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MATERIALS CHEMISTRY AND PHYSICS · 2018 · IF 2.21

Synthesis of cadmium chalcogenides nanowires via laser-activated gold catalysts in solution

Xuemin Chen,Ruihong Liu,Shizhang Qiao,Jing Mao,Xiwen Du

Laser irradiation is a green, simple and efficient technique for material synthesis. A laser-activated-catalyst (LAC) technique is proposed for fabrication of nanowires in solution under ambient conditions. In the present work, effects of intrinsic influential factors such as the activity of precursor, precursor concentration, laser energy density and laser irradiation time on the LAC growth of cadmium chalcogenide nanowires are systematically investigated, which help to reveal the fundamental principles of LAC technique. Laser energy density and activity of precursor are proven to be vital for the growth of nanowires, and our work demonstrates that LAC is a universal way for synthesis of cadmium chalcogenides semiconductors.

研究领域: 材料科学 · 纳米技术 · 半导体材料 · 无机化学 · 光化学
✓ 已验证 DOI 高影响因子
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CERAMICS INTERNATIONAL · 2020 ·Vol. 47 ·期 5 ·5918-5928 · IF 3.83

Microstructure and mechanical properties of Ti–C–TiN-reinforced Ni204-based laser-cladding composite coating

Yu Zhao,Tianqi Zhang,Liaoyuan Chen,Tianbiao Yu,Jiayu Sun,Chuang Guan

In situ Ti(C, N), ring phase, and multi-phase enhanced Ni204-based alloy coating were prepared by adding various Ti/C/TiN ratios particles. The effects of the reinforcement phase on the microstructure, microhardness , tribological property, and microstructure characteristics at the interface between the coating and substrate were investigated. The results show that the coatings with a 5:1 mass fraction ratio of TiN/C exhibits the highest microhardness , which is 3.78 times higher than that of the original Ni204 coating. While, the coating with 21:7:2 mass fraction ratio of TiN/Ti/C exhibits the lowest friction coefficient , which is 4.44 times smaller than that of the original Ni204 coating. The addition of Ti and C particles promotes the precipitation of ring phase and carbides , reduces ceramic agglomeration, alleviates the floating of ceramic particles, and improves the bonding strength of reinforcement phases. Owing to the good mutual solubility among Fe, Ni, and, Cr elements, the diffusion happened at the interface between the coating and substrate.

研究领域: 材料科学 · 表面工程 · 金属学与金属工艺 · 机械工程 · 复合材料
✓ 已验证 DOI 高影响因子
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APPLIED SURFACE SCIENCE · 2022 · IF 7.392

Nano-and micro-engineered vertical graphene/Ni for superior optical absorption

Jiemin Han,Yifei Ma,Mei Wang,Zhaomin Tong,Jonghwan Suhr,Liantuan Xiao,Suotang Jia,Xuyuan Chen

Black coatings benefit from low reflectance or high light absorption are utilized in multifarious optical applications. Due to their unique three-dimensional nanostructure and π-band optical transitions, vertical graphene (VG) has drawn great attention to the field of black coatings. However, how the morphology of VGs affects reflectance has not been comprehensively disclosed yet. In addition, the morphology of the substrate for VG growth also affects the absorption properties. Here, we report a nano-and micro-engineered VG/Ni structure based on VG and laser-modified nickel foil, which possesses omnidirectional low reflectance of ∼0.25% over the visible range. A larger spacing of graphene nanowalls is more conducive to the formation of light traps and improves the absorption property. Besides, the surface of nickel substrate by laser irradiation presents a “cauliflower-like” microstructure, which further enhances light-trapping ability.

研究领域: 材料科学 · 光学工程 · 纳米技术 · 表面工程 · 功能涂层
✓ 已验证 DOI 高影响因子
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OPTICS AND LASER TECHNOLOGY · 2024 · IF 4.6

Regulating thermal management by a CsPbClBr2/Ag hybrid microcavity for stable room temperature blue lasing with low threshold

Shulei Li,Zhenxu Lin,Quantong Deng,Fu Deng,Mingcheng Panmai,Junying Chen,Yuheng Mao,Shimei Liu,Jun Dai,Yunbao Zheng,Rui Huang,Sheng Lan

Realization of long-term stable lasing from all-inorganic perovskite supercrystals is highly desirable for practical applications in optoelectronic devices. However, lasing from perovskite supercrystals excited by continuous wave laser light remains a challenge due to the photoluminescence degradation induced by thermal accumulation. Here, we report highly stable lasing with low threshold fom a CsPbClBr 2 supercrystal placed on a thin Ag film, which form a CsPbClBr 2 /Ag microcavity, by managing the thermal distribution inside the CsPbClBr 2 supercrystal. Combined numerical simulations and lifetime measurements, the localized electric field in such a hybrid microcavity leads to a spatially localized temperature distribution, which plays a crucial role in suppressing the thermal accumulation on the surface and in eliminating non-radiative recombination defects. The effective thermal management in the hybrid microcavity renders highly stable lasing with low threshold under the irradiation of continuouw wave laser light. Our findings provide a feasible and universal approach to the development of long-term stable perovskite laser.

研究领域: 光学工程 · 凝聚态物理 · 材料科学 · 纳米光子学 · 激光技术
✓ 已验证 DOI 高影响因子
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OPTICAL MATERIALS · 2021 · IF 3.08

Tunable random laser in flexible hydrogel

Xiang Meng,Jiajun Ma,Kang Xie,Liang Hong,Junxi Zhang,Zhijia Hu

We have demonstrated a low threshold and tunable flexible random laser (RL) in dye-doped poly ethylene glycol diacrylate (PEG-DA) hydrogel, which was prepared by crosslinking polymerization using PEG-DA monomer and photoinitiator. The random lasering is attributed to the light scattering from the porous structure of hydrogels, and the wavelength of random lasing can be tuned by ~3.2 nm in the temperature range from 30 °C to 70 °C. Under the continuous increasing and decreasing temperature cycle, the random lasing tunable phenomenon can still be observed, which proves that this flexible material can be used as a new temperature sensor . In addition, we also explored the application of flexible laser in phototherapy. Considering the good elasticity and transparency of hydrogels, this thermo-responsive property will be of great significance to the biomedical applications of flexible material.

研究领域: 生物医学工程 · 光学工程 · 高分子材料科学 · 光子学 · 生物传感器
✓ 已验证 DOI 高影响因子
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CERAMICS INTERNATIONAL · 2024 ·Vol. 51 ·期 14 ·18384-18391 · IF 5.1

Enhanced optical properties and laser performance of Yb:LuScO3 transparent ceramics fabricated with ZrO(NO3)2

Fangliang Shen,Bingheng Sun,Tao Feng,Conghui Huang,Yin Hang,Benxue Jiang,Long Zhang,Jintai Fan

This work aims to fabricate the Yb:LuScO 3 sesquioxides transparent ceramics for use in ultrafast and ultrashort laser technology. 1 at.% Yb:LuScO 3 nanopowders were fabricated using the glycine-nitrate process. ZrO(NO 3 ) 2 was selected as the precursor of ZrO 2 which functions as a sintering aid. Yb:LuScO 3 transparent ceramics with different ZrO 2 content were fabricated by vacuum sintering at 1780 °C and HIPing at 1650 °C, among which the ceramic with 7 at.% ZrO 2 showed the highest transmittance, reaching 81 % at 2000 nm. The ceramic achieved a maximum output power of 1.5 W at 1038 nm with a slope efficiency of 34.8 % and tunable wavelength range exceeding 22 nm. The results demonstrated that Yb:LuScO 3 transparent ceramics can be considered as promising materials in 1 μm solid-state laser applications.

研究领域: 材料科学 · 光学工程 · 固体激光技术 · 无机非金属材料 · 先进陶瓷
✓ 已验证 DOI 高影响因子
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JOURNAL OF NON-CRYSTALLINE SOLIDS · 2019 · IF 2.6

Nd3+-doped antimony germanate glass for 1.06 μm fiber lasers

S.J. Huang,Y.B. Xiao,J.L. Liu,Y. Ji,L.Y. Mao,W.C. Wang

In this work, a multicomponent GeO 2 –Sb 2 O 3 –BaO (BSG) glass is explored to assess its potential for 1.06 μm fiber lasers . The glass-forming region of BSG system is predicted and determined experimentally based on a thermodynamic method. Benefitting from the incorporation of Sb 2 O 3 , this system possesses an exceptionally large glass-forming region, as well as high density and refractive index , wide infrared transmission range and low phonon energy. Furthermore, an efficient near-infrared emission at 1064 nm from Nd 3+ has been realized in this oxide glass with relatively long measured lifetime (200.58 ± 1.24 μs) and large emission cross-section (3.015 ± 0.090 × 10 −20  cm 2 ), indicating that Nd 3+ -doped BSG glass is a promising candidate for laser application in 1.06 μm region.

研究领域: 光学材料 · 玻璃科学 · 激光物理 · 无机非金属材料 · 光子学
✓ 已验证 DOI 高影响因子
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Defence Technology · 2021 ·Vol. 18 ·期 10 ·1852-1862 · IF 3.172

Novel aluminum-based fuel: Facile preparation to improve thermal reactions

Fa-yang Guan,Hui Ren,Wan-jun Zhao,Xin-zhou Wu,Qing-jie Jiao

To improve the thermal properties of aluminum (Al) in the energetic system, a coated structure with ammonium perchlorate (AP) was prepared by a facile approach. And N, N-Dimethylformamide (DMF) was chosen as an ideal solvent based on heterogeneous nucleation theory and molecular dynamics simulation. This coated structure could enlarge the contact area and improve the reaction environment to enhance the thermal properties. The addition of AP could accelerate oxidation temperature of Al with around 17.5 °C. And the heat release of 85@15 composition rises to 26.13 kJ/g and the reaction degree is 97.6% with higher peak pressure (254.6 kPa) and rise rate (1.397 MPa/s). An ideal ratio with 15 wt% AP was probed primarily. The high energy laser-induced shockwave experiment was utilized to simulate the reaction behavior in hot field. And the larger activated mixture of coated powder could release more energy to promote the growth of shockwave with higher speed up to 518.7 ± 55.9 m/s. In conclusion, 85@15 composition is expected to be applied in energetic system as a novel metal fuel.

研究领域: 材料科学 · 能源化学 · 热力学 · 纳米材料 · 燃烧学
✓ 已验证 DOI 高影响因子
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JOURNAL OF LUMINESCENCE · 2022 · IF 4.171

Controlling and optimizing amplified spontaneous emission based on CsPbBr3@MCM-41 molecular sieve composite

Zhaoping Chen,Qin Wang,Ziyao He,Jiaming Li,Enrou Mei,Xiaojuan Liang,Weidong Xiang

CsPbX 3 (X = Cl, Br, I) perovskites have emerged as promising candidate lasing materials due to their high optical gain , low defect state density, and high absorption coefficient. Unfortunately, they suffer from poor stability, particularly with respect to temperature, moisture, and light exposure, preventing their use in practical optoelectronic applications , such as for amplified spontaneous emission (ASE) with an ultralow laser threshold. Herein, CsPbBr 3 @MCM-41 molecular sieve (CMM) composites are controllably prepared by different ultrasonication and stirring treatments. In addition, different perovskite concentrations and heat-treatment conditions are also considered to demonstrate the ASE behaviors. In addition, CMM@PS (CMMP) and CMM@AB (CMMA) composites were fabricated successfully by further optimizing the mixing ratio of CMM and the polymer. More excitingly, the stability of the CMM@polymer films with respect to the external environment is greatly improved after the polymer coating . To our surprise, the CMM@ploymer thin films demonstrated ASE at room-temperature, with an ASE threshold as low as 0.136 mJ/cm 2 and 0.049 mJ/cm 2 for CMMA and CMMP, respectively. These results clearly shed light upon the control and optimization of CsPbBr 3 perovskite composite films , paving the way for their widespread use in optoelectronic applications .

研究领域: 光学材料 · 纳米复合材料 · 光电子学 · 激光物理 · 功能薄膜
✓ 已验证 DOI 高影响因子
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Small · 2019 ·Vol. 15 ·期 44 ·1902819 · IF 10.856

Microcontact Printing with Laser Direct Writing Carbonization for Facile Fabrication of Carbon-Based Ultrathin Disk Arrays and Ordered Holey Films

Xiaojun Ruan,Jiangjiang Luo,Rui Wang,Yanbo Yao,Jingjiao Guan,Tao Liu

A nanometer-thick carbon film with a highly ordered pattern structure is very useful in a variety of applications. However, its large-scale, high-throughput, and low-cost fabrication is still a great challenge. Herein, microcontact printing (µCP) and direct laser writing carbonization (DLWc) are combined to develop a novel method that enables ease of fabrication of nanometer-thick and regularly patterned carbon disk arrays (CDAs) and holey carbon films (HCFs) from a pyromellitic dianhydride-oxydianiline-based polyamic acid (PAA) solution. The effect of PAA concentration and pillar lattice structure of the polydimethyl siloxane stamp are systematically studied for their influence on the geometrical parameter, surface morphology, and chemical structure of the finally achieved CDAs and HCFs. Within the PAA concentration being investigated, the averaged thickness of CDAs and HCFs can be tailored in a range from a few tens to a few hundred of nanometers. The µCP+DLWc-enabled electrically conductive CDAs and HCFs possess the characteristics of ease-of-fabrication, nanometer-thickness, highly regular and controlled patterns and structures, and the ability to form on both hard and soft substrates, which imparts usefulness in electronics, photonics, energy storage, catalysis, tissue engineering, as well as physical, chemical, and bio-sensing applications.

研究领域: 材料科学 · 纳米科技 · 生物医学工程 · 表面化学 · 微纳加工
✓ 已验证 DOI 高影响因子
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Laser & Photonics Reviews · 2024 ·Vol. 18 ·期 12 ·2400812 · IF 9.8

Dynamic Information Encryption and Coding using Liquid Crystal Soft Helical Microstructures with Spiropyran Photochromic Switch

Guangyin Qu,Xiaojuan Zhang,Siqi Li,Yan Kuai,Feng Xu,Liang Lu,Yu Liu,Zhigang Cao,Benli Yu,Anderson S. L. Gomes,Zhijia Hu

In contrast to conventional anti-counterfeiting technologies, which are susceptible to decryption and exhibit limited effectiveness, the utilization of light to dynamically configure soft materials in a fully reversible and programmable manner not only enhances data security but also improves anti-counterfeiting performance. However, achieving precise control over reflection structural colors and laser wavelengths within a broad dynamic range remains a challenge. In this study, a UV-responsive soft helical superstructure is established by combining a photochromic compound with chiral liquid crystals (LCs). By manipulating the Bragg reflection angle, structural reflection colors ranging from red to cyan are successfully achieved. The introduction of an anti-counterfeiting technique that embeds diverse micro-structures provides features such as color adjustability, erasability, and angle-dependent stability. Using the unique properties of this soft helical superstructure, the implementation of a wavelength-tunable LC bandgap laser through optically reconfigurable Förster resonance energy transfer processes is showcased. Furthermore, a straightforward prototype information encoder is developed to mimic the processes of information encoding and decoding, bypassing the need for complex algorithm design. This research underscores the practicality of LC helical soft systems, emphasizing their distinctive responsiveness to light and their applicability in optical programming photonics.

研究领域: 光学材料 · 软物质物理 · 光子学 · 信息安全 · 功能材料 · 分子光化学
✓ 已验证 DOI 高影响因子
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OPTICAL MATERIALS · 2019 · IF 2.687

Third-order nonlinear optical responses and carrier dynamics in antimonene

Feng Zhang,Xiantao Jiang,Zhiliang He,Weiyuan Liang,Shixiang Xu,Han Zhang

Antimonene (Sb), a novel 2D crystalline, has recently received intense attention from optoelectronic communities, due to its enticing physical and chemical properties. Here we systematically investigate the broadband third-order nonlinear optical properties and carrier dynamics in antimonene. Efficient saturable absorption effect was observed at different wavelengths, indicating the use for broadband ultrafast laser generation. The nonlinear refractive indexes were characterized to be (2.55 ± 0.23) × 10 −14  cm 2 /W and (7.88 ± 0.37) × 10 −15  cm 2 /W at 800 nm and 1500 nm, respectively. Photoinduced carrier dynamics are investigated by a non-degenerate transient absorption spectrometer. Fast recovery processes were observed in antimonene and suggesting a high optical modulation speed to 500 GHz.

研究领域: 光学材料 · 凝聚态物理 · 纳米光子学 · 非线性光学 · 超快光谱学
✓ 已验证 DOI 高影响因子
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