Kinetic Matching in Photoredox/Nickel C(sp²)–C(sp³) Coupling: Radical Generation, Nickel-Species Stability, and Photon Flux
In 2014, Tellis, Primer, and Molander reported a photoredox/nickel dual-catalytic cross-coupling involving organotrifluoroborates. Conventional organoboron cross-coupling relies on a two-electron transmetalation process, whereas transmetalation of C(sp³) organoboron reagents is often relatively ...
危险品化学品经营许可证(带存储)