基本描述

别名	氯化(三苯基膦)金(I) \| 三苯基膦氯金
英文别名	(Ph3P)AuCl \| chlorogold; triphenylphosphane;CHloro(triphenylphosphine)gold(I) \| A807907 \| J-007651 \| MFCD00009588 \| chlorogold;triphenylphosphane \| Triphenylphosphinechlorogold \| Chloro(triphenylphosphane)gold(I) \| Chloro(triphenylphosphine)gold(I), Premi
规格或纯度	≥98%
英文名称	Chloro(triphenylphosphine)gold(I)
储存温度	2-8°C储存,充氩
运输条件	冰袋运输
产品介绍	Chloro(triphenylphosphine)gold(I) is a common reagent in gold chemistry. It catalyzes certain rearrangement reactions in organic synthesis. It is also used to prepare 1-methylthyminato-N3-triphenylphosphinegold(I) by reacting with 1-methylthymine. It acts as a precursor for the synthesis of gold(I) and gold(III) organometallic compounds. Chloro(triphenylphosphine)gold(I) is a common reagent in gold chemistry. It catalyzes certain rearrangement reactions in organic synthesis. It is also used to prepare 1-methylthyminato-N3-triphenylphosphinegold(I) by reacting with 1-methylthymine. It acts as a precursor for the synthesis of gold(I) and gold(III) organometallic compounds.

AI解读

名称和识别符

EC号	238-117-6
IUPAC Name	chlorogold;triphenylphosphane
INCHI	InChI=1S/C18H15P.Au.ClH/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h1-15H;;1H/q;+1;/p-1
InChi Key	IFPWCRBNZXUWGC-UHFFFAOYSA-M
Canonical SMILES	C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Au]
Isomeric SMILES	C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Au]
WGK Germany	3
分子量	494.71
Reaxy-Rn	14384071

化学和物理性质

溶解性	Soluble in methylene chloride, acetonitrile, benzene and acetone. Insoluble in water and ethanol.
敏感性	对光敏感;对湿度敏感
熔点	245.0 to 249.0 °C
分子量	494.700 g/mol
XLogP3
氢键供体数Hydrogen Bond Donor Count	0
氢键受体数Hydrogen Bond Acceptor Count	0
可旋转键计数Rotatable Bond Count	3
精确质量Exact Mass	494.027 Da
单同位素质量Monoisotopic Mass	494.027 Da
拓扑极表面积Topological Polar Surface Area	0.000 Å²
重原子数Heavy Atom Count	21
形式电荷Formal Charge	0
复杂度Complexity	204.000
同位素原子数Isotope Atom Count	0
定义的原子立体中心计数Defined Atom Stereocenter Count	0
未定义的原子立体中心计数Undefined Atom Stereocenter Count	0
定义的键立体中心计数Defined Bond Stereocenter Count	0
未定义的键立体中心计数Undefined Bond Stereocenter Count	0
所有立体化学键的总数The total count of all stereochemical bonds	0
共价键合单元计数Covalently-Bonded Unit Count	2

安全和危险性（GHS）

象形图	GHS07
信号词	Warning
危险声明	H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激
预防措施声明	P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P302+P352: 如皮肤沾染：用水充分清洗。 P321: 特殊处理（请参阅此标签上的...）。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P271: 仅在室外或通风良好的地方使用。 P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。 P403+P233: 存放在通风良好的地方。保持容器密闭。 P362+P364: 脱掉沾污的衣服，清洗后方可重新使用。 P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。 P337+P317: 如果眼睛刺激持续：寻求医疗帮助。 P332+P317: 如果出现皮肤刺激：请寻求医疗帮助。 P319: 如果你感到不适，请寻求医疗帮助。
WGK Germany	3
Reaxy-Rn	14384071
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

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批号(Lot Number)	证书类型	日期	货号
L2416054	分析证书	24-11-22	C118793
L2416056	分析证书	24-11-22	C118793
L2423481	分析证书	24-11-22	C118793
J2429308	分析证书	24-06-14	C118793
F2228153	分析证书	24-04-02	C118793
F2228154	分析证书	24-04-02	C118793
F2228159	分析证书	24-04-02	C118793
H2104044	分析证书	23-05-11	C118793
H2104050	分析证书	23-05-11	C118793

此产品的引用文献

如何在您的发表作品中引用阿拉丁的产品和网站?

1. Li Huiyong, Hu Dafeng, Zheng Zemin, Jiang Hao, Lu Jiangwei, Geng Xuemin, Zhang Xudong, Wan Yanfen, Yang Peng. (2020) Primary growth of binary nanoparticle superlattices with distinct systems contingent on synergy: softness and crystalline anisotropy. Applied Nanoscience, 10 (5): (1653-1666). [10.1007/s13204-019-01244-6]
2. Zhang Xudong, Ma Su, Li Aikun, Chen Linya, Lu Jiangwei, Geng Xuemin, Xie Ming, Liang Xiaoyu, Wan Yanfen, Yang Peng. (2020) Continuous high-flux synthesis of gold nanoparticles with controllable sizes: a simple microfluidic system. Applied Nanoscience, 10 (3): (661-669). [10.1007/s13204-019-01214-y]

参考文献

1. Jihan Talib,Jennifer L Beck,Stephen F Ralph. (2006-06-23) A mass spectrometric investigation of the binding of gold antiarthritic agents and the metabolite [Au(CN)2]- to human serum albumin.. Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 11 ((5)): (559-570). [PMID:16791640]
2. Gregory L Hamilton,Eun Joo Kang,Miriam Mba,F Dean Toste. (2007-07-28) A powerful chiral counterion strategy for asymmetric transition metal catalysis.. Science (New York, N.Y.), 317 ((5837)): (496-499). [PMID:17656720]
3. Xia Zhao,Zhenzhen Zhong,Lingling Peng,Wenxiong Zhang,Jianbo Wang. (2009-06-18) Au(PPh(3))Cl-AgSbF(6)-catalyzed rearrangement of propargylic 1,3-dithianes: formation of 8-membered 1,3-bisthio-substituted cyclic allenes.. Chemical communications (Cambridge, England), ((18)(18)): (2535-2537). [PMID:19532881]
4. Ming Zhang,Ablimit Abdukader,Yong Fu,Chengjian Zhu. (2012-03-08) Efficient synthesis of β-enaminones and β-enaminoesters catalyzed by gold (I)/silver (I) under solvent-free conditions.. Molecules (Basel, Switzerland), 17 ((3)): (2812-2822). [PMID:22395409]
5. Simbarashe Ngwerume,William Lewis,Jason E Camp. (2012-12-29) Development of a gold-multifaceted catalysis approach to the synthesis of highly substituted pyrroles: mechanistic insights via Huisgen cycloaddition studies.. The Journal of organic chemistry, 78 ((3)): (920-934). [PMID:23270303]
6. Katherine A Parrish,Mary King,Marshall R Ligare,Grant E Johnson,Heriberto Hernández. (2018-09-28) Role of sterics in phosphine-ligated gold clusters.. Physical chemistry chemical physics : PCCP, 21 ((4)): (1689-1699). [PMID:30260357]
7. Luiza G Tunes,Roberta E Morato,Adriana Garcia,Vinicius Schmitz,Mario Steindel,José D Corrêa-Junior,Hélio F Dos Santos,Frédéric Frézard,Mauro V de Almeida,Heveline Silva,Nilmar S Moretti,André L B de Barros,Rubens L do Monte-Neto. (2020-04-15) Preclinical Gold Complexes as Oral Drug Candidates to Treat Leishmaniasis Are Potent Trypanothione Reductase Inhibitors.. ACS infectious diseases, 6 ((5)): (1121-1139). [PMID:32283915]
8. Sang Ick Lee,Soo Min Kim,Mi Ra Choi,Sun Young Kim,Young Keun Chung,Won-Sik Han,Sang Ook Kang. (2006-12-02) Au(I)-catalyzed cyclization of enynes bearing an olefinic cycle.. The Journal of organic chemistry, 71 ((25)): (9366-9372). [PMID:17137363]
9. Elena Barreiro,José S Casas,María D Couce,Agustín Sánchez,Angeles Sánchez-Gonzalez,José Sordo,José M Varela,Ezequiel M Vázquez López. (2007-09-18) Synthesis, structure and cytotoxicity of triphenylphosphinegold(I) sulfanylpropenoates.. Journal of inorganic biochemistry, 102 ((2)): (184-192). [PMID:17870173]
10. Li Huiyong, Hu Dafeng, Zheng Zemin, Jiang Hao, Lu Jiangwei, Geng Xuemin, Zhang Xudong, Wan Yanfen, Yang Peng. (2020) Primary growth of binary nanoparticle superlattices with distinct systems contingent on synergy: softness and crystalline anisotropy. Applied Nanoscience, 10 (5): (1653-1666). [10.1007/s13204-019-01244-6]
11. Zhang Xudong, Ma Su, Li Aikun, Chen Linya, Lu Jiangwei, Geng Xuemin, Xie Ming, Liang Xiaoyu, Wan Yanfen, Yang Peng. (2020) Continuous high-flux synthesis of gold nanoparticles with controllable sizes: a simple microfluidic system. Applied Nanoscience, 10 (3): (661-669). [10.1007/s13204-019-01214-y]

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货号 (SKU)	包装规格	是否现货
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(三苯基膦)氯化金(I)

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基本描述

AI解读

名称和识别符

化学和物理性质

安全和危险性（GHS）

质检证书（CoA,COO,BSE/TSE 和分析图谱)

相关文档

此产品的引用文献

参考文献

溶液计算器

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