Aryl C–N

From Temporary Covalent Assembly to Intramolecular Smiles Aryl Migration: DCPDC-Mediated Phenol–Primary Amine C–N Cross-Coupling

Aryl C–N bonds are widely found in pharmaceuticals, agrochemicals, and functional molecules. Transition-metal-catalyzed amination reactions such as Buchwald–Hartwig amination typically employ aryl halides or pseudohalides as aryl electrophiles, whereas classical nucleophilic aromatic ...