甲醇中咪鲜胺溶液标准物质

CAS: 67747-09-5 货号: P283744 分子式: C15H16Cl3N3O2 分子量: 376.67 Beilstein号: 8155344 EC号: 266-994-5
有货
级别和纯度: 1000μg/mL in Methanol
别名
咪酰胺 | 咪鲜胺 | N-丙基-N-[2-(2,4,6-三氯苯氧基)乙基]-咪唑-1-甲酰胺
储存条件
2-8°C储存,避光
运输条件
低温运输
★
规格
库存
价格
数量
1.2ml
P283744-1.2ml
现货 Stock Image
¥185.90
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为什么选择此级别

,适用于对基线干扰要求严格的色谱和分析工作流程。

🌡

储存与运输

2-8°C储存,避光。低温运输 。请查阅批次 COA 获取详细规格。

📋

质量文档

SDS、COA、产品数据表及规格说明书均可下载。可通过批号查询获取批次 COA。

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文献证明

在色谱分析、有机合成和交叉偶联反应领域已被 24 篇同行评审文献引用。

概述

用途
本标准物质可作为工作标准,用于日常分析和检测;也可用于仪器校准、分析方法确认与评价、测量过程质量控制及技术仲裁与认证评价等。

样品制备

本标准物质采用纯度经准确定值的咪鲜胺( CAS : 67747-09-5 )为溶质,以甲醇为溶剂,在室温20±3℃洁净实验室中采用重量-容量法配制而成。


特征量值及扩展不确定度

组分标准值扩展不确定度(k=2)基体
咪鲜胺
1000μg/mL
3%甲醇

标准值的扩展不确定度主要由原料纯度、称量、定容以及均匀性、长期稳定性等不确定度合成。


包装、储存及使用

包装:本标准物质采用包装,规格1.2mL携带或运输时应有防碎裂保护。储存及使用:冷藏密闭及避光条件下保存。使用前应于室温(20±3℃)平衡,并充分摇动以保证均匀。安瓿瓶一经打开,应立即使用,不可再次熔封后作为标准物质使用,使用中严格防止沾污。


Application
This standard substance can be used as a working standard for daily analysis and testing; it can also be used for instrument calibration, analytical method confirmation and evaluation, measurement process quality control, and technical arbitration and certification evaluation.

Sample Preparation

This standard substance is prepared using prochloraz (CAS: 67747-09-5) whose purity has been accurately determined as the solute, methanol as the solvent, and the weight-volume method in a clean laboratory at room temperature of 20±3°C.


Characteristic value and expanded uncertainty

ComponentStandard valueExpanded uncertainty (k=2)Matrix
Prochloraz
1000μg/mL
3%methanol

The expanded uncertainty of the standard value is mainly synthesized by the uncertainty of raw material purity, weighing, constant volume, uniformity, and long-term stability.


Packaging, storage and use

Packaging: This standard material is packaged, and the specification 1.2mL should be protected from shattering when carried or transported. Storage and use: Keep it under refrigerated airtight and protected from light. Before use, it should be balanced at room temperature (20±3℃) and shake well to ensure uniformity. Once the ampoule is opened, it should be used immediately. It cannot be used as a standard substance after being re-sealed. Strictly prevent contamination during use.

规格

别名
咪酰胺 | 咪鲜胺 | N-丙基-N-[2-(2,4,6-三氯苯氧基)乙基]-咪唑-1-甲酰胺
英文别名
MFCD00016532 | NCGC00163713-05 | Z2TCZ088AV | ~{N}-propyl-~{N}-[2-[2,4,6-tris(chloranyl)phenoxy]ethyl]imidazole-1-carboxamide | Ascurit | 1H-Imidazole-1-carboxamide, N-propyl-N-(2-(2,4,6-trichlorophenoxy)ethyl)- | CCRIS 3109 | Mirage | N-Propyl-N-(2-(2,4,
规格或纯度
1000μg/mL in Methanol
英文名称
Prochloraz in Methanol
储存条件
2-8°C储存,避光
运输条件
低温运输
名称和识别符
EC号
266-994-5
分子类型
小分子
IUPAC Name
N-propyl-N-[2-(2,4,6-trichlorophenoxy)ethyl]imidazole-1-carboxamide
INCHI
1S/C15H16Cl3N3O2/c1-2-4-20(15(22)21-5-3-19-10-21)6-7-23-14-12(17)8-11(16)9-13(14)18/h3,5,8-10H,2,4,6-7H2,1H3
InChi Key
TVLSRXXIMLFWEO-UHFFFAOYSA-N
Smiles
CCCN(CCOC1=C(C=C(C=C1Cl)Cl)Cl)C(=O)N2C=CN=C2
Isomeric SMILES
CCCN(CCOC1=C(C=C(C=C1Cl)Cl)Cl)C(=O)N2C=CN=C2
分子量
376.67
Beilstein号
8155344
Reaxy-Rn
8155344
Reaxys-RN link address
https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=8155344&ln=

技术文档

📋 安全数据表 (SDS)

全面的危险、操作、储存及法规合规文件。

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✅ 分析证书 (COA)

批次质量数据。输入批号以获取对应 COA。

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📊 产品数据表

产品规格和应用的快速参考摘要。

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🔬 规格说明书

该级别的完整质量属性和验收标准。

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高级数据

系统学分类

分类树(Taxonomy Tree)

界(kingdom) 有机化合物
超类(Superclass) 苯类化合物
类(Class) 酚醚
亚类(Subclass) 暂无
中间层级节点(Intermediate Tree Nodes) 暂无
直接上位类(Direct Parent) 酚醚
其他上位类(Alternative Parents) 苯氧基化合物  氯苯类  羰基咪唑类  烷基芳基醚  N-取代咪唑  芳基氯化物  杂芳族化合物  尿素  氮杂环化合物  有机光子化合物  有机氮化合物  有机氯化物  有机氧化物  碳氢化合物衍生物  
分子骨架(Molecular Framework) 芳香族杂单环化合物
取代基(Substituents) 芳基醚 - 芳香族杂单环化合物 - 芳基氯化物 - 芳基卤化物 - 氮杂环 - 吡唑 - 碳酸衍生物 - 氯苯 - 乙醚 - 卤苯 - 杂芳香族化合物 - 烃衍生物 - 咪唑 - 咪唑-1-羰基 - 单环苯基基团 - N-取代咪唑 - 有机硝基化合物 - 有机氧化物 - 有机氧化合物 - 有机氯化物 - 有机卤化物 - 有机杂环化合物 - 有机氮化合物 - 有机氧化合物 - 有机氮化合物 - 苯酚醚 - 苯氧基化合物 - 脲
描述(Description) 该化合物属于酚醚类有机化合物。这类芳香化合物含有被苯环取代的醚基团。
外部描述符(External Descriptors) Amide fungicides
三维结构
交互式化学结构模型





关联靶点(人)
ESR1 Tclin Estrogen receptor alpha (17718 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
AR Tclin Androgen Receptor (11781 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
PPARG Tclin Peroxisome proliferator-activated receptor gamma (15191 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
THRB Tclin Thyroid hormone receptor beta-1 (7926 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
AHR Tclin Aryl hydrocarbon receptor (1071 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
NR1H4 Tclin Bile acid receptor FXR (6228 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
TP53 Tchem Cellular tumor antigen p53 (48468 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
关联靶点(其它种属)
Ppard Peroxisome proliferator-activated receptor delta (358 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Oculimacula yallundae (312 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Fusarium oxysporum (3998 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Alternaria alternata (757 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Fusarium culmorum (260 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Colletotrichum graminicola (112 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Macrophomina phaseolina (474 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Phytophthora cactorum (113 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Nfe2l2 Nuclear factor erythroid 2-related factor 2 (214 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Nr1i2 Nuclear receptor subfamily 1 group I member 2 (14 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Fusarium odoratissimum (44 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Neofusicoccum australe (78 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Musa acuminata AAA Group (20 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Diplodia mutila (102 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Neofusicoccum luteum (172 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Colletotrichum truncatum (198 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Oculimacula acuformis (31 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Monilinia laxa (436 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Zymoseptoria tritici (367 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Podosphaera fuliginea (1057 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Blumeria graminis f. sp. tritici (444 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
作用机制
作用机制 Action Type target ID Target Name Target Type Target Organism Binding Site Name 参考文献
化学和物理性质
分子量
376.700 g/mol
XLogP3
4.600
氢键供体数Hydrogen Bond Donor Count
0
氢键受体数Hydrogen Bond Acceptor Count
3
可旋转键计数Rotatable Bond Count
6
精确质量Exact Mass
375.031 Da
单同位素质量Monoisotopic Mass
375.031 Da
拓扑极表面积Topological Polar Surface Area
47.400 Ų
重原子数Heavy Atom Count
23
形式电荷Formal Charge
0
复杂度Complexity
377.000
同位素原子数Isotope Atom Count
0
定义的原子立体中心计数Defined Atom Stereocenter Count
0
未定义的原子立体中心计数Undefined Atom Stereocenter Count
0
定义的键立体中心计数Defined Bond Stereocenter Count
0
未定义的键立体中心计数Undefined Bond Stereocenter Count
0
所有立体化学键的总数The total count of all stereochemical bonds
0
共价键合单元计数Covalently-Bonded Unit Count
1
安全和危险性(GHS)
象形图
GHS07,   GHS09
信号词
警告
危险声明

H302: 吞食有害

H400: 对水生生物有剧毒

H410: 对水生生物有剧毒并具有长期持续影响

预防措施声明

P264: 处理后要彻底洗手。

P270: 使用本产品时,请勿进食、饮水或吸烟。

P273: 避免释放到环境中。

P330: 漱口

P391: 收集溢出物

P501: 将内容物/容器处理到。。。

P301+P317: 如果被吞咽:请寻求医疗帮助。

RTECS
NI4000400
质检证书(CoA,COO,BSE/TSE 和分析图谱)
C of A & Other Certificates(BSE/TSE, COO):
输入批号以搜索分析图谱:
此产品的引用文献
引用文献
1. Zhang Shuwen, Luo Ting, Weng You, Wang Dou, Sun Li, Yu Zheping, Zhao Yao, Liang Senmiao, Ren Haiying, Zheng Xiliang, Jin Yuanxiang, Qi Xingjiang.  (2023)  Toxicologic effect and transcriptome analysis for sub-chronic exposure to carbendazim, prochloraz, and their combination on the liver of mice.  ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH,  [PMID:38123780] [10.1007/s11356-023-31412-9]
2. Siting Lai, Li Li, Qian Li, Shijiang Zhu, Guang Wang.  (2023)  Discrimination of internal browning in pineapple during storage based on changes in volatile compounds.  FOOD CHEMISTRY,  [PMID:37688818] [10.1016/j.foodchem.2023.137358]
3. Junwei Yao, Heng Zhi, Qingshan Shi, Yu Zhang, Jin Feng, Jingxia Liu, Hui Huang, Xiaobao Xie.  (2023)  Tannic Acid Interfacial Modification of Prochloraz Ethyl Cellulose Nanoparticles for Enhancing the Antimicrobial Effect and Biosafety of Fungicides.  ACS Applied Materials & Interfaces,  [PMID:37602737] [10.1021/acsami.3c07761]
4. Yuwei Luo, Xin Chen, Jin Xin Che, Yonghua Zhang, Qiuli Ouyang, Nengguo Tao.  (2023)  (E)-2-Octenal suppresses the growth of a prochloraz-resistant Penicillium italicum strain and its potential antifungal mechanisms.  POSTHARVEST BIOLOGY AND TECHNOLOGY,  [10.1016/j.postharvbio.2023.112515]
5. Fei Tong, Zan Yang, Zheng Wang, Wenya Liu, Wanqi Jiang, Lu Zhu, Lei Wang, Mingming Zheng, Ruyan Hou, Yibin Zhou, Yingnan Liu.  (2023)  Enzyme-mediated Ru@UiO-66@MnO2 NSs/thiamine-based ratiometric fluorescence sensor for visual detection of organophosphorus pesticide residues.  FOOD CHEMISTRY,  [PMID:37487398] [10.1016/j.foodchem.2023.136945]
6. Wanqi Jiang, Zan Yang, Fei Tong, Siyu Zhang, Lu Zhu, Lei Wang, Lunjing Huang, Kang Liu, Mingming Zheng, Yibin Zhou, Ruyan Hou, Yingnan Liu.  (2023)  Two birds with one stone: An enzyme-regulated ratiometric fluorescent and photothermal dual-mode probe for organophosphorus pesticide detection.  BIOSENSORS & BIOELECTRONICS,  [PMID:36638562] [10.1016/j.bios.2023.115074]
7. Honglin Qin, Yuan Tao, Ruiting Niu, Bingyan Han, Lizhen Qiao.  (2022)  Flower-like mesoporous Fe3O4@SiO2@F/NiO composites for magnetic solid-phase extraction of imidazole fungicides in tap water, milk and green tea.  MICROCHEMICAL JOURNAL,  [10.1016/j.microc.2022.108292]
8. Jiajian Huang, Sukun Lin, Jingtong Zhou, Huiya Chen, Shiqi Tang, Jian Wu, Suqing Huang, Dongmei Cheng, Zhixiang Zhang.  (2022)  Dissipation and Distribution of Prochloraz in Bananas and a Risk Assessment of Its Dietary Intake.  Toxics,  10  (8): (435).  [PMID:36006113] [10.3390/toxics10080435]
9. Gui-Yang Zhu, Ying Chen, Su-Yan Wang, Xin-Chi Shi, Daniela D. Herrera-Balandrano, Victor Polo, Pedro Laborda.  (2022)  Peel Diffusion and Antifungal Efficacy of Different Fungicides in Pear Fruit: Structure-Diffusion-Activity Relationships.  Journal of Fungi,  8  (5): (547).  [PMID:35628802] [10.3390/jof8050547]
10. Ruofan Wei, Rong Wang, Yong Li, Moyi Yue, Wanlong Ding.  (2022)  Identification, biological characteristics and fungicide sensitivity of Colletotrichum species that cause anthracnose on Anemarrhena asphodeloides in China.  JOURNAL OF PHYTOPATHOLOGY,  170  (6): (373-381).  [10.1111/jph.13086]
11. Douxin Xiao, Jingli Cheng, Wenlong Liang, Lianli Sun, Jinhao Zhao.  (2021)  Metal-phenolic coated and prochloraz-loaded calcium carbonate carriers with pH responsiveness for environmentally-safe fungicide delivery.  CHEMICAL ENGINEERING JOURNAL,  [10.1016/j.cej.2021.129274]
12. Xiaoyu Liang, Yun Peng, Yanchao Liu, Meng Wang, Ye Yang, Yu Zhang.  (2019)  First report of Bipolaris bicolor causing a leaf spot disease on rubber tree.  JOURNAL OF PHYTOPATHOLOGY,  167  (10): (553-557).  [10.1111/jph.12839]
13. Yibing Yan, Fangxiang Song, Songye Li, Tingxian Li, Qian Li, Yan Li.  (2025)  Degradable mesoporous organosilicon nanoparticles coated with chitosan-Cu2+ complexes with dual stimulus-response for efficient prochloraz delivery.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,  [PMID:39920936] [10.1016/j.ijbiomac.2025.140709]
14. Xin-Yu Ji, Bing-Yi Wang, Yi-Feng Zhang, Yu-Jing Zhang, Ya-Jie Lai, Yang Yang, Xiang-Chen Wang, Su-Yan Wang, Pedro Laborda, Xin-Chi Shi.  (2024)  Dipicolinic acid reduces Epicoccum sorghinum symptoms on maize and inhibits tenuazonic acid biosynthesis.  PEST MANAGEMENT SCIENCE,  [PMID:39189553] [10.1002/ps.8393]
15. Guang Yang, Fengrui Li, Haoru Zhang, Honglei Yan, Shuang Gao, Ying Fu, Fei Ye.  (2024)  Electrospinning for producing antifungal nanofibers consisting of prochloraz/hydroxypropyl-γ-cyclodextrin inclusion complex.  INDUSTRIAL CROPS AND PRODUCTS,  [10.1016/j.indcrop.2024.118282]
16. Junqi Feng, Yanyan Zheng, Tao Luo, Fengna Xi, Hao Lai.  (2024)  Graphitic carbon nitride nanosheet supported silica nanochannel film for enhanced electrochemiluminescence sensing of 2,4,6-trichlorophenol and prochloraz.  RSC Advances,  14  (39): (28976-28983).  [PMID:39268050] [10.1039/D4RA03623A]
17. Qiongmei Mai, Yu Lu, Qianyu Cai, Jianglong Hu, Yunyou Lv, Yonglan Yang, Liqiang Wang, Yuezhao Zhou, Jie Liu.  (2024)  pH and Pectinase Dual-Responsive Zinc Oxide Core-Shell Nanopesticide: Efficient Control of Sclerotinia Disease and Reduction of Environmental Risks.  Nanomaterials,  14  (24): (2022).  [PMID:39728558] [10.3390/nano14242022]
18. Wen Hao, Jingwen He, Jie Wu, Lin Cai, Yifei Wang, Guozhen Fang, Shuo Wang.  (2024)  Built-in potential-regulated and exogenous excited electrochemiluminescence sensor based on dual-monomers molecularly imprinted polymer for the biomimetic detection of thiabendazole.  FOOD CHEMISTRY,  [PMID:39541690] [10.1016/j.foodchem.2024.141984]
19. Yongqing Yang, Yong Wang, Jing Gao, Zhidan Shi, Wenjin Chen, Haiyan Huangfu, Zhengnan Li, Yan Liu.  (2024)  Characterisation of Fusarium oxysporum f. sp. radicis-lycopersici in Infected Tomatoes in Inner Mongolia, China.  Journal of Fungi,  10  (9): (622).  [PMID:39330382] [10.3390/jof10090622]
20. Huang Zhixing, He Zhenrui, Ding Jiexin, Zhu Yiming, Zhou Erxun.  (2025)  Combined application of a biocontrol bacterium Pseudomonas aeruginosa E1 - 23 with the fungicide prochloraz for the effective control of soybean root rot caused by Fusarium neocosmosporiellum.  EUROPEAN JOURNAL OF PLANT PATHOLOGY,  [10.1007/s10658-025-03045-w]
21. Qianyu Cai, Yucheng Chen, Ting Wang, Qiongmei Mai, Jianglong Hu, Yunyou Lv, Yanhui Zhou, Jie Liu.  (2025)  Hydroxy propyl cellulose-coated and prochloraz-loaded calcium carbonate carriers with pH/cellulose responsiveness for environmentally-safe fungicide delivery.  NEW JOURNAL OF CHEMISTRY,  [10.1039/D5NJ00314H]
22. Yibing Yan, Songye Li, Shanshan Wang, Yifan Peng, Kaikun Pi, Bin Sun, Liang Cheng, Bing Liu, Fangxiang Song.  (2025)  Pectin-coated hollow organosilicon construction of a dual pH and pectinase stimulation-responsive prochloraz delivery system for the control of rice sheath blight.  PEST MANAGEMENT SCIENCE,  [PMID:41211611] [10.1002/ps.70341]
23. Xiumei Chen, Chen Zhu, Junyu Chen, Chaobo Bing, Qiuli Ouyang, Xiangrong Zhu, Nengguo Tao.  (2026)  Carboxymethyl cellulose/polyvinyl alcohol aerogel incorporating cinnamaldehyde-citronellal synergy for controlling green mold decay in citrus fruit.  POSTHARVEST BIOLOGY AND TECHNOLOGY,  [10.1016/j.postharvbio.2026.114187]
24. Liangliang Gao, Tengjie Li, Zengrong Xiong, Mingnan You, Jun Zhang, Nengguo Tao.  (2026)  N'-(4-fluorophenyl)-2-pyridinecarbohydrazide targets succinate dehydrogenase to control citrus blue mold.  FOOD MICROBIOLOGY,  [PMID:41963050] [10.1016/j.fm.2026.105077]
溶液计算器

常见问题

本产品应如何储存?
请于2–8 °C、避光条件下保存。本品对光敏感,请保存在原始的避光或棕色容器中。
本产品如何运输?
本产品采用湿冰冷藏运输。收货后请立即拆包,并按上述储存条件保存。
本产品的 CAS 号、分子式和分子量是多少?
本产品的 CAS 号为 67747-09-5,分子式为 C15H16Cl3N3O2,分子量为 376.67 g/mol。InChIKey TVLSRXXIMLFWEO-UHFFFAOYSA-N。
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