双-[γ-(三乙氧基硅)丙基]-四硫化物

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基本描述

别名 双[3-(三乙氧基硅)丙基]-四硫化物 | 3,3'-四硫双(丙基三乙氧基硅烷)
英文别名 TESPTS | 4,4,15,15-Tetraethoxy-3,16-dioxa-8,9,10,11-tetrathia-4,15-disilaoctadecane | DTXSID3029362 | bis(3-triethoxysilylpropyl)tetrasulfane | bis(triethoxysilylpropyl)tetrasulfide | Bis[3-(triethoxysilyl)propyl]tetrasulfide | bis(3-(triethoxysilyl)propy
规格或纯度 ≥90%
英文名称 Bis[3-(triethoxysilyl)propyl] tetrasulfide
运输条件 常规运输
产品介绍

易溶于乙醇、丙酮、苯、甲苯等多种溶剂,不溶于水中。 Bis[3-(triethoxysilyl)propyl] tetrasulfide (TESPTS) is generally used as a crosslinking agent and reinforcing filler in the manufacturing of rubber. TESPT film provides corrosion protection to the metallic substrates. It is also used as a precursor in the synthesis of mesoporous organosilicas.


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名称和识别符

PubChem SID 488188345
EC号 254-896-5
分子类型 小分子
IUPAC Name triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane
INCHI InChI=1S/C18H42O6S4Si2/c1-7-19-29(20-8-2,21-9-3)17-13-15-25-27-28-26-16-14-18-30(22-10-4,23-11-5)24-12-6/h7-18H2,1-6H3
InChi Key VTHOKNTVYKTUPI-UHFFFAOYSA-N
Canonical SMILES CCO[Si](CCCSSSSCCC[Si](OCC)(OCC)OCC)(OCC)OCC
Isomeric SMILES CCO[Si](CCCSSSSCCC[Si](OCC)(OCC)OCC)(OCC)OCC
WGK Germany 1
PubChem CID 162012
分子量 538.95
Beilstein号 2062235

化学和物理性质

溶解性 Miscible with toluene, primary alcohols, ketones, benzene, chlorinated hydrocarbons, acetonitrile, dimethylformaminde and dimethysulfoxide. Immiscible with water
密度 1.08
折光率 1.49
闪点(℉) 212 °F
闪点(℃) 91°C
沸点 250°C
分子量 539.000 g/mol
XLogP3
氢键供体数Hydrogen Bond Donor Count 0
氢键受体数Hydrogen Bond Acceptor Count 10
可旋转键计数Rotatable Bond Count 23
精确质量Exact Mass 538.14 Da
单同位素质量Monoisotopic Mass 538.14 Da
拓扑极表面积Topological Polar Surface Area 157.000 Ų
重原子数Heavy Atom Count 30
形式电荷Formal Charge 0
复杂度Complexity 321.000
同位素原子数Isotope Atom Count 0
定义的原子立体中心计数Defined Atom Stereocenter Count 0
未定义的原子立体中心计数Undefined Atom Stereocenter Count 0
定义的键立体中心计数Defined Bond Stereocenter Count 0
未定义的键立体中心计数Undefined Bond Stereocenter Count 0
所有立体化学键的总数The total count of all stereochemical bonds 0
共价键合单元计数Covalently-Bonded Unit Count 1

安全和危险性(GHS)

WGK Germany 1
个人防护装备 Eyeshields,Gloves

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批号(Lot Number) 证书类型 日期 货号
A2517083 分析证书 23-06-16 B115359
G2329147 分析证书 23-06-16 B115359
G2329141 分析证书 23-06-16 B115359
G2329130 分析证书 23-06-16 B115359
I2217161 分析证书 22-08-29 B115359
I2217132 分析证书 22-08-29 B115359
I2217117 分析证书 22-08-29 B115359
B2307214 分析证书 22-08-29 B115359
B2307121 分析证书 22-08-29 B115359
G2205169 分析证书 22-07-08 B115359
H2204337 分析证书 22-06-20 B115359
H2204338 分析证书 22-06-20 B115359
H2204339 分析证书 22-06-20 B115359
H2204351 分析证书 22-06-20 B115359
B2307112 分析证书 22-06-20 B115359
F1927039 分析证书 22-05-05 B115359
C2218053 分析证书 22-03-23 B115359

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此产品的引用文献

1. Jianhao Liang, Junhong Ling, Xu Zhang, Xiao–kun Ouyang, A.M. Omer, Guocai Yang.  (2024)  pH/glutathione dual-responsive copper sulfide-coated organic mesoporous silica for synergistic chemo-photothermal therapy.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,  657  (1).  [PMID:38029524] [10.1016/j.jcis.2023.11.146]
2. Jia Tan, Binbin Ding, Hao Chen, Qi Meng, Jing Li, Chunzheng Yang, Wenying Zhang, Xinyang Li, Di Han, Pan Zheng, Ping'an Ma, Jun Lin.  (2023)  Effects of Skeleton Structure of Mesoporous Silica Nanoadjuvants on Cancer Immunotherapy.  Small,  (2305567).  [PMID:37702141] [10.1002/smll.202305567]
3. Yihui Xu, Yudong Liu, Xuan Qin, Jun Liu, Liqun Zhang.  (2023)  A novel strategy to functionalize styrene butadiene rubber toward enhanced interfacial interaction with silica.  JOURNAL OF APPLIED POLYMER SCIENCE,  140  (39): (e54476).  [10.1002/app.54476]
4. Geng Yang, Ting Song, Hanxi Zhang, Mengyue Li, Xiaodan Wei, Wanyi Zhou, Chunhui Wu, Yiyao Liu, Hong Yang.  (2023)  Stimulus-Detonated Biomimetic “Nanobomb” with Controlled Release of HSP90 Inhibitor to Disrupt Mitochondrial Function for Synergistic Gas and Photothermal Therapy.  Advanced Healthcare Materials,  (2300945).  [PMID:37200205] [10.1002/adhm.202300945]
5. Shuting Zheng, Honglei Hu, Meirong Hou, Kai Zhu, Zede Wu, Li Qi, Hui Xia, Guoqiang Liu, Yunyan Ren, Yikai Xu, Chenggong Yan, Bingxia Zhao.  (2023)  Proton pump inhibitor-enhanced nanocatalytic ferroptosis induction for stimuli-responsive dual-modal molecular imaging guided cancer radiosensitization.  Acta Biomaterialia,  162  (72).  [PMID:36931419] [10.1016/j.actbio.2023.03.011]
6. Cuixian Li, Piao Zhu, Huijing Xiang, Yunjie Jin, Beilei Lu, Yujia Shen, Wenping Wang, Beijian Huang, Yu Chen.  (2023)  3D-CEUS tracking of injectable chemo-sonodynamic therapy-enabled mop-up of residual renal cell carcinoma after thermal ablation.  Materials Today Bio,  18  (100513).  [PMID:36569591] [10.1016/j.mtbio.2022.100513]
7. Zhou Shaoqian, Chen Xueying, Huang Rixin, Lin Yi, Ye Xiaoxia.  (2022)  Interfacial treatment-induced high-strength plant fiber/phenolic resin composite.  Frontiers in Materials,  [10.3389/fmats.2022.1072249]
8. Hao Chi, Guang Zhu, Yalin Yin, He Diao, Zicheng Liu, Shibo Sun, Zhaoming Guo, Weiping Xu, Jianqiang Xu, Changhao Cui, Xiao-Jin Xing, Kun Ma.  (2022)  Dual-Responsive multifunctional “core–shell” magnetic nanoparticles promoting Fenton reaction for tumor ferroptosis therapy.  INTERNATIONAL JOURNAL OF PHARMACEUTICS,  622  (121898).  [PMID:35688287] [10.1016/j.ijpharm.2022.121898]
9. Qiangtao Zhu, Dongyu Pan, Yangyi Sun, Dongming Qi.  (2022)  Controllable Microemulsion Synthesis of Hybrid TiO2–SiO2 Hollow Spheres and Au-Doped Hollow Spheres with Enhanced Photocatalytic Activity.  LANGMUIR,  38  (13): (4001–4013).  [PMID:35290732] [10.1021/acs.langmuir.1c03484]
10. Liping Wei, Mei Shen, Zhenxiang Xin.  (2022)  A novel material based on deep eutectic solvents and its application in in-situ modified silica-reinforced styrene-butadiene rubber.  JOURNAL OF APPLIED POLYMER SCIENCE,  139  (18): (52089).  [10.1002/app.52089]
11. Kun Zeng, Li Ma, Wenxiu Yang, Shan Lei, Mozhen Wang, Yezi You, Yu Zhao, Xuewu Ge.  (2020)  Biodegradable nano-organosilica gene carrier for high-efficiency gene transfection.  Journal of Materials Chemistry B,  (12): (2483-2494).  [PMID:32110782] [10.1039/D0TB00108B]
12. Jia Ke, Yumei Wang, Lingmei Wang, Baixue Yang, Kaijun Gou, Yanxin Qin, Sanming Li, Heran Li.  (2020)  Synthesis and characterization of core-shell mesoporous silica nanoparticles with various shell thickness as indomethacin carriers: In vitro and in vivo evaluation.  MICROPOROUS AND MESOPOROUS MATERIALS,  297  (110043).  [10.1016/j.micromeso.2020.110043]
13. Yang Qingsong, Li Li, Zhao Fang, Han Haoya, Wang Weihua, Tian Yuchuan, Wang Yunwei, Ye Zhishuang, Guo Xuhong.  (2019)  Hollow silica–polyelectrolyte composite nanoparticles for controlled drug delivery.  JOURNAL OF MATERIALS SCIENCE,  54  (3): (2552-2565).  [10.1007/s10853-018-2996-7]
14. Yangyi Sun, Min Chen, Limin Wu.  (2018)  Controllable synthesis of hollow periodic mesoporous organosilica spheres with radial mesochannels and their degradable behavior.  Journal of Materials Chemistry A,  (26): (12323-12333).  [10.1039/C8TA02569J]
15. Lijun Sun, Dangge Wang, Yu Chen, Liying Wang, Ping Huang, Yaping Li, Ziwei Liu, Heliang Yao, Jianlin Shi.  (2017)  Core-shell hierarchical mesostructured silica nanoparticles for gene/chemo-synergetic stepwise therapy of multidrug-resistant cancer.  BIOMATERIALS,  133  (219).  [PMID:28441616] [10.1016/j.biomaterials.2017.04.028]
16. Yanping Wu, Lei Chen, Songlv Qin, Jinlong Li, Huidi Zhou, Jianmin Chen.  (2017)  Functionalized graphene-reinforced rubber composite: Mechanical and tribological behavior study.  JOURNAL OF APPLIED POLYMER SCIENCE,  134  (25): [10.1002/app.44970]
17. Lin-Lin Hu, Dan-Dan Zhang, Yang Zhang, Yang Shu, Xu-Wei Chen, Jian-Hua Wang.  (2016)  Glutathione functionalized mesoporous organosilica conjugate for drug delivery.  RSC Advances,  (61): (56287-56293).  [10.1039/C6RA10841E]

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15. Jia Tan, Binbin Ding, Hao Chen, Qi Meng, Jing Li, Chunzheng Yang, Wenying Zhang, Xinyang Li, Di Han, Pan Zheng, Ping'an Ma, Jun Lin.  (2023)  Effects of Skeleton Structure of Mesoporous Silica Nanoadjuvants on Cancer Immunotherapy.  Small,  (2305567).  [PMID:37702141] [10.1002/smll.202305567]
16. Yihui Xu, Yudong Liu, Xuan Qin, Jun Liu, Liqun Zhang.  (2023)  A novel strategy to functionalize styrene butadiene rubber toward enhanced interfacial interaction with silica.  JOURNAL OF APPLIED POLYMER SCIENCE,  140  (39): (e54476).  [10.1002/app.54476]
17. Geng Yang, Ting Song, Hanxi Zhang, Mengyue Li, Xiaodan Wei, Wanyi Zhou, Chunhui Wu, Yiyao Liu, Hong Yang.  (2023)  Stimulus-Detonated Biomimetic “Nanobomb” with Controlled Release of HSP90 Inhibitor to Disrupt Mitochondrial Function for Synergistic Gas and Photothermal Therapy.  Advanced Healthcare Materials,  (2300945).  [PMID:37200205] [10.1002/adhm.202300945]
18. Shuting Zheng, Honglei Hu, Meirong Hou, Kai Zhu, Zede Wu, Li Qi, Hui Xia, Guoqiang Liu, Yunyan Ren, Yikai Xu, Chenggong Yan, Bingxia Zhao.  (2023)  Proton pump inhibitor-enhanced nanocatalytic ferroptosis induction for stimuli-responsive dual-modal molecular imaging guided cancer radiosensitization.  Acta Biomaterialia,  162  (72).  [PMID:36931419] [10.1016/j.actbio.2023.03.011]
19. Cuixian Li, Piao Zhu, Huijing Xiang, Yunjie Jin, Beilei Lu, Yujia Shen, Wenping Wang, Beijian Huang, Yu Chen.  (2023)  3D-CEUS tracking of injectable chemo-sonodynamic therapy-enabled mop-up of residual renal cell carcinoma after thermal ablation.  Materials Today Bio,  18  (100513).  [PMID:36569591] [10.1016/j.mtbio.2022.100513]
20. Zhou Shaoqian, Chen Xueying, Huang Rixin, Lin Yi, Ye Xiaoxia.  (2022)  Interfacial treatment-induced high-strength plant fiber/phenolic resin composite.  Frontiers in Materials,  [10.3389/fmats.2022.1072249]
21. Hao Chi, Guang Zhu, Yalin Yin, He Diao, Zicheng Liu, Shibo Sun, Zhaoming Guo, Weiping Xu, Jianqiang Xu, Changhao Cui, Xiao-Jin Xing, Kun Ma.  (2022)  Dual-Responsive multifunctional “core–shell” magnetic nanoparticles promoting Fenton reaction for tumor ferroptosis therapy.  INTERNATIONAL JOURNAL OF PHARMACEUTICS,  622  (121898).  [PMID:35688287] [10.1016/j.ijpharm.2022.121898]
22. Qiangtao Zhu, Dongyu Pan, Yangyi Sun, Dongming Qi.  (2022)  Controllable Microemulsion Synthesis of Hybrid TiO2–SiO2 Hollow Spheres and Au-Doped Hollow Spheres with Enhanced Photocatalytic Activity.  LANGMUIR,  38  (13): (4001–4013).  [PMID:35290732] [10.1021/acs.langmuir.1c03484]
23. Liping Wei, Mei Shen, Zhenxiang Xin.  (2022)  A novel material based on deep eutectic solvents and its application in in-situ modified silica-reinforced styrene-butadiene rubber.  JOURNAL OF APPLIED POLYMER SCIENCE,  139  (18): (52089).  [10.1002/app.52089]
24. Kun Zeng, Li Ma, Wenxiu Yang, Shan Lei, Mozhen Wang, Yezi You, Yu Zhao, Xuewu Ge.  (2020)  Biodegradable nano-organosilica gene carrier for high-efficiency gene transfection.  Journal of Materials Chemistry B,  (12): (2483-2494).  [PMID:32110782] [10.1039/D0TB00108B]
25. Jia Ke, Yumei Wang, Lingmei Wang, Baixue Yang, Kaijun Gou, Yanxin Qin, Sanming Li, Heran Li.  (2020)  Synthesis and characterization of core-shell mesoporous silica nanoparticles with various shell thickness as indomethacin carriers: In vitro and in vivo evaluation.  MICROPOROUS AND MESOPOROUS MATERIALS,  297  (110043).  [10.1016/j.micromeso.2020.110043]
26. Yang Qingsong, Li Li, Zhao Fang, Han Haoya, Wang Weihua, Tian Yuchuan, Wang Yunwei, Ye Zhishuang, Guo Xuhong.  (2019)  Hollow silica–polyelectrolyte composite nanoparticles for controlled drug delivery.  JOURNAL OF MATERIALS SCIENCE,  54  (3): (2552-2565).  [10.1007/s10853-018-2996-7]
27. Yangyi Sun, Min Chen, Limin Wu.  (2018)  Controllable synthesis of hollow periodic mesoporous organosilica spheres with radial mesochannels and their degradable behavior.  Journal of Materials Chemistry A,  (26): (12323-12333).  [10.1039/C8TA02569J]
28. Lijun Sun, Dangge Wang, Yu Chen, Liying Wang, Ping Huang, Yaping Li, Ziwei Liu, Heliang Yao, Jianlin Shi.  (2017)  Core-shell hierarchical mesostructured silica nanoparticles for gene/chemo-synergetic stepwise therapy of multidrug-resistant cancer.  BIOMATERIALS,  133  (219).  [PMID:28441616] [10.1016/j.biomaterials.2017.04.028]
29. Yanping Wu, Lei Chen, Songlv Qin, Jinlong Li, Huidi Zhou, Jianmin Chen.  (2017)  Functionalized graphene-reinforced rubber composite: Mechanical and tribological behavior study.  JOURNAL OF APPLIED POLYMER SCIENCE,  134  (25): [10.1002/app.44970]
30. Lin-Lin Hu, Dan-Dan Zhang, Yang Zhang, Yang Shu, Xu-Wei Chen, Jian-Hua Wang.  (2016)  Glutathione functionalized mesoporous organosilica conjugate for drug delivery.  RSC Advances,  (61): (56287-56293).  [10.1039/C6RA10841E]

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