INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
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2025
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IF 8.3
Xu Jia,Zhiqi Song,Jiaqi Zhang,Jiaolong Qiao,Liuxue Zhang,Xiulian Wang,Shuyan Jiao,Guomin Yu
To enhance the hydrogen production efficiency and stability in photocatalysis, a ternary heterojunction composite CdS@Ce-MOF/g-C 3 N 4 was developed by in-situ growth of Ce-MOF and CdS on graphitic carbon nitride (g-C 3 N 4 ). The synthesized composite not only mitigated the photocorrosion of sulfides but also established a stepwise energy-level alignment and built-in electric field within the heterojunction. These structural advantages effectively facilitated the separation of photogenerated electron-hole pairs and suppress their recombination, thereby significantly improving photocatalytic hydrogen evolution performance. Under simulated sunlight irradiation, the composite exhibited a hydrogen production rate of 4953.125 μmol g −1 , which is 7 times higher than that of pristine g-C 3 N 4 . Moreover, the hydrogen evolution rate remained stable with negligible degradation after multiple cycling tests, demonstrating excellent durability. The CdS@Ce-MOF/g-C 3 N 4 composite, with its superior hydrogen generation capacity and robust stability in photocatalytic water splitting, provides a promising alternative for advancing research on high-performance photocatalysts.
研究领域:
材料科学
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能源化学
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环境科学
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产品关联
DOI
高影响因子
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
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2025
·
IF 8.5
Zuozhu Yin,Qingqing Yu,Hong Chen,Xiaoxiang Chen,Kaiyuan Liu,Min Li,Xiaoze Yang,Yuhua Chen,Yu Xie,Yidan Luo,Mingshan Xue
The discharge of oily wastewater and sewage in industry and life was increasing, seriously affecting the sustainability of the environment and ecosystem. In this work, a multifunctional superhydrophobic nanocellulose-based membrane was prepared by spraying Ce-MOF nanoparticles onto the nanocellulose membrane, which had a hydrostatic contact angle of up to 170°: (i) Resistance to harsh conditions (including high temperatures, abrasion, ultraviolet light exposure, bending, and self-cleaning); (ii) Achieve efficient separation of mixed oil and water. It has shown commendable efficacy in separating wastewater containing mixed oils. The separation flux of mixed oil wastewater was 179 L·m −2 ·h −1 (n-hexane and chloroform/water), and the separation efficiency was >94 % (n-hexane and chloroform/water); (iii) Efficient and rapid photocatalytic removal of pollutants, which is a useful property to prevent organic pollution; (iv) Effectively prevent biological pollutants adhesion, reducing the amount of microbial adhesion by 67.74 %. In many fields, such as industrial production and urban sewage treatment, wastewater treatment in harsh environments as well as the durability of materials has always been an issue. The appearance of this new material provides a feasible solution to this problem.
研究领域:
环境科学
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材料科学
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化学工程
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产品关联
DOI
PubMed
高影响因子
Materials Today Chemistry
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2025
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IF 6.7
Jiaxu Zhao,Weilong Du,Dan Su,Xiaoyan He,Xiuqin Bai
Biofilms attached to various surfaces can lead to significant adverse effects in multiple areas. Cerium metal-organic framework (Ce-MOF) can function as haloperoxidase; however, their initial activity is relatively low. This study proposes a post-treatment method to enhance their enzymatic activity through the oxidation of the initial Ce-MOF. The research elucidates the haloperoxidase activity and anti-biofilm properties of Ce-MOFs. The synthesized Ce-MOFs exhibit a nanorod structure. The oxidized Ce-MOFs demonstrate substantial haloperoxidase activity, even in an alkaline environment. Both the initial and oxidized Ce-MOFs demonstrate exceptional antibacterial properties, with a concentration of 50 mg/L effectively eliminating bacteria within 30 min. The oxidized Ce-MOFs benefit from improved haloperoxidase activity, resulting in a significantly enhanced ability to inhibit biofilm formation and, consequently, improved anti-biofilm performance. This research offers methods for regulating the haloperoxidase activity of Ce-MOFs for marine antifouling applications.
研究领域:
生物化学
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材料科学
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微生物学
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产品关联
DOI
高影响因子
TALANTA
·
2024
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IF 5.6
Lulu Cui,Houshen Li,Weijie Shi,Yingying Jing,Shuhong Sun,Shiyun Ai,Zeyi Guo
Reducing the size of active species is a powerful means to improve the utilization rate of active metals and enhance the properties of bimetallic nanozymes. In this work, Fe was introduced into Ce-MOF through the coordination of Fe 3+ and organic ligands, and the coordination effect resulted in atomically dispersed Fe in the derived Fe/CeO 2 nanozyme. Due to the atomically dispersed Fe embedded in the lattice of CeO 2 , a large number of defect sites were generated, endowing the nanozyme with excellent peroxidase (POD)-like activity. The constructed total antioxidant capacity (TAC) sensor based on the POD-like activity of Fe 1.01 /CeO 2 nanozyme displayed a very wide linear concentration range for AA, Cys, Glu and Trolox. More importantly, this TAC sensor can be applied to the TAC detection in vitamin C tablets and beverages. This work provides theoretical guidance for the synthesis of high-performance bimetallic nanozymes for TAC detection.
研究领域:
材料科学
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生物医学
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产品关联
DOI
PubMed
高影响因子
Catalysts
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2022
·Vol. 12
·期 7
·775
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IF 4.501
Yang Liu,Gongda Chen,Jianjun Chen,Hejingying Niu
Metal organic framework (MOF) is a type of porous organic material. In this work, three catalysts loaded with noble metal Pt were prepared by NaBH4reduction method with three different morphologies of Ce–MOF as carriers. Their physicochemical properties were characterized by XRD, Raman, FTIR, N2adsorption, SEM, XPS, and TGA. The catalytic performances of different catalysts were evaluated via toluene oxidation and CO2selectivity. Rod–shaped Pt/MOF–BTC exhibited best catalytic performance compared to Pt/MOF–808 and Pt/UiO–66, its T50and T90were 140 °C and 149 °C, respectively. After deducting the effect of specific surface, Pt/MOF–BTC still had the lowest apparent activation energy (62.8 kJ·mol−1), which is due to the abundant atomic Pt and oxygen vacancy content on its surface. After the reaction, the structure of Pt/MOF–BTC may become amorphous according to XRD results. Furthermore, the presence of amorphous structure had no effect on the catalytic activity of the catalyst. In the stability test of Pt/MOF–BTC to toluene oxidation, both toluene conversion and CO2selectivity remained at 100%, and remained stable for 11 h. Moreover, Pt/MOF–BTC also had better resistance to high weight hourly space velocity (WHSV) or water resistance. The catalyst maintained high catalytic activity for 3 times reusability. This study provides valuable experience for the future work of MOF in the field of VOC catalytic oxidation.Keywords:Ce–MOF;noble metal;oxygen vacancy;catalytic oxidation
研究领域:
催化
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材料科学
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环境化学
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产品关联
DOI
高影响因子
JOURNAL OF FOOD COMPOSITION AND ANALYSIS
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2024
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IF 4
Tianyu Wang,Wenyan Guo,Yonghui Xia,Yuefang Zhu,Li Chen,Yafeng Zhang,Guangli Li
The abuse and persistent use of Lomefloxacin (LOM) produces residues that deteriorate the ecological environment and endanger human health. Therefore, it is highly urgent to establish a simple and reliable method for the determination of LOM to guarantee food safety. Herein, a sensitive voltametric sensor based on bimetallic UiO-66(Zr/Ce) MOF/reduced graphene oxide (UiO-66 (Zr/Ce)/rGO) was fabricated for the determination of trace LOM residues in milk. The UiO-66(Zr/Ce)/rGO increased the electroactive surface area and lowered the charge transfer resistance. Due to the synergistic interactions between UiO-66(Zr/Ce) MOFs with good electrocatalytic activity and rGO nanosheets with high electrical conductivity, the UiO-66(Zr/Ce)/rGO/GCE exhibited the highest peak current response of LOM, 4.2-fold higher than the bare GCE. Consequently, the UiO-66(Zr/Ce)/rGO showed remarkably electrocatalytic activity for LOM oxidation with two broad linear detection ranges (0.03 – 2.0 μM and 2.0 – 30 μM), high sensitivities (5.1254 and 0.2198 μM μA −1 ), and a low detection limit (5.0 nM). The UiO-66(Zr/Ce)/rGO exhibited strong anti-interfering ability against potential interfering species even at high concentration, and maintained robust voltametric responses up to 25 days. Moreover, the UiO-66(Zr/Ce)/rGO/GCE achieved accurate determination of trace LOM residues in liquid milk with good recovery (96.11 − 103.2 %) and highly consistent sensitivity with that in PBS.
研究领域:
分析化学
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食品安全
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材料科学
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环境科学
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产品关联
DOI
高影响因子
FOOD CHEMISTRY
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2023
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IF 8.8
Haohong Lai,Pingtao Ming,Maoqiang Wu,Shumei Wang,Duanping Sun,Haiyun Zhai
In this research, a signal-off electrochemical aptasensor with high sensitivity was constructed for trace detection of zearalenone (ZEN). Specifically, Ce-based metal–organic framework and multi-walled carbon nanotubes nanocomposite was functionalized with polyethyleneimine ( [email protected] ) and served as sensing platform for its high surface area and excellent electrochemical active. Subsequently, toluidine blue (TB) was electrodeposited as the signal probe, and [email protected] nanoparticles ( [email protected] ) were dropped for the attachment of aptamer (ZEA). In the presence of ZEN, the ZEA would specifically recognize and combine with the target, causing a decrease of electrochemical signal from TB. Under the optimal conditions, the aptasensor exhibited good linear relationship for ZEN in a concentration range from 5.0 × 10 −5 to 50.0 ng/mL, while the limit of detection (LOD, S/N = 3) and limit of quantitation (LOQ, S/N = 10) were 1.0 × 10 −5 ng/mL and 2.9 × 10 −5 ng/mL, respectively. Ultimately, the aptasensor was successfully applied into ZEN detection in semen coicis real samples.
研究领域:
分析化学
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食品安全
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电化学
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产品关联
DOI
PubMed
高影响因子
JOURNAL OF SOLID STATE CHEMISTRY
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2022
·
IF 3.656
Yue Chen,Shaobin Li,Li Zhang,Tao Jing,Jianxin Wang,Lijie Zhao,Fengbo Li,Chao Li,Jingyu Sun
Rational design and constructed new electrode material as high performance electrochemical sensor with outstanding selectivity, reproducibility and stability is an urgent demand for trace detection. Herein, a novel Ce-MOF/Ti 3 C 2 T X MXene composite as electrochemical sensor for L-Tryptophan (L-Trp) was constructed by utilizing the three-dimensional straw-sheaf-like Ce-MOF and Ti 3 C 2 T X MXene nanosheets . The combination of Ce-MOF and Ti 3 C 2 T X MXene not only significantly improves the conductivity of metal-organic framework (MOF) but also effectively prevents the stacking of Ti 3 C 2 T X MXene nanosheets. The electrochemical properties of the proposed sensor were investigated by electrochemical techniques in detail. The L-Trp sensor exhibits a wide linear range (0.2 μM–139 μM) and a low limit of detection (0.19 μM, S/N = 3). Moreover, the proposed sensor exhibits excellent selectivity, good reproducibility and long-term stability, as well as satisfactory practical ability in real blood serum samples.
研究领域:
材料科学
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生物医学工程
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分析化学
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产品关联
DOI
高影响因子
CORROSION SCIENCE
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2024
·
IF 7.4
Yiqian Lv,Jingmao Zhao,Baomin Fan,Hassan Murtaza,Jingbao Wang,Weixiao Jing,Liuwei Chao
Synergistical passive barrier enhancement and active self-healing has been an emerging tactic for developing prominent anti-corrosion coatings. Herein, a cerium/2-methylimidazole metal-organic framework (Ce-MOF) was that is in-situ grown on ultrathin α-ZrP nanosheets with outstanding dispersibility. The parallel arrangement of α-ZrP-based nanosheets within the epoxy matrix was driven by shear force from blade-coating technology optimizing the coating's physical barrier and self-repairing capability. This advancement may herald a new era in designing smart coatings and offering potent protection against diverse corrosion types such as filiform corrosion.
研究领域:
材料科学
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腐蚀工程
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纳米技术
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涂层技术
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产品关联
DOI
高影响因子
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
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2024
·
IF 7.7
Changzhou Chen,Jie Jiang,Yajun Liu,Xialin Ji,Mengqing Zhou,Jun Zhao,Jianchun Jiang
The enhanced utilization of biomass-derived chemicals for the generation of high value aromatics through an advanced catalytic strategy has captured considerable attention within the realm of eco-friendly manufacturing. This work presented four innovative three-dimensional rod-shaped mesoporous Ce-based MOF materials, which were coupled with a H-donor solvent to facilitate vanillin hydrodeoxygenation and macromolecular lignin. Under the optimized conditions (30 mg CoCe@C catalyst, 2 MPa N 2 pressure, 15 mL isopropanol, 190 °C, and 5 h), the CoCe@C catalyst achieved nearly complete conversion of vanillin and demonstrated 87.8 % selectivity in the hydrogen-donor solvent. The characterization findings suggested that the synergy between metallic Co and oxygen vacancy sites enabled the effective activation of CHO group in vanillin, leading to formation of reactive product MMP . In addition, the optimal CoCe@C catalyst could also achieve macromolecular lignin hydrodeoxygenation to obtain high yield of lignin oil products with narrower molecular weight distribution . This study presented a viable approach for the concurrent utilization of lignin derivatives in the generation of high value fuels and chemicals.
研究领域:
化学工程
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生物质能利用
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催化科学
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产品关联
DOI
PubMed
高影响因子
SENSORS AND ACTUATORS B-CHEMICAL
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2025
·
IF 7.7
Linjing Duan,Huali Jin,Yang Wen,Min Wei,Rui Guo,Zhiguang Suo,Keshavan Niranjan
As a food and environmental contaminant having harmful qualities like neurotoxicity and carcinogenicity, acrylamide (AA) is a risk to human health. In this study, Ce-MOF@AuPd NFs were utilized as electrode modification materials to develop a signal-off electrochemical aptasensor in combination with Mg 2 + -dependent DNAzyme-driven 3D DNA walker and triplex molecular switch (THMS) for the sensitive detection of AA. Ce-MOF@AuPd NFs exhibit an expansive surface area and enhanced conductive properties, enabling the binding of substantial DNA sequences and speeding up electron transfer. The Mg 2+ -dependent DNAzyme-driven 3D DNA walker improves the nucleic acid shearing efficiency with excellent signal amplification performance, and combines with the DNA-specific structure THMS to further boost sensor sensitivity. The sensor also demonstrated excellent specificity, reproducibility, repeatability, and stability, along with achieving satisfactory recovery rates when tested on potato chips and coffee samples. The electrochemical aptasensor offers strong application prospects for AA detection in food, according to the results.
研究领域:
生物传感技术
·
食品安全检测
·
分子生物学
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产品关联
DOI
高影响因子
BIOSENSORS & BIOELECTRONICS
·
2019
·
IF 9.518
Xiaoxue Fu,Junlin He,Chengli Zhang,Jun Chen,Yilin Wen,Jia li,Weiran Mao,Hangtian Zhong,Jiahao Wu,Xingduo Ji,Chao Yu
In this work, an aptamer was used as the target capturing agent and a trimetallic signal amplification strategy based on [email protected] and AuPtRu NPs was demonstrated for the sensitive detection of TSP-1. Herein, the synthesized AuPtRu nanocomposite (AuPtRu NPs) not only acts as the catalyst for catalyzing hydrogen peroxide but also acts as a nanocarrier for capturing the -NH 2 termination single strand DNA (S1) to obtain the signal probe (SP, AuPtRu nanocomposite/S1). Then, SP was efficiently linked into TSP-1 aptamers with the addition of complementary linking strands to form M1 (SP/aptamer). The [email protected] nanocomposites were obtained by in situ reduction and used as GCE electrode modification materials. The -NH 2 -modified capture probe (CP) DNA was immobilized on the surface of [email protected] nanocomposites for hybridizing SP. In the presence of the target TSP-1, the aptamer recognizes the target and binds strongly so that SP is released from the prepared M1 and then hybridized with CP. When the detection solution contains an electrochemical matrix of H 2 O 2 , AuPtRu NPs can oxidize H 2 O 2 to obtain an enhanced signal. Furthermore, the proposed aptasensor has a very low LOD of 0.13 fg mL −1 TSP-1 in the detection range of 1 fg mL −1 to 10 ng mL −1 . Moreover, the proposed platform also has application implications for other potential targets.
研究领域:
分析化学
·
纳米技术
·
生物传感器
·
电化学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
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