ELECTROCHIMICA ACTA
·
2023
·
IF 6.6
Liyu Chen,Jiaxin Yang,Yifan Zhang,Shaohua Wu,Youjian Yang,Wenju Tao,Jiangyu Yu,Zhaowen Wang
The electrochemical behavior of Zr(IV) on a molybdenum (Mo) electrode in a KF-AlF 3 -Al 2 O 3 -ZrO 2 molten salt system was studied using cyclic voltammetry (CV), square-wave voltammetry (SWV) and chronopotentiometry (CP). The reduction process of Zr(IV) was found to follow a two-step, two-electron transfer mechanism: Zr(IV)+2e − →Zr(II) and Zr(II)+2e − →Zr(0). The reduction process was quasi-reversible and controlled by diffusion. Al-Zr alloys were successfully obtained on Mo and liquid aluminum electrodes by potentiostatic electrodeposition . Flower-like AlZr 3 and irregular granular Al 3 Zr were obtained on the Mo electrode, which were mainly attributed to the electrochemical co-reduction of Al(III) and Zr(IV) in the molten salt. Three Al-Zr alloy phases, Al 3 Zr , Al 3 Zr 2, and Al 2 Zr, were obtained on the liquid aluminum electrode, among which Al 3 Zr was dominant in the product, followed by Al 3 Zr 2 .
研究领域:
材料科学
·
电化学
✓ 已验证
产品关联
DOI
高影响因子
INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS
·
2015
·
IF 1.989
Z.M. Xie,T. Zhang,R. Liu,Q.F. Fang,S. Miao,X.P. Wang,C.S. Liu
Dense fine-grained pure W, W–1.0 wt.%Zr (WZ), W–1.0 wt.%ZrC (WZC) and W–1.0 wt.%Zr–1.0 wt.%ZrC (WZZC) alloys were fabricated by spark plasma sintering . The grains in WZ and WZZC alloys are stable at annealing temperatures below 1400 °C (1 h), while the grains in pure W grow significantly above 1100 °C annealing. The tensile tests indicate that WZ is ductile already at 400 °C, which is about 200 °C lower than that for pure W. WZC exhibits higher hardness at room temperature than pure W. The ultimate tensile strength of WZC at 600 °C is 798 MPa, about 2.6 times that of pure W. Based on microstructural analysis , the good thermal stability of tungsten grains in WZ and WZZC samples is suggested to be originated from the W–Zr–O and/or Zr–C–O particles which are dispersed on or near the grain boundaries of tungsten and inhibit their migration. The improved tensile properties of the WZ, WZC and WZZC alloys originate (i) from the enhanced GB cohesion by Zr micro-alloying and (ii) from dispersion strengthening by nano-sized ZrC particles.
研究领域:
材料科学
·
金属学
✓ 已验证
产品关联
DOI
高影响因子
Materials
·
2025
·Vol. 18
·期 9
·1988
·
IF 3.2
Yushi Qi,Fangming Wei,Yu Wang,Yu Jin,Xusheng Chang,Gang Chen
To enhance the mechanical properties of 6082 aluminum alloy, a novel Sc- and Zr-microalloyed 6082 alloy was fabricated through squeeze casting technology. Microalloying with Sc and Zr substantially refined the microstructure of alloy, achieving an average grain size of 136.36 μm—a 31.7% reduction compared to the baseline 6082 alloy. Furthermore, the addition of Sc and Zr effectively refined the coarse AlFeMnSi intermetallic phases, mitigating their inherent brittleness. The Sc/Zr-modified alloy exhibited delayed age-hardening kinetics, requiring 100% longer aging time to reach peak hardness due to Sc/Zr-induced retardation of β’’-phase precipitation. The optimized alloy demonstrated better mechanical properties, showing 10.4%, 8.0%, and 71.8% enhancements in yield strength, ultimate tensile strength, and elongation, respectively, over the non-microalloyed counterpart. The squeeze-cast Sc/Zr-modified alloy valve body showed yield strength exceeding 300 MPa and elongation above 10% across various sections, which verifies the effectiveness of this integrated microalloying and forming approach.
研究领域:
材料科学
·
金属加工工程
✓ 已验证
DOI
PubMed
高影响因子
ELECTROCHIMICA ACTA
·
2021
·
IF 6.901
Na Li,Yaru Peng,Zeng Chen,Wenjuan Xiong,Jiaqi Sun,Yiming Chen,Putao Zhang,Meiyue Liu,Shengjun Li
The electro-deoxidation of MgO does not proceed efficiently due to the electrical insulation properties of MgO and large molar volume of metallic magnesium. In this experiment, an attempt was done to prepare Mg-Zr alloy from their oxides using the method of electro-deoxidation. The electrochemical mechanism of the deoxidation process of MgO, ZrO 2 and MgO-ZrO 2 composite was studied through cyclic voltammetry using metallic cavity electrode (MCE). There was an intermediate phase (Zr 3 O) in the reduction process of ZrO 2 . The electro-deoxidation of MgO occurred for MgO-ZrO 2 composite in CaCl 2 -NaCl molten salt. Moreover, the electro-deoxidation of MgO was promoted by the addition of polyvinyl butyral (PVB). The formation of metal phase Mg was confirmed by XRD, EDS, Raman spectroscopy, and inductively-coupled plasma spectroscopy. The electro-deoxidation products showed significant differences with the concentration of PVB and the ratio between MgO and ZrO 2 . The electro-deoxidation of MgO and ZrO 2 was favorable when the PVB concentration was 5.0% (wt.%). Pure metal phase of Mg-Zr alloys was formed when the molar ratio of MgO and ZrO 2 was 1:2. The atomic fraction of Mg in the electrolytic product was ca. 28.0 mol.%. This work shows that MgO could be directly electro-deoxidized to Mg without the formation of intermediate phase oxide.
研究领域:
材料科学
·
冶金工程
·
无机化学
·
电化学
·
金属合金制备
✓ 已验证
DOI
高影响因子
Lubrication Science
·
2023
·Vol. 35
·期 7
·513-527
·
IF 1.9
Qi Liu,Jing Li,Junfeng Zhang,Hengdi Yuan,Ange Nsilani Kouediatouka,Guangneng Dong
Currently, substantial adhesion wear frequently occurs in Zr alloy cold rolling, which not only affects the quality of product's surface, but shortens the mould's service life. In this paper, water-based lubricant was prepared by using ZnO as additive and hydroxyethyl cellulose (HEC) as dispersant. The tribological test results showed the friction coefficient decreased by a maximum of 84.6%, and the friction surface was smooth and flat, with essentially no wear. By analysing the friction area, it was found after ZnO entered the friction interface, HEC carried a hydrated molecular layer to form a stable lubrication film at the interface. This film worked with nanoparticles to reduce friction and wear, and is expected to prolong the service life of rolling dies.
研究领域:
材料科学
·
机械工程
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）