计算溶液所需的质量、体积或浓度。
为什么选择此级别
，适用于对基线干扰要求严格的色谱和分析工作流程。
储存与运输
。 。请查阅批次 COA 获取详细规格。
质量文档
SDS、COA、产品数据表及规格说明书均可下载。可通过批号查询获取批次 COA。
文献证明
在色谱分析、有机合成和交叉偶联反应领域已被 0 篇同行评审文献引用。
概述
Opteon™ SF33 的化学名是六氟丁烯(化学名HFO-1336mzzZ) ，它是非常环保的产品，ODP为零，GWP又非常低。它非常适合于设备清洁，洗涤和干燥等应用。它可以取代目前使用的氢氯氟烃(如 HCFC141b)和多氟烷烃(PFC)等产品。产品的基本信息如下表：
表 1 Opteon™ SF33 物理指标
| 性能 | 指标 |
| 分子量 | 164 |
| 沸点，C | 33 |
| 表面张力 dye/cm | 12.9 |
| 液体密度20C g/cm3 | 1.358 |
| 凝固点 C | -151 |
| 在水中的溶解度，ppm | 140 |
| 水的溶解度，ppm | 490 |
| 临界温度 C | 171.3 |
| 临界压力 MPa | 2.9 |
| 蒸发潜热（沸点）KJ/kg | 164 |
| 比热 20C KJ/kg C | 1.17 |
| 粘度，cPs | 0.034 |
| ODP | 0 |
| GWP(CO2 100years) | 9.4 |
| 有机挥发物 VOC | 否 |
| 可燃性(ASTM 681) | 否 |
| AEL(8hours) | 500ppm |
典型应用：
• 清洁和洗涤；
• 干燥液体；
• 颗粒物清除；
• 氟素润滑油的载体；
• 溶剂和分散介质；
• 热传导液体；
• 绝缘流体；
• 可取代多种氟液体如 HCFC-141b ，PFC 和CFC-113 等
Opteon™ SF33 是非常理想的对细微颗粒清洁的产品，可清除包括金属和非金属的颗粒。在清洁应用中，清除细微颗粒的污染物需要一个溶剂能形成很细小的薄层且小于污染物的直径，它产生的动能就可以渗入污染物与基体之间从而将之去除。Opteon™ SF33 由于它的粘度小，密度高，表面张力低，所以很容易形成薄层，从而有效地实现对污染物的清洁。普通的水性清洁液如水，或是水与清洁剂的混合物， 由于其粘度高，表面张力高，清洁效率低。
在清洗应用中，可以加入少量的醇来增加清洗剂的极性， 以克服污染物与表面之间的电荷吸引力。在清洗中另外一种常用的方法是在清洗过程中加入超声波，高频率的超声波可以在清洁过程中产生一些小的泡，从而加强清洗的效果。
蒸汽清洁过程
蒸汽清洁技术可用于间歇式的批次清洁或是连续的清洁技术。这个过程一般有一个专用的设备系统，它有一个高的自由挡板和一个次级的低温冷凝管（-29C），这可以减少在清洁过程中的蒸汽损失。通常的清洁过程包括：去除油脂，去除焊药和干燥设备等过程。
纯净的 Opteon™ SF33 可用于洗涤，干燥和清洁方面的应用，也可以加入其它溶剂来形成共沸物或是共混物来增强清洗性能，如增强溶剂性或是去除油脂。
共溶剂性
与其它的 PFCs 溶剂不同，Opteon™ SF33 完全溶于多数的酯，酮，醇酯和低级醇中。如甲醇，乙醇，异丙醇等。和低级的烷烃如已烷，庚烷也是相容的。它在其它高分子量的化学品中，溶解性有限，如高级烷烃油，硅油，蜡和油脂等。它也可以增加一些溶剂的溶解性，也可以提高一般溶剂对一些氟碳油脂如Krytox®和Fomblin 等润滑脂的溶解性。
相容性较好溶剂包括：
二元酯，直链烷烃， 乙二醇丙醚，氮甲基吡咯烷酮，丙二醇丁醚，丙二醇单甲醚， 四氢呋喃，低级醇等。
表 2 ，Opteon™ SF33 的共溶剂性能
| 混和物 | 沸点 | KB 值 |
| Opteon™ SF33 | 33 | 11.3 |
| Opteon™ SF33+反式二氯乙烯 | 28.9 | 50 |
| Opteon™ SF33+环戊烷 | 26.7 | 32 |
| Opteon™ SF33+ 乙醇 | 33.1 | 32 |
| Opteon™ SF33+ 甲醇 | 31.6 | 29 |
| Opteon™ SF33+ 甲酸甲酯 | 30.8 | 14 |
表 3 不同含氟液体的性能比较
| 性能 | HCFC-141b | Opteon SF33 | Vertrel XF | HFE-7100 |
| 化学分子式 | CHCl2-CH2F | CF3 CH=CHCF3 | C5H2F10 | CF3(CF2)3OCH3 |
| ODP | 0.11 | 0 | 0 | 0 |
| GWP | 725 | 9.4 | 1700 | 320 |
| 闪点( ℃) | None | None | None | None |
| 沸点( ℃) | 32 | 33 | 55 | 61 |
| 凝固点( ℃) | -103 | -151 | -80 | -135 |
| 蒸发潜热(KJ/kg) | 223 | 164 | 130 | 126 |
| 表面张力(dye/cm) | 19.3 | 13.5 | 14.1 | 13.6 |
| 液体密度 | ||||
| KB 值 | 56 | 11.3 | 9 | 10 |
塑料和弹性体的相容性
多数的塑料和弹性体与 Opteon™ SF33 是相容性，可以直接暴露在液体中，下表中列出了与常用塑料材料短时间暴露接触的结果。测试条件是将试样浸泡到液体中，放置 14 天，测试结果如下。
表 4 Opteon™ SF33 的非金属材料相容性能
| Material塑料 | 重量变化% | 接触后24小时接触后的重量变化% | 硬度表面硬度变化% | 24小时后的表面硬度变化% |
| 天然橡胶 | -0.55 | -0.98 | 7.1 | 2.58 |
| EPDM | 2.39 | 0.84 | 2.56 | 0.64 |
| 聚酯 | 10.04 | 4.94 | -1.01 | -0.51 |
| Nylon 尼龙树脂 | -0.74 | -0.79 | -1 | -2 |
| 环氧树脂 | 0.66 | 0.56 | -1.01 | -3.54 |
| PET 聚酯 | 3.73 | 3.54 | 0 | 0 |
| PBT 聚酯 | 1.15 | 1.13 | -1 | -1 |
| PC 聚碳 | 0.74 | 0.75 | -1 | 0 |
| PEI 聚酰亚胺 | 0.79 | 0.79 | 0 | 0 |
| 氟塑料 | 3.05 | 2.72 | -0.5 | 0 |
| Teflon FEP | 3.29 | 3.09 | 0 | -0.51 |
| Tefzel ETFE | 6.25 | 5.61 | 0 | 0 |
| Phenolic 酚醛 | -0.18 | -0.31 | 0 | 0 |
| PVC 聚氯乙烯 | 0.68 | 0.7 | 0 | 0 |
| PEEK 聚醚醚酮 | -0.06 | 0.01 | 0 | 0 |
注：具体的材料相容性需要根据实际情况进行测试
与金属和其它材料的相容性
Opteon™ SF33 与常用的金属如铁，铜，铝进行了封闭管实验，实验金属样块浸没于液体中，封闭后放入不同温度的烘箱内两周，发现无分解物出现，使用温度可高达 250℃。
| 温度℃ | 氟离子(F-)浓度 |
| 150 | <0.15 |
| 175 | <0.15 |
| 200 | 0.18 |
| 225 | 0.23 |
| 250 | 1.5 |
暴露极限
急性毒性实验数据显示 Opteon™ SF33 的毒性很低，它的 AEL（可接受的暴露极限）值是 500ppm,属于 A 类产品，与目前使用 HCFC-141b 的安全暴露浓度是一样的。
表 6 ，Opteon™ SF33 与其它溶剂的暴露极限
| 溶剂 | Opteon™SF33 | HCFC-141b | HFC-365mfc | 甲酸甲酯 |
| AEL(ppm) | 500 | 500 | 1000 | 100 |
AEL 指的是 8 小时工作场合可允许的暴露浓度
安全性/可燃性
Opteon™ SF33 是不可燃的液体，在沸腾和蒸发过程中也不会变成可燃性的物质。在开口和闭口杯实验中也无闪点。在 NATT 和 DOT 分类中也不属于可燃性液体。它的热稳定性高于 250℃。
储存和处置
Opteon™ SF33 的热稳定性好，它不氧化，存储过程中也不会降解。应存储于阴凉，清洁和干燥的区域。防止泄漏和潜在的污染。
Opteon ™ The chemical name of SF33 is hexafluorobutene (chemical name HFO-1336mzzZ), which is a very environmentally friendly product with zero ODP and very low GWP. It is very suitable for applications such as equipment cleaning, washing, and drying. It can replace currently used products such as hydrochlorofluorocarbons (HCFC141b) and polyfluorocarbons (PFC). The basic information of the product is shown in the table below:
Table 1 Opteon ™ SF33 physical indicators
| Property | Specification |
|---|---|
| Molecular Weight | 164 |
| Boiling Point, °C | 33 |
| Surface Tension, dyne/cm | 12.9 |
| Liquid Density at 20 °C, g/cm³ | 1.358 |
| Freezing Point, °C | −151 |
| Solubility in Water, ppm | 140 |
| Water Solubility, ppm | 490 |
| Critical Temperature, °C | 171.3 |
| Critical Pressure, MPa | 2.9 |
| Latent Heat of Vaporization (at boiling point), kJ/kg | 164 |
| Specific Heat at 20 °C, kJ/kg·°C | 1.17 |
| Viscosity, cPs | 0.034 |
| ODP | 0 |
| GWP (CO₂, 100 years) | 9.4 |
| VOC | No |
| Flammability (ASTM 681) | No |
| AEL (8 hours) | 500 ppm |
Typical applications:
• Cleaning and washing;
• Dry liquid;
• Particle removal;
Carrier of fluorine lubricating oil;
• Solvent and dispersion medium;
• Thermal conductive liquid;
• Insulating fluid;
Can replace various fluorine liquids such as HCFC-141, PFC, and CF113, etc
Opteon ™ SF33 is an ideal product for cleaning fine particles, capable of removing both metallic and non-metallic particles. In cleaning applications, removing fine particles of pollutants requires a solvent that can form a very thin layer that is smaller than the diameter of the pollutant. The kinetic energy it generates can penetrate between the pollutant and the substrate to remove it. Opteon ™ Due to its low viscosity, high density, and low surface tension, SF33 easily forms a thin layer, effectively achieving the cleaning of pollutants. Ordinary water-based cleaning solutions, such as water or mixtures of water and cleaning agents, have low cleaning efficiency due to their high viscosity and surface tension.
In cleaning applications, a small amount of alcohol can be added to increase the polarity of the cleaning agent to overcome the charge attraction between pollutants and the surface. Another commonly used method in cleaning is to add ultrasonic waves during the cleaning process. High frequency ultrasonic waves can generate small bubbles during the cleaning process, thereby enhancing the cleaning effect.
Steam cleaning process
Steam cleaning technology can be used for intermittent batch cleaning or continuous cleaning techniques. This process usually involves a dedicated equipment system with a high free baffle and a secondary low-temperature condenser (-29C), which can reduce steam loss during the cleaning process. The usual cleaning process includes removing grease, welding flux, and drying equipment.
Pure Opteon ™ SF33 can be used for washing, drying, and cleaning applications, and can also be added with other solvents to form azeotropes or blends to enhance cleaning performance, such as increasing solvent solubility or removing grease.
Cosolvent property
Unlike other PFCs solvents, Opteon ™ SF33 is completely soluble in most esters, ketones, alcohol esters, and lower alcohols. Such as methanol, ethanol, isopropanol, etc. It is also compatible with lower alkanes such as hexane and heptane. It has limited solubility in other high molecular weight chemicals, such as advanced hydrocarbon oils, silicone oils, waxes, and fats. It can also increase the solubility of some solvents and improve the resistance of general solvents to some fluorocarbon oils such as Krytox ® The solubility of lubricating grease such as Fomblin.
The solvents with good compatibility include:
Binary esters, linear alkanes, ethylene glycol propylene ether, N-methylpyrrolidone, propylene glycol butyl ether, propylene glycol monomethyl ether, tetrahydrofuran, lower alcohols, etc.
Table 2, Opteon ™ The cosolvent properties of SF33
| Mixture | Boiling Point | KB Value |
|---|---|---|
| Opteon™ SF33 | 33 | 11.3 |
| Opteon™ SF33 + trans-1,2-dichloroethylene | 28.9 | 50 |
| Opteon™ SF33 + cyclopentane | 26.7 | 32 |
| Opteon™ SF33 + ethanol | 33.1 | 32 |
| Opteon™ SF33 + methanol | 31.6 | 29 |
| Opteon™ SF33 + methyl formate | 30.8 | 14 |
Table 3 Performance Comparison of Different Fluorinated Liquids
| Property | HCFC-141b | Opteon™ SF33 | Vertrel™ XF | HFE-7100 |
|---|---|---|---|---|
| Chemical Formula | CHCl₂-CH₂F | CF₃CH=CHCF₃ | C₅H₂F₁₀ | CF₃(CF₂)₃OCH₃ |
| ODP | 0.11 | 0 | 0 | 0 |
| GWP | 725 | 9.4 | 1700 | 320 |
| Flash Point (°C) | None | None | None | None |
| Boiling Point (°C) | 32 | 33 | 55 | 61 |
| Freezing Point (°C) | −103 | −151 | −80 | −135 |
| Latent Heat of Vaporization (kJ/kg) | 223 | 164 | 130 | 126 |
| Surface Tension (dyne/cm) | 19.3 | 13.5 | 14.1 | 13.6 |
| Liquid Density | — | — | — | — |
| KB Value | 56 | 11.3 | 9 | 10 |
Compatibility between plastics and elastomers
Most plastics and elastomers are compatible with Opteon ™ SF33 is compatible and can be directly exposed to liquids. The table below lists the results of short-term exposure to commonly used plastic materials. The testing condition is to immerse the sample in liquid and leave it for 14 days. The test results are as follows.
Table 4 Opteon ™ Compatibility performance of non-metallic materials in SF33
| Material (Plastic) | Weight Change % | Weight Change After 24 h Contact % | Surface Hardness Change % | Surface Hardness Change After 24 h % |
|---|---|---|---|---|
| Natural Rubber | −0.55 | −0.98 | 7.1 | 2.58 |
| EPDM | 2.39 | 0.84 | 2.56 | 0.64 |
| Polyester | 10.04 | 4.94 | −1.01 | −0.51 |
| Nylon Resin | −0.74 | −0.79 | −1 | −2 |
| Epoxy Resin | 0.66 | 0.56 | −1.01 | −3.54 |
| PET Polyester | 3.73 | 3.54 | 0 | 0 |
| PBT Polyester | 1.15 | 1.13 | −1 | −1 |
| PC Polycarbonate | 0.74 | 0.75 | −1 | 0 |
| PEI Polyetherimide | 0.79 | 0.79 | 0 | 0 |
| Fluoroplastic | 3.05 | 2.72 | −0.5 | 0 |
| Teflon FEP | 3.29 | 3.09 | 0 | −0.51 |
| Tefzel ETFE | 6.25 | 5.61 | 0 | 0 |
| Phenolic | −0.18 | −0.31 | 0 | 0 |
| PVC Polyvinyl Chloride | 0.68 | 0.7 | 0 | 0 |
| PEEK Polyetheretherketone | −0.06 | 0.01 | 0 | 0 |
Note: The specific material compatibility needs to be tested according to the actual situation
Compatibility with metals and other materials
Opteon ™ SF33 conducted closed tube experiments with commonly used metals such as iron, copper, and aluminum. The experimental metal samples were immersed in liquid and placed in ovens at different temperatures for two weeks after sealing. No decomposition products were found, and the operating temperature could reach up to 250 ℃.
| Temperature (°C) | Fluoride Ion (F⁻) Concentration |
|---|---|
| 150 | <0.15 |
| 175 | <0.15 |
| 200 | 0.18 |
| 225 | 0.23 |
| 250 | 1.5 |
Exposure limit
Acute toxicity test data shows Opteon ™ The toxicity of SF33 is very low, with an acceptable exposure limit (AEL) value of 500ppm, which belongs to Class A products and is the same as the safe exposure concentration currently used for HCFC-141b1.
Table 6, Opteon ™ Exposure limits of SF33 and other solvents
| Solvent | Opteon™ SF33 | HCFC-141b | HFC-365mfc | Methyl Formate |
|---|---|---|---|---|
| AEL (ppm) | 500 | 500 | 1000 | 100 |
AEL refers to the permissible exposure concentration in an 8-hour workplace
Safety/Flammability
Opteon ™ SF33 is a non flammable liquid that does not become flammable during boiling and evaporation processes. There is no flash point in both open and closed cup experiments. It is also not classified as a flammable liquid in the NATT and DOT classifications. Its thermal stability is higher than 250 ℃.
Storage and disposal
Opteon ™ SF33 has good thermal stability, it does not oxidize, and it will not degrade during storage. It should be stored in a cool, clean, and dry area. Prevent leaks and potential contamination.
规格
英文名称
Opteon™ SF33 environmentally friendly cleaning and solvent fluorinated solution
法律信息
Opteon is a registered trademark of The Chemours Company FC, LLC
技术文档
高级数据
质检证书(CoA,COO,BSE/TSE 和分析图谱)
C of A & Other Certificates(BSE/TSE, COO):
输入批号以搜索分析图谱:
技术文档和文章
溶液计算器
产品仅提供给经过验证的企业、机构和合格的专业人员用于研发。不适用于人类、动物、诊断或治疗。
Copyright © 2023至今 上海阿拉丁生化科技股份有限公司 SSE:688179 保留所有权利。
危险品化学品经营许可证（带存储）