Energy Material Advances
·
2022
·
IF 0
Jinxing Yu,Xiaoxiang Xu
Halide perovskites have been emerging as promising photocatalytic materials for H 2 evolution from water due to their outstanding photoelectric properties. However, the lack of proper surface reactive sites greatly hinders the photocatalytic potential of these fascinating compounds. Here, Mo 2 C nanoparticles have been anchored onto methylammonium lead iodide (MAPbI 3 ) as a nonnoble metal cocatalyst to promote H 2 evolution reactions. The Mo 2 C nanoparticles have opposite zeta potential with MAPbI 3 thereby electrostatically assembled onto the MAPbI 3 surface, i.e., Mo 2 C@MAPbI 3 . Our results show that the anchored Mo 2 C nanoparticles have a strong interplay with MAPbI 3 substrate so that photogenerated electrons of MAPbI 3 can be rapidly separated and transferred into Mo 2 C for further H 2 evolution reactions. Under optimal conditions, Mo 2 C@MAPbI 3 delivers exceptionally high photocatalytic performance for visible light-driven H 2 evolution that clearly outperforms pristine MAPbI 3 and Pt-deposited MAPbI 3 . An apparent quantum efficiency as high as 12.65% at 600 ± 40 nm has been attained for H 2 evolution, surpassing most of the MAPbI 3 -based photocatalyst reported. These results signify the usefulness and applicability of Mo 2 C as a new nonnoble metal-based cocatalyst in solar water splitting.
✓ 已验证
DOI
JOURNAL OF COLLOID AND INTERFACE SCIENCE
·
2015
·
IF 3.368
Shutao Gao,Tao Feng,Cheng Feng,Ningzhao Shang,Chun Wang
In this paper, a novel visible-light responsive photocatalyst of Ag/AgCl@MIL-101 was synthesized via vapor diffusion-photoreduction strategy. The as-prepared composite material was characterized using X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy, transmission electron microscopy, ultraviolet–visible diffuse reflection spectra and X-ray photoelectron spectroscopy. Due to the synergistic effect between Ag/AgCl and MIL-101, the composite photocatalyst exhibited an enhanced and stable photoactivity for the degradation of Rhodamine B under visible light irradiation. The relationship between the photocatalytic activity and the structure of Ag/AgCl@MIL-101 hybrid material was discussed and the possible reaction mechanism was proposed.
✓ 已验证
DOI
高影响因子
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
·
2018
·
IF 2.88
Tao Liu,Zhihai Xie,Qing Liu
A sensitive, simple and novel method was developed to determine diclofenac sodium (DS) using silver nanoparticles (AgNPs) as probe by resonance light scattering (RLS) technique. It was found that DS could quench the RLS intensity of AgNPs . Moreover, the decrease in RLS intensity was linearly correlated to the concentration of DS over the range of 0.01–2.0 μg mL −1 . DS can be measured in a short time (5 min) without any complicated or time-consuming sample pretreatment process. Parameters that affect the RLS intensities such as pH, concentration of AgNPs, reaction time, electrolyte concentration , and coexisting substances were systematically investigated and optimized. The results showed that the method had a very good selectivity and could be used conveniently for the determination of DS. The limit of detection (LOD) was 2.85 ng mL −1 (3σ), and the relative standard deviation (RSD) was less than 3.6% ( n = 6). Possible mechanism for the RLS changes of AgNPs in the presence of DS was discussed and the method was successfully applied for the analysis of tablets and urine samples.
✓ 已验证
DOI
高影响因子
Journal of Materials Chemistry C
·
2023
·Vol. 11
·期 6
·2137-2143
·
IF 6.4
Jingshan Hou,Jianghua Wu,Zhiyu Qin,Yongzheng Fang,Leijun Shen,Xin Qiao,Langping Dong,Ganghua Zhang,Yufeng Liu,Guoying Zhao,Haijie Chen
Low-dimensional metal halides have attracted extensive attention because of their superior optoelectronic properties, high stability and structural diversity. In this work, we report a two-dimensional (2D) lead-free halide Cs2MnCl4:Cu+ as a new phosphor for white light-emitting diodes (LEDs). By doping copper(I) into manganese(II) sites, a strong green emission with a photoluminescence quantum yield (PLQY) of 70% was observed. The luminescence center was located at 530 nm and the optimal excitation wavelength was determined to be 310 nm, which suggests a large Stokes shift of 220 nm. Steady-state and transient fluorescence spectra show a decay time of 114.19 μs, indicating a self-trapped exciton (STE) emission mechanism which was further confirmed by temperature-dependent steady-state photoluminescence spectroscopy. This work suggests that manganese halides could be considered as a new family with high luminescence efficiency for optoelectronic applications.
✓ 已验证
DOI
高影响因子
Journal of Materials Chemistry C
·
2019
·Vol. 7
·期 13
·3751-3755
·
IF 6.641
Jiao Ma,Hao Wu,Jianbei Qiu,Jing Wang,Qi Wang,Yong Yang,Dacheng Zhou,Jin Han
All-inorganic CsPbX3 (X = Cl, Br, and I) perovskite quantum dots have great potential in the field of white light emission owing to their excellent optical properties. However, to date the research on white light based on perovskite quantum dots has focused on downconversion luminescence, while the up-conversion luminescence properties of quantum dots have received less attention due to lacking the anti-Stokes luminescence properties of the material itself, resulting in limitations in upconversion white light emission to some extent. In this paper, upconversion lanthanide ion-doped fluoride nanoparticles and perovskite quantum dots are combined; the luminescence of the quantum dots is excited successfully by the upconversion luminescence of the nanoparticles and then composite samples with white emission are obtained with regulators of concentration.
✓ 已验证
DOI
高影响因子
Research
·
2022
·
IF 11.036
Kewei Ma,Qingfeng Gui,Cihui Liu,Yunyi Yang,Fangjian Xing,Yunsong Di,Xiaoming Wen,Baohua Jia,Zhixing Gan
Multicolor fluorescence of mixed halide perovskites enormously enables their applications in photonics and optoelectronics. However, it remains an arduous task to obtain multicolor emissions from perovskites containing single halogen to avoid phase segregation. Herein, a fluorescent composite containing Eu-based metal-organic frameworks (MOFs), 0D Cs 4 PbBr 6 , and 3D CsPbBr 3 is synthesized. Under excitations at 365 nm and 254 nm, the pristine composite emits blue (B) and red (R) fluorescence, which are ascribed to radiative defects within Cs 4 PbBr 6 and 5 D 0 → 7 F J transitions of Eu 3+ , respectively. Interestingly, after light soaking in the ambient environment, the blue fluorescence gradually converts into green (G) emission due to the defect repairing and 0D-3D phase conversion. This permanent and unique photochromic effect enables anticounterfeiting and microsteganography with increased security through a micropatterning technique. Moreover, the RGB luminescence is highly stable after encapsulation by a transparent polymer layer. Thus, trichromatic light-emitting modules are fabricated by using the fluorescent composites as color-converting layers, which almost fully cover the standard color gamut. Therefore, this work innovates a strategy for construction of tunable multicolor luminescence by manipulating the radiative defects and structural dimensionality.
✓ 已验证
DOI
高影响因子
JOURNAL OF ALLOYS AND COMPOUNDS
·
2019
·
IF 4.175
Quansheng Wu,Quan Zhao,Ziyu He,Wenbo Chen,Qiang Huang,Penghui Zheng,Dongfeng Xiang,Jiangcong Zhou
The exploration of rare-earth-free phosphors is desirable for white LEDs applications. In this work, Cr 3+ doped Na 2 TiSiO 5 self-activated phosphors were synthesized by conventional solid-state reaction. The electronic structure of Na 2 TiSiO 5 was calculated using density functional theory (DFT) methods. The variations in crystal structure, luminescence properties and thermal stability of Na 2 Ti 1-x SiO 5 : x Cr 3+ were exhaustively investigated by the analysis of XRD patterns , photoluminescence (PL) spectra, diffuse reflection spectra, PL decay curves and temperature-dependent PL spectra. Owing to the red shift of absorption edge and energy transfer between Cr 3+ ions and Ti 4+ ions, the emission intensity and thermal stability of Na 2 TiSiO 5 were improved by the introduction of Cr 3+ ions, and the peak position was red-shifted. The results indicate that the introduction of Cr 3+ ions could be an effective method to regulate the luminescence of Ti 4+ -activated oxide phosphors.
✓ 已验证
DOI
高影响因子
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
·
2015
·
IF 3.615
Wenrong Cao,Lifang Chen,Zhiwen Qi
Novel Ag/Ag 2 SO 4 /ZnO nanostructures were successfully fabricated by a facile microwave-assisted template-free hydrothermal method. The results reveal that Ag/Ag 2 SO 4 nanoparticles are uniformly dispersed on the surfaces of ZnO plates, which forms the hierarchical Ag/Ag 2 SO 4 /ZnO (AZ) nanostructures. The AZ-2 photocatalyst obtained by adjusting the amounts of thiourea and AgNO 3 with the molar ratio of 1:1 exhibits the highest photocatalytic efficiency, and rhodamine B can be decolorized within 35 min and 20 min under visible-light ( λ > 420 nm) and natural sunlight irradiation, respectively. The enhanced photocatalytic performance of AZ catalysts may result from the synergistic effects of Ag/Ag 2 SO 4 nanoparticles loaded on ZnO surfaces, which can enhance visible-light absorption capability of ZnO and promote photoinduced electron–hole separation. Therefore, the Ag/Ag 2 SO 4 nanoparticles doped on semiconductors can be used as effective visible-light photocatalysts and show a great potential for practical applications in the treatment of dye-containing wastewater.
✓ 已验证
DOI
高影响因子
JOURNAL OF LUMINESCENCE
·
2022
·
IF 4.171
Liwei Zeng,Jiyou Zhong,Chaojie Li,Zeqiang Zhuang,Lei Chen,Weiren Zhao
Near-infrared phosphor-converted light-emitting diodes (NIR pc-LEDs) have attracted more and more attention for the applications in spectroscopic technology, promoting the demand of searching broad-band near-infrared phosphors. In this work, Cr 3+ -doped NaInP 2 O 7 phosphors with broadband NIR emission were synthesized via conventional high-temperature solid-state reaction method. The crystal, photoluminescence , and the performance of fabricated device were investigated in detail. The photoluminescence demonstrates this material exhibits an intense absorption in blue light region, matching well with the blue LED chip; while the emission spectra peaking at 870 nm covers 650–1150 nm region with a full width at half maximum (FWHM) of about 150 nm. The quantum yield (QY) and absorption efficiency was determined to be 28.2% and 49.82%, respectively, under 460 nm blue light excitation. Finally, a NIR pc-LED device was fabricated by using a commercial 455 nm blue LED combined with as-prepared NaInP 2 O 7 :Cr 3+ phosphor, which has an output power of 9.08 mW and photoelectronic conversion efficiency of 2.98% under a driving current of 100 mA, indicating that the as-prepared phosphors might have a good potential for application in NIR pc-LEDs.
✓ 已验证
DOI
高影响因子
Science Advances
·
2021
·Vol. 7
·期 34
·
IF 14.143
Jun-Hua Wei,Jin-Feng Liao,Lei Zhou,Jian-Bin Luo,Xu-Dong Wang,Dai-Bin Kuang
Although single-source white emissive perovskite has emerged as a class of encouraging light-emitting material, the synthesis of lead-free halide perovskite materials with high luminous efficiency is still challenging. Here, we report a series of zero-dimensional indium-antimony (In/Sb) alloyed halide single crystals, BAPPIn 2–2 x Sb 2 x Cl 10 (BAPP = C 10 H 28 N 4 , x = 0 to 1), with tunable emission. In BAPPIn 1.996 Sb 0.004 Cl 10 , bright yellow emission with near 100% photoluminescence quantum yield (PLQY) is yielded when it was excited at 320 nm, which turns into bright white-light emission with a PLQY of 44.0% when excited at 365 nm. Combined spectroscopy and theoretical studies reveal that the BAPP 4+ -associated blue emission and inorganic polyhedron–afforded orange emission function as a perfect pair of complementary colors affording white light in BAPPIn 1.996 Sb 0.004 Cl 10 . Moreover, the interesting afterglow behavior, together with excitation-dependent emission property, makes BAPPIn 2–2 x Sb 2 x Cl 10 as high-performance anti-counterfeiting/information storage materials.
✓ 已验证
DOI
高影响因子
Journal of Materials Chemistry C
·
2023
·Vol. 11
·期 48
·16941-16949
·
IF 6.4
Shuxian Wang,Jiaming Song,Linghao Zong,Juanjuan Yang,Bingda Li,Feng Teng,Peng Hu,Haibo Fan,Xin Zhao
As promising candidates in optoelectronics, transition metal thiophosphates (MTPs) have attracted intensive research interest due to their strong light absorption and tunable bandgaps. As a member of the MTP family, SnP2S6 has demonstrated significant potential for application in photodetectors (PDs). Here, we report a SnP2S6-based metal–semiconductor–metal (MSM) photodetector with asymmetric electrode contacts. The device demonstrated a responsivity of 146.82 mA W−1 and a detectivity of 8.0 × 1010 Jones in the visible light region. Moreover, it showed self-powered behavior at zero bias voltage with an ultra-low dark current, fast response speed, high responsivity and high detectivity. The self-powered response current of the device could be attributed to the net current generated by the unbalanced energy barriers of the two asymmetric Schottky contacts between the crystal and the gold electrodes. This work provides a possible way for the application of SnP2S6-based PDs in portable energy saving devices.
✓ 已验证
DOI
高影响因子
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
·
2016
·Vol. 28
·期 6
·4669-4675
·
IF 1.798
Zhang Xiufang,Mei Jie,Wang Song,Zheng Yingying,Cui Can,Pan Jiaqi,Li Chaorong
The cotton cellulose nanofibers(CCNFs)/ZnO/CuS nanocomposites have been successfully fabricated by the electrospun-hydrothermal method and successive ionic layer adsorption. The results of XRD, SEM and TEM indicate that the CuS are successfully combined with the ZnO. The photocatalytic activity of the CCNFs/ZnO/CuS nanocomposites is investigated by the degradation of methylene blue under visible light irradiation, and it is demonstrated to be significantly enhanced after the CuS is introduced. Furthermore, the direct interfacial charge transfer of the ZnO/CuS is considered as the main reason for the enhancement.
✓ 已验证
DOI
高影响因子
危险品化学品经营许可证（带存储）