1,5-二氮杂双环[4.3.0]-5-壬烯(DBN)

规格名称和识别符技术文档高级数据系统学分类三维结构质检证书（CoA,COO,BSE/TSE 和分析图谱) 化学和物理性质安全和危险性（GHS）此产品的引用文献技术文档和文章引用文献溶液计算器常见问题

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为什么选择此级别

提供 ≥98% 纯度，适用于对基线干扰要求严格的色谱和分析工作流程。

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储存与运输

避光,室温,充氩,干燥。常规运输。请查阅批次 COA 获取详细规格。

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质量文档

SDS、COA、产品数据表及规格说明书均可下载。可通过批号查询获取批次 COA。

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文献证明

在色谱分析、有机合成和交叉偶联反应领域已被 49 篇同行评审文献引用。

规格

别名

1,5-二叠氮双环[4.3.0]壬-5-烯 | 1,5-二叠氮双环[4.3.0]壬-5-烯 | 1,5-二氮双环[4.3.0]壬-5-烯

英文别名

DBN | A820145 | AKOS005206778 | 1,5-Diazabicyclo(4.3.0)non-5-ene | 2,3,4,6,7,8-hexahydropyrrolo(1,2-a)pyrimidine | C93461 | 1,5-diazabicyclo[4.3.0] -5-nonene | 1,5-Diazabicyclo[4.3.0]non-5-ene, 98% | Thiazolyl Blue Monotetrazolium | EN300-39944 | NBU | 1,

规格或纯度

≥98%

英文名称

1,5-Diazabicyclo[4.3.0]-5-nonene

应用

1,5-二氮杂二环[4.3.0]壬-5-烯（DBN）可以用作：通过脱氢/脱羧芳构化将四氢-β-咔啉合成为β-咔啉的一种试剂通过Friedel−Crafts酰化反应进行的吡咯和吲哚的区域选择性C-酰化中的亲核有机催化剂。三元液相-液相变化系统配方中的超强碱，并与十六烷和己醇一起用于捕获硫化氢气体。使用超临界二氧化碳作为反应物和溶剂，由2-氨基苄腈制备1H-喹唑啉-2,4-二酮的一种碱。 2-氨基硫酚与CO2通过C-S键形成的环羰基化反应合成苯并噻唑酮的催化剂

储存条件

避光,室温,充氩,干燥

运输条件

常规运输

纯度

≥98%

名称和识别符

PubChem SID

488185254

EC号

221-087-3

分子类型

小分子

IUPAC Name

2,3,4,6,7,8-hexahydropyrrolo[1,2-a]pyrimidine

INCHI

1S/C7H12N2/c1-3-7-8-4-2-6-9(7)5-1/h1-6H2

InChi Key

SGUVLZREKBPKCE-UHFFFAOYSA-N

Smiles

C1CC2=NCCCN2C1

Isomeric SMILES

C1CC2=NCCCN2C1

分子量

124.18

Beilstein号

2417

Reaxy-Rn

2417

Reaxys-RN link address

https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=2417&ln=

技术文档

📋 安全数据表 (SDS)

全面的危险、操作、储存及法规合规文件。

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✅ 分析证书 (COA)

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📊 产品数据表

产品规格和应用的快速参考摘要。

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🔬 规格说明书

该级别的完整质量属性和验收标准。

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高级数据

系统学分类

分类树（Taxonomy Tree）

界（kingdom) 有机化合物
- 超类（Superclass) 有机杂环化合物
  - 类（Class) 吡咯并嘧啶

界（kingdom)	有机化合物
超类（Superclass)	有机杂环化合物
类（Class)	吡咯并嘧啶
亚类（Subclass）	暂无
中间层级节点（Intermediate Tree Nodes）	暂无
直接上位类(Direct Parent)	吡咯并嘧啶
其他上位类（Alternative Parents）	N-烷基吡咯烷咪唑内酰胺类氢化嘧啶炔丙基型1,3-偶极有机化合物甲脒类甲脒类氮杂环化合物有机光子化合物碳氢化合物衍生物
分子骨架（Molecular Framework)	脂肪族杂多环化合物
取代基（Substituents）	1,4,5,6-四氢嘧啶 - 脂肪族杂多环化合物 - 氨基脒 - 氮杂环 - 羧酰亚胺 - 羧酰胺基 - 烃衍生物 - 羟吡啶 - 咪唑内酰胺 - N-烷基吡咯烷 - 有机1,3-双极性化合物 - 有机硝基化合物 - 有机氮化合物 - 有机氮化合物 - 丙炔型1,3-双极性有机化合物 - 吡咯烷 - 吡咯吡啶
描述（Description）	该化合物属于吡咯嘧啶类有机化合物。这类化合物含有吡咯嘧啶结构单元，即吡咯环与嘧啶环共轭连接。吡咯为五元环，由四个碳原子和一个氮原子构成；嘧啶为六元环，由四个碳原子及位于1位和3位的两个氮原子中心构成。
外部描述符（External Descriptors）	暂无

三维结构

交互式化学结构模型

球棍
棍棒
线框模型
空间填充
显示氢气
动画

化学和物理性质

溶解性

可溶于乙醚,甲醇,丙酮，水

密度

1.04

敏感性

对空气和湿度和光线敏感

折光率

1.52

闪点(℉)

201.2 °F

闪点(℃)

98°C

沸点

108°C/15mmHg

分子量

124.180 g/mol

XLogP3

-0.200

氢键供体数Hydrogen Bond Donor Count

氢键受体数Hydrogen Bond Acceptor Count

可旋转键计数Rotatable Bond Count

精确质量Exact Mass

124.1 Da

单同位素质量Monoisotopic Mass

124.1 Da

拓扑极表面积Topological Polar Surface Area

15.600 Å²

重原子数Heavy Atom Count

形式电荷Formal Charge

复杂度Complexity

140.000

同位素原子数Isotope Atom Count

定义的原子立体中心计数Defined Atom Stereocenter Count

未定义的原子立体中心计数Undefined Atom Stereocenter Count

定义的键立体中心计数Defined Bond Stereocenter Count

未定义的键立体中心计数Undefined Bond Stereocenter Count

所有立体化学键的总数The total count of all stereochemical bonds

共价键合单元计数Covalently-Bonded Unit Count

安全和危险性（GHS）

象形图

GHS05

信号词

危险

危险声明

H314: 造成严重的皮肤灼伤和眼睛损伤

预防措施声明

P264: 处理后要彻底洗手。

P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。

P310: 立即致电解毒中心或医生。

P301+P330+P331: 如误吞咽：漱口。不要诱导呕吐。

P303+P361+P353: 如皮肤（或头发）沾染：立即脱掉所有沾染的衣服。用水清洗皮肤/淋浴。

P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。

P405: 密闭存放

P501: 将内容物/容器处理到。。。

WGK Germany

个人防护装备

Faceshields,full-face respirator (US),Gloves,Goggles,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter

质检证书（CoA,COO,BSE/TSE 和分析图谱)

C of A & Other Certificates(BSE/TSE, COO):

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找到27个结果

批号(Lot Number)	证书类型	货号
B2328383	分析证书	D111442
B2328542	分析证书	D111442
B2328544	分析证书	D111442
B2328551	分析证书	D111442
C2631275	分析证书	D111442
C2631274	分析证书	D111442
C2631272	分析证书	D111442
C2631270	分析证书	D111442
I2209272	分析证书	D111442
I2209273	分析证书	D111442
C2422181	分析证书	D111442
H2307655	分析证书	D111442
H2307657	分析证书	D111442
H2307701	分析证书	D111442
B2328541	分析证书	D111442
B2328540	分析证书	D111442
B2328539	分析证书	D111442
I2209274	分析证书	D111442
D2503019	分析证书	D111442
E2523057	分析证书	D111442
A2206104	分析证书	D111442
A2206109	分析证书	D111442
D1809073	分析证书	D111442
H2307665	分析证书	D111442
L1518009	分析证书	D111442
I2209275	分析证书	D111442
K1411010	分析证书	D111442

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技术文档和文章

DBU 在不同体系中的反应角色：强有机碱、亲核催化与反应路径参与的实验判断

目录：技术文章

探索主题:

DBU 双环脒类试剂

Reaction Roles of DBU in Different Systems: Experimental Judgment from a Strong Organic Base to Nucleophilic Catalysis and Participation in the Reaction Pathway

目录：技术文章

探索主题:

DBU Bicyclic amidine reagents

氮杂三环烷烃的张力释放：三维氮杂桥环的桥位模块化官能团化与立体控制

目录：技术文章

探索主题:

ABCAs 氮杂双环[x.1.1]烷烃

Strain Release of Azatricycloalkanes: Modular Bridge-Position Functionalization and Stereochemical Control of Three-Dimensional Bridged Aza Scaffolds

目录：技术文章

探索主题:

ABCAs azabicyclo[x.1.1]alkanes

此产品的引用文献

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引用文献

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5. Jiqing Dong, Ran Ping, Xun Dai, Dongchao Wang, Fusheng Liu, Shanshan Du, Mengshuai Liu. (2022) Pyrrolidine-2,5-dione-derived ionic liquids promoted efficient transformation of flue gas CO2 into α-alkylidene cyclic carbonates at room temperature. Journal of CO2 Utilization, [10.1016/j.jcou.2022.102227]
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7. Yanyan Xie, Hongshuai Gao, Puyu Zhang, Congwen Qin, Yi Nie, Xue Liu. (2022) Preparation of Degradable Wood Cellulose Films Using Ionic Liquids. ACS Applied Polymer Materials, [10.1021/acsapm.2c00167]
8. Ruixia Liu, Tingting Ding, Pingping Deng, Xiaofan Yan, Fuquan Xiong, Jienan Chen, Zhiping Wu. (2021) Preparation of LCST regulable DES-lignin-g-PNVCL thermo-responsive polymer by ARGET-ATRP. INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, [PMID:34800520] [10.1016/j.ijbiomac.2021.11.077]
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11. Ran Ping, Penghui Zhao, Qianqian Zhang, Guangyu Zhang, Fusheng Liu, Mengshuai Liu. (2021) Catalytic Conversion of CO2 from Simulated Flue Gases with Aminophenol-Based Protic Ionic Liquids to Produce Quinazoline-2,4(1H,3H)-diones under Mild Conditions. ACS Sustainable Chemistry & Engineering, [10.1021/acssuschemeng.1c01466]
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13. Xiaomin Zhang, Wenjie Xiong, Lingling Peng, Youting Wu, Xingbang Hu. (2020) Highly selective absorption separation of H2S and CO2 from CH4 by novel azole-based protic ionic liquids. AICHE JOURNAL, 66 (6): (e16936). [10.1002/aic.16936]
14. Fusheng Liu, Ran Ping, Yongqiang Gu, Penghui Zhao, Bin Liu, Jun Gao, Mengshuai Liu. (2020) Efficient One Pot Capture and Conversion of CO2 into Quinazoline-2,4(1H,3H)-diones Using Triazolium-Based Ionic Liquids. ACS Sustainable Chemistry & Engineering, [10.1021/acssuschemeng.9b07242]
15. Junjie Guo, Xianfang Meng, Hongwei Zhu, Mengmeng Sun, Yibo Wang, Weina Wang, Mingyu Xing, Fei Zhang. (2018) Boosting the performance and stability of perovskite solar cells with phthalocyanine-based dopant-free hole transporting materials through core metal and peripheral groups engineering. ORGANIC ELECTRONICS, [10.1016/j.orgel.2018.09.045]
16. Feng Wang, Jian Lin, Hongye Wang, Shansheng Yu, Xiaoqiang Cui, Asghar Ali, Tao Wu, Yang Liu. (2018) Precise mono-Cu+ ion doping enhanced electrogenerated chemiluminescence from Cd–In–S supertetrahedral chalcogenide nanoclusters for dopamine detection. Nanoscale, 10 (34): (15932-15937). [PMID:30116817] [10.1039/C8NR05046E]
17. Qiang Jia, Yue Ma, Yinxian Peng, Yanhong Liu, Wenli Zhang. (2018) Selective recognition and separation of luteolin based on the molecular imprinted hollow SnO2 and boronate affinity. CHEMICAL ENGINEERING JOURNAL, [10.1016/j.cej.2018.02.103]
18. Jun-Jie Guo, Zheng-Chen Bai, Xian-Fang Meng, Meng-Meng Sun, Jia-Hao Song, Zhen-Sheng Shen, Nan Ma, Zheng-Lei Chen, Fei Zhang. (2017) Novel dopant-free metallophthalocyanines based hole transporting materials for perovskite solar cells: The effect of core metal on photovoltaic performance. SOLAR ENERGY, [10.1016/j.solener.2017.05.089]
19. Yingjie Xu. (2017) CO2 absorption behavior of azole-based protic ionic liquids: Influence of the alkalinity and physicochemical properties. Journal of CO2 Utilization, [10.1016/j.jcou.2017.03.001]
20. Jian Lin, Dan-Dan Hu, Qian Zhang, Dong-Sheng Li, Tao Wu, Xianhui Bu, Pingyun Feng. (2016) Improving Photoluminescence Emission Efficiency of Nanocluster-Based Materials by in Situ Doping Synthetic Strategy. Journal of Physical Chemistry C, [10.1021/acs.jpcc.6b09126]
21. Feng Wang, Jian Lin, Tingbi Zhao, Dandan Hu, Tao Wu, Yang Liu. (2016) Intrinsic “Vacancy Point Defect” Induced Electrochemiluminescence from Coreless Supertetrahedral Chalcogenide Nanocluster. Journal of the American Chemical Society, [PMID:27228563] [10.1021/jacs.6b03662]
22. Jian Lin, Le Wang, Qian Zhang, Fei Bu, Tao Wu, Xianhui Bu, Pingyun Feng. (2016) Highly effective nanosegregation of dual dopants in a micron-sized nanocluster-based semiconductor molecular single crystal for targeting white-light emission. Journal of Materials Chemistry C, 4 (8): (1645-1650). [10.1039/C5TC04191K]
23. Jian Lin, Qian Zhang, Le Wang, Xiaochun Liu, Wenbo Yan, Tao Wu, Xianhui Bu, Pingyun Feng. (2014) Atomically Precise Doping of Monomanganese Ion into Coreless Supertetrahedral Chalcogenide Nanocluster Inducing Unusual Red Shift in Mn2+ Emission. Journal of the American Chemical Society, [PMID:24625310] [10.1021/ja501288x]
24. Jiabao Li, Dongxia Yan, Xiujie Cheng, Chunrui Rong, Jian Feng, Xin Feng, Jiayu Xin, Qing Zhou, Yi Li, Junli Xu, Xingmei Lu. (2024) Efficient Methanolysis of PET Catalyzed by Nonmetallic Deep Eutectic Solvents. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, [10.1021/acs.iecr.4c00720]
25. Bin Xu, Zhong-Ming Xia, Rui Zhan, Ke-Ke Yang. (2024) Fabricating High Strength Bio-Based Dynamic Networks from Epoxidized Soybean Oil and Poly(Butylene Adipate-co-Terephthalate). Polymers, 16 (16): (2280). [PMID:39204500] [10.3390/polym16162280]
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