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The detection for hypochlorite by UV–Vis and fluorescent spectra based on oxidized ring opening and successive hydrolysis reaction

Journal 2016 · IF 2.653 · 发表于 2016 年 5 月 14 日
作者: Kangming Xiong,Caixia Yin,Jianbin Chao,Yongbin Zhang,Fangjun Huo
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摘要

In this work, two high selective and sensitive fluorescent probes for ClO − , 7-Hydroxycoumarin and 4-Hydroxycoumarin were designed. The reaction mechanism that we speculated was the oxidized ring opening reaction and hydrolysis. The detection could be realized in quasi-aqueous phase and the detection limits of probe [7] and probe [4] for ClO − were found to be 56.8   nM and 70.5   nM. Furthermore, the probes can be used to cell imagings.