JOURNAL OF MATERIALS SCIENCE
·
2021
·Vol. 56
·期 13
·8079-8090
·
IF 4.22
Liu Jiali,Yang Qiang,Liu Jikai,Luo He’an
Tungsten trioxide (WO 3 ) has been conceived as a promising photoanode material for photoelectrochemical (PEC) water oxidation. Therefore, many efforts have been made to improve its PEC performances. Herein, a novel heterojunction is fabricated through combining rocksalt CoO (R-CoO) or blende CoO (B-CoO) nanosheets with WO 3 nanoplates using a spin-coating method. The typical type II heterojunctions, e.g., WO 3 /R-CoO and WO 3 /B-CoO, both have exhibited higher photocurrent densities than pristine WO 3 photoanode. The photocurrent densities of WO 3 /R-CoO, WO 3 /B-CoO and WO 3 are 0.53 mA cm −2 , 0.45 mA cm −2 and 0.31 mA cm −2 at 1.23 V vs. reversible hydrogen electrode, respectively. For the WO 3 /R-CoO photoanode, the surface charge separation efficiency is 50.95% and the photoconversion efficiency is 0.062%, which are both higher than the WO 3 and WO 3 /B-CoO photoanodes. The enhanced PEC performances are due to the type II heterojunction between WO 3 and R-CoO (or B-CoO), which facilitates the absorption of visible light and charge transport. The better performance of WO 3 /R-CoO than that of WO 3 /B-CoO may be due to the deeper valence band position of R-CoO. Our work demonstrates that R-CoO (or B-CoO) can couple with WO 3 to form a type II heterojunction to improve the PEC water oxidation performance.
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ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
·
2021
·Vol. 28
·期 13
·16470-16479
·
IF 4.223
Wang Lifang,Chen Jingfan,Li Xian,Chen Letian,Zhang Kaige,Wang Xuefeng,Zhu Guifen
A novel eco-friendly molecularly imprinted polymer (MIP) was proposed as solid-phase extraction (SPE) adsorbent to selective adsorption tylosin (TYL) in animal muscle samples. The MIP was synthesized in aqueous by using 1,4-butanediyl-3,3-bis-1-vinyl imidazolium chloride and 2-acrylamide-2-methylpropanesulfonic acid as bifunctional monomer. The obtained MIP had excellent selectivity towards TYL in water, and the maximum binding capacity can reach 123.45 mg g −1 . Combined with high-performance liquid chromatography, the presented MIP can be used as SPE sorbent to recognize and detect TYL in the range of 0.008 to 0.6 mg L −1 ( R 2 = 0.9995). The limit of detection and limit of quantification were 0.003 mg L −1 and 0.008 mg L −1 , and the intraday and interday precision were 1.05% and 3.36%, respectively. Under the optimal condition, the established MIP-SPE-HPLC method was successfully applied to separate and determine trace TYL in chicken, pork, and beef samples with satisfactory recoveries ranged from 94.0 to 106.3%, and the MIP-SPE cartridge can be cycled at least 20 times. This study implies a promising green MIP-SPE-HPLC method for highly selective adsorption and analysis trace TYL in complex matrices.
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Nano-Micro Letters
·
2020
·Vol. 13
·期 1
·1-15
·
IF 12.264
Liu Pengfei,Li Xiaofeng,Min Peng,Chang Xiyuan,Shu Chao,Ding Yun,Yu Zhong-Zhen
AbstractSection
Highlights
Lamellar-structured graphene aerogels with vertically aligned and closely stacked high-quality graphene lamellae are fabricated.
The superior thermally conductive capacity of the aerogel endows epoxy with a high through-plane thermal conductivity of 20.0 W m −1 K −1 at 2.30 vol% of graphene content.
The nacre-like structure endows the epoxy composite with enhanced fracture toughness.
AbstractSection
Abstract
Although thermally conductive graphene sheets are efficient in enhancing in-plane thermal conductivities of polymers, the resulting nanocomposites usually exhibit low through-plane thermal conductivities, limiting their application as thermal interface materials. Herein, lamellar-structured polyamic acid salt/graphene oxide (PAAS/GO) hybrid aerogels are constructed by bidirectional freezing of PAAS/GO suspension followed by lyophilization. Subsequently, PAAS monomers are polymerized to polyimide (PI), while GO is converted to thermally reduced graphene oxide (RGO) during thermal annealing at 300 °C. Final graphitization at 2800 °C converts PI to graphitized carbon with the inductive effect of RGO, and simultaneously, RGO is thermally reduced and healed to high-quality graphene. Consequently, lamellar-structured graphene aerogels with superior through-plane thermal conduction capacity are fabricated for the first time, and its superior through-plane thermal conduction capacity results from its vertically aligned and closely stacked high-quality graphene lamellae. After vacuum-assisted impregnation with epoxy, the resultant epoxy composite with 2.30 vol% of graphene exhibits an outstanding through-plane thermal conductivity of as high as 20.0 W m −1 K −1 , 100 times of that of epoxy, with a record-high specific thermal conductivity enhancement of 4310%. Furthermore, the lamellar-structured graphene aerogel endows epoxy with a high fracture toughness, ~ 1.71 times of that of epoxy.
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ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
·
2020
·Vol. 28
·期 7
·8486-8497
·
IF 3.056
Wei Xiuzhen,Zhang Qian,Cao Shiyu,Xu Xufeng,Chen Yi,Liu Lu,Yang Ruiyuan,Chen Jinyuan,Lv Bosheng
Nanofiltration (NF) membranes show great potential for advanced water treatment, especially for trace organic pollutant removal. The removal efficiency of pharmaceuticals and personal care products (PPCPs) and environmental estrogenic hormones (EEHs) by positively charged hollow fiber NF membranes (PEI-NF) were evaluated. The separation properties were evaluated by changing the operating pressure, temperature, ionic strength, and cation species. A relationship between the physicochemical characteristics of the pharmaceuticals and the NF membrane retention behavior was established. The results showed that the rejection rates of the PEI-NF membrane for the selected PPCPs and EEHs ranged from 81 to ~ 91.26%. For positively (negatively) charged pharmaceutical molecules, the electrostatic repulsion (attraction) effect and steric hindrance were the dominant rejection mechanisms of the PEI-NF membrane. For neutral pharmaceutical molecules, in addition to the size sieving effect, the hydration-induced size increase of hydrophilic substances improved the rejection rates. Both the molecular structure and diffusion coefficient of pharmaceutical molecules influenced their rejection by the PEI-NF membrane to a certain extent. Moreover, the PEI-NF membrane showed a high removal effect for PPCPs and EEHs in water samples from actual tap water plants.
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APPLIED BIOCHEMISTRY AND BIOTECHNOLOGY
·
2021
·Vol. 193
·期 4
·1116-1128
·
IF 2.926
Wang Qian,Wu Xiaomei,Lu Xinyi,He Yucai,Ma Baodi,Xu Yi
Currently, the biotechnological preparation of fragrances using natural materials attracted growing attention. Enzymatic synthesis of vanillin from isoeugenol by recombinant isoeugenol monooxygenase from Pseudomonas nitroreducens Jin1 was systematically investigated herein. With series of work on the construction of recombinant E. coli over-expressing isoeugenol monooxygenase, optimization of the culture conditions for enzyme production and reaction process for converting isoeugenol into vanillin, an increase of 22-fold in the enzyme activity (2050 U/L) was obtained, and the conversion was significantly increased at high substrate concentration with the aid of magnetic chitosan membrane for product isolation in situ. Under optimal conditions, the product concentration and space-time yield reached 252 mM and 115 g/L/d, respectively, and vanillin was obtained in 82.3% yield and > 99% purity in the gram preparative scale. The developed bioprocess showed application potential for efficient preparation of vanillin from inexpensive natural resources.
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JOURNAL OF FLUORESCENCE
·
2021
·Vol. 31
·期 2
·339-348
·
IF 2.217
Lv Rongyao,Li Genrong,Lu Shuting,Wang Ting
Carbon dots are nano-sized photoluminescence materials which have good biocompatibility and low cytotoxicity, while the previously synthesized carbon dots lack tumor targeting capability and therapy function so that it cannot achieve the purpose of diagnosis and treatment. Herein, a new kind of multi-functional carbon dots (GFCDs) is promising to be applied in tumor cells imaging and clinical targeted therapy. Gallic acid (GA) was used as the carbon resource and antitumor active molecule, folic acid (FA) was used as the nitrogen resource and tumor targeting molecule, and citric acid monohydrate (CA) was used as the auxiliary carbon source. Multi-functional GACDs were synthesized by a simple one-step microwave-assisted procedure and analyzed with UV − vis spectrophotometer, fourier transform infrared spectrometer, transmission electron microscopy and X-ray photoelectron spectrometer. Results show that the diameter of GFCDs is about 3 nm. And GFCDs are pale-yellow under natural light which turn blue under 360 nm UV lamp. Besides ester bond is the connecting mode between functional molecules. In addition, the results of in vitro cell imaging experiments and in vivo antitumor experiments demonstrate the targeting imaging and antitumor abilities towards Hela cells. Graphical abstract
The synthesis route and properties of GFCDs.
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FIBERS AND POLYMERS
·
2020
·Vol. 21
·期 11
·2625-2634
·
IF 1.797
Chen Yuan,Wu Xiaoqing,Wei Junfu,Wu Hailiang
In order to nondestructively prepare polyamine modified polyethylene glycol terephthalate (PET) fabric, codeposition of catechol and polyethyleneimine onto PET fiber was conducted by the means of mussel-inspired method. The surface morphology, composition of woven fabric were investigated by FESEM and ATR-FTIR, XPS, respectively, whose results demonstrated successful modification has taken place on PET fiber surface. The TG-DSC data proved that the melting temperature and decomposition temperature increased from 253.78 °C and 394.08 °C to 255.01 C and 398.21 °C, respectively. The surface polarity was characterized through the dynamic contact angle. The results indicated that the fabric displayed optimal surface properties at the PEI-CA mass ratio of 1:1. The modified PET fabric was utilized to prepare the fiber reinforced epoxy composite and its mechanical performances including tensile, flexural and short beam shear strength were evaluated. The obtained results indicated that the interlaminar shear strength (ILSS) has been significantly improved by 57.02 %. The novel way to modify fabrics has great potential in recycling waste fabric for preparing fiber reinforced composite.
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JOURNAL OF NANOPARTICLE RESEARCH
·
2020
·Vol. 22
·期 12
·1-10
·
IF 2.132
Zhang Sainan,Feng Min,Liu Ying,Wang Daoai
Ta 2 O 5 -TiO 2 heterojunction photocatalysts with a structure of TiO 2 nanodots deposited on Ta 2 O 5 nanotube (NTs) were prepared by anodization and in situ growth methods following annealing treatment. The heterojunction photocatalytic material exhibited enhanced photodegradation behavior of methylene blue (MB) and photoelectrochemical water splitting performance under simulated solar light. The degradation rate of MB and photocurrent density of heterojunction is 3.99 and 8.33 times higher than that of pure Ta 2 O 5 NTs respectively. The synergetic effect of the phase heterojunction and highly ordered structure increased the specific surface area and improved the separation and transmission efficiency of photogenerated electrons and holes, thereby enhancing the photocatalytic activities. Hence, Ta 2 O 5 TNs-TiO 2 nanodots heterojunction has promising application in the fields of photodegradation, photoelectrochemical water splitting, solar cells, and other photocatalytic devices. Graphical abstract
The heterojunction photocatalytic material exhibits enhanced photodegradation behavior of methylene blue (MB) and photoelectrochemical water splitting performance under simulated solar light. The degradation rate of MB is 3.17and 3.99 times higher than that of pure TiO 2 NTs and Ta 2 O 5 NTs, respectively; the photocurrent density increases by 8.33 times and 1.6 times compared with pure Ta 2 O 5 NTs and TiO 2 , respectively.
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CATALYSIS LETTERS
·
2021
·Vol. 151
·期 9
·2638-2646
·
IF 3.186
Li Xiao,Qin Tingting,Li Liusha,Wu Bo,Lin Tiejun,Zhong Liangshu
Abstract A green route for one−pot synthesis of acetals by tandem hydroformylation−acetalization of olefins using supported Rh−based catalysts was developed. Experimental results demonstrated that suitable Rh loading (1 wt%) with appropriate reaction temperature (120 °C) and reaction time (8 h) were favorable for the formation of acetals, and a high acetals selectivity of 94.6% was achieved. More importantly, the selectivity to valuable linear products was enhanced in this tandem catalysis. Based on the catalytic mechanism study, highly dispersed RhO x nanoparticles and abundant acid sites on the supports were responsible for the hydroformylation and acetalization, respectively. Graphical abstract One-pot synthesis of acetals directly from olefins with high selectivity was achieved over heterogeneous bifunctional catalysts via tandem hydroformylation-acetalization.
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JOURNAL OF THERMAL SPRAY TECHNOLOGY
·
2021
·Vol. 30
·期 4
·873-885
·
IF 2.757
Ye Fuxing,Yang Wenqi,Yan Shuai,Yu Jianxing
CMAS corrosion is one of the significant failure mechanisms for thermal barrier coatings (TBCs). In this work, the corrosion behaviors and wettability of CMAS on M-YTaO 4 at 1350 °C are studied to evaluate the M-YTaO4 ceramics’ potential to replace YSZ. The results show that the contact angles of CMAS on M-YTaO 4 with different time (1 min, 0.5 h, 4 h, 10 h and 24 h) are around 14.3° (14.4°14.4°, 14.4°, 14.3° and 14.2°, respectively), and larger than that on YSZ (8.0°, 1 min), which means the wettability of CMAS on M-YTaO 4 is worse than that on YSZ and which is benefit to improve its corrosion resistance. The thickness of reaction layer is increasing with elapsed time, but the increasing rate is decreased, and the maximum reaction thickness is 31.42 μm at 24 h. There are four main phases after reaction, which are M-YTaO 4 , M’-YTaO 4 , Ca 2 Ta 2 O 7 and Y 2 Si 2 O 7 . For the effects of lattice distortion and thermodynamics reason, M’-YTaO 4 can retain steadily at room temperature. Besides, the chemical reaction process between CMAS and yttrium tantalite is also be discussed.
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JOURNAL OF NANOPARTICLE RESEARCH
·
2020
·Vol. 22
·期 11
·1-9
·
IF 2.132
Gao Wenshan,Zhang Yuangong,Zheng Ying,Zhang Hailei,Wang Xiaoke,Bai Libin,Wu Yonggang,Ba Xinwu
The 19 F nuclear magnetic resonance (NMR) has been widely employed as a detection tool in biological studies due to its low biological background, noninvasiveness, high sensitivity, and real-time monitoring capability. Herein, we report a one-pot synthesis of halloysite nanotubes (HNTs) treated with benzeneboronic acids (6FBB) to afford the HNT-based 19 F NMR probe which is capable to detect the H 2 O 2 in low concentration. The product was well characterized by nuclear magnetic resonance (NMR), Fourier transform infrared spectroscopy (FTIR), transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD). The intensity of signals of 19 F was enhanced with the increasing concentration of fluorine, and the signals apparently shifted from − 62.68 to − 62.85 ppm upon the addition of H 2 O 2 . The obtained 19 F NMR probes also displayed a long spin-spin (T2) relaxation time (91.27 ms), which can strengthen image intensity. Moreover, the 19 F NMR probe exhibited non-toxic against HeLa cell. The 19 F NMR probe may serve as a desirable candidate to predict the change of H 2 O 2 in vivo.
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Nanoscale Research Letters
·
2020
·Vol. 15
·期 1
·1-12
·
IF 3.578
Qin Xiaoyun,Shi Dongdong,Guo Bowen,Fu Cuicui,Zhang Jin,Xie Qingqing,Shi Xiangdong,Chen Fenghua,Qin Xiaomei,Yu Wei,Feng Xiangli,Liu Yan,Luo Dan
One-dimensional (1D) nanomaterials with specific architectures have received increasing attention for both scientific and technological interests for their applications in catalysis, sensing, and energy conversion, etc. However, the development of an operable and simple method for the fabrication of 1D nanostructures remains a challenge. In this work, we developed an “anion-regulated morphology” strategy, in which anions could regulate the dimensionally-restricted anisotropic growth of ZnO nanomaterials by adjusting the surface energy of different growth facets. ZnO 1D necklace-like nanostructures (NNS) could be prepared through a hydrothermal treatment of zinc acetate and urea mixture together with a subsequent calcination procedure at 400 °C. While replacing the acetate ions to nitrate, sulfate, and chlorion ions produced ZnO nanoflowers, nanosheets and hexagonal nanoplates, respectively. Density functional theory calculations were carried out to explain the mechanism behind the anions-regulating anisotropic crystal growth. The specified ZnO 1D NNS offered improved electron transport while the grain surface could supply enlarged specific surface area, thus providing advanced photocatalytic ability in the following photodegradation of methyl orange (MO). Among the four photocatalysts with different morphologies, ZnO 1D NNS, possessing the highest catalytic activity, degraded 57.29% MO in the photocatalytic reaction, which was 2 times, 10 times and 17 times higher than nanoflowers, nanosheets and hexagonal nanoplates, respectively. Our work provides new ideas for the construction and application of ZnO 1D nanomaterials.
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