Advanced Electronic Materials
·
2017
·Vol. 4
·期 1
·1700285
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IF 4.193
Hua Wu,Yu Zhang,Xiaoyu Zhang,Min Lu,Chun Sun,Xue Bai,Tieqiang Zhang,Guang Sun,William W. Yu
The high photoluminescence quantum yield, wide color tunability and narrow bandwidth of perovskite nanocrystals make them favorable for light source and display applications. Here, highly transparent green-light-emitting devices (LEDs) using inorganic cesium lead halide perovskite nanocrystal films as the emissive layer are reported. The effect of multilayered nanostructured transparent electrode on optical properties and performance within the LEDs is investigated by fine tuning layer thickness. The results show that the light transmission in visible region can be enhanced with this nanostructured film. These LEDs exhibited a high transmittance (average 73% over 400–700 nm) and high brightness of 2640 and 1572 cd m −2 for indium-doped tin oxide (ITO) cathode and MoO x /Au/MoO x anode sides, respectively.
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ACS Applied Materials & Interfaces
·
2024
·
IF 8.3
Shuang Yang,Zhenyu Tang,Bo Qu,Lixin Xiao,Zhijian Chen
Copper (Cu)-based perovskites are promising for lead-free perovskite light-emitting diodes (PeLEDs). However, it remains a significant challenge to achieve high performance devices due to the nonradiative loss caused by the disordered crystallization and lack of passivation. Crown ethers are known to form host–guest complexes by the interaction between C–O–C groups and certain cations, and 18-crown-6 (18C6) with an appropriate complementary size can interact with Cs+ and Cu+ cations. Herein, we studied the interaction between CsCu2I3 and two crowns with the same cyclic size, 18C6 and dibenzo-18-crown-6 (D18C6). Particularly, D18C6 can reduce the nonradiative recombination rate of CsCu2I3 film by passivating the defects and optimizing the film morphology effectively. The room mean square (RMS) decreased from 5.06 to 2.95 nm, and the PLQY was promoted from 4.71% to 19.9%. Besides, D18C6 can also decrease the barrier of hole injection. The PeLEDs based on D18C6-modified CsCu2I3 realized noticeable improvement with a maximum luminance and EQE of 583 cd/m2 and 0.662%, respectively.
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Nano Energy
·
2024
·
IF 16.8
Yongji Li,Zhongyuan Tian,Changjun Li,Zheng Li,Zhong-Zhen Yu,Dan Yang
Soft actuators with biomimetic behavior have widely been utilized in intelligent robotics and artificial muscles. Herein, tannic acid (TA) non-covalently modified and γ-methacrylic trimethoxysilane (MPS) covalently modified MXene (MPS-TA-MXene) are incorporated into a poly(n-isopropylacrylamide-polyacrylamide) (PNIPAM-PAM) copolymer hydrogel to yield a light-responsive hydrogel nanocomposite, denoted as MNA. TA effectively preserves the surface characteristics of MXene while the double bonds in MPS form covalent bonding between MXene and PNIPAM-PAM copolymer, ensuring uniform dispersion of MPS-TA-MXene in MNA hydrogel. Under exposure to ultraviolet light, the resulting MNA hydrogel actuators with nematode- or starfish-shaped exhibit not only bending capabilities in various directions and angles but also demonstrate remarkable multiple-freedom rolling behavior in water environments due to their volume shrinkage induced by the phase transition of MNA hydrogel. Overall, the proposed simply assembled MNA hydrogel actuators with multiple and continuous bionic motions, distinguishing them from conventional single soft actuators limited to bending in one specific direction or performing a simple singular action of rolling, look promising for use in underwater exploration.
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JOURNAL OF COLLOID AND INTERFACE SCIENCE
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2024
·
IF 9.4
Xue Fu,Haixu Dou,Yong Fan,Jianing Xu,Hui Qi,Chengchun Zhang,Lingjie Song,Jie Zhao,Luquan Ren,Weihua Ming
Great attentions have been paid to anticorrosion coatings with self-healing performances to enhance its reliability and protection period, but massive challenges still remain for developing a coating with selectively triggered and accurately controllable self-healing behaviors. Herein, by integrating lamellar graphene oxide (GO) into a polycaprolactone (PCL) nanofiber loaded with 8-hydroxyquinoline (8HQ) corrosion inhibitors, a composite coating with precisely controllable self-healing capabilities is developed. The coating defects can be remotely and accurately repaired under near-infrared (NIR) light irradiation within a very short time. Notably, the precisely controllable defect recovery even within a minimal region of ∼0.03 cm 2 can be achieved, without causing pristine performance recession of irrelevant regions. The embedded GO can work both as efficient photothermal conversion materials, and yield “labyrinth effect” to enhance the passive barrier against corrosive media. Moreover, encapsulated corrosion inhibitors 8HQ can be rapidly released into acid/alkaline microregions in a corrosive-triggered manner, to form self-assembly protective layers and offer instant safeguarding for damaged sites. The integrated precise self-healing system enables extremely high corrosion inhibition efficiency exceeding 98.6 %. This work illustrates a feasible approach for combining remotely precise self-healing and active/passive enhanced passive barrier, presenting perspective potential in practical engineering anticorrosion applications or other controllable micro-reaction function surfaces.
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DYES AND PIGMENTS
·
2017
·
IF 3.473
Qiang Li,Heng-guo Wang,Yanhui Li,Yanwei Li,Qian Duan
A series of metallophthalocyanine-based conjugated microporous polymers (MPc-CMPs, M = Co, Cu, Zn) were synthesized and used for the photodegradation of organic pollutants for the first time. The as-obtained MPc-CMPs were characterized by UV-vis spectroscopy, Fourier transform infrared spectra (FTIR), scanning electron microscope (SEM). Their photocatalytic activities were assessed by the photodegradation of RhB in the presence of H 2 O 2 under visible light irradiation. Moreover, the possible mechanism to predict this reaction pattern was proposed. As a result, the as-obtained MPc-CMPs, especially CoPc-CMP, exhibit excellent photocatalytic efficiency, recyclability and stability. These results indicate that the MPc-CMPs are potentially applicable in the environmental purification of organic pollutants in the industrial wastewater.
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CHEMICAL ENGINEERING JOURNAL
·
2017
·
IF 6.216
Ling Cheng,Lan Liu,Kai Yan,Jingdong Zhang
Photoelectrocatalysis (PEC) and electroenzymatic (EEC) process are two important techniques for degradation of refractory organic compounds. In this work, we coupled PEC and EEC (PEC-EEC) to develop a novel system for efficient removal of chloramphenicol (CAP) driven by visible light. This coupling system was constructed by a CdS/WO 3 /FTO photoanode and a hemin-graphene immobilized cathode. The photoanode was fabricated by layer-by-layer assembly of CdS quantum dots on WO 3 /FTO to provide high visible light activity. In order to achieve the EEC process, graphite cathode was modified with hemin-graphene composite, in which hemin served as the mimic enzyme. When CdS/WO 3 /FTO anode was irradiated under visible light, photogenerated holes participated in the formation of hydroxyl radicals while photogenerated electrons were driven by bias potential to the cathode for the reduction of oxygen into hydrogen peroxide. Thus, organic pollutant could be degraded by the oxidation reactions either with the hydroxyl radicals or the hydrogen peroxide under the catalysis of hemin. The visible light-driven PEC-EEC system was applied to the removal of CAP. The intermediates formed during the degradation process were separated by high-performance liquid chromatography and identified by liquid chromatography-mass spectrometry, and a degradation pathway for CAP in such a PEC-EEC system was proposed.
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ENVIRONMENTAL ENGINEERING SCIENCE
·
2024
·
IF 1.8
Yiting Wang,Mingze Xu,Jinhua Li,Tingsong Zhang
Titanium dioxide (TiO2) has been widely studied as a photocatalyst owing to its advantages of low cost, good stability, and nonpollution. However, they can only be excited by ultraviolet light, resulting in low utilization of solar energy and limited photocatalytic efficiency. In recent years, researchers have found that the nonprecious metal Al can effectively improve the photocatalytic performance of TiO2. However, the current studies focus only on enhancing the ultraviolet photocatalysis performance of semiconductors with Al on the substrate. In this study, Al nanoparticles (NPs) and TiO2 were prepared into composite materials. The effects of ligand, Al particle size, and the molar ratio of Al and TiO2 on the photocatalytic degradation of methylene blue (MB) by Al NPs and TiO2 composites (Al NPs/TiO2) were investigated. The results showed that the Al NPs/TiO2 prepared with a particle size of 200 nm of Al, glutathione as the ligand bridge, and an Al:TiO2 ratio of 2:1 were the most effective for the degradation of MB. The degradation rate of 5 mg/L MB solution within 70 min under visible light was up to 99.5%, which was three times higher than that of P25 TiO2. The photocatalytic performance was further enhanced under sunlight with a degradation rate of 99.7% within 50 min, which is four times higher than that of P25 TiO2 under the same light source. Therefore, Al NPs/TiO2 is a potential photocatalytic material for the treatment of organic pollutants in water.
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ChemistrySelect
·
2024
·Vol. 9
·期 27
·e202303733
·
IF 1.9
Yao Gu,Dongjian Shi,Liang Wang,Mingqing Chen
Graphical A range of Fe 3 O 4 /Ag/BiVO 4 /sepiolite composite materials, featuring varying Fe 3 O 4 concentrations, were synthesized utilizing the co-precipitation method. The inherent magnetic characteristics of Fe 3 O 4 , combined with the resultant Z-type heterojunction structure, confer exceptional photo-catalytic prowess upon the material. This enables swift degradation of rhodamine B, and furthermore, facilitates its retrieval for subsequent reuse. To increase specific surface area and light utilization of photo-catalysts, a series of Fe 3 O 4 /Ag/BiVO 4 /sepiolite composites with different Fe 3 O 4 contents were synthesized via co-precipitation. The structure, composition, and optical properties of these composites were characterized using X-ray diffraction (XRD), nitrogen adsorption and desorption (BET), UV-Vis diffuse reflectance spectroscopy (UV-Vis DRS), and fluorescence spectroscopy (PL). The photo-catalytic activity of the composites was further evaluated using rhodamine B as a model for photo-catalytic degradation. The results revealed that the composites with optimal Fe 3 O 4 loading exhibited the narrowest bandgap width, approximately 2.13 eV, and the highest electron-hole pair separation efficiency. Rhodamine B could be almost completely degraded within a short illumination time in the presence of the Fe 3 O 4 /Ag/BiVO 4 /sepiolite composites. The degradation mechanism of rhodamine B was proposed to involve the improvement of the photo-catalytic activity of the resulting composites by the Fe 3 O 4 and the Z-type heterojunction structure. Additionally, the composites could be recycled and reused multiple times, making them an environmentally friendly and sustainable option.
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ACS Applied Materials & Interfaces
·
2024
·
IF 8.3
Yuanyuan Wang,Dawei Yang,Heng Zhang
Although high-performance quantum-dot light-emitting diodes (QLEDs) have been achieved, their stability is still limited due to the use of unstable PEDOT:PSS as the hole injection layer (HIL). Here, we developed a PEDOT:PSS-free QLED by using a binary PTAA:F4-TCNQ HIL. Because the PTAA, with a highest occupied molecular orbital (HOMO) level of ∼5.20 eV, can facilitate hole injection from ITO to the hole transport layer, and the F4-TCNQ can act as the electron acceptor dopant to improve the hole density and hole mobility of PTAA, the PTAA:F4-TCNQ HIL can exhibit excellent hole injection capability. As a result, the PEDOT:PSS-free QLED can exhibit a high EQE of 24.19% and an impressive brightness of 367,200 cd/m2, which are significantly higher than those of conventional QLEDs. Moreover, due to the improvement of device performance and the removal of PEDOT:PSS, the PEDOT:PSS-free QLED can also exhibit a high T95 operational lifetime of 4206 h at 1000 cd/m2 and an excellent T80 shelf lifetime of 207.41 h at 136400 cd/m2, which are about 1.6- and 3.3-fold those of conventional QLEDs, respectively. We believe that the demonstrated PEDOT:PSS-free QLED, with higher performance and stability, will promote the practical application of QLEDs in displays.
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Journal of Manufacturing Processes
·
2025
·
IF 6.8
Feng Xu,Hang Jin,Zhuomin Zhou,Acan Jiang,Lingling Liu,Haohang Fang,Qiang Gao,Yu-Chuan Su,Zhengmao Ding,Qinnan Chen,Songyue Chen,Daoheng Sun
Digital light processing (DLP) has emerged as one of the most promising methods for constructing intricate 3D hydrogel structures. However, the material availability of hydrogels is quite limited for resin vat-based printing. To overcome this issue, we propose a surface tension confined digital light processing (STC-DLP) technique that utilizes liquid surface tension and surface-treated substrates to confine the hydrogel solution during printing, to minimize the solution consumption. The “top-down” DLP printing enables layer-by-layer curing of hydrogel solutions into controlled 3D structures. A soft and a rigid hydrogel solution was selected as demonstration. By adding hydrogel solution with desired volume, highly accurate microtissue models, flexible sensors, and microfluidic chips with complex 3D structures were fabricated with high solution availability. This approach achieves efficient utilization of hydrogel solutions, and is expected to be especially applicable for printing of scarce or expensive materials.
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Results in Chemistry
·
2025
·
IF 4.2
Qin Gao,Qi Pan,Youzhi Cao,Yingping Chen,Sixue Zhai,Haijing Qiu,Beibei Fan,Yanyan Yang,Chunhai Luo
Hospital wastewater poses significant public health risks due to the presence of antibiotic-resistant bacteria and other pathogens. Herein, a positively charged GO/ MoS 2 @PEI (GMP) nanozyme for ecofriendly, low energy consumption and low systemic toxicity were synthesized. The positive surface potential of GMP enhances the adsorption of anionic lipopolysaccharide (LPS) and lipoteichoic acid (LTA) present on bacterial membranes, thereby improving bacterial capture and interaction with the antibacterial agent. Under visible light (VL) illumination from a common fluorescent lamp, the GMP nanozyme shows a synergistic photocatalytic effect, achieving 100 % antibacterial efficiency against both Gram-negative and Gram-positive bacteria. Electron paramagnetic resonance (EPR) experiments confirmed the pivotal role of superoxide radicals (•O 2 − ) and hydroxyl radicals (•OH) in the bacterial inactivation process. This work provides innovative synergistic strategy for constructing nanomaterials for highly efficient biofouling control in hospital wastewater.
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CHEMISTRY-A EUROPEAN JOURNAL
·
2025
·
IF 3.7
Jinbo Ouyang,Longping Jiang,Jiayao Li,Feiqiang He,Zhi Gao,Mengmeng Wang,Limin Zhou,Zongbo Xie,Zhiqiang Zhu,Yifu Chen
Graphical Three isomeric fluorinated acylhydrazone derivatives (DFBP-IND, DFBP-BHD, DFBP-3-FBHD) were successfully synthesized and demonstrated dynamic photo-responsive behavior ranging from crack initiation to crystal fragmentation under 365 nm UV irradiation. The photochemical mechanism was explored in detail and highlighted the essential role of the C═N bond in the acylhydrazone framework for enabling [2+2] cycloaddition-driven actuation. Our structural engineering strategy established a design paradigm for photoresponsive materials through rational selection of hydrazide precursors, enabling precise modulation of optomechanical properties. Crystalline materials with photomechanical responsiveness have garnered significant attention in flexible actuators and micro/nano-electromechanical systems due to their unique capability to directly convert light into mechanical energy. In this work, four novel fluorinated acylhydrazone compounds were successfully synthesized through direct condensation reactions between 4,4′-difluorobenzophenone (DFBP) and acylhydrazine compounds, including benzoylhydrazine (BHD), 3-fluorobenzoylhydrazine (3-FBHD), isoniazid (IND), and acetylhydrazine (AED). Systematic investigation of their photomechanical responses revealed distinct molecular mechanisms. Experimental results demonstrate that isomeric fluorinated acylhydrazone derivatives (DFBP-BHD, DFBP-3-FBHD, DFBP-IND) exhibit dynamic photo-responsive behavior ranging from crack initiation to crystal fragmentation under 365 nm UV irradiation, whereas the hydrazone derivative DFBP-AED remains inert. This confirms the essential role of [2 + 2] photocycloaddition-dependent C = N double bonds in photomechanical activity. Comprehensive characterization through DSC, TG, XRD, ¹H/¹ 3 C NMR, and MS elucidated the formation pathways and structural characteristics of photocycloaddition products. Density functional theory calculations revealed that energy disparities between (0 0 1) and (1 0 0) crystallographic planes govern longitudinal fragmentation patterns. This study establishes a “molecular structure-crystal arrangement-macroscopic response” multi-scale regulation strategy, offering novel insights for developing high-performance light-driven materials.
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