JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
·
2022
·
IF 6.364
Yumin An,Kun Wan,Yi Yang,Yongna Jia,Yehong Cheng
Herein, biomimetic C f /ZrB 2 -SiC ceramic composites with bouligand structures are fabricated by combining precursor impregnation, coating, helical assembly and hot-pressing sintering. First, C f /ZrB 2 -SiC ceramic films are achieved through a precursor impregnation method using polycarbosilane (PCS). Second, the PCS-C f /ZrB 2 -SiC ceramic films are coated with ZrB 2 and SiC ceramic layers. Finally, hot-pressing sintering is employed to densify helical assembly C f /ceramic films with a fixed angle of 30°. The microstructures and carbon fiber content on the mechanical properties of biomimetic C f /ZrB 2 -SiC ceramic composites are analyzed in detail. The results show that the coated ceramic layer on PCS-C f /ZrB 2 -SiC films can heal the cracks formed by pyrolysis of PCS, and the mechanical properties are obviously improved. Meanwhile, the mechanical properties could be tuned by the contents of the carbon fiber. The toughening mechanisms of C f /ZrB 2 -SiC ceramic composites with bouligand structures are mainly zigzag cracks, crack deflection, multiple cracks, carbon fiber pulling out and bridging.
研究领域:
材料科学
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仿生学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
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2018
·Vol. 102
·期 4
·2041-2052
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IF 2.956
Yehong Cheng,Yang Lyu,Wenbo Han,Ping Hu,Shanbao Zhou,Xinghong Zhang
The design of bioinspired architectures is effective for increasing the toughness of ceramic materials. Particularly, a dual composite equiaxial architecture is ideal for fabricating weak interface-toughened ZrB 2 -SiC ceramics with isotropic performance. In this paper, ZrB 2 -SiC-Graphene@ZrB 2 -SiC dual composite ceramics were synthesized via an innovative processing technique of granulating-coating method. ZrB 2 -20 vol.% SiC containing 30 vol.% Graphene was selected as weak interface to realize multiscale toughening and improve the thermal shock resistance of ZrB 2 -SiC ceramic materials. The incorporation of ZrB 2 -SiC-Graphene weak interface into the ZrB 2 -SiC matrix improved the damage tolerance and critical thermal shock temperature difference. The design of equiaxial structures moderated the anisotropy of performance in different planes. The graphene sheets incorporated in the ZrB 2 -SiC-Graphene interface phase played a key role in multiscale toughening, including macroscopic toughening of crack deflection and microcracks, and microscopic toughening of graphene bridging and pull-out.
研究领域:
材料科学
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陶瓷工程
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF ALLOYS AND COMPOUNDS
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2018
·
IF 3.779
Anzhe Wang,Ping Hu,Cheng Fang,Dongyang Zhang,Xinghong Zhang
The effects of cooling rate and initial temperature on thermal shock behavior of ZrB 2 -SiC ceramic were studied by water spraying method with a thermocouple real-time temperature acquisition technique for the first time. It was shown that the cooling rate could be adjusted by changing the water flow rate, and the fracture behavior strongly depended on both the cooling rate and initial temperature. When the extreme value of cooling rate was constant, the decrease of initial temperature would lead to the increase of thermal stress, accompanied by a more serious damage of material, which was mainly because of the nonlinear relationship between thermal expansion coefficient and temperature.
研究领域:
材料科学
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工程热物理
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
·
2021
·Vol. 105
·期 4
·2385-2391
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IF 3.784
Yumin An,Yi Yang,Yongna Jia,Wenbo Han,Yehong Cheng
Biomimetic Bouligand architecture is constructed in the ceramic to improve its toughness. Firstly, unidirectional carbon fiber-reinforced ZrB 2 -SiC ceramic films are achieved through a vacuum-assisted filtration method using graphene oxide. Then, ceramic films are helically assembled at a fixed angle of 30° in the graphite die based on the fiber orientation. Finally, the spark plasma sintering method was utilized to densify helical assembly carbon fiber/ceramic films. By constructing Bouligand structure, high fracture toughness (7.4 MPa·m 0.5 ) and work of fracture (∼1055 J/m 2 ) are achieved in ZrB 2 -based ceramic. The toughening mechanisms mainly are crack deflection, twisting and branching, carbon fiber pulling out, and bridging.
研究领域:
材料科学
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仿生学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
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2020
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IF 4.495
Yushi Qi,Kai Jiang,Changling Zhou,Wenbo Han,Zhiming Du
The development of novel cermet composites based on porous ceramics with high porosity, interconnected pore structure and good mechanical property has attracted considerable attention in engineering application. In this work, water-based freeze casting process was employed to fabricate ZrB 2 -SiC porous ceramic with aligned lamellar-channels structure using PAA-NH 4 as the dispersant. The results revealed that the well-dispersed suspension with best rheological behavior was obtained using 1.0 wt% PAA-NH 4 at pH 9. The crack-free porous ceramic exhibited small volume shrinkage ranging from 2.59 % to 1.87 %. By varying the solid loading, the fabricated samples displayed a tailored porosity ranging from 76.12% to 59.37% and an excellent compressive strength of 7 MPa to 78 MPa. After oxidation, the samples displayed a decreased porosity and an increased compressive strength. The ZrB 2 SiC porous ceramic fabricated in this work will be a promising candidate for the framework of cermet composite.
研究领域:
材料科学
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陶瓷工程
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
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2020
·
IF 4.495
Yehong Cheng,Yaxiong Liu,Yumin An,Ning Hu
Graphene derivative materials exhibit excellent mechanical and thermal properties, which have been extensively used to toughen ceramics and improve thermal shock resistance . To overcome the thermal agglomeration of graphene oxide (GO) during heating and drying process, ZrB 2 -SiC particles decorated GO hybrid foam with uniformly anchored ceramic particles was synthesized by electrostatic self-assembly and liquid nitrogen-assisted freeze-drying process. Densified rGO/ZrB 2 -SiC ceramics with varying microstructure, thermal physical and mechanical properties were obtained by adjusting the content of decorated ceramic particles. Although the flexural strength of rGO/ZrB 2 -SiC ceramics have an attenuation compared with that of ZrB 2 -SiC ceramic, the thermal conductivity , work of fracture and thermal shock resistance are greatly improved. rGO/ZrB 2 -SiC ceramics exhibit delayed fracture and increasing R-curve behavior during the crack propagation . The novel preparation technology allows for the well dispersion of rGO in ZrB 2 -SiC ceramics and can be easily extended to other ceramic or metal materials systems.
研究领域:
材料科学
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工程学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN
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2018
·Vol. 126
·期 7
·504-509
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IF 0.887
Zhiwu JIANG,Peizhong FENG,Xiaohong WANG,Hanzhu ZHANG,Yanan LIU
MoSi2–ZrB2–SiC ceramics were synthesized using Mo, Zr, Si and B4C powders by self-propagating high-temperature synthesis and densifying by spark plasma sintering. The effects of MoSi2 content on the combustion synthesis process, microstructure, and mechanical properties of the ceramics were investigated. The results showed that combustion synthesis is an unstable mode, spiral combustion. The Gibbs calculations and combustion temperature curves indicate there are two reactions occurring at the same time. The volume fraction of the four different phases and their relative densities were also measured and calculated. Compared to pure MoSi2, the 1.0MoSi2–0.2ZrB2–0.1SiC (M10) ceramic exhibits excellent mechanical properties with its maximum Vickers hardness and fracture toughness being 14.0 GPa and of 5.5 MPa m1/2, respectively. The hardness is in agreement with the rule of mixture. The morphology of indentation cracks reveals that the fracture toughness improves as a result of toughening mechanisms such as crack bridge, crack deflection, and microcracks.
研究领域:
材料科学
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工程学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
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2020
·
IF 4.495
Qinghua Feng,Panpan Lin,Tiesong Lin,Peng He,Yan Liu,Weimin Long,Jian Li
A novel design of a multi-layered joint architecture, characterized by the controllable spatial distribution of ceramic reinforcements, was obtained, when brazing ZrB 2 -SiC ceramics and Ti-6Al-4 V reinforced by TiB whiskers with AgCu filler. To induce SiC reinforcements to cluster together, within the center of the filler and especially away from the ZrB 2 -SiC, SiC was added into joint, in the form of a SiC interlayer featuring a 3D-bridged network structure with continuous micro-channels infiltrated by capillary force by liquid filler during brazing. Different SiC particles were connected together, by micro-bridges being not destroyed during brazing. The layer rich in SiC could reduce thermal expansion mismatch between different substrates, the AgCu next to the ZrB 2 -SiC could relax the strain energy by high plastic deformation. Compared to joint brazed with single AgCu, joint strain energy decreased from 10.8 × 10 −6 J to 8.6 × 10 −6 J, accordingly joint shear strength increased from ∼5.4 MPa to ∼41.2 MPa.
研究领域:
材料科学
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焊接工程
✓ 已验证
产品关联
DOI
高影响因子
TRIBOLOGY INTERNATIONAL
·
2023
·
IF 6.2
Yumin An,Mingyao Song,Kun Wan,Yongna Jia,Yi Yang,Yehong Cheng
The anisotropic friction properties of biomimetic C f /ZrB 2 -SiC ceramic composites with fibers disposed along Bouligand structures are analyzed. First, the friction properties parallel to and vertical to the hot-pressing surfaces are analyzed for the C f /ZrB 2 -SiC ceramic composites with different carbon fiber contents. The anisotropy of friction properties of the biomimetic C f /ZrB 2 -SiC ceramic composites with Bouligand structures is analyzed based on the microstructures of wear surfaces. Second, the anisotropic friction properties of biomimetic C f /ZrB 2 -SiC ceramic composites with Bouligand structures under high speed and wet conditions are also explored. Under various working environments, the wear mechanisms including abrasive wear , adhesive wear , oxidation wear, and fatigue wear are analyzed in detail based on the microstructures of the wear surfaces. This paper provides a good reference for analyzing the anisotropic friction properties of ceramic composites with Bouligand structures.
研究领域:
材料科学
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机械工程
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表面工程
✓ 已验证
产品关联
DOI
高影响因子