 80.6% capacity retention after 350 cycles at 25 °C, 73.4% after 100 cycles at −20 °C, and 82.6% after 300 cycles at 45 °C, which are significantly higher than that in standard electrolyte (STD), corresponding to 36.4% at 25 °C, 40.3% at −20 °C, and failure at 45 °C, respectively. According to density functional theory (DFT) simulations and quantitative calculations, the PTM preferentially reduces on the anode and oxidizes on the cathode to participate in the formation of solid electrolyte interphase (SEI) films. In addition, the scanning electron microscopy (SEM), Transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS) and other analysis suggest that the formed SEI films are thinner and more stable for the electrolyte containing PTM, and the formed SEI films effectively control the decomposition of carbonate-based electrolytes and greatly decrease the increased resistance during the cycle.
研究领域:
电化学
·
材料科学
·
能源存储
·
锂电池技术
·
界面化学
✓ 已验证
DOI
高影响因子
ELECTROCHIMICA ACTA
·
2015
·
IF 4.504
Xinhe Yang,Zicheng Zuo,Haiyan Wang,Quanbin Chen,Hui Zhang,Zhenlei Huang,Borong Wu,Henghui Zhou
A one-step synthesis method is developed to prepare the Li[Ni 0.5 Co 0.2 Mn 0.3 ]O 2 (NCM 523) cathode with uniform tungsten-coating layer for lithium-ion battery . Such modified material shows similar properties with the bare NCM 523 in terms of the primary particles, secondary structure , and specific capacity. With W coating layer , the NCM 523 gives remarkable improvement in the long-term capacity retention in the half-cell testing, which is sharply inconsistent with the result from the full-battery tests, indicating a contradiction between the half-cell and full-battery tests in some case. After further investigations, such conflict between the half-cell and full-cell tests in evaluating the W-coating strategy is attributed to the dissolution of Li 2 WO 4 layer in the electrolyte, which probably destroys the solid electrolyte interface (SEI) on the graphite anode and irreversibly consumes the active lithium ions for renovating SEI in full-cell testing. These results will benefit researchers in the area of lithium-ion batteries to fully understand the differences between the half-cell and full-cell testing, and develop the effective strategies for cathode modifications.
研究领域:
电化学
·
材料科学
·
能源存储
·
电池技术
·
表面改性
·
固态离子学
✓ 已验证
DOI
高影响因子
FUEL
·
2021
·
IF 6.609
Hongsheng Yu,Suhang Chen,Xiaodong Yu,Wei Zhang,Christian Paravan,Luigi T. DeLuca,Ruiqi Shen
The slow regression rate induced by the difficulty of pyrolysis has limited the practical application of hydroxyl-terminated polybutadiene (HTPB)-based fuels for hybrid rocket propulsion. A possible strategy is the use of suitable transition metal elements promoting polymer matrix thermal decomposition of fuels. This paper investigates the effects of nickel acetylacetonate, Ni(acac) 2 , on the thermal stability and combustion of HTPB-based fuel formulations. The presented experimental results show that the addition of Ni(acac) 2 can intensely decrease the thermal stability of HTPB thus enhancing the solid fuel regression rate even at a small additive mass fraction: under an oxygen mass flux of 50 kg/m 2 s, HTPB + 5 wt% Ni(acac) 2 shows a 25.5% increase over the non-loaded baseline. Kinetics analyses reveal that the catalytic effect is mainly induced by the Ni 2+ in Ni(acac) 2 at the early stage of decomposition, and by the NiO produced from the oxidative decomposition of Ni(acac) 2 in the fuel final degradation stage. On the other hand, the addition of Ni(acac) 2 decreases the combustion heat of HTPB-based fuels significantly and implies the accumulation of its decomposition products (much metal Ni, moderate elemental C, and a little NiO.) at the fuel regressing surface. Eventually, when the content of Ni(acac) 2 exceeds 5 wt%, the growth of regression rate slows down rapidly, and a performance detriment occurs at 40 wt%. This study verifies the catalytic effect of Ni(acac) 2 on polymer matrix for HTPB based fuels showing the attractive regression rate performance of this additive.
研究领域:
推进剂化学
·
燃烧学
·
高分子材料科学
·
航天动力工程
·
催化化学
✓ 已验证
DOI
高影响因子
ELECTROCHIMICA ACTA
·
2022
·
IF 7.336
Feihong Zhang,Qiaohang Weng,Yanxiang Zhang,Na Ai,San Ping Jiang,Chengzhi Guan,Yanqun Shao,Huihuang Fang,Yu Luo,Kongfa Chen
Solid oxide fuel cells (SOFCs) are the most efficient energy conversion technology to convert the chemical energy of fuels like hydrogen, natural gas, etc. to electricity. However, one of the limiting factors in the commercial viability of SOFCs technologies is the time-consuming and high-cost multiple cell fabrication processes. Here, we report the development of a facile procedure for the preparation of an electrolyte-supported cell with a Ni-Gd 0.1 Ce 0.9 O 1.95 composite anode and a La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3-δ cathode, and the fabrication procedure of the electrodes decreases from four steps of screen-printing and sintering of conventional cell preparation processes to two steps of screen-printing using a direct assembly approach without the high-temperature sintering steps. The most important observation is the simultaneous formation of the electrode/electrolyte interfaces of both the anode and cathode by in situ passing a current through the directly assembled cells at 800 ℃. The power density of the directly assembled cell reaches 0.41 W cm −2 at a voltage of 0.7 V and 800 ℃, close to 0.46 W cm −2 of the sintered cell. The directly assembled cell shows comparable operational stability to the sintered cell at 800 ℃ for 100 h. This work sheds light on the facile fabrication of electrolyte-supported cells with substantially simplified preparation procedures and reduced costs.
研究领域:
材料科学
·
能源化学
·
电化学
·
燃料电池技术
·
无机功能材料
✓ 已验证
DOI
高影响因子
危险品化学品经营许可证（带存储）