(R)-(-)-2-丁醇

≥99%(GC)

CAS编号: 14898-79-4
分子式: C₂H₅CH(OH)CH₃
分子量: 74.12
Beilstein号: 1718764
EC号: 238-967-8
MDL号: MFCD00064280
PubChem编号: 84682
PubChem SID: 504755769

有货

库存信息

关闭

库存信息

关闭

库存信息

关闭

货号 (SKU)	包装规格	是否现货
R138264-1ml	1ml	现货
R138264-5ml	5ml	现货
R138264-25ml	25ml	现货

查看相关系列

不对称合成 (593) 手性非杂环砌块 (285)

Skip to the end of the images gallery

Skip to the beginning of the images gallery

基本描述

别名	发酵丁醇 \| (R)-(-)-仲丁醇
英文别名	(R)-(-)-sec-butyl alcohol \| ethyl alpha-(bromomethyl)acrylate \| (-)-2-Butanol \| J-008537 \| R-(-)-2-Butanol \| DTXSID30904709 \| NSC212288 \| 2-Butanol, (2R)- (9CI) \| l-butanol \| (r)-(-)-sec-butanol \| DB02606 \| DLH38K423J \| DC85DE0F-332E-491E-BC2E-35FEBD70F75
规格或纯度	≥99%(GC)
英文名称	(R)-(-)-2-Butanol
运输条件	常规运输
产品介绍	用途 ( R )-(-)-2-丁醇已被用作冷冻容器中长期冷冻保存平滑肌细胞样品期间的冷冻干燥介质。(R)-(−)-2-丁醇可以用作合成以下物质的试剂：①、由3,5 二苯基-1H-1,2,4 三唑通过Mitsunobu反应生成1-[(S)-2-丁基]-3,5 二苯基-1H-1,2,4 三唑，②、与甲苯磺酰氯反应生成甲苯磺酸2-丁酯结构单元 Application (R)-(-)-2-Butanol is a important organic intermediate. It can be used in agrochemical, pharmaceutical and dyestuff field.

AI解读

名称和识别符

PubChem SID	504755769
EC号	238-967-8
IUPAC Name	(2R)-butan-2-ol
INCHI	InChI=1S/C4H10O/c1-3-4(2)5/h4-5H,3H2,1-2H3/t4-/m1/s1
InChi Key	BTANRVKWQNVYAZ-SCSAIBSYSA-N
Canonical SMILES	CCC(C)O
Isomeric SMILES	CC[C@@H](C)O
WGK Germany	3
PubChem CID	84682
分子量	74.12
Beilstein号	1718764
Reaxy-Rn	1718764

化学和物理性质

溶解性	可溶于水；可混溶于乙醚、酒精
密度	0.807
折光率	1.4
比旋光度	-13° (neat)
闪点(℉)	71.6 °F
闪点(℃)	22 °C
沸点	100 °C
分子量	74.120 g/mol
XLogP3	0.600
氢键供体数Hydrogen Bond Donor Count	1
氢键受体数Hydrogen Bond Acceptor Count	1
可旋转键计数Rotatable Bond Count	1
精确质量Exact Mass	74.0732 Da
单同位素质量Monoisotopic Mass	74.0732 Da
拓扑极表面积Topological Polar Surface Area	20.200 Å²
重原子数Heavy Atom Count	5
形式电荷Formal Charge	0
复杂度Complexity	19.600
同位素原子数Isotope Atom Count	0
定义的原子立体中心计数Defined Atom Stereocenter Count	1
未定义的原子立体中心计数Undefined Atom Stereocenter Count	0
定义的键立体中心计数Defined Bond Stereocenter Count	0
未定义的键立体中心计数Undefined Bond Stereocenter Count	0
所有立体化学键的总数The total count of all stereochemical bonds	0
共价键合单元计数Covalently-Bonded Unit Count	1

安全和危险性（GHS）

象形图	GHS07, GHS02
信号词	Warning
危险声明	H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H336: 可能引起嗜睡或头晕 H226: 易燃液体和蒸气
预防措施声明	P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P370+P378: 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P210: 远离热源，热表面，火花，明火和其他点火源。 - 禁止抽烟。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P233: 保持容器密闭。 P240: 地面/粘结容器和接收设备 P403+P235: 存放在通风良好的地方。保持低温。 P303+P361+P353: 如皮肤（或头发）沾染：立即脱掉所有沾染的衣服。用水清洗皮肤/淋浴。 P271: 仅在室外或通风良好的地方使用。 P241: 使用防爆的[电气/通风/照明/.../]设备。 P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。 P403+P233: 存放在通风良好的地方。保持容器密闭。 P242: 仅使用无火花的工具。 P243: 采取防静电措施 P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。 P337+P317: 如果眼睛刺激持续：寻求医疗帮助。 P319: 如果你感到不适，请寻求医疗帮助。
WGK Germany	3
Reaxy-Rn	1718764
Merck Index	1541
个人防护装备	Eyeshields， Faceshields， full-face respirator (US)， Gloves， multi-purpose combination respirator cartridge (US)， type ABEK (EN14387) respirator filter

技术规格说明书

Density (20°C)	0.807-0.81
Purity(GC)	99-100（%）
Refractive index n20/D	1.396-1.398
Specific Rotation [a]20/D(c=Neat)	-14--11（°）
Appearance（R138264)	Colorless liquid
NMR Spectrum 1H	Conforms to Structure

技术规格说明书

质检证书（CoA,COO,BSE/TSE 和分析图谱)

C of A & Other Certificates(BSE/TSE, COO):

输入批号以搜索分析图谱:

通过匹配包装上的批号来查找并下载产品的 COA，每批产品都进行了严格的验证，您可放心使用！

找到7个结果

批号(Lot Number)	证书类型	日期	货号
E2306973	分析证书	23-05-12	R138264
L2311283	分析证书	23-05-12	R138264
E2306950	分析证书	23-05-12	R138264
E2306963	分析证书	23-05-12	R138264
E2306964	分析证书	23-05-12	R138264
E2306967	分析证书	23-05-12	R138264
E2306975	分析证书	23-05-12	R138264

可替换产品

参考文献

1. K W van Dijk,B J van Vlijmen,M P de Winther', "B van 't Hof", 'A van der Zee,H van der Boom,L M Havekes,M H Hofker. (1999-12-11) Hyperlipidemia of ApoE2(Arg(158)-Cys) and ApoE3-Leiden transgenic mice is modulated predominantly by LDL receptor expression.. Arteriosclerosis, thrombosis, and vascular biology, 19 ((12)): (2945-2951). [PMID:10591674]
2. J H P Lardenoye,M R De Vries,J M Grimbergen,L M Havekes,M W M Knaapen,M M Kockx,V W M van Hinsbergh,J H van Bockel,P H A Quax. (2002-09-17) Inhibition of accelerated atherosclerosis in vein grafts by placement of external stent in apoE*3-Leiden transgenic mice.. Arteriosclerosis, thrombosis, and vascular biology, 22 ((9)): (1433-1438). [PMID:12231562]
3. Patrycja Seroka,Marcin Płosiński,Jacek Czub,Paweł Sowiński,Jan Pawlak. (2005-12-17) Monosaccharides as internal probes for the determination of the absolute configuration of 2-butanol.. Magnetic resonance in chemistry : MRC, 44 ((2)): (132-138). [PMID:16358294]
4. Saeko Shin,Munetaka Nakata,Yoshiaki Hamada. (2006-02-10) Analysis of vibrational circular dichroism spectra of (s)-(+)-2-butanol by rotational strengths expressed in local symmetry coordinates.. The journal of physical chemistry. A, 110 ((6)): (2122-2129). [PMID:16466246]
5. Robert Brosnan,Diane Gong,Joseph Cotten,Bharat Keshavaprasad,C Spencer Yost,Edmond I Eger,James M Sonner. (2006-06-23) Chirality in anesthesia II: stereoselective modulation of ion channel function by secondary alcohol enantiomers.. Anesthesia and analgesia, 103 ((1)): (86-91). [PMID:16790632]
6. Mark B Shiflett,A Yokozeki. (2006-07-21) Vapor-liquid-liquid equilibria of pentafluoroethane and ionic liquid [bmim][PF6] mixtures studied with the volumetric method.. The journal of physical chemistry. B, 110 ((29)): (14436-14443). [PMID:16854153]
7. Dagmara Wojtków,Mirosław A Czarnecki. (2006-09-08) Effect of temperature and concentration on the structure of sec-butyl alcohol and isobutyl alcohol/water mixtures: near-infrared spectroscopic study.. The journal of physical chemistry. A, 110 ((36)): (10552-10557). [PMID:16956236]
8. Prabha Dwivedi,Ching Wu,Laura M Matz,Brian H Clowers,William F Siems,Herbert H Hill. (2006-12-15) Gas-phase chiral separations by ion mobility spectrometry.. Analytical chemistry, 78 ((24)): (8200-8206). [PMID:17165808]
9. Caroline Cheng,Dennie Tempel,Rien van Haperen,Hetty C de Boer,Dolf Segers,Martin Huisman,Anton Jan van Zonneveld,Pieter J M Leenen,Anton van der Steen,Patrick W Serruys,Rini de Crom,Rob Krams. (2007-02-17) Shear stress-induced changes in atherosclerotic plaque composition are modulated by chemokines.. The Journal of clinical investigation, 117 ((3)): (616-626). [PMID:17304353]
10. Megan D Reeves,Adam K Schawel,Weidong Wang,Phoebe Dea. (2007-03-21) Effects of butanol isomers on dipalmitoylphosphatidylcholine bilayer membranes.. Biophysical chemistry, 128 ((1)): (13-18). [PMID:17368700]
11. Charles O Stanier,Ravi K Pathak,Spyros N Pandis. (2007-05-31) Measurements of the volatility of aerosols from alpha-pinene ozonolysis.. Environmental science & technology, 41 ((8)): (2756-2763). [PMID:17533835]
12. Hirofumi Sonoda,Taro Okada,Saleem Jahangeer,Shun-ichi Nakamura. (2007-09-28) Requirement of phospholipase D for ilimaquinone-induced Golgi membrane fragmentation.. The Journal of biological chemistry, 282 ((47)): (34085-34092). [PMID:17897952]
13. Feng Gao,Yilin Wang,Luke Burkholder,Wilfred T Tysoe. (2007-11-16) Enantioselective chemisorption of propylene oxide on a 2-butanol modified Pd(111) surface: the role of hydrogen-bonding interactions.. Journal of the American Chemical Society, 129 ((49)): (15240-15249). [PMID:18001023]
14. Willeke de Haan,Jitske de Vries-van der Weij,José W A van der Hoorn,Thomas Gautier,Caroline C van der Hoogt,Marit Westerterp,Johannes A Romijn,J Wouter Jukema,Louis M Havekes,Hans M G Princen,Patrick C N Rensen. (2008-05-07) Torcetrapib does not reduce atherosclerosis beyond atorvastatin and induces more proinflammatory lesions than atorvastatin.. Circulation, 117 ((19)): (2515-2522). [PMID:18458167]
15. (2008-05-27) Breath monitor tracks medication adherence.. AIDS patient care and STDs, 22 ((5)): (437-437). [PMID:18500923]
16. R A Rosenberg,M Abu Haija,P J Ryan. (2008-11-13) Chiral-selective chemistry induced by spin-polarized secondary electrons from a magnetic substrate.. Physical review letters, 101 ((17)): (178301-178301). [PMID:18999792]
17. J W A van der Hoorn,J W Jukema,L M Havekes,E Lundholm,G Camejo,P C N Rensen,H M G Princen. (2009-02-18) The dual PPARalpha/gamma agonist tesaglitazar blocks progression of pre-existing atherosclerosis in APOE3Leiden.CETP transgenic mice.. British journal of pharmacology, 156* ((7)): (1067-1075). [PMID:19220285]
18. Jacqueline T Jonker,Yanan Wang,Willeke de Haan,Michaela Diamant,Luuk J Rijzewijk,Rutger W van der Meer,Hildo J Lamb,Jouke T Tamsma,Albert de Roos,Johannes A Romijn,Patrick C N Rensen,Johannes W A Smit. (2010-02-13) Pioglitazone decreases plasma cholesteryl ester transfer protein mass, associated with a decrease in hepatic triglyceride content, in patients with type 2 diabetes.. Diabetes care, 33 ((7)): (1625-1628). [PMID:20150294]
19. J C Sullivan,S M Budge,A Timmins. (2010-04-24) Rapid method for determination of residual tert-butanol in liposomes using solid-phase microextraction and gas chromatography.. Journal of chromatographic science, 48 ((4)): (289-293). [PMID:20412651]
20. Flaminia Rondino,Alessandra Paladini,Alessandra Ciavardini,Annarita Casavola,Daniele Catone,Mauro Satta,Hans Dieter Barth,Anna Giardini,Maurizio Speranza,Susanna Piccirillo. (2010-12-07) Chiral recognition between 1-(4-fluorophenyl)ethanol and 2-butanol: higher binding energy of homochiral complexes in the gas phase.. Physical chemistry chemical physics : PCCP, 13 ((3)): (818-824). [PMID:21132202]
21. Xiaofeng Hu,Richard A Rosenberg,Michael Trenary. (2011-01-26) Thermal and electron-induced decomposition of 2-butanol on Pt(111).. The journal of physical chemistry. A, 115 ((23)): (5785-5793). [PMID:21261270]
22. Fengli Yang,Qishun Liu,Min Yue,Xuefang Bai,Yuguang Du. (2011-03-04) Tantalum compounds as heterogeneous catalysts for saccharide dehydration to 5-hydroxymethylfurfural.. Chemical communications (Cambridge, England), 47 ((15)): (4469-4471). [PMID:21369620]
23. Akimitsu Miyaji,Teppei Miyoshi,Ken Motokura,Toshihide Baba. (2011-07-12) The substrate binding cavity of particulate methane monooxygenase from Methylosinus trichosporium OB3b expresses high enantioselectivity for n-butane and n-pentane oxidation to 2-alcohol.. Biotechnology letters, 33 ((11)): (2241-2246). [PMID:21744144]
24. Maria Dolores Romero,Jose Maria Gomez,Beatriz Diaz-Suelto,Alicia Garcia-Sanz,Nicola Baster. (2011-08-13) Kinetic resolution of (R,S)-2-butanol using enzymatic synthesis of esters.. Applied biochemistry and biotechnology, 165 ((5-6)): (1129-1140). [PMID:21837379]
25. H Yasui,S Wakamura,N Fujiwara-Tsujii,N Arakaki,A Nagayama,Y Hokama,F Mochizuki,T Fukumoto,H Oroku,K Harano,S Tanaka. (2011-09-29) Mating disruption by a synthetic sex pheromone in the white grub beetle Dasylepida ishigakiensis (Coleoptera: Scarabaeidae) in the laboratory and sugarcane fields.. Bulletin of entomological research, 102 ((2)): (157-164). [PMID:21944472]
26. Zlata Novalic,Annemieke M van der Wal,Wouter N Leonhard,Gudrun Koehl,Martijn H Breuning,Edward K Geissler,Emile de Heer,Dorien J M Peters. (2012-02-22) Dose-dependent effects of sirolimus on mTOR signaling and polycystic kidney disease.. Journal of the American Society of Nephrology : JASN, 23 ((5)): (842-853). [PMID:22343118]
27. Uri Cogan,Avi Shpigelman,Irina Portnaya,Abraham Rutenberg,Yosef Scolnik,Meir Shinitzky. (2012-05-10) Intermolecular chiral assemblies in R(-) and S(+) 2-butanol detected by microcalorimetry measurements.. Chirality, 24 ((7)): (500-505). [PMID:22570171]
28. Kari V Ahonen,Manu K Lahtinen,Miika S Löfman,Anniina M Kiesilä,Arto M Valkonen,Elina I Sievänen,Nonappa,Erkki T Kolehmainen. (2012-07-21) Structural studies of five novel bile acid-4-aminopyridine conjugates.. Steroids, 77 ((11)): (1141-1151). [PMID:22813632]
29. Ravi K Pathak,Kent Salo,Eva U Emanuelsson,Cilan Cai,Anna Lutz,Asa M Hallquist,Mattias Hallquist. (2012-09-19) Influence of ozone and radical chemistry on limonene organic aerosol production and thermal characteristics.. Environmental science & technology, 46 ((21)): (11660-11669). [PMID:22985264]
30. S Kooijman,I Meurs,M van der Stoep,K L Habets,B Lammers,J F P Berbée,L M Havekes,M van Eck,J A Romijn,S J A Korporaal,P C N Rensen. (2014-10-28) Hematopoietic α7 nicotinic acetylcholine receptor deficiency increases inflammation and platelet activation status, but does not aggravate atherosclerosis.. Journal of thrombosis and haemostasis : JTH, 13 ((1)): (126-135). [PMID:25345495]
31. Jing Fan,Xin Teng,Ling Liu,Katherine R Mattaini,Ryan E Looper,Matthew G Vander Heiden,Joshua D Rabinowitz. (2014-11-19) Human phosphoglycerate dehydrogenase produces the oncometabolite D-2-hydroxyglutarate.. ACS chemical biology, 10 ((2)): (510-516). [PMID:25406093]
32. Sander Kooijman,Illiana Meurs,Lianne van Beek,P Padmini S J Khedoe,Annabel Giezekamp,Karin Pike-Overzet,Cathy Cailotto,Jan van der Vliet,Vanessa van Harmelen,Guy Boeckxstaens,Jimmy F P Berbée,Patrick C N Rensen. (2015-06-21) Splenic autonomic denervation increases inflammatory status but does not aggravate atherosclerotic lesion development.. American journal of physiology. Heart and circulatory physiology, 309 ((4)): (H646-H654). [PMID:26092978]
33. Marieke F Fransen,Hreinn Benonisson,Wendy W van Maren,Heng Sheng Sow,Cor Breukel,Margot M Linssen,Jill W C Claassens,Conny Brouwers,Jos van der Kaa,Marcel Camps,Jan Willem Kleinovink,Kelly K Vonk,Sandra van Heiningen,Ngaisah Klar,Lianne van Beek,Vanessa van Harmelen,Lucia Daxinger,Kutty S Nandakumar,Rikard Holmdahl,Chris Coward,Qingshun Lin,Sachiko Hirose,Daniela Salvatori,Thorbald van Hall,Cees van Kooten,Piero Mastroeni,Ferry Ossendorp,J Sjef Verbeek. (2018-03-11) A Restricted Role for FcγR in the Regulation of Adaptive Immunity.. Journal of immunology (Baltimore, Md. : 1950), 200 ((8)): (2615-2626). [PMID:29523656]
34. Richard G Ijzerman,Coen D A Stehouwer,Eco J de Geus,Mirjam M van Weissenbruch,Henriette A Delemarre-van de Waal,Dorret I Boomsma. (2002-11-20) The association between low birth weight and high levels of cholesterol is not due to an increased cholesterol synthesis or absorption: analysis in twins.. Pediatric research, 52 ((6)): (868-872). [PMID:12438663]
35. Timothy E Morey,Matthew Booth,Scott Wasdo,Judith Wishin,Brian Quinn,Daniel Gonzalez,Hartmut Derendorf,Susan P McGorray,Jane Simoni,Richard J Melker,Donn M Dennis. (2012-09-25) Oral adherence monitoring using a breath test to supplement highly active antiretroviral therapy.. AIDS and behavior, 17 ((1)): (298-306). [PMID:23001413]
36. Irene O C M Vroegrijk,Jan Bert van Klinken,Janna A van Diepen,Sjoerd A A van den Berg,Maria Febbraio,Laura K M Steinbusch,Jan F C Glatz,Louis M Havekes,Peter J Voshol,Patrick C N Rensen,Ko Willems van Dijk,Vanessa van Harmelen. (2013-03-21) CD36 is important for adipocyte recruitment and affects lipolysis.. Obesity (Silver Spring, Md.), 21 ((10)): (2037-2045). [PMID:23512311]
37. Mattijs M Heemskerk,Sjoerd A A van den Berg,Amanda C M Pronk,Jan-Bert van Klinken,Mariëtte R Boon,Louis M Havekes,Patrick C N Rensen,Ko Willems van Dijk,Vanessa van Harmelen. (2014-01-30) Long-term niacin treatment induces insulin resistance and adrenergic responsiveness in adipocytes by adaptive downregulation of phosphodiesterase 3B.. American journal of physiology. Endocrinology and metabolism, 306 ((7)): (E808-E813). [PMID:24473440]
38. K Kulyk,O Rebrov,M Ryding,R D Thomas,E Uggerud,M Larsson. (2017-09-25) Low-Energy Collisions of Protonated Enantiopure Amino Acids with Chiral Target Gases.. Journal of the American Society for Mass Spectrometry, 28 ((12)): (2686-2691). [PMID:28936701]

溶液计算器

摩尔浓度计算器

计算溶液所需的质量、体积或浓度。

质量

浓度

体积

分子量

g/mol

稀释计算器

计算配制储备溶液所需的稀释度。

浓度1（C1）

体积 1 (V1)

浓度 2 (C2)

体积 2 (V2)

复溶计算器

复溶计算器允许您快速计算试剂的体积，以复溶小瓶。只需输入试剂的质量和目标浓度，计算器将确定其余部分。

体积（添加到小瓶中）

质量（小瓶）

所需的复溶浓度

(R)-(-)-2-丁醇

库存信息

库存信息

库存信息

基本描述

AI解读

名称和识别符

化学和物理性质

安全和危险性（GHS）

技术规格说明书

质检证书（CoA,COO,BSE/TSE 和分析图谱)

相关文档

可替换产品

参考文献

溶液计算器

摩尔浓度计算器

稀释计算器

复溶计算器