JOURNAL OF SOLID STATE CHEMISTRY
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2024
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IF 3.2
Ziqiang Zhang,Zhengfeng Shen,Chuanyu Zhu,Yunfang Wang,Yawen Wang,Caimei Fan,Rui Li,Jianxin Liu
Producing hydrogen from organic/inorganic hydrides is an innovative clean energy alternative to fossil fuels , addressing the increasing energy demands. Here, we first propose coupled photocatalytic water hydrogen production and N,N-dimethylformamide (DMF, C 3 H 7 NO) dehydrogenation technology to obtain high value-added H 2 and N,N-dimethylcarbamic acid (C 3 H 7 NO 2 ). ZnIn 2 S 4 @MIL-125(Ti) nanoheterostructures were synthesized using a simple solvothermal method and resulting in a photocatalytic H 2 production rate of 2.135 mmol h −1 g −1 (apparent quantum efficiency at 380 nm was 2.6 %) which is 2.77 times higher than pure ZnIn 2 S 4 . Liquid-phase mass spectrometry indicates that the DMF oxidation activity of ZIS@MIL heterojunction is double pure ZnIn 2 S 4 and only microcrystalline CO 2 is produced. Isotopes indicate that the production pathway of H 2 results from the coupling of the –CHO bond in DMF and the –H in water. The improved photocatalytic activity of the ZnIn 2 S 4 @MIL-125(Ti) heterostructure is attributed to facilitating efficient charge carrier transfer and separation and DMF depletion of holes accelerates electron transfer .
研究领域:
材料科学
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能源科学
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化学工程
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产品关联
DOI
高影响因子
MATERIALS CHARACTERIZATION
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2016
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IF 2.383
Zhaobing Cai,Guo Jin,Xiufang Cui,Zhe Liu,Wei Zheng,Yang Li,Liquan Wang
Ni-Cr-Co-Ti-V-Al high-entropy alloy coating on Ti-6Al-4V was synthesized by laser surface alloying. The coating is composed of a B2 matrix and (Co, Ni)Ti 2 compounds with few β-Ti phases. Focused ion beam technique was utilized to prepare TEM sample and TEM observations agree well with XRD and SEM results. The formation of HEA phases is due to high temperature and rapid cooling rate during laser surface alloying. The thermodynamic parameters, ΔH mix , ΔS mix and δ as well as Δχ, should be used to predict the formation of the BCC solid solution, but they are not the strict criteria. Especially when Δχ reaches a high value (≥ 10%), BCC HEA will be partially decomposed, leading to the formation of (Co, Ni)Ti 2 compound phases.
研究领域:
材料科学
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表面工程
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产品关联
DOI
高影响因子
RSC Advances
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2017
·Vol. 7
·期 68
·42819-42825
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IF 3.108
Yanghe Fu,Huan Yang,Rongfei Du,Gaomei Tu,Chunhui Xu,Fumin Zhang,Maohong Fan,Weidong Zhu
Co-doped NH2-MIL-125(Ti) catalysts [Co/NH2-MIL-125(Ti)] are developed for the photocatalytic reduction of CO2 upon visible-light irradiation. Compared with NH2-MIL-125(Ti), Co/NH2-MIL-125(Ti) exhibits a significantly enhanced activity in CO2 reduction, due to the fact that the doping of Co nanoparticles onto NH2-MIL-125(Ti) can promote the visible-light harvesting and electron transfer. In addition, when benzylic alcohols as electron donors, instead of triethanolamine (TEOA) which is often used as a sacrificial agent, are added into the reaction system, Co/NH2-MIL-125(Ti) can simultaneously catalyze CO2 reduction to formic acid (HCOOH) and the selective oxidation of the benzylic alcohols to the corresponding aldehydes, making the proposed process more economical and environment-friendly.
研究领域:
材料科学
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环境科学
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化学工程
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产品关联
DOI
高影响因子
APPLIED SURFACE SCIENCE
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2017
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IF 3.387
Yanping Zhu,Runliang Zhu,Gangqiang Zhu,Miaomiao Wang,Yannan Chen,Jianxi Zhu,Yunfei Xi,Hongping He
Nowadays, two-dimensional (2D) nanosheets, such as layered double hydroxides (LDH), have received considerable attention for their potential to meeting clean energy demand and solving environmental problems. In this work, novel and efficient photocatalysts of plasmonic Ag nanoparticles coated Zn/Ti-LDH nanosheets have been synthesized through low-temperature reduction method. The structural characteristics of the as-prepared products were investigated by a series of characteristic methods The scanning electron microscopy (SEM) and transmission electron microscope (TEM) images showed that Ag nanoparticles were distributed on the surface of Zn/Ti-LDH uniformly. The UV–vis diffuse reflectance spectra (DRS) showed that the absorbance of Ag/LDH in visible-light region enhanced markedly and presented a broad band at 500–600 nm, which was resulted from the surface plasmon resonance (SPR) effect of Ag nanoparticles. The photocatalytic activities of Ag/LDH were evaluated by degradation of Rhodamine-B (RhB) and NO. The photocatalytic experiments showed that Ag/LDH had higher photocatalytic activity than that of pure LDH , and 2%Ag/LDH exhibited the highest photocatalytic activity. In addition, the 2%Ag/LDH exhibited high photochemical stability after multiple reaction runs. The obtained results from photoluminescence (PL) spectroscopic measurement and transient photocurrent ( I – V ) analysis both revealed the existence of Schottky barriers between LDH and Ag nanoparticles. The electron spin resonance (ESR) showed that OH were the dominant active species in the photo-degradation process. The enhanced photocatalytic performance of the composite should be ascribed to both the SPR effect of Ag nanoparticles in visible light and the Schottky barriers between LDH and Ag nanoparticles.
研究领域:
材料科学
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环境科学
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产品关联
DOI
高影响因子
Materials
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2025
·Vol. 18
·期 6
·1343
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IF 3.2
Hangmin Xu,Hao Song,Xiaozhi Wang,Xingwang Zhu
The substantial release of industrial carbon dioxide has been identified as a key factor in the development of various environmental issues. In addressing these concerns, the utilization of photocatalytic technology for carbon reduction has garnered significant attention. The disadvantage of CO2photoreduction is the problem of product yield and selectivity. It is known that MIL-125(Ti) with a high specific surface area (SBET) possesses more active sites using Ti as a node. The calcination of MIL-125(Ti) in a reducing atmosphere has been shown to introduce oxygen vacancies (OV), thereby enhancing the material’s surface and internal pores. This process has been demonstrated to result in a significant increase in the SBETand an enhancement of the Ti3+/Ti4+ratio. The increased Ti3+centers have been found to improve the material’s reducing properties. The results demonstrate that the OV-rich MIL-125-2H material exhibits the high-performance and highly selective photoreduction in CO2.
研究领域:
环境科学
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材料科学
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化学工程
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产品关联
DOI
PubMed
高影响因子
Frontiers in Energy Research
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2021
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IF 4.008
Li Jiayi,Zhou Wei,Huang Yuming,Gao Jihui
Replacing the oxygen evolution reaction (OER), which is of high energy consumption and slow kinetics, with the more thermodynamically favorable reaction at the anode can reduce the electricity consumption for hydrogen production. Here we developed a lignin-assisted water electrolysis (LAWE) process by using Ti/PbO2 with high OER overpotential as the anode aimed at decreasing the energy consumption for hydrogen production. The influence of key operating parameters such as temperature and lignin concentration on hydrogen production was analyzed. Compared with alkaline water electrolysis (AWE), the anode potential can be decreased from 0.773 to 0.303 (V vs. Hg/HgO) at 10 mA/cm2 in LAWE, and the corresponding cell voltage can be reduced by 546 mV. With increasing the temperature and lignin concentration, current density and H2 production rate were efficiently promoted. Furthermore, the anode deactivation was investigated by analyzing the linear sweep voltammetry (LSV) and cyclic voltammetry (CV) tests. Results showed that the anode deactivation was affected by the temperature.
研究领域:
能源化学
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环境科学
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产品关联
DOI
高影响因子
CHEMOSPHERE
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2022
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IF 8.943
Cheng Cheng,Dongyun Chen,Najun Li,Hua Li,Qingfeng Xu,Jinhui He,Jianmei Lu
This paper reports the application of NH 2 -MIL-125(Ti) modified carbon nitride C v -C 3 N 4 with carbon vacancies in the removal of NO. We performed a series of characterizations of the complex and compared various ratios with the individual components. The results of UV spectrum analysis show that the composite's range of light absorption expanded due to the modification of Ti metal–organic framework. Furthermore, the results of photocurrent and electrical impedance indicate the compound has a better ability to generate and transfer electrons . The increase in the compound's NO removal efficiency (up to 63%) indicates that MOF has a positive effect on C v -C 3 N 4 modification—a good method for photocatalysis . Moreover, the compound can promote photocatalysis in a favorable direction.
研究领域:
材料科学
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环境科学
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DOI
高影响因子
APPLIED CATALYSIS B-ENVIRONMENTAL
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2023
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IF 22.1
Haiying Xu,Zhaoliang Wang,Hehua Liao,Dongmiao Li,Jinni Shen,Jinlin Long,Wenxin Dai,Xuxu Wang,Zizhong Zhang
Photocatalytic converting CO 2 into C 2 products is highly desirable but is extremely sensitive to catalyst structure. In this work, Ti-H species and oxygen vacancies are simultaneously integrated on hydrogenated SrTiO 3 surface by thermally treating with NaBH 4 , which promotes the activation of CO 2 into HCOO - and CO* intermediates. The proximity of oxygen vacancies and Ti-H species contributes to the C-C coupling of intermediates into acetylene (C 2 H 2 ) products. To the best of our knowledge, this is the first example for the photocatalytic CO 2 reduction into C 2 H 2 main products. The optimal hydrogenated SrTiO 3 has the C 2 H 2 yield of 39.0 μmol·g −1 with a 76.0 % selectivity among C 2 products. Therefore, this work provides an approach of designing the adjacent active sites for photocatalytic CO 2 conversion into C 2+ products.
研究领域:
材料科学
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环境科学
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产品关联
DOI
高影响因子
CHEMICAL PHYSICS LETTERS
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2025
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IF 3.1
Ziqi Zhong,Borui Du,Guowu Zhan,Jingran Xiao
Herein, the 3D printing technology is harnessed as a new and flexible strategy to fabricate a structural-parameter adjustable 3D-structured Ti-Fe 2 O 3 photoanode. The Ti alloy was discovered to be practicable during the synthesis of Ti-Fe 2 O 3 and enlisted as a substrate material for crafting a conical-array patterned Ti-Fe 2 O 3 photoanode. The conical array fashions an angle between the incident light (longitudinal side) and the photogenerated charge transport (transverse side), along with a considerably augmented light-receiving area. Significantly, the charge separation efficiency progressively escalates as the cone height augments. This undertaking accentuates the importance of modulating the parameter of a 3D-structured Fe 2 O 3 photoanode.
研究领域:
材料科学
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能源科学
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产品关联
DOI
高影响因子
MATERIALS CHEMISTRY AND PHYSICS
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2021
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IF 4.094
Shenghang Xu,Tingting Lu,Kaijie Shen,Junjie Lan,Bin Hu,Huibin Zhang,Yiping Tang,Huazhen Cao,Guoqu Zheng
Ti–5Al–5V–5Mo–3Cr (Ti-5553) metastable β titanium alloy possesses excellent high temperature mechanical properties , however, the oxidation resistance is fairly poor. In this work, a SiO 2 coating was prepared on Ti-5553 alloy by cathodic electro-deposition. The high temperature oxidation resistance of the deposited SiO 2 coating was evaluated at 800 °C. The results show that the optimal current density of deposition is −2.0 mA/cm 2 for 300 s, and the thickness of the compact SiO 2 film reaches 5.5 μm. The SiO 2 film can react with Ti-5553 substrate and form protective Ti 5 Si 3 layer, which inhibits the inward diffusion of oxygen from air, leading to the remarkable improvement of oxidation resistance. The mass gain is only 1.13 mg/cm 2 after oxidation at 800 °C for 80 h. The oxide scale consists of TiO 2 , Al 2 O 3 , V 2 O 5 , Cr 2 O 3 and SiO 2 , but Mo 2 O 5 is absent. The occurrence of Kirkendall voids as well as the cracks induced by internal stress should be responsible for the deterioration of oxidation resistance, which may provide extra channels for oxygen diffusion inwards the substrate.
研究领域:
材料科学
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表面工程
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产品关联
DOI
高影响因子
Metals
·
2020
·Vol. 10
·期 7
·927
·
IF 2.117
Xuelei Wang,Qiufeng Wang,Zhaojun Dong,Xiaoqian Zhou,Xiaoliang Wang,Boyan Zhang,Chao Meng
Ti(C,N)-based cermets with multicomponent ingredients were prepared using vacuum sintering technology. The effect of molding agents, binder phase and sintering temperature on Ti(C,N)-based cermets were studied. The optimum molding performance was obtained by adding 2% polyvinyl alcohol (PVA-1788). The microstructure and mechanical properties of Ti(C,N)-based cermets were investigated. The Ti(C,N)-based cermet with a weight percentage of TiC:TiN:Ni:Co:Mo:WC:Cr3C2:C = 40:10:20:10:7:8:4:1 and sintered at 1450 °C had the optimal mechanical properties. The relative bending strength, Vickers hardness, elastic modulus and wear resistance were 2010 MPa, 15.01 GPa, 483.57 GPa and 27 mg, respectively. Additionally, X-ray diffraction (XRD), backscatter scanning electron microscopy pictures (SEM–BSE), energy dispersive spectrometry (EDS) and optical micrographs of Ti(C,N)-based cermets were characterized.Keywords:Ti(C,N)-based cermet;vacuum sintering;NiCoMo powder;microstructure;mechanical properties
研究领域:
材料科学
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机械工程
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产品关联
DOI
高影响因子
SENSORS AND ACTUATORS B-CHEMICAL
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2014
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IF 3.84
Ying Zhang,Bo Fu,Kuixue Liu,Yupeng Zhang,Xu Li,Shanpeng Wen,Yu Chen,Shengping Ruan
FeCl 3 -NH 2 -MIL-125(Ti) with different FeCl 3 content was prepared and characterized by XRD , SEM and XPS . The humidity sensing properties of FeCl 3 -NH 2 -MIL-125(Ti) have been investigated. Compared with NH 2 -MIL-125(Ti), FeCl 3 -NH 2 -MIL-125(Ti) was more effective in the humidity sensing. The optimal mixing ratio was FeCl 3 -NH 2 -MIL-125(Ti) (8 wt%), which exhibited the best linearity. The impedance of FeCl 3 -NH 2 -MIL-125(Ti) (8 wt%) decreases by almost three orders of magnitude in the range of 11%-95% RH. The response time and recovery time of the humidity sensor by FeCl 3 -NH 2 -MIL-125(Ti) (8 wt%) are 11 s and 86 s respectively. These results indicate the potential application of FeCl 3 -NH 2 -MIL-125(Ti) in humidity sensors.
研究领域:
材料科学
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传感器技术
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纳米材料
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功能材料
✓ 已验证
DOI
高影响因子
危险品化学品经营许可证（带存储）