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介孔沸石
CHINESE JOURNAL OF POLYMER SCIENCE · 2015 ·Vol. 33 ·期 7 ·976-987 · IF 1.835

Enhanced ultraviolet resistance of polypropylene random copolymer filled by ZnO-supported mesoporous zeolite

Li Mei,Li Gu,Zhang Zi-shou,Dai Xin,Yang Yue-wen,Mai Kan-cheng

To enhance the ultraviolet resistance of ZnO based polymer materials, ZnO-supported mesoporous zeolite (M-ZnO) was prepared and characterized by atomic absorption spectroscopy and scanning electron microscopy. The ultraviolet resistance, crystallization behavior and melting characteristics of ZnO and M-ZnO filled PPR composites were compared by FTIR spectra and differential scanning calorimetry. The ultraviolet resistance of M-ZnO filled PPR composites is higher than that of ZnO filled PPR composites, indicating higher ultraviolet resistance of M-ZnO than that of ZnO. The crystallization temperatures of mesoporous zeolite filled PPR were higher than those of M-ZnO and decreased with increasing UV-irradiation time. But the crystallization temperatures of M-ZnO filled PPR composites were not influenced by UV-irradiation time. The ZnO supported on the surface of zeolite is effective in enhancing the ultraviolet resistance of ZnO based polymer materials.

研究领域: 高分子材料科学 · 功能复合材料 · 材料老化与稳定性 · 纳米复合材料 · 聚合物改性
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