FLUID PHASE EQUILIBRIA
·
2020
·
IF 2.838
Jinbei Yang,Shucui Han,Qiuju Xu,Meiqiong Yu
The density and viscosity of pure liquid 2, 4-dichlorofluorobenzene and 2, 6-dichlorofluorobenzene were measured in the temperature range of (318.15–348.15) K at the local atmospheric pressure of 99.8 kPa. The saturated vapor pressures of pure 2, 4-dichlorofluorobenzene and 2, 6-dichlorofluorobenzene and the isobaric vapor-liquid equilibria (VLE) data for the 2, 4-dichlorofluorobenzene + 2, 6-dichlorofluorobenzene binary system at atmospheric pressure were determined experimentally by a modified Rose still. The density values were accurately described by DIPPR equation. The viscosity data were well correlated using the Litovitz, Ghatee and VFT, and Andrade equations, and the VFT equation shows the best accuracy. Both Antoine and Riedel equations can well describe the relationship between saturated vapor pressure and temperature, which meet the requirements of engineering design. The Riedel equation is more accurate due to the lower average relative deviation. The VLE data were successfully correlated with NRTL and Wilson activity coefficient models, and the interaction parameters were obtained. The result indicates that there is no azeotrope in the binary mixture. The above thermodynamic properties of pure component and the VLE data presented are crucial for the design and operation of distillation for the isomeric mixture separation of 2, 4-dichlorofluorobenzene + 2, 6-dichlorofluorobenzene.
研究领域:
化学工程
·
热力学
✓ 已验证
产品关联
DOI
高影响因子
ENVIRONMENTAL SCIENCE & TECHNOLOGY
·
2021
·
IF 9.028
Zhen Cao,Hao Li,Gregory V. Lowry,Xiaoyang Shi,Xiangcheng Pan,Xinhua Xu,Graeme Henkelman,Jiang Xu
Groundwater contamination by halogenated organic compounds, especially fluorinated ones, threatens freshwater sources globally. Sulfidized nanoscale zero-valent iron (SNZVI), which is demonstrably effective for dechlorination of groundwater contaminants, has not been well explored for defluorination. Here, we show that SNZVI nanoparticles synthesized via a modified post-sulfidation method provide rapid dechlorination (∼1100 μmol m–2 day–1) and relatively fast defluorination (∼6 μmol m–2 day–1) of a halogenated emerging contaminant (florfenicol) under ambient conditions, the fastest rates that have ever been reported for Fe0-based technologies. Batch reactivity experiments, material characterizations, and theoretical calculations indicate that coating S onto the metallic Fe surface provides a highly chemically reactive surface and changes the primary dechlorination pathway from atomic H for nanoscale zero-valent iron (NZVI) to electron transfer for SNZVI. S and Fe sites are responsible for the direct electron transfer and atomic H-mediated reaction, respectively, and β-elimination is the primary defluorination pathway. Notably, the Cl atoms in florfenicol make the surface more chemically reactive for defluorination, either by increasing florfenicol adsorption or by electronic effects. The defluorination rate by SNZVI is ∼132–222 times higher with chlorine attached compared to the absence of chlorine in the molecule. These mechanistic insights could lead to new SNZVI materials for in situ groundwater remediation of fluorinated contaminants.
研究领域:
环境科学
·
材料科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
Journal of Saudi Chemical Society
·
2024
·
IF 5.8
Zhengjie Li,Miao Liu,Chunxia Fang,Huanshu Zhang,Tianyi Liu,Yixian Liu,Heli Tian,Jilong Han,Zhikun Zhang
The widespread use and subsequent accumulation of florfenicol (FFC), a common antibiotic, through the food chain poses significant risks to aquatic ecosystems and human health, necessitating effective strategies for its removal from water bodies. To solve the challenge, herein, we developed a novel aluminum-based metal–organic framework CAU-1, engineered for the efficient adsorption of FFC. CAU-1 contains the plentiful –NH 2 and μ-OH groups with the positively charged on the surface. In the adsorption process, CAU-1 perform hydrogen bonding interactions with FFC’s functional groups (−F, –OH, −Cl, –NH–, and −SO 2 –). Furthermore, the positively charged surface of CAU-1 enhances FFC adsorption via electrostatic attraction together. FFC adsorption equilibrium on CAU-1 is attained within 180 min with a monolayer adsorption capacity of 386 mg/g at 303 K, surpassing most of the reported adsorbents. The exothermic FFC adsorption process on CAU-1 remains largely unaffected by coexisting ions. Additionally, CAU-1 can be efficiently regenerated using a mixed solution of 0.1 M HCl and ethanol–water as an eluent. This work highlights CAU-1’s potential as an effective adsorbent for FFC removal, emphasizing the importance of tuning or designing surface functional groups on adsorbents to boost their adsorption capabilities.
研究领域:
环境科学
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材料科学
✓ 已验证
产品关联
DOI
高影响因子
Heliyon
·
2024
·
IF 3.4
Chenhan Lv,Haixiang Cheng,Rui Fan,Jingyu Sun,Xinghai Liu,Yinghui Ji
Organic fluorine compounds are acute carcinogenic and mutagenic to humans. Photoelectrocatalysis (PEC) treatment is an innovative technology in the field of the removal of fluorine compounds, and thus current research focused on improving stability and catalytic ability of photoanode. In this study, it has been synthesized a rGO/BiOI photocathode for the efficient degradation of 4-Fluoroaniline (4-FA). The physical characterization and photoelectrochemical properties of the photocathode was determined. The results indicate that the PEC treatment with the rGO/BiOI photocathode was more efficient compared with individual processes. During the optimization experiments, the PEC treatment achieved 99.58 % and 72.12 % of 4-FA degradation and defluorination within 1 h. Cyclic stability experiments show that rGO/BiOI photocathode was efficient and stable, which reached 96.91 % and 67.64 % of 4-FA degradation and defluorination after five cycles. Mechanism analysis indicates that the PEC process was based on an electrochemical reaction and photo-induced processes. The degradation product of 4-FA was mainly 2,4-di-t-butylphenol, and trapping experiments indicates that h + is the primary oxidizing species. Therefore, PEC treatment with rGO/BiOI photocathode is a competitive green approach to remove fluorine compounds pollutants and brings new insights into development of PEC treatment.
研究领域:
环境科学
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材料科学
✓ 已验证
DOI
PubMed
高影响因子
ENVIRONMENTAL SCIENCE & TECHNOLOGY
·
2019
·
IF 7.149
Huiling Liu,Jinglong Han,Jili Yuan,Chengbin Liu,Dong Wang,Tian Liu,Meijun Liu,Jinming Luo,Aijie Wang,John C. Crittenden
Efficient elimination of antibacterial activity of halogenated antibiotics by dehalogenation pretreatment is desired for a biochemical treatment process. In this study, crystalline cobalt phosphide nanosheet arrays on a Ti plate (C-CoP/Ti) are fabricated by a simple electrodeposition and phosphorization process. The crystalline structure greatly promotes atomic hydrogen (H*) generation. Moreover, the nanosheet arrays can provide abundant active sites and accelerate electron transfer and mass transport. As a result, the dehalogenation rate of florfenicol (FLO, an emerging organic pollutant) on C-CoP/Ti is 11.1, 2.97, and 13.6 times higher than that on amorphous CoP/Ti, Pd/Ti, and bare Ti, respectively. The C-CoP/Ti electrode achieves 97.4% dehalogenation of FLO (20 mg L–1) within 30 min at −1.2 V (vs Ag/AgCl). Nearly 100% of Cl and 20% of F are broken away within 120 min, showing the highest electrocatalytic defluorination efficiency reported so far. Both experimental results and theoretical calculations reveal that the dehalogenation of FLO on C-CoP/Ti is synergistically accomplished via direct reduction of electron transfer and indirect reduction of H*. This study develops a highly efficient non-noble metal electrode material for dehalogenation of halogenated organic compounds.
研究领域:
环境科学
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材料科学
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化学
✓ 已验证
DOI
PubMed
高影响因子
CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
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2018
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IF 0.824
Ran LI,Ze-Jia LIN,Jin-Yi YANG,Zhen-Lin XU,Hong WANG,Hong-Tao LEI,Yuan-Ming SUN,Yu-Dong SHEN
A high-affinity polyclonal antibody was prepared by immunizing animals with haptens FFD and FFM. Under the optimal combination of coating antigen and antibody, an indirect competitive enzyme-linked immunosorbent assay (icELISA) for simultaneous detection of florfenicol and thiamphenicol residues in animal meat and urine samples was developed. The icELISA showed an IC 50 value of 1.32 ng mL −1 for florfenicol and 2.13 ng mL −1 for thiamphenicol, respectively. The linear ranges were from 0.31 to 5.61 ng mL −1 with a limit of detection of 0.12 ng mL −1 for florfenicol, and 0.41 to 11.2 ng mL −1 with a limit of detection of 0.15 ng mL −1 for thiamphenicol, respectively. The average recoveries of florfenicol and thiamphenicol in spiked samples ranged from 77.2% to 116.0% with a relative standard deviation of less than 15%. Therefore, this proposed icELISA provided a valid detection method for florfenicol and thiamphenicol residues in animal tissue and urine samples.
研究领域:
免疫学
·
食品安全检测
✓ 已验证
DOI
高影响因子
PEST MANAGEMENT SCIENCE
·
2021
·Vol. 77
·期 6
·2964-2970
·
IF 4.845
Ning Shen,Yao Li,Kipchoge Leviticus,Xiao Li Chang,Tao Tang,Li Cui,Zhao Jun Han,Chun Qing Zhao
BACKGROUND Two-spotted spider mite (TSSM), Tetranychus urticae Koch, is one of the most serious pests of agricultural crops. Broflanilide exhibits high lethality against various pests and has been marketed worldwide under the Vedira and Tenebenal brands in 2020. Nevertheless, little information has been reported about its effects on agricultural mites. RESULTS Broflanilide displayed higher toxicity to TSSM eggs (24 h LC 50 , 1.015 mg L −1 ) and adult females (24 h LC 50 , 2.062 mg L −1 ) than commercial acaricides, including cyflumetofen, bifenazate, and profenofos. In contrast, the adverse effects of broflanilide on the predatory mite, Typhlodromips swirskii Athias-Henriot, was lower than those of fenpyroximate and abamectin. In the sublethal effect study, while adult females were treated with broflanilide, the number of eggs and longevity were reduced in LC 10 and LC 30 treatments; when eggs were treated with broflanilide, the egg duration and deutonymph duration were prolonged in LC 30 treatment. A significant decrease in the total life span and duration and fecundity of adult females was observed in LC 10 and LC 30 treatments. Furthermore, the number of eggs per adult female was significantly reduced from 103.48 ± 3.69 in the control group to 69.42 ± 2.22 and 48.33 ± 1.75 in LC 10 and LC 30 treatments, respectively. In the greenhouse bioassay, broflanilide 5% suspension concentrate (MCI-8007) showed excellent acaricidal activity to TSSM, with 99.22% corrected control, compared with the MCI-8007 untreated group. CONCLUSION Our results indicated that broflanilide has a high acaricidal activity to TSSM and significant inhibition to fecundity of adult female, and could be considered as a potential alternative for TSSM management. © 2021 Society of Chemical Industry.
研究领域:
农业科学
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害虫管理
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植物保护
✓ 已验证
产品关联
DOI
PubMed
高影响因子
Journal of Environmental Chemical Engineering
·
2025
·
IF 7.2
Junjing Li,Han Yu,Yongjiao Ding,Liang Wang
In order to improve the metal utilization of the noble metal Pd and the catalytic activity of the reaction, a novel and efficient Pd/Ti 4 O 7 /Ti electrode was prepared by introducing a Ti 4 O 7 intermediate layer for electrocatalytic hydrodechlorination (EHDC) of chlorinated pharmaceuticals and personal care products (PPCPs). The presence of oxygen vacancies (Ov) on the Ti 4 O 7 surface was confirmed by electron paramagnetic resonance (EPR). The results showed that the introduction of Ti 4 O 7 increased the electrochemical active surface area electrode (ECSA) of the Pd/Ti 4 O 7 /Ti electrode, accelerated the electron transfer rate on the catalyst surface, and promoted the generation of electron-rich Pd, which in turn improved the dechlorination efficiency. The Pd/Ti 4 O 7 /Ti electrode had a removal efficiency of 99.6% for florfenicol (FLO) within 180 min. Meanwhile, the removal efficiency of the Pd/Ti 4 O 7 /Ti electrode was still above 95% in seven cycles, which significantly improved the catalytic activity and stability compared with that of the Pd/Ti electrode. In addition, the reaction pathway for the electrocatalytic hydrodechlorination process of FLO at Pd/Ti 4 O 7 /Ti electrode was proposed. The ecotoxicity of the pollutants was also evaluated by the Toxicity Estimation Software Tool (T.E.S.T) model. In this study, an efficient electrocatalyst for EHDC was explored, and the Pd/Ti 4 O 7 /Ti electrode provided strong support for pollutant removal.
研究领域:
环境科学
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材料科学
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产品关联
DOI
高影响因子
ELECTROPHORESIS
·
2024
·
IF 3
Weiyan Li,Chuansheng Sun,Haiping Wang,Qingyan Bai,Yi Xu,Chunmiao Bo,Junjie Ou
Detection of florfenicol (FF) residues in animal-derived foods, as one of the most widely used antibiotics, is critically important to food safety. The fluorescent molecularly imprinted polymer (MIP) was synthesized by surface-initiated atom transfer radical polymerization technique with poly(glycidyl methacrylate- co -ethylene glycol dimethacrylate) microspheres, 4-vinylpyridine, ethylene glycol dimethacrylate, and FF as the matrix, functional monomer, crosslinker, and template molecule, respectively. Meanwhile, N–S co-doped carbon dot (CD) was synthesized with triammonium citrate and thiourea as precursors under microwave irradiation at 400 W for 2.5 min and then integrated into FF-MIP to obtain CD@FF-MIP. For comparison, non-imprinted polymer (NIP) without FF was also prepared. The adsorption capacity of CD@FF-MIP to FF reached 53.1 mg g −1 , which was higher than that of FF-MIP (34.7 mg g −1 ), whereas the adsorption capacity of NIP was only 17.3 mg g −1 . The adsorption equilibrium of three materials was reached within 50 min. Particularly, CD@FF-MIP exhibited an excellent fluorescence quenching response to FF in the concentration range of 3–50 µmol L −1 . As a result, CD@FF-MIP was successfully utilized to extract FF in milk samples, which were analyzed by high-performance liquid chromatography. The standard recoveries were 95.8%–98.2%, and the relative standard deviation was 1.6%–4.2%. The method showed the advantages of simple operation, high sensitivity, excellent selectivity, and low cost, and also demonstrated a great application prospect in food detection.
研究领域:
食品安全
·
分析化学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
JOURNAL OF COLLOID AND INTERFACE SCIENCE
·
2025
·
IF 9.7
Yue Sun,Xiang Li,Bin Du,Jialong Cui,Ali Abdullah,Yanji Zhu,Huaiyuan Wang,Di Bao
Global warming is attributed to excessive emissions of greenhouse gases, which are being addressed through the deployment of carbon capture technologies aimed at mitigating climate change. However, this approach faces significant challenges, as high concentrations of CO 2 pose a huge risk of corrosion, compromising integrity. The active inhibitor polyfluoroaniline grown on the surface of graphene (Gr-PFAN) is encapsulated in epoxy novolac (EN) coating. And highly reactive nitrogen-containing poly(p-phenylenediamine-fluoroaniline) (Gr-PPFAN) was synthesized by changing the polymerization monomer. For the first time, primary amine nitrogen-containing active sites are discussed in CO 2 shielding material. The gas transmission rate (GTR) test showed that the GTR of the composite film containing Gr-PPFAN was 3.7 times higher than that of Gr-PFAN. And the presence of highly reactive amines in the polymer mass transfer behavior was calculated by molecular simulation. Therefore, the PPFAN coating is a serious failure in H 2 O-CO 2 environment. The introduction of the low content of active sites in Gr-PFAN into the epoxy resin matrix resulted in significant enhancement of the H 2 O, H 2 O-CO 2 and H + corrosion resistance. The small amount of active amine not only enhances the phase interface between the resin and the flake filler, but also facilitates the formation of a protective layer on the metal surface. Experimental results demonstrated that Gr-PFAN/EN exhibited the highest |Z| 0.01 Hz value (3.5 × 1011 O × cm 2 ) after 90 days of immersion in 3.5 wt% NaCl solution and 1.5 × 1011 O × cm 2 for 30 days in the carbon capture environment. Furthermore, it makes Gr-PFAN/EN a promising candidate for practical applications in CO 2 capture projects. The findings provide a scientific basis for the development of efficient anti-corrosion coatings suitable for carbon capture technologies.
研究领域:
材料科学
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环境科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
CHEMICAL ENGINEERING JOURNAL
·
2024
·
IF 13.3
He Jiang,Haoliang Wei,Xinkai Li,Yijun Zhang,Tingjiang Lu,Feili Li,Shuang Song,Yan Yu,Meilan Pan,Weiting Yu
The widespread discharge of halogenated organic pollutants (HOPs) in wastewater brings significant risks to the environment and human health due to potent high toxicity, antibacterial activity, and strong biodegradation resistance. Adsorbed atomic hydrogen (H* ads )-mediated electrocatalytic hydrodehalogenation (EHDH) has been recognized as an efficient strategy for HOPs removal through selectively breaking carbon-halogen bonds. In this work atomic Pd uniformly anchored on molybdenum disulfide (denoted as Pd-MoS 2 ) was synthesized through a facile hydrothermal method and found with state-of-the-art specific activity in florfenicol (FLO) removal via the H* ads -mediated EHDH process. Pd-MoS 2 completely dehalogenated (∼100 %) FLO within 30 min at a rate constant of 0.15 min −1 , which was 6.0, 6.5 and 33.1 times the value of MoS 2 , Pd/C and carbon paper samples, respectively. Notably, the toxicity of the wastewater was reduced to 1/6 of its original value after the treatment. Moreover, Pd-MoS 2 presented superior catalytic stability in five successive cycles. Furthermore, Pd-MoS 2 was also robust in complex water environment with practical applicability for industrial wastewater treatment. A dual-active-center mechanism with enhanced H* ads production capacity and the improved H* ads utilization efficiency was contributed to the increased EHDH activity on Pd-MoS 2 .
研究领域:
环境科学
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材料科学
·
化学工程
✓ 已验证
DOI
高影响因子
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
·
2019
·Vol. 166
·期 8
·B654
·
IF 3.12
Ya-Mu Xia,Wen Zhang,Meng-Ying Li,Meng Xia,Li-Jia Zou,Wei-Wei Gao
In this paper, a highly effective electrochemical sensor based on graphene (Gr)/copper phthalocyanine (CuPc) nanocomposites was successfully designed and achieved. The morphology of Gr/CuPc nanocomposites was characterized by UV-vis, IR, Raman spectra and scanning electron microscopy (SEM). Gr/CuPc nanocomposites were gathered on the surface of the glassy carbon electrode (GCE), and the performence of Gr/CuPc/GCE toward chloramphenicol (CAP) and florfenicol (FF) was investigated by cyclic voltammetry (CV) and differential pulse voltammetry (DPV). The Gr/CuPc/GCE presented good electrochemical properties, stability, reproducibility, excellent anti-interference ability and satisfying recovery rate in real samples for the detection of CAP and FF. The performance of Gr/CuPc/GCE exhibited a linear ranging from 1.0 × 10−7 to 2.0 × 10−5 M with a detection limit of 2.7 × 10−8 M (−0.652 V vs. Hg/Hg2Cl2, S/N = 3) toward CAP. For FF, it exhibited a linear ranging from 1.0 × 10−6 to 3.0 × 10−5 M with a detection limit of 7.5 × 10−7 M (−0.863 V vs. Hg/Hg2Cl2, S/N = 3). Furthermore, it is for the first time that FF is determined by electrochemical sensor through nanocomposites modified electrode. This proposed electrochemical sensor can provide an opportunity for convenient and reliable determination of CAP or FF.
研究领域:
分析化学
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材料科学
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环境科学
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）