MACROMOLECULAR RAPID COMMUNICATIONS
·
2021
·Vol. 42
·期 22
·2100457
·
IF 5.734
Xiaobin Li,Ending Zhang,Jun Shi,Xiaoyan Xiong,Jiaming Lin,Qiang Zhang,Xiaohua Cui,Liqin Tan,Kun Wu
In the past two decades, ionic conductive hydrogel has attracted tremendous research interests for their intrinsic characteristics in the field of flexible sensor. However, synchronous achievement of high mechanical strength, satisfied ionic conductivity, and broad adhesion to various substrates is still a challenge. Herein, a novel zwitterionic composite hydrogel that displayed excited strechability (up to 900%), satisfied strength (about 30 kPa), high ionic conductivity (1.2 mS cm −1 ), and adhesion to polar and nonpolar materials is fabricated though the combination of waterborne polyurethanes (PU) and poly(sulfobetaine zwitterion- co -acrylamide) (SAm). Especially, this facile strategy demonstrates that PU has a synergistic effect on enhancing mechanical strength and ionic conductivity for ionic conductive hydrogel. Moreover, the hydrogel-based strain/stress sensor shows high sensitivity, wide sensing range, great stability, and accuracy for human body movements detecting and voice recognition. This novel ionic conductive hydrogel has promoted the development of wearable devices.
研究领域:
生物材料
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高分子科学
·
柔性电子学
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生物医学工程
·
传感器技术
✓ 已验证
DOI
高影响因子
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
·
2017
·
IF 2.714
Zhilin Xi,Zhenya Feng,Ang Li
For the control of pulverized coal, we propose a dust suppressant by applying a blend of mixed polyethylene oxide (g-PEO) and sodium dodecyl sulfate ( SDS ). In our experimental study, the thermal characteristics, critical micelle concentration ( CMC ), wettability and adhesion of the dust suppressant are investigated. It was found that g-PEO had a low fusing temperature and its combustion temperature was close to that of coal, thus, the solution containing g-PEO applied coal dust control did not affect the use of the coal. Based on steady-state fluorescence using pyrene as a fluorescent label, quantitative analysis revealed that the CMC s of g-PEO and SDS were 1 and 20 g/L in g-PEO& SDS solution, respectively. The solution containing SDS had the best wettability, but it only had a short-term effect. The solution containing g-PEO showed negligible wetting ability to wet coal dust. The solution containing g-PEO& SDS had better wetting ability and adhesion. Scanning electron microscopy showed that the coal dust covered by g-PEO& SDS on its surface could form a thin layer of armor by holding the particles together after air-drying. It was concluded that the g-PEO& SDS solution containing g-PEO for 1 g/L and SDS for 20 g/L could suppress coal dust and maintain a long-term effect.
研究领域:
环境工程
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矿业安全
·
颗粒物控制
·
表面化学
·
燃烧科学
✓ 已验证
DOI
高影响因子
JOURNAL OF ALLOYS AND COMPOUNDS
·
2017
·
IF 3.133
Lei Meng,Bin Yao,Yongfeng Li,Zhanhui Ding,Zhenyu Xiao,Kaisi Liu,Gang Wang
The back contact adhesion is the important factor of the microstructural performance which can determine the optoelectronic properties of the kesterite-based solar cells. Here, we present a rational and effective strategy to significantly enhance the back contact adhesion of Cu 2 (Zn,Cd)Sn(S,Se) 4 (CZCTSSe) absorber layers by insetting the appropriate thickness carbon-doping CZCTS thin films . We chose the oleylamine as the carbon-doping reagent which can generate a small amount of carbon in the annealing process . The suitable thickness carbon-doping CZCTS films can significantly change the crystal growth mechanism of CZCTSSe absorber layers, and eliminate the holes in the back contact. The efficiency of CZCTSSe solar cells fabricated by insetting the appropriate thickness carbon-doping CZCTS films is above 7%, and shows the excellent repeatability and long-term air stability compared with the control devices.
研究领域:
材料科学
·
光伏技术
·
半导体物理
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表面与界面工程
·
无机功能材料
✓ 已验证
DOI
高影响因子
Small
·
2017
·Vol. 14
·期 7
·1702288
·
IF 8.643
Meiling Zhu,Kongchang Wei,Sien Lin,Xiaoyu Chen,Chia-Ching Wu,Gang Li,Liming Bian
Targeted and sustained delivery of drugs to diseased tissues/organs, where body fluid exchange and catabolic activity are substantial, is challenging due to the fast cleansing and degradation of the drugs by these harsh environmental factors. Herein, a multifunctional and bioadhesive polycaprolactone-β-cyclodextrin (PCL-CD) polymersome is developed for localized and sustained co-delivery of hydrophilic and hydrophobic drug molecules. This PCL-CD polymersome affords multivalent crosslinking action via surface CD-mediated host–guest interactions to generate a supramolecular hydrogel that exhibits evident shear thinning and efficient self-healing behavior. The co-delivery of small molecule and proteinaceous agents by the encapsulated PCL-CD polymersomes enhances the differentiation of stem cells seeded in the hydrogel. Furthermore, the PCL-CD polymersomes are capable of in situ grafting to biological tissues via host–guest complexation between surface CD and native guest groups in the tissue matrix both in vitro and in vivo, thereby effectively extending the retention of loaded cargo in the grafted tissue. It is further demonstrated that the co-delivery of small molecule and proteinaceous drugs via PCL-CD polymersomes averts cartilage degeneration in animal osteoarthritic (OA) knee joints, which are known for their biochemically harsh and fluidically dynamic environment.
研究领域:
药物递送
·
生物材料
·
组织工程
·
纳米医学
·
再生医学
·
关节生物学
·
转化医学
✓ 已验证
DOI
高影响因子
危险品化学品经营许可证（带存储）