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六氯三聚磷腈

规格或纯度: 98%
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货号 (SKU) 包装规格 是否现货 价格 数量
P107062-5g
5g 现货 Stock Image
P107062-25g
25g 现货 Stock Image
P107062-100g
100g 现货 Stock Image
P107062-500g
500g 现货 Stock Image
P107062-2.5kg
2.5kg 现货 Stock Image
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六元杂环化合物 腈类

基本描述

别名 三聚氯化磷腈,六氯环三磷腈|膦酰氯三聚体|六氯环三聚膦腈
英文别名 Phosphonitrilic chloride trimer|940-71-6|Hexachlorocyclotriphosphazene|Triphosphonitrilic chloride|Hexachlorophosphazene|Triphosphonitrile chloride|Hexachlorotriphosphonitrile|Phosphononitrilic chloride trimer|Cyclophosphazene dichloride trimer|Hexachloro
规格或纯度 98%
英文名称 Phosphonitrilic chloride trimer
储存温度 充氩
运输条件 常规运输
产品介绍

用于合成"蒲公英"(球状)树枝状聚合物的试剂。开环聚合、用于过渡金属的配位体和/或配位体前体以及研究 P-Cl 键取代反应都是该产品倍受关注的应用。

A reagent for the synthesis of dandelion (spherical) dendrimers. Ring opening polymerization, ligands and / or precursor ligands for transition metals, and the study of p-cl bond substitution reaction are the applications of this product.

名称和标识符

EC号 213-376-8
IUPAC Name 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2λ5,4λ5,6λ5-triphosphacyclohexa-1,3,5-triene
INCHI InChI=1S/Cl6N3P3/c1-10(2)7-11(3,4)9-12(5,6)8-10
InChi Key UBIJTWDKTYCPMQ-UHFFFAOYSA-N
Canonical SMILES N1=P(N=P(N=P1(Cl)Cl)(Cl)Cl)(Cl)Cl
Isomeric SMILES N1=P(N=P(N=P1(Cl)Cl)(Cl)Cl)(Cl)Cl
WGK Germany 3
PubChem CID 220225
UN Number 3260
分子量 347.66
Reaxy-Rn 1216896

化学和物理性质

溶解性 不溶于水,可溶于甲苯,易溶于苯,乙醚
密度 1.98
敏感性 对湿度敏感
沸点 127°C
熔点 111-115°C

安全和危险性(GHS)

象形图
ghs05

Corrosive

信号词 Danger
危险声明 H314: Causes severe skin burns and eye damage
预防措施声明 P280,P321,P405,P501,P264,P260,P301+P330+P331,P304+P340,P363,P305+P354+P338,P302+P361+P354,P316
WGK Germany 3
Reaxy-Rn 1216896
个人防护装备 Eyeshields,Faceshields,full-face particle respirator type N100 (US),Gloves,respirator cartridge type N100 (US),type P1 (EN143) respirator filter,type P3 (EN 143) respirator cartridges

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参考文献

1. S Paasch,K Krüger,B Thomas.  (1995-07-01)  Solid-state nuclear magnetic resonance investigations on chlorocyclophosphazenes..  Solid state nuclear magnetic resonance,  ((5)):  (267-280).  [PMID:7583063]
2. M Anzai,M Ohashi.  (1984-06-01)  Studies on the reaction of hexachlorocyclotriphosphazene and 2-hydroxyethyl methacrylate and on the physical properties of its polymer..  The Journal of Nihon University School of Dentistry,  26  ((2)):  (109-118).  [PMID:6592289]
3. Hiroyoshi Kawakami,Shota Kanezaki,Miyuki Sudo,Masayoshi Kanno,Shoji Nagaoka,Sunao Kubota.  (2002-09-26)  Biodegradation and biocompatibility of polyorganophosphazene..  Artificial organs,  26  ((10)):  (883-890).  [PMID:12296930]
4. Tam T T Bui,Simon J Coles,David B Davies,Alex F Drake,Robert J Eaton,Michael B Hursthouse,Adem Kiliç,Robert A Shaw,Serkan Yeşilot.  (2005-08-13)  Chiral separation and CD characterisation of enantiomeric cyclotriphosphazene derivatives..  Chirality,  17  ((8)):  (438-443).  [PMID:16096990]
5. Ji-Yeon Seong,Yong Joo Jun,Byong Moon Kim,Yong Man Park,Youn Soo Sohn.  (2006-03-22)  Synthesis and characterization of biocompatible poly(organophosphazenes) aiming for local delivery of protein drugs..  International journal of pharmaceutics,  314  ((1)):  (90-96).  [PMID:16549280]
6. Cheng Zheng,Liyan Qiu,Xiaping Yao,Kangjie Zhu.  (2009-05-12)  Novel micelles from graft polyphosphazenes as potential anti-cancer drug delivery systems: drug encapsulation and in vitro evaluation..  International journal of pharmaceutics,  373  ((1-2)):  (133-140).  [PMID:19429298]
7. David K Y Lee,Anne-Martine S Jackson,Toshiki Fushimi,Hemant Yennawar,Harry R Allcock.  (2010-05-05)  Synthesis and inclusion behavior of cyclotriphosphazene molecules with asymmetric spiro rings..  Dalton transactions (Cambridge, England : 2003),  39  ((22)):  (5341-5348).  [PMID:20440426]
8. Wajdi M Zoghaib,John Husband,Usama A Soliman,Ibrahim A Shaaban,Tarek A Mohamed.  (2013-01-26)  Analysis of UV and vibrational spectra (FT-IR and FT-Raman) of hexachlorocyclotriphosphazene based on normal coordinate analysis, MP2 and DFT calculations..  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy,  105  ():  (446-455).  [PMID:23348197]
9. Paritosh Mohanty,Lilian D Kull,Kai Landskron.  (2011-07-21)  Porous covalent electron-rich organonitridic frameworks as highly selective sorbents for methane and carbon dioxide..  Nature communications,  ():  (401-401).  [PMID:21772272]