摘要
The use of photogenerated carriers to regulate interfacial photo-redox reactions and improve the efficiency of photocatalytic applications has become a hot topic in photocatalyst research. We proposed a novel strategy, which enables efficient charge separation by uniformly deposition CuS/Bi₂S₃ nanoparticles on three-dimensional porous cellulose-derived carbon aerogel (CA), and utilizes highly active holes excited by ultraviolet-visible light to drive surface reactions, demonstrating excellent performance in the photo-oxidative degradation of methylene blue (MB) organic pollutants. The samples were characterized and structurally tested using techniques such as X-ray fluorescence spectroscopy, X-ray diffraction analysis, scanning electron microscopy, and a BET specific surface area analyzer. Under visible light irradiation, the composite material demonstrated remarkable degradation efficiency for methylene blue, achieving 98.98% removal within 80 min while maintaining over 87.48% of its initial activity after five consecutive reaction cycles. The enhanced photocatalytic performance is attributed to the fact that the carbon aerogel matrix provides a 3D framework with high surface area to effectively disperse catalyst nanoparticles and organic dye molecules near the active site, its conductive network facilitates efficient electron transport, and the porous structure can optimally separate photogenerated electron-hole pairs by enhancing light absorption through internal scattering mechanisms. We identified that superoxide anions (·O₂ − ) and hydroxyl radicals (·OH) act as the primary active species in the degradation process through radical trapping experiments. This study not only presents a high-performance, environmentally friendly catalyst for wastewater treatment but also offers valuable design principles for developing biomass carbon-based photocatalytic systems with S-scheme heterojunctions.
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