Applied Sciences-Basel
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2020
·Vol. 10
·期 6
·1917
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IF 2.474
Bilin Yang,Yujun Xie,Pan Zeng,Yurong Dong,Qiongrong Ou,Shuyu Zhang
Pressure and temperature are powerful tools applied to perovskites to achieve recrystallization. Lamination, based on recrystallization of perovskites, avoids the limitations and improves the compatibility of materials and solvents in perovskite device architectures. In this work, we demonstrate tightly compacted perovskite laminates on flexible substrates via hot-pressing and investigate the effect of hot-pressing conditions on the lamination qualities and optical properties of perovskite laminates. The optimized laminates achieved at a temperature of 90 °C and a pressure of 10 MPa could sustain a horizontal pulling pressure of 636 kPa and a vertical pulling pressure of 71 kPa. Perovskite laminates exhibit increased crystallinity and a crystallization orientation preference to the (100) direction. The optical properties of laminated perovskites are almost identical to those of pristine perovskites, and the photoluminescence quantum yield (PLQY) survives the negative impact of thermal degradation. This work demonstrates a promising approach to physically laminating perovskite films, which may accelerate the development of roll-to-roll printed perovskite devices and perovskite tandem architectures in the future.Keywords:perovskite lamination;hot-pressing;recrystallization;flexible substrates
研究领域:
材料科学
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光电技术
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DOI
高影响因子
MICROCHEMICAL JOURNAL
·
2022
·
IF 5.304
Liang Tian,Mengyuan Jiang,Mengjie Su,Xiaoqing Cao,Qiyu Jiang,Quan Liu,Chunmei Yu
In this work, a highly selective and sensitive cortisol immunosensor based on MXene and multi-walled carbon nanotubes (MXene-MWCNTs) hybrid composite was proposed. The immunosensor was developed by screen printing technique on a flexible polyethyleneterephthalate (PET) substrate followed by modification of MXene-MWCNTs and anti-cortisol antibodies with EDC/NHS coupling agent. Owing to the large surface area and excellent conductivity of MXene-MWCNTs, the immunosensor exhibited a low detection limit and a wide linear range toward cortisol from 0.1 fg/mL to 1 µg/mL, which covered the normal range of free cortisol in sweat. Additionally, the immunosensor was applied to evaluate the cortisol level in human sweat samples, and the results were validated by a commercial chemiluminescence immunoassay (CLIA) assay. The present platform provides an effective method for non-invasive monitoring of human sweat cortisol levels, which may be well-suited for hormone screenings in healthy monitoring and medical diagnosis.
研究领域:
生物医学工程
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分析化学
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医疗诊断
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DOI
高影响因子
Nanomaterials
·
2022
·Vol. 12
·期 11
·1898
·
IF 5.719
Xuan Chen,Jin Li
With the increasing water pollution, traditional treatments cannot sufficiently remove pollutants, thereby prompting the development of photocatalysts. In this study, ZnO–carbon cloth (CC) and spherical ZnO/CdSe–CC heterostructures with different CdSe loadings were synthesized using an ultrasonic-hydrothermal method on flexible CC. Z20CdSe–CC (ZnO with 20 mg CdSe loaded on CC) exhibited the best visible-light-responsive photocatalytic performance, with approximately 83.5% methylene blue reduced in 180 min. In addition, the degradation efficiency of Z20CdSe–CC was maintained at 70.9% after three cycles in relation to that of the ZnO powder. The synergistic effect of CdSe and CC not only effectively widened the light absorption range of ZnO/CdSe–CC but also further promoted the effective transfer of carriers and realized an efficient photocatalytic degradation process. Therefore, the ZnO/CdSe–CC photocatalytic material with CC as the flexible substrate exhibited high photocatalytic activity and stability in environmental remediation. This provides a design idea for the development of an efficient and flexible photocatalytic material in line with the concept of green chemistry.Keywords:ZnO/CdSe–CC;heterostructure;photocatalysis
研究领域:
材料科学
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环境科学
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DOI
PubMed
高影响因子
APPLIED SURFACE SCIENCE
·
2024
·
IF 6.3
Jiping Shi,Liuqing Hua,Lu Ruan,Xingjian Zhang,Zhengdao Li,Fengyun Su,Xin Li,Haiquan Xie,Yong Zhou
The ZnIn 2 S 4 nanosheets were successfully synthesized on the surface of compacted stainless steel mesh using a simple solvothermal method, and further modified with Cu x O nanoparticles to form ZnIn 2 S 4 /Cu x O heterojunction photocatalyst via a wet chemistry approach. These photocatalysts were then utilized for photothermal catalytic CO 2 reduction under full spectrum solar light. The experimental results demonstrated that the deposition of the photocatalyst on the flexible substrate effectively prevented the aggregation of ZnIn 2 S 4 nanosheets. The incorporation of Cu x O nanoparticles enhanced the specific surface area of the photocatalyst, and created a Z-scheme heterojunction with ZnIn 2 S 4 to improve the utilization efficiency of photogenerated electrons. It was noteworthy that the dark red Cu x O exhibited a full spectrum response and excellent photothermal effect, thereby facilitating carrier migration and reducing CO 2 catalytic reaction barriers. Consequently, the optimized ZnIn 2 S 4 /Cu x O exhibited significantly enhanced CO 2 to CO yield of 1515.8 μmol m -2 h −1 and CH 4 yield of 1579.4 μmol m -2 h −1 , which was about 7.5 and 7.6 times higher than those achieved by pure ZnIn 2 S 4 , respectively. Furthermore, this study provided detailed insights into the mechanism of photocatalytic CO 2 reduction over composite material as well as valuable guidance for designing immobilized photocatalysts with high activity for CO 2 reduction.
研究领域:
材料科学
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环境科学
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化学工程
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DOI
高影响因子
RSC Advances
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2019
·Vol. 9
·期 8
·4351-4360
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IF 3.049
Xuan Wang,Bingbing Gao,Zhongze Gu
Patterned nanomaterials have promising applications in various fields, particularly for microfluidic analysis and functional surfaces. Studies on such materials have focused on developing effective methods for fabricating patterns with various nanomaterials. Here, inspired by pollen transfer by bees, we present a simple and effective method for patterning multiple functional materials onto flexible substrates by using adhesive tapes. With the advantages of high alignment accuracy, high pattern resolution and not requiring additional etching or harsh processes, the proposed method can easily be applied to diverse nanomaterials that would not be tolerant of physical, thermal, or chemical treatments, as such treatments could deform the thin film and alter its functionalities. Patterned devices were fabricated and showed excellent performance, demonstrating the applicability of this simple and practical transfer printing technique. The proposed patterning method possesses the distinct advantages of a short operating time and high patterning yield, which highlight the considerable potential for the application of this method for optical and biomedical devices.
研究领域:
材料科学
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纳米技术
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生物医学工程
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DOI
PubMed
高影响因子
ACS Applied Nano Materials
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2023
·
IF 5.9
Jianfang Xia,Lei He,Zhilai Lu,Jianan Song,Qingshan Wang,Linpeng Liu,Yanling Tian
In recent years, there has been a significant surge of interest in flexible strain sensors within the domains of wearable electronics and human–computer interaction. However, as these fields continue to advance rapidly, there is an urgent need to improve the comprehensive performance of flexible strain sensors including sensitivity, sensing range, response speed, and durability. In this study, we address this issue by transferring carbon black/graphene (CB/Gr) conductive nanocomposites onto the surface of an Ecoflex flexible substrate, which has been pretreated using sandpaper to enhance adhesion. The resulting flexible strain sensor exhibits high sensitivity, with a gauge factor of 51.4, while offering a wide sensing range of 100%. Notably, this sensor demonstrates high performance across various aspects, including a fast response time (60 ms) and excellent durability (up to 4000 stretching–releasing cycles). The versatility of this sensor is evident in its ability to effectively monitor both small strain activities, such as speech recognition, and larger strain activities, such as elbow bending. Moreover, the sensor has demonstrated outstanding performance in various application scenarios, including human health and motion condition monitoring as well as acoustic wave and vibration signals detection. Consequently, this highlights the sensor’s remarkable adaptability and substantial potential for wide-range applications in these domains.
研究领域:
材料科学
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生物医学工程
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传感器技术
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产品关联
DOI
高影响因子
LANGMUIR
·
2017
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IF 3.833
Sanjun Yang,Qiming Liu
An aligned Ag nanowire array was directly synthesized by galvanic replacement on curved poly(ethylene terephthalate) (PET) by using a Cu2O microcrystal as a reductant. A more orderly aligned nanowire array was obtained when the curvature radius was reduced. A second growth with different orientation produced Ag nanowire networks. The guided growth was also achieved when using Zn as a reductant or polystyrene as a substrate. This plain method with facile control over the orientation and density of the Ag nanowire array enriches the grow-in-place methodology and can potentially be applied to various fields.
研究领域:
材料科学
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纳米技术
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DOI
PubMed
高影响因子
VACUUM
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2024
·
IF 3.8
Longhao Liu,Kaixi Bi,Ganying Zeng,Yan Zhuang,Shuqi Han,Shengguo Zhang,Linyu Mei
With the advancement of infrared modulation technologies, infrared display devices have attracted increasing attention. Previous studies have mainly focused on the response time of infrared display devices and have achieved great success. Nevertheless, owing to the restricted material properties or modulation approaches, the response time of the majority of infrared modulating devices remains trapped at level for a few seconds. In this paper, we fabricated an infrared images display device based on lithium-ion intercalated multilayer graphene (MLG). By changing the lithium-ion content and current value, we had successfully improved its response time from approximately 140,000 ms to around 6 ms.Meanwhile, its absorbance also has significant changes within 0.8–1.8 μm (∼75 %–∼25 %) and 2.5–25 μm (∼45 %–∼2 %). In addition, multi-pixel infrared display unit has been realized on a flexible substrate. The letters "N, U, and C″ were dynamically displayed continuously at 3∗3 pixels by controlling lithium-ions intercalate MLG state. Our work is expected to provide theoretical and technological support for ultrafast flexible dynamic infrared display devices.
研究领域:
材料科学
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光学工程
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DOI
高影响因子
JOURNAL OF MEMBRANE SCIENCE
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2024
·
IF 8.4
Ziheng Li,Yan Dai,Xuehua Ruan,Xiangcun Li,Miao Yu,Tiantian Li,Xiujuan Zhang,Xiaobin Jiang,Xuemei Wu,Wenji Zheng,Gaohong He
Defect-free MOFs membrane on flexible substrate is challenging and promising for industrial applications. In this work, electrospun nanofiber substrates were employed to construct deep-rooted and defect-free ZIF-8 membranes by a symbiotic layer composed of interpenetrated nanofibers and ZIF-8. Nanofibers provide sufficient nucleation sites to construct an interpenetrated “symbiotic layer”, which further supports ZIF-8 growing to be defect-free. Importantly, benefiting from this symbiotic layer, the rigidity difference between substrate and ZIF-8 is well balanced, resulting in ZIF-8 membrane deep-rooted within the support. Furthermore, tannic acid (TA), was combined to modulate the surface chemistry and inter-crystalline defects of ZIF-8 membranes. Finally, a hierarchical ZIF-8 membrane with nanofibers as flexible substrates were obtained. The prepared PAN/TA 2 -NZIF-8 0.25 membrane exhibits H 2 permeance of 2408 GPU and H 2 /CO 2 selectivity of 21.80. Specifically, compared with the reported MOFs membrane for H 2 separation, the H 2 permeance of this work locates in a very high region, while proper H 2 /CO 2 separation factor is still remained, exceeding the 2008 upper bound of H 2 /CO 2 separation. Importantly, this membrane presents stable microstructures and separation performance after twisting. The proposed deep-rooted and defect-free ZIF-8 membrane on flexible substrate is competitive to achieve industrial application.
研究领域:
材料科学
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化学工程
·
纳米技术
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产品关联
DOI
高影响因子
Advanced Science
·
2025
·
IF 14.1
Guannan Zhang,Zhao Sun,Zhuofei Gan,Chuwei Liang,Liyang Chen,Hongbo Mo,Yuanzhi Jiang,Mingjian Yuan,Aleksandra B. Djurišić,Ji Tae Kim,Wen-Di Li
Halide perovskite single crystals have demonstrated enormous potential for next-generation integrated optoelectronic devices. However, there is a lack of a facile method to realize the controllable growth of large-scale, high-quality, and high-resolution perovskite single crystal arrays on diverse types of substrates, which hinders their application in practical scenarios. Here, a one-step wettability-guided blade coating approach is reported for the rapid in situ crystallization of large-scale, multicolor, and sub-100 nm perovskite single-crystal arrays in the ambient environment. By this strategy, the physical dimensions of perovskite single crystals can be precisely regulated from 90 to 260 nm, with a size variation coefficient < 10% and an area of over 900 mm 2 . All three typicalhalogen perovskites for multi-color luminescence, CsPbX 3 (X = Cl, Br, I) and their mixtures (Cl/Br or Br/I systems), are appliable to this fabrication process through the demonstration of complex RGB patterns with remarkable photoluminescence properties. Moreover, various rigid substrates such as silicon oxide (SiO 2 ), silicon (Si), and glass can also be used to construct the wettability-constrast templates where perovskite crystal nucleate and grow. After that, the perovskite single-crystal arrays or complex patterns can be transferred onto flexible substrates, for instance, COC. This method combines convenient solution processing with conventional photolithography to prepare the high-resolution, large-area, and superior-quality perovskite single crystal arrays in a high-throughput manner, showing great potential in the integration of perovskite nano-optoelectronic devices and chips.
研究领域:
材料科学
·
光学工程
·
纳米技术
✓ 已验证
产品关联
DOI
PubMed
高影响因子
ACS Applied Materials & Interfaces
·
2024
·
IF 8.3
Chengwen Bin,Xu Hou,Zeqing Yu,Luocheng Liao,Han Yang,Yunya Liu,Jie Wang
Flexible ferroelectric films with high polarization hold great promise for energy storage and electrocaloric (EC) refrigeration. Herein, we fabricate a lead-free Mn-modified 0.75 Bi(Mg0.5Ti0.5)O3–0.25 BaTiO3 (BMT–BTO) thin film based on a flexible mica substrate. Excellent EC performance with maximum adiabatic temperature change (ΔT ∼23.5 K) and isothermal entropy change (ΔS ∼33.1 J K–1 kg–1) is achieved in the flexible BMT–BTO film, which is attributed to the local structural transition and lattice disorder near 90 °C. Meanwhile, a good energy storage density of ∼70.6 J cm–3 and a quite high efficiency of ∼82% are realized in the same ferroelectric film, accompanied by excellent stability of frequency and electric fatigue (500–10 kHz and 108 cycles). Furthermore, there is no apparent variation in performance under different bending strains. These prominent properties indicate that the multifunctional BMT–BTO ferroelectric film is a promising candidate for applications of flexible energy storage and EC refrigeration.
研究领域:
材料科学
·
能源技术
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DOI
高影响因子
ADVANCED MATERIALS
·
2020
·Vol. 32
·期 23
·2001082
·
IF 27.398
Ye Zhang,Pu Huang,Jia Guo,Rongchao Shi,Weichun Huang,Zhe Shi,Leiming Wu,Feng Zhang,Lingfeng Gao,Chao Li,Xiuwen Zhang,Jialiang Xu,Han Zhang
Graphdiyne (GDY), a newly emerging 2D carbon allotrope, has been widely explored in various fields owing to its outstanding electronic properties such as the intrinsic bandgap and high carrier mobility. Herein, GDY-based photoelectrochemical-type photodetection is realized by spin-coating ultrathin GDY nanosheets onto flexible poly(ethylene terephthalate) (PET) substrates. The GDY-based photodetectors (PDs) demonstrate excellent photo-responsive behaviors with high photocurrent ( P ph , 5.98 µA cm - 2 ), photoresponsivity ( R ph , 1086.96 µA W - 1 ), detectivity (7.31 × 10 10 Jones), and excellent long-term stability (more than 1 month). More importantly, the PDs maintain an excellent P ph after 1000 cycles of bending (4.45 µA cm - 2 ) and twisting (3.85 µA cm - 2 ), thanks to the great flexibility of the GDY structure that is compatible with the flexible PET substrate. Density functional theory (DFT) calculations are adopted to explore the electronic characteristics of GDY, which provides evidence for the performance enhancement of GDY in alkaline electrolyte. In this way, the GDY-based flexible PDs can enrich the fundamental study of GDY and pave the way for the exploration of GDY heterojunction-based photodetection.
研究领域:
材料科学
·
电子工程
·
理论计算
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DOI
PubMed
高影响因子
危险品化学品经营许可证（带存储）