Electronic transition pathways in energy transfer processes for upconversion photoluminescence of Yb3+/Ho3+ co-doped NaLa(MoO4)2 microcrystals

In recent years, upconversion photoluminescent micro/nanocrystals with unique anti-Stokes luminescence properties have shown high application value in many relevant fields. In this work, pure tetragonal phase NaLa(MoO 4 ) 2 :Yb 3+ /Ho 3+ microspheres have been synthesized by a solvothermal method in the presence of oleic acid and 1-octadecene. Under the excitation of 980 nm laser, NaLa(MoO 4 ) 2 :Yb 3+ /Ho 3+ microcrystals emit red, green and near infrared upconversion luminescence with peak wavelengths at 660/643 nm, 541 nm, and 756 nm. Based on the analysis of excitation power-dependent upconversion luminescence intensities and energy level diagram of Yb 3+ /Ho 3+ , electronic transition pathways in the energy transfer processes for upconversion luminescence of NaLa(MoO 4 ) 2 :Yb 3+ /Ho 3+ microcrystals are studied. For red upconversion luminescence at 660/643 nm, the predominant population pathway to state 5 F 5 (Ho 3+ ) is “Yb 3+ ( 2 F 5/2 ) + Ho 3+ ( 5 I 7 ) → Yb 3+ ( 2 F 7/2 ) + Ho 3+ ( 5 F 5 )”. While, “Yb 3+ ( 2 F 5/2 ) + Ho 3+ ( 5 I 6 ) → Yb 3+ ( 2 F 7/2 ) + Ho 3+ ( 5 F 4 / 5 S 2 )” process accounts for the population of state 5 F 4 / 5 S 2 (Ho 3+ ) for radiative transitions of upconversion luminescence at 541 and 756 nm. Energy back transfer contributes to the intense red upconversion luminescence at 660/643 nm. These electronic transition pathways in energy transfer processes are further confirmed by the analyses based on energy level mismatch and luminescent lifetimes.