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The anti­oxidant methyl 3-(3,5-di-tert-butyl-4-hy­droxy­phen­yl)propionate

Journal 2014 · IF 0.535 · 70(11): 1050-1053 · 发表于 2014 年 10 月 15 日
作者: Li X.,Wang Z.-G.,Chen H.-H.,Liu S.-G.
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摘要

The title compound, C18H28O3, was prepared by the reaction of 2,6-di-tert-butyl­phenol with methyl acrylate under basic conditions using di­methyl sulfoxide as the promoter. The structure of this anti­oxidant indicates significant strain between the ortho tert-butyl substituents and the phenolic OH group. In spite of the steric crowding of the OH group, it participates in inter­molecular hydrogen bonding with the ester carbonyl O atom.