Synthesis and characterization of 1,3-diamino-graphene as a heterogeneous ligand for a CuI-catalyzed C–N coupling reaction
1,3-Diamino-graphene (NH2-G-NH2) materials were synthesized using a simple chemical method. The as-prepared materials were characterized using FT-IR, TG, XRD, XPS, and SEM measurements. The results revealed that a 1,3-diamino group was successfully grafted on graphene and could immobilize CuI by coordination interactions. The NH2-G-NH2 materials can be used as heterogeneous ligands for CuI-catalyzed C–N coupling reactions, and the desired products were obtained with good yields. The reaction system is much smoother at lower temperature compared with others previously reported. Additionally, the new method can easily realize the purification of products and recycling of catalysts.
研究领域:
材料科学
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有机化学
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催化化学
✓ 已验证
DOI
高影响因子
危险品化学品经营许可证（带存储）