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3,6-二(2-吡啶基)-1,2,4,5-四嗪

规格或纯度: >98.0%(HPLC)
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货号 (SKU) 包装规格 是否现货 价格 数量
D155574-1g
1g 现货 Stock Image
D155574-5g
5g 现货 Stock Image
D155574-10g
10g 期货 Stock Image
D155574-25g
25g 现货 Stock Image
D155574-100g
100g 现货 Stock Image

基本描述

别名 3,6-二-2-吡啶基-1,2,4,5-四嗪|3,6-双(2-吡啶基)-1,2,4,5-四嗪
英文别名 1671-87-0|3,6-di(pyridin-2-yl)-1,2,4,5-tetrazine|3,6-Di-2-pyridyl-1,2,4,5-tetrazine|3,6-Di(2-pyridyl)-1,2,4,5-tetrazine|3,6-dipyridin-2-yl-1,2,4,5-tetrazine|3,6-Di-2-pyridinyl-1,2,4,5-tetrazine|3,6-Bis(2-pyridyl)-1,2,4,5-tetrazine|MLS000038825|1,2,4,5-Tet
规格或纯度 >98.0%(HPLC)
英文名称 3,6-Di(2-pyridyl)-1,2,4,5-tetrazine
应用 3,6-Di-2-pyridyl-1,2,4,5-tetrazine may be used in the following studies: . Preparation of mononuclear, cyclic tetranuclear, and 1-D helical-chain Cu(II) complexes, via metal-assisted hydrolysis. . Synthesis of novel cyclic tetranuclear ZnII complex. . Synthesis of substituted 3,6-di(2-pyridyl)pyridazines, via inverse electron demand Diels Alder reaction with alkenes or alkynes.
运输条件 常规运输
产品介绍

3,6-Di-2-pyridyl-1,2,4,5-tetrazine (DPTZ) undergoes solvothermal reaction with CuSO4.6H2O and Cu(Ac)2.H2O to afford copper containing coordination polymers. It reacts with enamine derivative of morpholine and 5-,6-,7- and 8-membered cyclic ketones to afford pyridazine derivatives. 3,6-Di-2-pyridyl-1,2,4,5-tetrazine undergoes solid-state reaction with fullerene C60 by high-speed vibration milling technique. It acts as electron-deficient diene in the inverse electron demand Diels Alder reaction.3,6-Di-2-pyridyl-1,2,4,5-tetrazine may be used in the following studies: . Preparation of mononuclear, cyclic tetranuclear, and 1-D helical-chain Cu(II) complexes, via metal-assisted hydrolysis. . Synthesis of novel cyclic tetranuclear ZnII complex. . Synthesis of substituted 3,6-di(2-pyridyl)pyridazines, via inverse electron demand Diels Alder reaction with alkenes or alkynes.


通过高速振动铣削技术,3,6-二-2-吡啶基-1,2,4,5-四嗪可与富勒烯C60发生固态反应。 它在逆电子需求Diels Alder反应中充当缺电子二烯。3,6-二-2-吡啶基-1,2,4,5-四嗪(DPTZ)与CuSO4·6H2O和Cu(Ac)2·H2O进行溶剂热反应可生成含铜配位聚合物。 它能与吗啉的烯胺衍生物和5-、6-、7-和8-元环酮反应,得到哒嗪衍生物。

3,6-Di-2-pyridyl-1,2,4,5-tetrazine (DPTZ) undergoes solvothermal reaction with CuSO4.6H2O and Cu(Ac)2.H2O to afford copper containing coordination polymers. It reacts with enamine derivative of morpholine and 5-,6-,7- and 8-membered cyclic ketones to afford pyridazine derivatives. 3,6-Di-2-pyridyl-1,2,4,5-tetrazine undergoes solid-state reaction with fullerene C60 by high-speed vibration milling technique. It acts as electron-deficient diene in the inverse electron demand Diels Alder reaction.
3,6-Di-2-pyridyl-1,2,4,5-tetrazine may be used in the following studies: . Preparation of mononuclear, cyclic tetranuclear, and 1-D helical-chain Cu(II) complexes, via metal-assisted hydrolysis. . Synthesis of novel cyclic tetranuclear ZnII complex. . Synthesis of substituted 3,6-di(2-pyridyl)pyridazines, via inverse electron demand Diels Alder reaction with alkenes or alkynes.

名称和标识符

PubChem SID 488189453
PubChem SID url https://pubchem.ncbi.nlm.nih.gov/substance/488189453
IUPAC Name 3,6-dipyridin-2-yl-1,2,4,5-tetrazine
INCHI InChI=1S/C12H8N6/c1-3-7-13-9(5-1)11-15-17-12(18-16-11)10-6-2-4-8-14-10/h1-8H
InChi Key JFBIRMIEJBPDTQ-UHFFFAOYSA-N
Canonical SMILES C1=CC=NC(=C1)C2=NN=C(N=N2)C3=CC=CC=N3
Isomeric SMILES C1=CC=NC(=C1)C2=NN=C(N=N2)C3=CC=CC=N3
WGK Germany 3
PubChem CID 315109
分子量 236.24
Beilstein号 26(5)19,377
Reaxy-Rn 405091

化学和物理性质

溶解性 Slightly soluble in water.
熔点 225°C

安全和危险性(GHS)

象形图
ghs07

Harmful

信号词 Warning
危险声明 H315: Causes skin irritation
H319: Causes serious eye irritation
H335: May cause respiratory irritation
预防措施声明 P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P271,P304+P340,P403+P233,P362+P364,P264+P265,P337+P317,P332+P317,P319
WGK Germany 3
Reaxy-Rn 405091
个人防护装备 dust mask type N95 (US), Eyeshields, Gloves

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参考文献

1. Xian-He Bu,He Liu,Miao Du,Lei Zhang,Ya-Mei Guo,Mitsuhiko Shionoya,Joan Ribas.  (2002-04-02)  New mononuclear, cyclic tetranuclear, and 1-D helical-chain Cu(II) complexes formed by metal-assisted hydrolysis of 3,6-di-2-pyridyl-1,2,4,5-tetrazine (DPTZ): crystal structures and magnetic properties..  Inorganic chemistry,  41  ((7)):  (1855-1861).  [PMID:11925180]