JOURNAL OF THE ELECTROCHEMICAL SOCIETY
·
2023
·Vol. 170
·期 7
·077512
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IF 3.9
Jinjin Zhang,Wenjing Liu,Qi Wang,Jianying Qu
In this paper, composites of Ti3C2/ZIF-8/ZIF-67 were obtained through in situ growing ZIF-8/ZIF-67 on Ti3C2 with two-dimensional structure prepared by etching MXene using HF. Furtherly, novel materials of Ti3C2 modified with hollow polyhedrons composed of Co nanoparticles and N-doped carbon nanotube (Ti3C2/CoNP-NCNTHP) was got through derivation with high temperature calcination. The materials were combinations of two-dimensional nanosheets and three-dimensional hollow polyhedras, which were characterized by SEM, TEM, XRD, XPS and EIS. Based on this, a new electrochemical sensor of Ti3C2/CoNP-NCNTHP/GCE was constructed to detect paracetamol (PA) and 4-aminophenol (4-AP) simultaneously. Under optimal conditions, the linear ranges for detection of PA and 4-AP were 0.50–350.00 μM and 0.50–200.00 μM with the limits of detection of 0.05 μM and 0.07 μM, respectively. This proposed sensor has lower detection limits and good linear ranges, which was successfully applied for river water and acetaminophen tablets with good accuracy and has potential prospects for practical applications.
研究领域:
材料科学
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分析化学
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产品关联
DOI
高影响因子
Journal of Environmental Chemical Engineering
·
2022
·
IF 7.968
Kun Wang,Xun Zhu,Yang Yang,Dingding Ye,Rong Chen,Qiang Liao
4-Nitrophenol (4-NP) is one of the most difficult treated water pollutants in industrial wastewater . Herein, the silver nanoparticle/polydopamine (Ag-PDA/PDMS) composite is successfully prepared by in situ reducing Ag catalyst on PDA surface. The Ag-PDA/PDMS catalytic layer possesses an excellent light-to-heat conversion ability and stability under light irradiation. The degradation rate of 4-NP to 4-aminophenol (4-AP) under light irradiation is significantly higher than that of non-irradiation, resulting from both the temperature rise in the catalytic layer, and hot electrons produced by Ag nanoparticles. The temperature rise caused by the photothermal conversion of light-irradiated catalytic layer dominates the performance improvement. The degradation rate of 4-NP reaches 95 % under light irradiation, demonstrating an efficient pathway to design the robust catalyst composites with high-performance photothermal conversion efficiency.
研究领域:
环境科学
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催化化学
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材料科学
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产品关联
DOI
高影响因子
MATERIALS CHEMISTRY AND PHYSICS
·
2019
·
IF 2.781
Zhiqiang Xu,Xianhua He,Mingwei Liang,Lijuan Sun,Di Li,Kenan Xie,Li Liao
Catalytic reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) over high-performance non-noble metal catalysts is attracting intensive attention. Herein, we report a graphene supported Cu@Ni bimetallic nanowires catalyst by a facile liquid phase reduction method with the assistance of an external magnetic field. The morphology and structure of the composite are studied by SEM, TEM and XPS. The vibrating sample magnetometer (VSM) is used to analyze its magnetic properties . Owing to the synergistic effect of graphene and bimetallic nanowires, the catalyst shows superior catalytic performance and excellent stability. The results of catalysis exhibit an extraordinary rate constant (1.16 min −1 ) and activity factor (5.81 min −1 mg −1 ) at room temperature, which are much higher than a majority of non-noble metal catalysts, even noble metal catalysts. Also, compared with noble metal catalyst, the novel catalyst possesses ferromagnetism , which facilitates the separation of catalyst and reaction system, and guarantees recyclability. Moreover, a possible synergistic catalytic mechanism based on the fact that electron transfer between copper-nickel nanowires and graphene has been proposed. It is believed that the novel catalyst has a great importance for the application of nanowires in the field of catalysis.
研究领域:
催化化学
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材料科学
✓ 已验证
DOI
高影响因子
INORGANIC CHEMISTRY COMMUNICATIONS
·
2019
·
IF 1.795
Tursunjan Aydan,Chao Yang,Yang Xu,Tongtong Yuan,Min Zhang,Hui Li,Xueming Liu,Xintai Su,Jide Wang
A Hybrid magnetic composite material Fe 3 O 4 @Cu x O y /C (where, x = 1–2; y = 0–1) was prepared via pyrolysis of FeOOH decorated Cu 3 (BTC) 2 (where, BTC = 1, 3, 5-benzenetricarboxylic acid) as a precursor. The obtained products was successfully applied to reduction reaction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) as a catalyst. Compared with other reported materials, Fe 3 O 4 @Cu x O y /C exhibits high catalytic activity with excellent recyclability.
研究领域:
材料科学
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催化
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纳米技术
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产品关联
DOI
高影响因子
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
·
2020
·
IF 3.573
Kun Wang,Rong Chen,Xun Zhu,Qiang Liao,Dingding Ye,Gang Chen,Ming Liu
In this study, a simple method for directly synthesizing Ag nanoparticles on the inner wall of a microreactor was proposed to catalytically convert 4-NP to 4-AP. The proposed method employed silver ammonia as the precursor and polydopamine (PDA) to modify the surface of the microreactor. Because PDA contains numerous reducing agents of phenolic hydroxyl groups, the silver ions can be effectively reduced to Ag nanoparticles. Moreover, due to the zwitterionic nature of PDA, the use of silver ammonia as a precursor, which intrinsically has a high pH value, can allow for more silver ions to be adsorbed on the surface than the conventionally used AgNO3 as a precursor. Accordingly, the precursor utilization could be greatly improved, leading to the increase of the catalyst loading and thereby boosting the catalytic conversion and durability. It was also found that an increase in the reduction time required for the catalyst preparation could lead to the increase of the catalyst loading and thereby the catalytic performance but a too long reduction time did not continue to make more contribution. Experimental results demonstrate that the microreactor prepared by this simple method is able to exhibit good catalytic activity and durability, providing a new approach for developing high-performance microreactors.
研究领域:
化学工程
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纳米材料科学
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环境催化
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DOI
高影响因子
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
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2020
·Vol. 167
·期 13
·136513
·
IF 3.721
Nannan Dou,Jianying Qu
Herein, a hybrid nanomaterial of copper-nickel bimetal and reduced graphene (rGO) was simply and quickly synthesized by hydrothermal method, which was characterized by transmission electron microscope, field emission scanning electron microscopy, fourier transform infrared spectroscopy, electrochemical impedance and X-ray diffractometry. A new type of electrochemical sensor was constructed by fixing this hybrid on the glassy carbon electrode (GCE). Square wave voltammetry and cyclic voltammetry indicate that this Cu-Ni/rGO/GCE sensor has highly sensitive electrocatalytic activities to 4-aminophenol (4-AP) and acetaminophen (AC). The linear detection ranges were 0.10∼50.00 μM for AC and 0.10∼30.00 μM for 4-AP, with the detection limits of 2.13 nM for AC and 2.19 nM for 4-AP, respectively. The Cu-Ni/rGO/GCE was successfully used for the determination of 4-AP and AC simultaneously of paracetamol tablets, and satisfactory results were obtained.
研究领域:
材料科学
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分析化学
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生物医学
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DOI
高影响因子
JOURNAL OF THE CHINESE CHEMICAL SOCIETY
·
2023
·Vol. 70
·期 4
·848-856
·
IF 1.8
Xiqiang Tian,Yanping Dong,Muhammad Zahid
The excellent photocatalytic hydrogenation of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) with NaBH 4 in the aqueous medium is still a big challenge. Herein, we report a facile one-pot evaporation-induced self-assembly (EISA) method to synthesize a series of CuO/TiO 2 nanocomposites. The as-synthesized CuO/TiO 2 photocatalysts exhibit remarkable catalytic activity under direct sunlight in selective hydrogenation of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) due to the synergistic interaction of guest copper nanoparticles with host titanium dioxide (TiO 2 ) species. Especially, 5 wt% CuO/TiO 2 nanocomposite revealed superior reaction rate constant (k) value (0.306 min −1 ) when compared to 3 wt% CuO/TiO 2 (0.192 min −1 ) and 7 wt% CuO/TiO 2 (0.240 min −1 ). Moreover, several characterization techniques (XRD, TEM, N 2 adsorption–desorption isotherm, DRS, and XPS) were executed to deeply investigate the effect of copper content on the bulk and interfacial properties of the catalysts. The characterization results proved that the superior photocatalytic hydrogenation over 5 wt% CuO/TiO 2 catalyst can be ascribed to moderate CuO loading as well as even dispersion of CuO species on the surface of active TiO 2 host, which can largely improve the light absorption ability within visible light region. Besides, the 5 wt% CuO/TiO 2 catalyst exhibits remarkable recyclability and durability, retaining its superior activity (above 95%) up to several repeating cycles, proving its practical applicability for hydrogenation reactions at domestic and industrial levels.
研究领域:
材料科学
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环境科学
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化学工程
✓ 已验证
产品关联
DOI
高影响因子
SENSORS AND ACTUATORS B-CHEMICAL
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2019
·
IF 6.393
Yanling Shen,Hong Yan,Hua Guo,Yumei Long,Weifeng Li
A new electrochemical sensor has been developed for the simultaneous determination of 4-aminophenol (4-AP) and phenol (Ph) based on the defect-rich hexagonal boron nitride (D-h-BN). The D-h-BN was prepared via one-step calcination route using a single-source precursor. The obtained D-h-BN was structurally characterized by X-ray diffraction (XRD), fourier transform infrared (FTIR) spectroscopy and transmission electron microscopy (TEM). Photoluminescent (PL) result suggested that the as-synthesized h-BN was highly defective. More interestingly, such D-h-BN exhibited favorable electrocatalytic activity in the redox reaction of Ph and 4-AP, which was confirmed by cyclic voltammetry (CV) and differential pulse voltammetry (DPV) measurements. The enhanced electrocatalytic activity of D-h-BN was attributed to its large surface-active sites and fast electron transfer mediated by defect structure. Thus, D-h-BN was employed to modify glassy carbon electrode (GCE) without any binder agents and the as-fabricated sensor showed good electrochemical performances in the simultaneous determination of 4-AP and Ph. By using DPV method, the linear detection ranges between concentrations and current intensities for 4-AP and Ph were 0.01–30 and 0.1–30 μM, respectively, and their detection limits (S/N = 3) were estimated to be 0.003 and 0.035 μM. Moreover, the desirable selectivity and reproducibility make the proposed method successfully applied for real sample assay.
研究领域:
材料科学
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分析化学
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产品关联
DOI
高影响因子
ELECTROCHIMICA ACTA
·
2019
·
IF 5.383
Yuanyuan Dong,Min Zhou,Lei Zhang
3D multiporous Co, N co-doped MoO 2 /MoC (3D Co,N-MoO 2 /MoC) nanorods hybrids were successfully synthesized via carburizing core-shell ZIF-67-cladded MoO 3 nanorods precursor at high temperature. As-fabricated Co,N-MoO 2 /MoC nanorods coated glassy carbon electrodes (GCE) was demonstrated to possess superior electrocatalytic activity for the electro-oxidation of acetaminophen (AC) and 4-aminophenol (4-AP). Such excellent electrochemical performance was largely attributed to the synergistic effect of the unique multiporous structure, the optimal component and abundant active sites of the nanorods. The corresponding electrode reaction mechanisms were studied in detail in this article. Under optimal conditions, the linear detection ranges were 0.05–200.0 μmol/L for AC and 0.05–140.0 μmol/L for 4-AP, respectively, with the low detection limits of 0.013 μmol/L and 0.012 μmol/L. Furthermore, the 3D Co,N-MoO 2 /MoC/GCE revealed excellent sensitivity, good reproducibility, stability and anti-interference ability. The developed electrode was evaluated towards the detecting AC and 4-AP in biological fluids, environment water and pharmaceutical formulations with satisfactory recovery, which had a broad application prospect.
研究领域:
材料科学
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分析化学
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电化学
✓ 已验证
产品关联
DOI
高影响因子
APPLIED SURFACE SCIENCE
·
2021
·
IF 6.707
Xiqiang Tian,Muhammad Zahid,Wang Sun,Yujun Zhu
TiO 2 with different morphology as supports can lead to different surface properties and catalytic activities of catalysts. Herein, we reported a novel facile evaporation-induced assisted hydrothermal approach to synthesize three-dimensional hierarchical structure TiO 2 assembled from needle flakes by using Brij-35 as the morphology-directing agent. The morphology of the prepared TiO 2 from flower-like (TiO 2 -FT), sea urchin-like (TiO 2 -SUT), to ball-like (TiO 2 -BT), as well as the size of needle flakes, were controlled by adjusting the amount of Brij-35. These TiO 2 supported palladium catalysts were facilely prepared using a green bio-reductive method with Catalpa Fruit extract as reducing agent, where they showed remarkable catalytic activity in selective hydrogenation of 4-nitrophenol by sodium borohydride. Especially, 1 wt%Pd/TiO 2 -SUT with sea urchin-like exhibited higher reaction rate constant (1.44 min −1 ) than 1 wt%Pd/TiO 2 -FT (1.08 min −1 ) and 1 wt%Pd/TiO 2 -BT (0.72 min −1 ). Furthermore, XRD, N 2 adsorption–desorption, SEM, TEM, CO-FTIR, XPS and CO chemisorption measurements were performed to study the effects of different surface morphologies on the surface properties of catalysts. It reveals that the high catalytic performance of 1 wt%Pd/TiO 2 -SUT can be attributed to its specific hierarchical structure and much higher surface area, improving the uniform dispersion of Pd nanoparticles on the support to expose extra active surface Pd atoms (Pd 0 species) over 1 wt%Pd/TiO 2 -SUT.
研究领域:
材料科学
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催化
·
化学工程
✓ 已验证
产品关联
DOI
高影响因子
ACS Applied Nano Materials
·
2024
·
IF 5.3
Caiwen Pan,Xiaoyan Dong,Qinghong Shi,Linling Yu,Yan Sun
Methyl parathion (MP) is a typical organophosphate pesticide widely used in agriculture, causing serious pollution. MP hydrolysis generates a toxic 4-nitrophenol (4-NP) with environmental risks, but a subsequent reduction of 4-NP produces a nontoxic 4-aminophenol (4-AP), which serves as a resource for further use in chemical synthesis. Thus, the detoxification and resourcilization of MP are of great significance for environmental remediation and sustainable development. However, most reports on MP cascade conversion require two different catalysts, each of which is single-catalytic. Herein, we report the first self-cascade nanocatalyst with bicatalytic activities of hydrolysis and reduction based on cupric metal–organic framework (Cu-AZB) nanosheets for the conversion of MP to 4-AP. It was found that Cu-AZB could completely convert MP to 4-AP in the presence of NaBH4 within 10 min. Moreover, hydrolysis was 19-fold accelerated by the NaBH4-mediated reduction in the self-cascade catalysis, so a catalyst with a high cascade conversion efficiency against MP with an activity factor of 513.2 min–1 g–1, a reaction rate constant of 0.25 min–1, and a half-life of 2.82 min was achieved, which was more efficient than literature-reported cascade catalysts. The results demonstrated the application potential of the bicatalytic Cu-AZB in the complete detoxification and conversion of the toxic pollutant into a nontoxic resource through one-pot cascade catalysis.
研究领域:
环境科学
·
催化
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材料科学
·
化学工程
✓ 已验证
产品关联
DOI
高影响因子
LANGMUIR
·
2025
·
IF 3.9
Caiwen Pan,Qinghong Shi,Xiaoyan Dong,Linling Yu,Yan Sun
Effective degradation and detoxification of the highly toxic organophosphate pesticide methyl parathion (MP) are important for pollution treatment and sustainable development. Enzymatic hydrolysis of MP by organophosphate hydrolase (OPH) is an effective way. However, hydrolytic product 4-nitrophenol (4-NP) remains environmentally hazardous. A promising strategy is to reduce 4-NP to 4-aminophenol (4-AP), which not only is weakly toxic but also has high application value. To realize the cascade conversion of MP to 4-AP with the dual objectives of detoxification and recycling, we designed a chemoenzymatic catalyst by immobilizing the OPH within a reduction-catalytic nanocomposite (NCu) constructed by generating copper nanoparticles (Cu NPs) in a zirconium-based metal–organic framework, NU-1000. Optimized OPH@NCu exhibited a 239% enhancement in catalytic activity compared to free OPH, attributed to substrate enrichment by NCu and activation of OPH by Cu2+. Moreover, OPH@NCu exhibited an average cascade conversion rate of 11.1 μmol min–1 gcatalyst–1, achieving a complete conversion of 50 μM MP to 4-AP within 9 min by using a low reductant concentration (15 mM NaBH4). Notably, OPH@NCu demonstrated robust stability, retaining >86% of its activity after being stored for 10 days and nearly 80% of its activity over six reuse cycles. These results validate OPH@NCu as an efficient and sustainable platform for the cascaded detoxification and recycling of MP.
研究领域:
环境毒理学
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生物催化
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纳米生物技术
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环境污染治理
·
酶工程
·
可持续化学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
危险品化学品经营许可证（带存储）