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CERAMICS INTERNATIONAL · 2020 ·Vol. 47 ·期 4 ·5028-5037 · IF 3.83

Preparation and anisotropic tribological properties of MoAlB/Al laminated composites

Qinhuan Wang,Dong Zhao,Mengqi Li,Fuqiang Ren,Chunyang Duan,Zenghua Zhao,Yunfa Chen,Yu Wang

The unique microstructure of biomaterials provides inspiration in materials structure design and performance breakthroughs. Here we prepared a MoAlB reinforced Al matrix composites with laminated structure and strong interfacial bonding. This work mainly focuses on the relationship between tribological properties of the MoAlB/Al laminated composites and the MoAlB layer orientation. The results show that the tribological properties of the composites deeply depend on the relation of sliding direction VS. the MoAlB layer orientation, while the dependency gradually decreases with the MoAlB content increasing. The friction coefficient and wear rate of the composites can be decreased by 55.5% and 95.1%, lower than those of pure Al, when 15 vol% MoAlB reinforcement is added. The friction and wear mechanisms of the MoAlB/Al laminated composites are proposed, and the outstanding tribological properties are ascribed to the formation of tribochemical worn film and different stress states caused by the laminated structure.

研究领域: 材料科学 · 复合材料工程 · 表面工程 · 摩擦学 · 结构-性能关系
✓ 已验证 DOI 高影响因子
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TRIBOLOGY LETTERS · 2019 ·Vol. 67 ·期 1 ·1-17 · IF 2.235

RETRACTED ARTICLE: Effects of Copper Nanoparticles Located in Different Regions of Polytetrafluoroethylene/Polyimide Blends on the Morphology, Mechanical and Tribological Properties of PTFE Composites

Zhao Yuanliang,Qi Xiaowen,Zhang Wenli,Fan Bingli,Yang Qingxiang

The effects of copper nanoparticles (Cu) located in different regions of polytetrafluoroethylene/polyimide (PTFE/PI) blends on the morphology, thermal, mechanical, and tribological properties of PTFE composites were studied. Region one is PI phases (the corresponding composites is denoted as PPC), region two is PTFE phases and the interface between PTFE and PI (the corresponding composites is denoted as PPC-m). Results indicate that the incorporation of Cu nanoparticles into PI phases improves the dispersibility and homogeneity of PI phases. As a consequence, the crystallinity of PTFE composites is reduced, but compressive strength and modulus of PTFE composites are enhanced by 50.3% and 14.4% respectively. In addition, self-lubricity and wear resistance of PTFE composites are improved by 10.4% and 50.5%. Scanning electron microscopy (SEM) demonstrates that PI phases with Cu nanoparticles hinder the direct contact between PTFE matrix and counterparts. However, Cu nanoparticles located in PTFE matrix and the interface between PTFE and PI deteriorates the dispersibility and homogeneity of PI phases, which lead to the poor mechanical and tribological performance of PTFE composites.

CAS / MDL: 2530-83-8
研究领域: 材料科学 · 纳米技术
✓ 已验证 产品关联 DOI 高影响因子
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CERAMICS INTERNATIONAL · 2020 ·Vol. 47 ·期 5 ·5918-5928 · IF 3.83

Microstructure and mechanical properties of Ti–C–TiN-reinforced Ni204-based laser-cladding composite coating

Yu Zhao,Tianqi Zhang,Liaoyuan Chen,Tianbiao Yu,Jiayu Sun,Chuang Guan

In situ Ti(C, N), ring phase, and multi-phase enhanced Ni204-based alloy coating were prepared by adding various Ti/C/TiN ratios particles. The effects of the reinforcement phase on the microstructure, microhardness , tribological property, and microstructure characteristics at the interface between the coating and substrate were investigated. The results show that the coatings with a 5:1 mass fraction ratio of TiN/C exhibits the highest microhardness , which is 3.78 times higher than that of the original Ni204 coating. While, the coating with 21:7:2 mass fraction ratio of TiN/Ti/C exhibits the lowest friction coefficient , which is 4.44 times smaller than that of the original Ni204 coating. The addition of Ti and C particles promotes the precipitation of ring phase and carbides , reduces ceramic agglomeration, alleviates the floating of ceramic particles, and improves the bonding strength of reinforcement phases. Owing to the good mutual solubility among Fe, Ni, and, Cr elements, the diffusion happened at the interface between the coating and substrate.

研究领域: 材料科学 · 表面工程 · 金属学与金属工艺 · 机械工程 · 复合材料
✓ 已验证 DOI 高影响因子
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JOURNAL OF APPLIED POLYMER SCIENCE · 2024 ·Vol. 142 ·期 13 ·e56669 · IF 2.7

Revealing the Relationship Between the Entanglement Densities and Tribological Performance of UHMWPE

Peng Wei,Yang Sui,Kunhang Yan,Junhao Han,Yi Cui,Chuanbo Cong,Qiong Zhou,Pengpeng Bai,Yu Tian

Ultra-high molecular weight polyethylene (UHMWPE) can be used as the candidate material for mixed transmission pipelines due to its fabulous wear durability, corrosion resistance, and self-lubricating qualities. Nonetheless, the connection between its microstructures and tribological performance is still unclear, and hence it is difficult to elucidate the mechanism of its wear resistance. Four types of UHMWPE samples (GUR 400Fine, GUR 4012, GUR 4130, and GUR 4150) were chosen for this study, and their tribological properties were tested. The results show that the coefficient of friction (COF) and wear rate (WR) of GUR 4130 decrease as the temperature increases, but its crystallinity would not be changed while its entanglement density increases and they were confirmed by dynamic mechanical analysis. Additionally, GUR 400Fine and GUR 4012 have similar molecular weight, GUR 400Fine's COF and WR are 1.12 and 1.37 times higher than those of GUR 4012 due to its lower entanglement density. Additionally, higher molecular weight causes higher entanglement density and better tribological performance. In conclusion, we have prepared UHMWPE with better wear resistance through a simple processing method.

研究领域: 高分子材料科学 · 摩擦学 · 材料工程 · 聚合物物理 · 表面工程
✓ 已验证 DOI 高影响因子
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CERAMICS INTERNATIONAL · 2022 ·Vol. 49 ·期 7 ·10265-10272 · IF 5.532

Effect of various morphology of in situ generated NbC particles on the wear resistance of Fe-based cladding

Wenchao Xi,Boxue Song,Zhengyu Sun,Tianbiao Yu,Jun Wang,Qi Sun

To improve the wear resistance of Fe-based cladding, NbC particles with different morphology are generated in situ by adding Nb, Cr 3 C 2 and C with different content. The composition of samples and the morphology of NbC particles generated in situ are revealed by XRD , SEM and EDS. The wear resistance is studied by a reciprocating friction and wear testing machine. The wear mode and the wear mechanism of each sample are investigated. The results show that although NbC particles are generated in situ in samples with different Nb, Cr 3 C 2 and C content, the morphology of NbC particles is varied. The wear resistance of samples containing cross-shaped NbC particles is more outstanding than that of samples containing only rectangular NbC particles. In addition, changing Nb, Cr 3 C 2 and C content does not result in a change in wear mode, but leads to the formation of continuous lattice structure of Cr 0.19 Fe 0.7 Ni 0.11 and Cr 23 C 6 compounds at grain boundaries and a change in the wear resistance. When the additions of Nb, Cr 3 C 2 and C are 11.2 wt%, 8.6 wt% and 0.2 wt% respectively, the coefficient of friction of the sample is the lowest, and the wear resistance is the most outstanding.

研究领域: 材料科学 · 金属学与热处理 · 表面工程 · 摩擦学 · 复合材料
✓ 已验证 DOI 高影响因子
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BIOMASS & BIOENERGY · 2022 · IF 5.774

Valorization of industrial lignin as lubricating additives by C–C Bond Cleavage and doping heteroelement-rich groups

Jie Zhang,Danyang Cao,Shanshan Wang,Xin Feng,Jiahua Zhu,Xiaohua Lu,Liwen Mu

In this study, heteroelement-rich groups (N and B elements, tris (2-hydrazinylethyl) borate) were successfully synthesised on lignin by microwave amination. The reaction between lignin and heteroelement-rich groups was confirmed using several characterization techniques, including fourier transform infrared (FT-IR) spectroscopy, thermogravimetric (TG) analysis, and X-ray photoelectron spectroscopy (XPS). A lignin model compound (2-phenoxyacetophenone (L-M)) was used to study the bond-breaking mechanism of lignin depolymerization , and the amine group, which acted as a nucleophile , attacked the C–C bond to form an amide bond with the lignin. As an effective additive, modified lignin can increase the viscosity of poly (ethylene glycol) 200 (PEG200), reducing the wear volume and friction coefficient in the friction test. Theoretical calculations showed that the polarity of the modified lignin increased, which allowed the modified lignin to form a strong physical adsorption on the metal surface. In addition, the reciprocal hydrogen bonding between the modified lignin and PEG200 contributes synergistically to the enhanced lubrication film strength , and thus, the better tribological properties of these new lubricants.

研究领域: 高分子化学 · 材料科学 · 绿色化学 · 表面工程 · 能源材料 · 可持续技术
✓ 已验证 DOI 高影响因子
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Nano Energy · 2018 · IF 13.12

Ultralight, self-powered and self-adaptive motion sensor based on triboelectric nanogenerator for perceptual layer application in Internet of things

Xuan Zhao,Zhuo Kang,Qingliang Liao,Zheng Zhang,Mingyuan Ma,Qian Zhang,Yue Zhang

In the Internet of things (IoT), motion sensor in the perceptual layer is at the forefront of the information collection, which plays a crucial role in the IoT. However, with a large number of commercial applications, several problems of motion sensor limit the development of IOT such as poor portability, poor environmental adaptability, and high energy consumption, etc. In this work, an ultralight, self-powered and self-adaptive motion sensor (UMS) is reported. Total mass of the UMS is less than 20 mg. Self-powered characteristic of the UMS is achieved based on the principle of triboelectric nanogenerator by using the coupling of triboelectrification and electrostatic induction as governed by the Maxwell's displacement current. Moreover, the UMS shows satisfactory self-adaptive performance of both temperature and humidity, less-sensitive to temperature in surroundings, from 15 ℃ to 60 ℃, and ambient humidity under 90% RH. Furthermore, sensing signals triggered by different motion behaviors, such as grasping, walking, stooping and so on, can be distinguished by the processor clearly, which can be applied to motion recognition and machine control. This work presents a novel UMS with characteristics of portability, energy conservation and environmental friendliness. The UMS shows broad prospect in perceptual layer application in IoT.

研究领域: 纳米能源 · 传感器技术 · 物联网 · 微纳系统 · 智能感知 · 生物医学工程 · 可穿戴设备
✓ 已验证 DOI 高影响因子
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DIAMOND AND RELATED MATERIALS · 2019 · IF 2.29

Magnesium silicate hydroxide modified by carbon from hydrothermal carbonization of gelatin for tribological application

Qiuying Chang,Hao Zhang,Rongqin Gao

A new nanocomposite was prepared by combining Magnesium silicate hydroxide (MSH) with decomposed gelatin under one-pot hydrothermal synthesis conditions. The chemical reaction process involved the MSH formation and the gelation decomposing into carbonaceous species. The characterization of resultant nanoparticles revealed that the nanocomposite was a combination of hydrogenated amorphous carbon and MSH. And the addition of gelatin during synthesis increased the content of granular nanoparticles in nanocomposite samples. The results of tribological experiments of MSH modified by carbon (MSH@C) as lubricant additive showed that the nanocomposites presented much better anti-wear property and friction stability than the MSH without modification. Thus MSH@C nanocomposites were expected to be a promising candidate for lubricant additives. The amorphous carbon film was detected on the wear scar which might account for the significant tribological property.

研究领域: 材料科学 · 纳米科技 · 表面工程 · 摩擦学 · 复合材料
✓ 已验证 DOI 高影响因子
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CHEMICAL ENGINEERING JOURNAL · 2024 · IF 13.3

Low-temperature resistant hydrogel with inkjet-printed MXene on microspine surface for pressure sensing and triboelectric energy harvesting

Weijun Jiang,Jingyuan Liu,Hongsen Zhang,Dalei Song,Jing Yu,Qi Liu,Rongrong Chen,Jiahui Zhu,Jun Wang

Wearable, flexible sensors based on hydrogel fabrication have recently gained significant attention due to their unique properties. However, developing hydrogel sensors that maintain high sensitivity and work effectively in sub-zero temperatures remains a formidable challenge. Herein, a hydrogel with surfaces featuring randomly distributed microspines is synthesized by combining sodium alginate (SA) and acrylamide (AM) as the hydrogel components. To fabricate a wearable sensor, a highly conductive MXene layer is inkjet-printed onto the surface of the hydrogel microspines. The resulting sensor exhibits a remarkable array of features, including exceptional sensitivity (15.03 kPa −1 ), a low detection limit (10 Pa), a vast operating range (0.12–70 kPa), rapid response and recovery (40/100 ms), reliable performance (over 1000 cycles), and outstanding resistance to low temperatures (-20 °C). Moreover, this hydrogel-based sensor facilitates the efficient collection of human monitoring data, such as vocal patterns, pulse, and joint movements, even when operating at −20 °C and in ice bath conditions. Importantly, the surface-based inkjet MXene hydrogels could be assembled into a deformable triboelectric nanogenerator (TENG), allowing mechanical energy harvesting. The TENG exhibited peak output voltage and current values of 5 V and 2.5 μA, respectively.

研究领域: 生物医学工程 · 柔性电子 · 纳米能源 · 可穿戴设备 · 传感器技术 · 功能材料 · 转化医学
✓ 已验证 DOI 高影响因子
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COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS · 2019 · IF 3.131

Tribological behaviors of polyimide composite films enhanced with fluorographene

Shengguo Zhou,Wentao Li,Wenjie Zhao,Chao Liu,Zhiwen Fang,Xiulei Gao

As one of the youngest graphene derivative, fluorinated graphene (FG) with excellent mechanical strength and lubricity was incorporated into polyimide polymer (PI) to strengthen the comprehensive performance of nanocomposite . This article gives a detailed characterization to investigate the tribological behaviors of PI/FG nanocomposite films under different friction conditions including both of dry sliding and seawater lubrication . Firstly, the chloroform-treated FG was proved to be stably dispersed in the PI matrix . Subsequently, mechanical properties, thermal stability and tribological properties of PI/FG nanocomposite films were greatly improved. Finally, analysis of the reasons for the significant improvement in wear resistance from the viewpoint of thermal, mechanical properties and the evolution of friction products. Meanwhile, the transfer of FG from polymer matrix to frictional duality was revealed during tribological testing. The above results suggest the potential application of FG in the field of reinforcing polymer friction properties.

研究领域: 材料科学 · 高分子材料 · 表面工程 · 摩擦学 · 纳米复合材料
✓ 已验证 DOI 高影响因子
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POLYMERS FOR ADVANCED TECHNOLOGIES · 2016 ·Vol. 27 ·期 11 ·1501-1507 · IF 1.823

Structure and tribological properties of Cu–PU–PTFE composite coatings prepared by low-energy electron beam dispersion with glow discharge

Zhubo Liu,Bing Zhou,A.V. Rogachev,M.A. Yarmolenko

Polytetrafluoroethylene (PTFE) composite coatings doped copper acetate and polyurethane (PU) were prepared on rubber substrate by low-energy electron beam dispersion technique. The effects of dopant and glow discharge treatment on the surface morphology, structure and tribological properties of the coatings were investigated. The results showed that Cu–PTFE composite coatings form uniform surface and dense column structure with spherical aggregations under glow discharge treatment. PU coating shows the large size of protuberance structure but PU–PTFE coating presents spherical structure. Both of the coatings become relative dense and smooth after discharge treatment, and Cu–PU–PTFE composite coatings possess a smoother surface and lower polar component of surface energy. Cu doping weakens the crystallinity and ordering degree of composite coatings, but glow discharge increases the ordering degree and branched structure of C―H groups. Friction experiment indicated that Cu fails to improve the wear resistance of PTFE coatings but glow discharge treatment can do it. Cu–PU–PTFE coatings after discharge treatment have the higher wear resistance and lower coefficient of friction. Copyright © 2016 John Wiley & Sons, Ltd.

研究领域: 材料科学 · 表面工程 · 高分子材料 · 摩擦学 · 等离子体物理 · 涂层技术
✓ 已验证 DOI 高影响因子
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TRIBOLOGY LETTERS · 2019 ·Vol. 67 ·期 2 ·58 · IF 2.235

Synthesis of a Multi-phenol Antioxidant and Its Compatibility with Alkyl Diphenylamine and ZDDP in Ester Oil

Jin Yongliang,Duan Haitao,Cheng Bingxue,Wei Lei,Tu Jiesong,Liu Jianfang,Li Jian

In this study, a multi-phenol antioxidant 2,4,6-tris(3,5-di-tert-butyl-4-hydroxyphenylthio)-1,3,5-triazine (THA) was synthesized. The thermal stability of THA and its oxidation resistance in triisodecyl trimellitate (TDTM) ester oil were evaluated compared with several commercial phenol antioxidants. Further investigations on the oxidation resistance and tribological performance of THA with dinonyl diphenylamine (Am) and ZDDP composites were conducted to determine the additive compatibility in TDTM. The results indicate that the THA possesses higher thermal stability and more effectiveness of oxidation resistance than the commercial phenol antioxidants. The synergistic anti-oxidative effect is confirmed for the THA/Am mixtures in TDTM ester oil. However, the addition of THA alone or THA/Am mixtures shows no improvement for the tribological performance of TDTM. Excitingly, the THA/Am/ZDDP composite additives not only have the superior oxidation resistance, but exhibit the effective friction and wear reductions. It suggests the excellent compatibility of the synthesized THA antioxidant with Am and ZDDP additives in TDTM ester oil.

研究领域: 材料化学 · 润滑材料 · 应用化学 · 高分子化学 · 表面科学 · 机械工程 · 石油化学 · 摩擦学
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