JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
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2019
·Vol. 31
·期 1
·677-683
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IF 2.195
Wang Jing,Shen Bowen,Zhu Kongjun,Qiu Jinhao
With the ever increasing requirements for the structural health monitoring systems, the deposition of the piezoelectric films on the metallic or structural materials has turned out to be an important issue. Pb(Mg, Nb)O 3 -PbTiO 3 films with different buffer layers, i.e., in situ NiO, pre-fabricated NiO and LaNiO 3 , were successfully deposited on the Ni foil via the chemical solution deposition. The crystal structures and electric performances showed evident dependence on the buffer layer. Pre-deposited NiO and LaNiO 3 efficiently prevented the diffusion and complex reactions occurring at the interface, offered abundant nucleation sites, and thus helped the formation of pure high-qualified perovskite PMN-PT films at higher annealing temperatures.
研究领域:
材料科学
·
物理学
✓ 已验证
DOI
高影响因子
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
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2019
·Vol. 30
·期 13
·11945-11951
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IF 2.195
Zhang Ying,Li Yong,Du Jinghua,Sun Ningning,Hao Xihong,Jiang Haitao,Zhai Jiwei
Antiferroelectric (AFE) Pb 0.94 La 0.04 Zr 0.97 Ti 0.03 O 3 (PLZT) thick film was successfully fabricated on nickel foils by using sol–gel method. The film exhibits dense microstructure with low surface roughness and pure perovskite phase. It displays high dielectric constant of 433 at 100 kHz and room temperature, which is 28% larger than that on traditional silicon substrate. Calculated by polarization-field (P–E) hysteresis loop, the recoverable energy-storage density (W rec ) of 18.4 J/cm 3 and the efficiency (Ƞ) value of 54% at 1400 kV/cm are obtained in the thick film. Measured by resistance–inductance–capacitance (RLC) circuit, the maximum pulsed discharge energy-storage density (W dis ) of 12.4 J/cm 3 is found at the same electric field of 1400 kV/cm. Moreover, 90% of the energy is released in a short time of about 84 ns, displaying super-fast discharging characteristic. The AFE film with high discharge energy-storage density and fast discharge time provides strong potential for the application in modern electronics and electrical power systems.
研究领域:
材料科学
·
电子工程
✓ 已验证
DOI
高影响因子
JOURNAL OF ELECTRONIC MATERIALS
·
2024
·
IF 2.2
Hou Guangya,Wu Yitao,Chen Qiang,Zhang Jianli,Tang Yiping
Constructing low-cost, high-catalytic-performance anode electrocatalysts is a significant challenge for methanol oxidation (MOR) and urea oxidation (UOR) reactions. Using paper templates with abundant pores to prepare thin porous metal materials helps to obtain high-performance electrode materials. The nano amorphous B-doped Ni/crystalline Ni (nanoam Ni-B/Ni) foil composite electrodes were derived from paper templates prepared by impregnation, high-temperature reduction, and electrodeposition methods. Porous Ni foils (Nip) derived thinnest rice (“Xuan”) paper, initially used for Chinese calligraphy and painting, exhibits the best performance due to its strong adsorption and wettability. Compared to direct current electrodeposition, pulse electrodeposition yields finer amorphous B-doped Ni nanoparticles with good catalytic performance. Under a current density of 100 mA·cm −2 , the nanoam Ni-B/Ni composite electrode prepared under a duty cycle of 0.5–1.0 s achieved current densities of 290.4 mA·cm −2 (MOR) and 340.4 mA·cm −2 (UOR) at 0.8 V, which are improved by 37.1% and 55.1%, respectively, compared to those of Nip. After 2000 cycles, with solution replacement, the current densities maintained 99.2% (MOR) and 81.6% (UOR) of the original values, showing excellent electrocatalytic stability. This research provided a new use for Chinese rice paper, and the prepared Nip-based electrode, with a thickness of about 60 μm and a low area quality, had a simple preparation process and good electrochemical properties, and can be used as a potential substitute for commercial Ni foam for portable or small electrochemical devices. Graphical Abstract
研究领域:
材料科学
·
电化学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
·
2019
·Vol. 102
·期 10
·6107-6114
·
IF 3.094
Ying Zhang,Yong Li,Xihong Hao,Haitao Jiang,Jiwei Zhai
Flexible antiferroelectric ( AFE ) Pb 0.94 La 0.04 Zr 0.97 Ti 0.03 O 3 (PLZT) thick-film capacitors were fabricated on nickel foil substrates using sol-gel method. The thick PLZT film shows pure perovskite phase with dense microstructure. The discharge energy-storage properties of the thick PLZT film are directly evaluated by the resistance-inductance-capacitance ( RLC ) circuit. The maximum value of the discharge energy-storage density ( W dis ) is 15.8 J/cm 3 at 1400 kV/cm and 90% of the corresponding energy is released in a short time of about 250 ns. In addition, the W dis and discharge time could be adjusted by the bent radius of the film, which provides a simple and feasible solution for the regulation of the electrical performance. Furthermore, the flexible AFE film exhibits good mechanical properties under cycling tests with bending radii down to 2.5 mm and 1500 rounds. This work shows a critical significance in fabricating flexible AFE capacitors for application in modern electronics and electrical power systems.
研究领域:
材料科学
·
电子工程
✓ 已验证
产品关联
DOI
高影响因子
Nano Energy
·
2023
·
IF 17.6
Xiao Meng,Zaiqi Li,Yuanyuan Liu,Zeyan Wang,Peng Wang,Zhaoke Zheng,Ying Dai,Baibiao Huang,Hefeng Cheng,Jr-Hau He
Hydrogen production from solar water splitting, especially via photovoltaic-electrocatalysis, has been regarded as a promising approach for the conversion of abundant but intermittent solar energy into storable chemical fuels. Despite much progress, conventional combined photoelectrochemical devices usually suffer from severe instability issues, which largely inhibit them for practical applications and may also lead to the uncertain efficiency value for true overall water splitting. Here, we report an unassisted solar water splitting device with concurrent high efficiency and stability, which is constructed by spatial coupling of tandem III-V-based GaInP/GaAs/Ge light absorber and robust earth-abundant Ni foil-based MoNi 4 /MoO 2 bifunctional electrocatalysts . Remarkably, apart from the outstanding hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) performance, bifunctional MoNi 4 /MoO 2 electrocatalysts also largely avoid electrode contamination issues, while the robust Ni substrate protects III-Vs from conventional corrosion problems . Consequently, this integrated photovoltaic-electrolysis system device exhibits a high solar-to-hydrogen (STH) conversion efficiency of 17.6 % in alkaline electrolytes with long-term stability of up to 845 h. Further construction into a wireless unassisted monolithic device could lead to an artificial leaf with an STH efficiency of 4.28 %, holding great promise in future solar fuel production with concurrent high efficiency, good stability as well as low cost.
研究领域:
可再生能源
·
电化学
·
材料科学
·
太阳能燃料
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）