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MOLECULAR CRYSTALS AND LIQUID CRYSTALS · 2019 · IF 0.559

Enlargement of blue-phase stability by modified graphene oxide platelets

Yuzhen Zhao,Yang Zhao,Zhun Guo,Zongcheng Miao

For wider temperature blue-phase liquid crystal (BPLC), the optimized structures of blue-phase liquid crystal with 4′-(6-amino-hexyloxy)-biphenyl carbonitrile modified graphene oxide (GOre-LC) platelets were discussed in this article. It was shown experimentally that the blue-phase stability was enlarged based on the doping GOre-LC, a stable blue-phase with a wide temperature range (4.9 °C) was obtained, and a peculiar optical texture of the BP I phase was observed.

CAS / MDL: 110-46-3
研究领域: 材料科学 · 液晶物理
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TRIBOLOGY INTERNATIONAL · 2022 · IF 5.62

The synergetic effects of laser texturing and super-hydrophobic coatings on improving wear properties of steel

Hujun Wang,Lulin Tian,Jing Zheng,Dan Yang,Zhihui Zhang

To investigate the synergetic effects of laser texturing and super-hydrophobic coatings on tribological performances , we prepare micro-grooves on steel substrates by femtosecond laser and then deposit super-hydrophobic coatings in the micro-grooves to obtain coated groove-textured surfaces (CGSs). The tribological behaviors of polished steel surfaces (PSSs), groove-textured surfaces (GSs), and CGSs under water lubrication are examined. Compared with PSSs and GSs, CGSs show significant anti-friction and wear-resisting properties under a relatively low load. With increasing the texture density, the wear resistance of CGSs decreases. When a load of 0.5 N is applied on the CGSs with a texture density of 10%, the friction coefficient and wear loss are reduced by 22.3% and 73.5%, respectively, compared with PSSs.

CAS / MDL: 3069-21-4
研究领域: 材料科学 · 表面工程
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FOOD CHEMISTRY · 2022 · IF 9.231

Effects of temporary rearing with organic selenium on the muscle flavor and texture properties of largemouth bass (Micropterus salmonides)

Hailan Li,Yanan Chen,Meijin Li,Jiajun Huang,Xiaoyan Zu,Tao Liao,Guangquan Xiong

In this study, the influences of organic selenium (Se, 0.002 mg/L) on the muscle flavor and texture properties of Micropterus salmonides under fasting temporary rearing (8 weeks) was investigated. Electronic nose and headspace solid-phase microextraction-gas chromatography – mass spectrometry analysis suggested that organic Se regulated the types and contents of volatile compounds, especially aldehydes and ketones, which were increased in the early temporary rearing but decreased in the late stage. Organic Se significantly increased the content of 5′-inosine monophosphate by approximately 15 % ( p  < 0.05), and decreased the content of hypoxanthine and hypoxanthine ribonucleoside by more than 20 % ( p  < 0.05). After the 8th temporary rearing week, muscle hardness and springiness increased by at least 10 % ( p  < 0.01), resilience and gumminess improved by at least 18 % ( p  < 0.05) and 5.9 % ( p  < 0.05), respectively. In conclusion, organic Se ameliorates the flesh quality of M. salmonides during long-term temporary rearing.

研究领域: 水产养殖学 · 食品科学
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ACS Nano · 2025 · IF 16

Single (002)-Textured Zinc Anode via Nonepitaxial Electrodeposition with In Situ Texture Maintenance for Stable Aqueous Zinc Batteries

Xiaotong Li,Wentao Yuan,Yue Wang,Xuewei Bao,Tongqiang Bi,Dingwen Cui,Zishuai Yang,Guoqiang Ma,Yuanyuan Wang,Zhaoxi Shen,Ning Zhang

Crystallography regulation of a zinc (Zn) metal substrate to expose more (002) textures holds great promise for stabilizing Zn anodes. However, significant challenges remain in directly constructing a single (002)-plane-textured Zn metal anode (S-(002)-Zn) and realizing a sustainable (002)-texture exposure in working batteries. Herein, we report an anion and cation coregulated nonepitaxial electrodeposition to fabricate S-(002)-Zn by introducing 1-ethyl-3-methylimidazolium iodide (EmimI) additives in low-cost ZnSO4 aqueous electrolyte (ZS). Mechanistic studies reveal that the cooperation of Emim+ and I– with oriented adsorption behaviors on Zn can synergistically boost the (100) plane growth, depress the (002) plane growth, and suppress H2 evolution, thus enabling compact S-(002)-Zn electrodeposition. Moreover, other similar organic iodides (e.g., dimethyl-imidazolium iodide and 1-propyl-3-methylimidazolium iodide) are applicable to this scalable electrodeposition. On the other hand, the as-designed ZS-EmimI electrolyte can be directly applied in working Zn batteries, thus effectively sustaining the smooth (002) texture of S-(002)-Zn and inhibiting HER during cycling. Consequently, the combination of single-(002)-texture and ZS-EmimI electrolyte endows the S-(002)-Zn anode with an ultralong lifespan over 10,100 h (>14 months) at 1 mAh cm–2 and superior deep-cycling stability under 88.0% utilization (25 mAh cm–2) over 500 h and assures the stable operation of full Zn batteries.

研究领域: 材料科学 · 电化学
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Nano-Micro Letters · 2025 ·Vol. 17 ·期 1 ·1-17 · IF 36.3

Breaking Performance Limits of Zn Anodes in Aqueous Batteries by Tailoring Anion and Cation Additives

Mai Zhaoxu,Lin Yuexing,Sun Jingying,Wang Chenhui,Yang Gongzheng,Wang Chengxin

Cationic benzyltriethylammonium chloride enables high (002)-textured Zn via selective adsorption, outperforming prior additives. In situ homogenization converts commercial Zn foil into highly (002)-textured Zn anodes without pretreatments. Cl − -induced pitting corrosion mechanism uncovered, leading to a breakthrough in performance limits of Zn anodes.

研究领域: 材料科学 · 电化学
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ACS Applied Energy Materials · 2024 · IF 5.4

Effect of Areal Parameter of Sputtered Cu Layers on C2 Products for CO2 Electroreduction

Xiang Li,Zhitao Liu,Liyuan Zeng,Wanyi Ye,Guangxing Yang,Qiao Zhang,Shengjun Du,Zhiting Liu,Feng Peng

The CO2 electrochemical reduction (CO2ER) to produce valuable multicarbon products represents a promising approach for enhancing CO2 conversion. While previous research has investigated the impact of Cu electrode surface topography on C2 production, it is important to note that other parameters were also altered concurrently with changes in roughness. To isolate the specific effect of surface texture on CO2 electroreduction, this study prepared Cu layers with varying textures using the sputtering method with a varied sputtering time. To characterize the surface features of the sputtered Cu layers, the developed interfacial area ratio (Sdr), known as areal parameter, was introduced, with the aim of correlating it with C2 product selectivity. The results of this study indicate that the improved selectivity of C2 products can be attributed to higher Sdr values, primarily due to a rougher and finer surface texture that increases the local concentration of CO and OH–. This research underscores the significance of surface topography and offers perspectives for designing efficient Cu electrodes for the CO2ER.

CAS / MDL: 584-08-7
研究领域: 材料科学 · 电化学
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Small · 2025 · IF 12.1

Selective Acid Etching Construction of High (101) Texture Zinc Metal Anodes for High-Performance Zinc Ion Batteries

Zhongwei Zhao,Bingshu Guo,Yun Huang,Xichang Wang,Jin Bao,Chunmei Feng,Xing Li,Mingshan Wang,Yuanhua Lin,Haijun Cao

Aqueous zinc-ion batteries (AZIB) are significantly constrained by the poor stability of Zn anodes in aqueous electrolytes, which is caused by uncontrollable deposition behavior and parasitic reactions. The construction of specific crystalline surfaces represents an effective method for stabilizing Zn anodes. Therefore, a stable Malic acid@Zn (MA@Zn) anode with a highly (101) texture configuration is developed through acid etching. The mechanism of MA selective etching is investigated through theoretical calculations, where Zn atoms detach from the (002) crystal surface due to the strong interaction of MA with the (002) surface, leading to the preferential corrosion of the (002) surface and the formation of a unique (101) texture configuration morphology. This texture is conducive to the MA@Zn anode, as it enhances the affinity of MA@Zn for Zn 2+ and optimizes the electric field distribution on the surface, thereby facilitating a more stable Zn deposition. Consequently, the MA@Zn symmetric battery is subjected to stable cycling for a period exceeding 2400 h at a current density of 5 mA cm −2 . In comparison, the cycle life of the Zn//V 2 O 5 full battery is significantly improved by >6000 cycles, pouch battery also shows better performance.

研究领域: 材料科学 · 电化学
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ACS Applied Electronic Materials · 2024 · IF 4.3

Phosphor-Converted LED for Iris Acquisition Based on Visible and Near-Infrared Phosphors

Changfu Xu,Yan Yuan,Haiyan Shi,Minchun Lin,Yuan Tang,Zhaoqi Liu,Nian Pan,Xiaohong Zhang,Pengbo Lyu,Lizhong Sun

Capturing both structural and pigmented iris textures is essential for accurate identity authentication and medical testing, particularly for heavily pigmented irises. Traditional near-infrared (NIR) lighting captures only structural details, while multiwavelength LEDs capture both but hinder device miniaturization. We present a solution using a phosphor-converted LED (pc-LED) that emits both visible and NIR light, combining commercial CaAlSiN3:Eu2+ and Ca3LuAlGe3O12:Cr3+ phosphors. This compact lighting source improves the emission efficiency and thermal stability through Lu3+ substitution with Al3+, allowing for the capture of clear iris images that reveal both structural and pigmented textures. Our results highlight the potential of visible and NIR pc-LEDs to enhance iris biometrics for portable devices and reduce the cost of iris medical testing equipment.

研究领域: 光学工程 · 生物识别技术 · 医学成像
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JOURNAL OF THE EUROPEAN CERAMIC SOCIETY · 2020 · IF 4.495

Effects of texture orientation in Ti3SiC2 on growth kinetics of interfacial compound layers in diffusion bonded TiAl/Ti3SiC2 joints

Qi Wang,Ming-hao Li,Guo-qing Chen,Xue-song Fu,Wen-long Zhou

Adjusting the growth kinetics of the interfacial compound layers may be a feasible way to enhance joint properties or service performance. In this study, the textured Ti 3 SiC 2 was obtained by hot-deforming the sintered Ti 3 SiC 2 (TSC), and the effects of the texture orientation on the interfacial microstructural evolution and growth kinetics of the interfacial compounds in the diffusion bonded TiAl/Ti 3 SiC 2 joints were investigated. The texture orientation of Ti 3 SiC 2 had little effect on the interfacial microstructural evolution but had a significant effect on the growth kinetics. When bonded at the same temperature, the growth rate of the interfacial compound layers in the TiAl/TSC ∥ joint (TSC ∥ , TSC ⊥ : Ti 3 SiC 2 with [0001] texture orientation parallel, perpendicular to the bonded seam) was fastest; which was slowest in the TiAl/TSC ⊥ joint and was in the middle in the TiAl/TSC joint. The highest shear strengths of the three different joints were similar (about 54 MPa).

研究领域: 材料科学 · 工程学
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TRIBOLOGY INTERNATIONAL · 2021 · IF 4.872

Synergetic effects of biomimetic microtexture with multi-solid lubricants to improve tribological properties of AISI 4140 steel

Qipeng Huang,Xiaoliang Shi,Yawen Xue,Kaipeng Zhang,Yangyang Gao,Chaohua Wu

Inspired by the ability of tree frog toes to regulate body fluids, this control mechanism is applied to the tooth surface of slewing bearing (AISI 4140 steel (AS)) by adopting the regular hexagonal microtexture. SnAgCu-TiC (SACT) lubricants are filled in the microtextures. Results of two-factor analysis of variance show that there is a significant interaction between the microtexture and lubricants. When the microtextures with 1000 µm side are filled with SnAgCu-4 wt% nano-TiC (AS-SACT410), coefficient of friction (COF) of sample is the lowest. Compared with AS (0.437), COF of AS-SACT410 is reduced to 0.085, decreased by 80.55%. Macroscopic anti-friction originates because SnAgCu wraps around nano-TiC to form tribofilms containing submicron rollers, achieving substantially reduced COF.

研究领域: 材料科学 · 仿生学 · 摩擦学
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JOURNAL OF THE AMERICAN CERAMIC SOCIETY · 2018 ·Vol. 102 ·期 5 ·2415-2425 · IF 2.956

Surface engineering of the flexible metallic substrate by SDP-Gd-Zr-O layer for IBAD-MgO templates

Jingyuan Chu,Yue Zhao,Guangyu Jiang,Wei Wu,Zhiwei Zhang,Zhiyong Hong,Zhijian Jin

Tuning substrate properties is an effective methodology to modulate the texture development of MgO films deposited by ion beam-assisted deposition (IBAD) process for epitaxial oxide films. Herein, a solution deposition planarization (SDP) technique is employed to deposit Gd-Zr-O layer for engineering surface properties of the flexible metal substrate. The correlation between the Gd-Zr-O thin film microstructure and the IBAD-MgO texture is investigated. The coordinated study on atomic force microscopy (AFM) and reflection high-energy electron diffraction (RHEED) reveal that the grain coarsening during high-temperature sintering negatively influences the texture formation of IBAD-MgO. Moreover, the chemical environment of the atoms on the surface of Gd-Zr-O seed layer also plays a critical role, which is normally overlooked. The X-ray photoelectron spectroscopy (XPS) analysis indicates that the carbon residue and intermediate phase result in the poor texture of the IBAD-MgO. This phenomenon is related to the partial decomposition and synthesis reactions due to the lower sintering temperature or reduced surface to volume ratio. We demonstrate the high-quality texture of IBAD-MgO layer, deposited on mono-coated thick Gd-Zr-O film, by using optimal heat-treatment conditions. The cross-sectional TEM images present the dense Gd-Zr-O film with Gd 2 Zr 2 O 7 nanograins. The multifunctionalities, such as planarization, a barrier layer, and seed layer, of Gd-Zr-O layers are realized in full-stacked CeO 2 /LaMnO 3 /IBAD-MgO/SDP-Gd-Zr-O/C276 samples. This work demonstrates a route for simplifying the architecture of 2G-HTS using Gd-Zr-O layer and explores the effect of the surface properties on texture formation in IBAD-MgO layer.

CAS / MDL: 17501-44-9
研究领域: 材料科学 · 物理学
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MATERIALS & DESIGN · 2024 · IF 7.6

Prediction and fabrication of textured Si3N4 ceramics via grain rotation model

Yunwei Shi,Jinghan Wang,Yichao Ren,Aiyang Wang,Qianglong He,Yanbo He,Hao Wang,Weimin Wang,Zhengyi Fu

The grain preferential orientation has a significant influence on the mechanical properties of silicon nitride (Si 3 N 4 ) ceramics. Based on the Jeffery’s theory, a grain rotation model under uniaxial compression is created to predict the texture evolution mechanism during sintering of Si 3 N 4 ceramics. With deformation, the grain orientation was predicted to rotate towards the plane perpendicular to the pressure direction, and large strain was favorable for the formation of strong texture. According to guidance of the model, the weakly textured microstructure prepared by normal hot pressing is attributed to the limited strain, due to the constrains of graphite die. Therefore, a new PHIP (pseudo-hot isostatic pressing) process with the large deformation is guided to fabricate the strongly textured ceramics by promoting the grain rotation and dynamic grain growth. Generally, the experimental results are well accordance with the model prediction. Furthermore, this model could be applied to guide the design and fabrication of other isotropic and anisotropic ceramic materials.

研究领域: 材料科学 · 陶瓷工程
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