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Cellulose-supported Pd nanoparticles: effective for the selective oxidation of glucose into gluconic acid

Journal 2019 · IF 1.858 · 77(2): 1003-1014 · 发表于 2019 年 4 月 24 日
作者: Zhang Xinxin,Shi Haoyan,Chi Quan,Liu Xixi,Chen Lianqing
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摘要

Cellulose-supported on Pd nanoparticles (Pd/cellulose) were successfully prepared by chemical reduction technique and characterized by various experimental tools. The Pd/cellulose catalyst was found to effectively promote the oxidation of glucose into gluconic acid under mild conditions. The base played a crucial role in the oxidation of glucose into gluconic acid. Glucose was fully converted at room temperature after 3 h by the use of stoichiometric amount of Na 2 CO 3 to neutralize gluconic acid, and gluconic acid was obtained in a high yield of 91.2%. The catalyst was recovered from product and reused up to five times without significant loss in its catalytic activity.

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