JOURNAL OF ALLOYS AND COMPOUNDS
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2019
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IF 4.175
Man Zhou,Jingwen Chen,Yakang Zhang,Mengting Jiang,Song Xu,Qian Liang,Zhongyu Li
As a typical perovskite-type metal oxide , SrTiO 3 has emerged as prospective candidate for many fields. However, the synthesis of SrTiO 3 with controlled morphology, high surface area, and enhanced photocatalytic activity are still lacking. Herein, a series of porous SrTiO 3 with well-controlled morphologies including assembled nanoparticles (ANPs), golf-like particles (GLPs), star-like microspheres (SLMs), urchin-like microspheres (ULMs), and flower-like microspheres (FLMs) were successfully prepared via an ethylene glycol-water mixed solvothermal route. The ratio of V EG /V H2O play an important role in the shape-evolution during the solvothermal reaction. A comparative study of photocatalytic H 2 production and photodegradation was performed, and a possible photocatalysis mechanism of SrTiO 3 has been proposed. Significantly, the ULMs and FLMs photocatalysts of SrTiO 3 with optimized low Pt loading amount (0.075 wt %) exhibited outstanding H 2 production rates (8.21 and 7.29 mmol g −1 h −1 ) due to its unique structure of high-surface area and defect-rich surface. The facile and shape-controlled synthesis of varied SrTiO 3 structures is believed to be useful for the design and application of perovskite .
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NEW JOURNAL OF CHEMISTRY
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2016
·Vol. 40
·期 6
·5198-5208
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IF 3.277
Chunbo Liu,Guoling Wu,Jibin Chen,Kai Huang,Weidong Shi
In our study, a new visible light-driven photocatalyst SrTiO3/Fe2O3 was first prepared via a simple two-step process using a hydrothermal process and electrospinning technique. The photocatalysts, composed of Fe2O3 nanowires (about 200 nm in diameter), were modified with SrTiO3 nanocube (about 50 nm) photocatalysts based on photoinduced interfacial charge transfer (IFCT). The as-prepared SrTiO3/Fe2O3 photocatalysts exhibit enhanced photocatalytic activity in degrading tetracycline (TC) over their corresponding single component under visible light irradiation. The efficient photocatalytic performance of the composites could be ascribed to the enhancement in visible light absorption efficiency and the efficient electron transfer from the valence band of the SrTiO3 nanoparticles to the Fe2O3 nanowires. This study shows their potential application in purifying TC pollution in environmental wastewater because of their high efficiency and stability.
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ACS Applied Materials & Interfaces
·
2024
·
IF 8.3
Ke Jia,Yawei Wang,Lixia Jiang,Mi Lai,Wenlan Liu,Liping Wang,Huihui Liu,Xiaohua Cao,Yuze Li,Zongxiu Nie
Lung cancer ranks among the cancers with the highest global incidence rates and mortality. Swift and extensive screening is crucial for the early-stage diagnosis of lung cancer. Laser desorption/ionization mass spectrometry (LDI-MS) possesses clear advantages over traditional analytical methods for large-scale analysis due to its unique features, such as simple sample processing, rapid speed, and high-throughput performance. As n-type semiconductors, titanate-based perovskite materials can generate charge carriers under ultraviolet light irradiation, providing the capability for use as an LDI-MS substrate. In this study, we employ Rh-doped SrTiO3 (STO/Rh)-assisted LDI-MS combined with machine learning to establish a method for urine-based lung cancer screening. We directly analyzed urine metabolites from lung cancer patients (LCs), pneumonia patients (PNs), and healthy controls (HCs) without employing any pretreatment. Through the integration of machine learning, LCs are successfully distinguished from HCs and PNs, achieving impressive area under the curve (AUC) values of 0.940 for LCs vs HCs and 0.864 for LCs vs PNs. Furthermore, we identified 10 metabolites with significantly altered levels in LCs, leading to the discovery of related pathways through metabolic enrichment analysis. These results suggest the potential of this method for rapidly distinguishing LCs in clinical applications and promoting precision medicine.
研究领域:
癌症研究
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质谱分析
·
机器学习
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代谢组学
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PubMed
高影响因子
JOURNAL OF COLLOID AND INTERFACE SCIENCE
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2019
·
IF 6.361
Xiaochao Yu,Yan Lin,Haiyang Liu,Chunping Yang,Yanrong Peng,Cheng Du,Shaohua Wu,Xiang Li,Yuanyuan Zhong
In this work, Ag 3 PO 4 /PANI/Cr:SrTiO 3 photocatalysts were designed to effectively eliminate organic pollutants including Rhodamine B and phenol from high salinity wastewater under visible light . The phase composition , optical properties , and morphology of powders were studied, and the effects of inorganic salts on removal performance of the as-prepared particles were also tested. Results showed that the photocatalytic activities of Ag 3 PO 4 /PANI/Cr:SrTiO 3 composites for Rhodamine B and phenol reached 100% within 10 min and 18 min, respectively. The reaction rate of pure Ag 3 PO 4 was 7 times less than that of the ternary composite with the adding of PANI and Cr:SrTiO 3 . The activity of Ag 3 PO 4 /PANI/Cr:SrTiO 3 remained at 92.25% after five cycles, so the photocatalytic and recyclable performance of ternary composite was greatly improved. In addition, when there was SO 4 2− with a content of ranging from 1% to 21%, the degradation activity of the ternary catalyst under visible light was not changed for Rhodamine B, which indicated that the ternary catalyst exhibited the excellent sulfate resistance ability. Results from ESR and radical trapping experiments showed that O 2 − and h + made an important contribution to visible-light photocatalytic activities .
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高影响因子
INORGANIC CHEMISTRY
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2022
·
IF 5.436
Wenli Song,Bing Zhang,Wenli Zhou,Jilin Zhang,Liping Yu,Shixun Lian
All-inorganic perovskite quantum dots (PQDs, CsPbX3, X = Cl, Br, and I) show outstanding application prospects in the field of photoelectric devices. In recent years, the development of PQDs has greatly improved their stability to water, oxygen, and light. However, thermal quenching of PQDs greatly limits their practical application. Herein, we embed PQDs into ATiO3 (A = Ca, Ba, and Sr) of three different mesoporous spherical structures to explore the effect on thermal quenching of PQDs. Because of the unique mesoporous hollow microsphere structure and low thermal conductivity of SrTiO3, it can effectively block the heat transfer and improve the thermal quenching of PQDs. The photoluminescence (PL) intensity of CsPbBr3@SrTiO3 composites is 72.6% of the initial intensity after heating to 120 °C. Moreover, the PL intensity of CsPbBr3@SrTiO3 composites remains about 80% of the initial value even when stored in air for 20 days or irradiated by 365 nm UV light for 48 h. A neutral white light-emitting diode is assembled by a blue chip, CsPbBr3@SrTiO3 composites, and red phosphor of K2SiF6:Mn4+, which has a color temperature of 5389 K and a color gamut covered 133% of National Television Standards Committee (NTSC).
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高影响因子
JOURNAL OF COLLOID AND INTERFACE SCIENCE
·
2022
·
IF 9.965
Ge Yang,Jinyan Xiong,Mengjie Lu,Weiming Wang,Wei Li,Zhipan Wen,Shaozhong Li,Weijie Li,Rong Chen,Gang Cheng
Photocatalytic CO 2 reduction into valuable fuel and chemical production has been regarded as a prospective strategy for tackling with the issues of the increasing of greenhouse gases and shortage of sustainable energy. A composite photocatalysis system employing a semiconductor enriched with oxygen vacancy and coupled with metallic cocatalyst can facilitate charge separation and transfer electrons . In this work, mesoporous TiO 2 and titanium-based perovskite oxides (BaTiO 3 and SrTiO 3 ) nanoparticle assembly incorporated with abundant oxygen vacancy and copper particles have been successfully synthesized for CO 2 photoreduction . As an example, the TiO 2 decorated with different amounts of Cu particles has an impact on photocatalytic CO 2 reduction into CH 4 and CO. Particularly, the optimal TiO 2 /Cu-0.1 exhibits nearly 13.5 times higher CH 4 yield (22.27 μmol g −1 h −1 ) than that of pristine TiO 2 (1.65 μmol g −1 h −1 ). The as-obtained BaTiO 3 /Cu-0.1 and SrTiO 3 /Cu-0.1 also show enhanced CH 4 yields towards photocatalytic CO 2 reduction compared with pristine ones. Based on the temperature programmed desorption (TPD) and photo/electrochemical measurements, the co-embedding of Cu particles and abundant oxygen vacancy into the titanium-based oxides could promote CO 2 adsorption capacity as well as separation and transfer of photoinduced electron-hole pairs, and finally result in efficient CO 2 photoreduction upon the TiO 2 /Cu, SrTiO 3 /Cu, and BaTiO 3 /Cu composites.
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高影响因子
Journal of Physical Chemistry C
·
2025
·
IF 3.2
Yushuai Jia,Liping Xu,Jiale Chen,Yueyuan Zeng,Zhihong Duan,Taifeng Liu,Xin Liu
Defect engineering can effectively promote light absorption and carrier dynamics of semiconductor photocatalysts. However, it is still difficult to modulate the distribution and concentration of defects in the photocatalyst via a facile strategy. The perovskite SrTiO3 is a promising semiconductor photocatalyst for hydrogen production, but its performance is restricted by limited UV absorption and severe carrier recombination. Herein, we develop a visible light-responsive SrTiO3 photocatalyst with Ti3+ and oxygen vacancies distributed both in the bulk and on the surface through a solvothermal synthesis coupled with light illumination. In situ EPR and XPS disclose that bulk defects are produced during the solvothermal synthesis, while the surface defects can be generated by light irradiation. The concentration of Ti3+ and oxygen vacancies can be facilely adjusted by varying the solvothermal time, resulting in the regulation of visible absorption in the range of 450–650 nm. Density functional calculations demonstrate the formation of an in-gap band consisting of defect energy levels, which induces a two-step electron transition and accounts for the visible light response. As revealed by synchrotron radiation X-ray absorption spectroscopy, ultrafast transient absorption spectroscopy, and electrochemical analysis, the increase of defect concentration leads to the decrease of Ti–O coordination number as well as the increase of carrier lifetime and carrier density, which ensures promoted carrier dynamics and boosted hydrogen evolution activity driven by visible light. The present research uncovers the role of defects in tuning light absorption and carrier dynamics and opens new opportunities for achieving highly efficient solar energy conversion.
研究领域:
材料科学
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能源化学
·
物理化学
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高影响因子
CHINESE JOURNAL OF CATALYSIS
·
2023
·
IF 16.5
Zhidong Wei,Jiawei Yan,Weiqi Guo,Wenfeng Shangguan
The light penetration effect will weaken the driving force of charge separation from phase to surface by the built-in electric field of nanoscale photocatalysts, like low-dimensional materials. Therefore, in this study, a novel nanoscale lamination catalyst design method was proposed using a polymeric carbon nitride (PCN)-nano polyhedral SrTiO 3 core-shell structure catalyst (PCN-SrTiO 3 ). The results showed that the nanoscale lamination effect could be generated by the formation of the N–Sr bond, which could regulate the built-in electric field of the PCN simultaneously. Moreover, detailed characterization indicated that the N–Sr bond, which facilitates the generation of N vacancies in PCN, could act as a novel channel for charge transfer. Both surface and interior core N-deficient PCN have been discovered, resulting in more positive and negative VB positions, respectively. Synchronously, the light absorption ability of the PCN-SrTiO 3 samples increased. Consequently, the enhanced photocatalytic overall water splitting could be ascribed to the synergism of the built-in electric field regulation caused by the N-Sr formation-induced nanoscale lamination effect, which was favorable for energy flow adaption on the spatiotemporal scale.
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高影响因子
CHEMICAL ENGINEERING JOURNAL
·
2022
·
IF 16.744
Yixuan Zhang,Cong Liu,Ye Zhou,Jinnan Wang,Aimin Li,Philippe François-Xavier Corvini
Hollow double-shelled Ag@SrTiO 3 -TiO 2 with Z-scheme heterostructure was constructed for highly efficient photocatalytic reduction of nitrate to N 2 . The 3D finite-difference-time-domain analysis indicated that hollow double-shelled structure improved light harvesting due to multiple reflections. Photo-generated electrons transfer from SrTiO 3 to Ag 0 caused by electron sink effect were utilized to reduce nitrate, while photo-generated electrons of TiO 2 migrated to SrTiO 3 via transport bridge of Ti 3+ defects for electron–hole recombination. Such charge carriers migration pathway facilitated the construction of Z-scheme heterostructure, which enhanced charge separation yet still retained high redox powers. Both photogenerated electrons and CO 2 − played important role in photocatalytic denitrification. Furthermore, Ag 0 acted as co-catalyst which not only promoted photogenerated electrons transfer to nitrate but also enhanced nitrate conversion selectivity to N 2 . Combining the above advantages, nitrate removal rate and the nitrogen selectivity reached 97.2 % and 98.8 % within 60 min, respectively. Even after five cycles, it still remained satisfied photocatalytic activity and stability. In summary, this work proposed a feasible strategy to construct Z-scheme hollow double-shelled photocatalyst for efficient photocatalytic denitrification.
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高影响因子
MATERIALS RESEARCH BULLETIN
·
2024
·
IF 5.3
Gang Chen,Xue Bai,Cong Ji,Zhijun Zhou,Zixuan Zhang,Chao Chen,Zhengtang Su,Wei Cai,Rongli Gao,Chunlin Fu
Bi 0.5 Na 0.5 TiO 3 ceramic is a promising dielectric energy storage material due to its high spontaneous polarization (> 40 μC/cm 2 ) . Although many studies have been carried out to enhance the energy storage performance of Bi 0.5 Na 0.5 TiO 3 ceramic, achieving better energy storage performance is still a considerable challenge. Herein, Bi 0.5 Na 0.5 TiO 3 -BiYbO 3 -SrTiO 3 (BNT-BY-STO) relaxor ferroelectric ceramics were constructed, and <111>-oriented (1- x )(0.99BNT-0.01BY)- x STO ceramics were successfully fabricated by a templated grain growth method. The moderate energy storage performance (the reversible energy storage density of 3.26 J/cm 3 and energy storage efficiency of 76.3% under 290 kV/cm) can be achieved in <111>-oriented 0.8(0.99BNT-0.01BY)-0.2STO ceramics. The enhanced energy storage performance of textured BNT-BY-STO ceramics could be mainly attributed to the grain refinement of STO, and the improved breakdown strength and relaxation behavior caused by orientation engineering. These findings demonstrate that the co-doping of BY and STO and orientation engineering are effective strategies for improving the energy storage performance of BNT ceramic.
研究领域:
材料科学
·
电陶瓷
·
储能材料
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高影响因子
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