磷钼酸水合物

CAS: 51429-74-4 货号: P598898 分子式: H3[P(Mo3O10)4] · xH2O 分子量: 1825.25 (anhydrous basis) EC号: 610-660-7
有货
级别和纯度: 工业级 ? 工业级 —— 工业品质纯度,无严格杂质保证。适用于成本优先的大规模或非关键工艺。 MO:30%
别名
十二钼磷酸|钼磷酸
储存条件
室温,充氩
运输条件
常规运输
★
规格
库存
价格
数量
5g
P598898-5g
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¥29.90
25g
P598898-25g
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¥89.90
100g
P598898-100g
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¥279.90
500g
P598898-500g
期货 Stock Image
¥1,099.90
1kg
P598898-1kg
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¥1,999.90
2.5kg
P598898-2.5kg
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¥3,999.90
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为什么选择此级别

工业级 ,适用于对基线干扰要求严格的色谱和分析工作流程。

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储存与运输

室温,充氩。常规运输 。请查阅批次 COA 获取详细规格。

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质量文档

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文献证明

在色谱分析、有机合成和交叉偶联反应领域已被 47 篇同行评审文献引用。

概述

Phosphomolybdic acid (PMA) hydrate is primarily used in spectrophotometric determination of phosphate ions. PMA is a component in the 3-color histology stain called Masson’s trichrome; employed in the differentiation step, Phosphomolybdic acid is one of the solutions fixed tissues are immersed in prior to subsequent staining. Phosphomolybdic acid is also used as reagent for simple and rapid colorimetric determination of phenothiazine derivatives. PMA oxidizes the phenothiazine derivative to a cationic free radical, forming a coloured salt. A preliminary extraction is necessary if certain reductants (sulphite or ascorbic acid) are present as stabilizers, as they will reduce the reagent to phosphomolybdenum blue.

A reagent used for spectrophotometric determination of phosphate ions.
用于制备有机-无机杂化电活性材料,可用作电池中的阳离子插入电极。

磷钼酸水合物可用于合成二硫化钼(MoS2)还原的石墨烯氧化物(RGO)复合材料,其可用作钠离子电池的电极。以过氧化氢作为氧化剂时,它也可以用作催化剂前体,用于催化柴油燃料中的二苯并噻吩氧化。
有机-无机杂化材料分子电池的前体,用作阳离子插入电极。

Phosphomolybdic acid (PMA) hydrate is primarily used in spectrophotometric determination of phosphate ions. PMA is a component in the 3-color histology stain called Masson’s trichrome; employed in the differentiation step, Phosphomolybdic acid is one of the solutions fixed tissues are immersed in prior to subsequent staining. Phosphomolybdic acid is also used as reagent for simple and rapid colorimetric determination of phenothiazine derivatives. PMA oxidizes the phenothiazine derivative to a cationic free radical, forming a coloured salt. A preliminary extraction is necessary if certain reductants (sulphite or ascorbic acid) are present as stabilizers, as they will reduce the reagent to phosphomolybdenum blue.

A reagent used for spectrophotometric determination of phosphate ions.Employed in preparation of a hybrid organic-inorganic, electroactive material with potential application as a cation-insertion electrode in batteries.
Phosphomolybdic acid hydrate may be used in the synthesis of molybdenum disulfide (MoS2)-reduced graphene oxide (RGO) composites with potential application as electrodes for sodium ion battery. It may also be used as a catalyst precursor in the presence of hydrogen peroxide as oxidant for the dibenzothiophenes oxidation in diesel fuels.
A precursor to hybrid organic-inorganic based molecular batteries with applications as cation-insertion electrodes.

规格

别名
十二钼磷酸 | 钼磷酸
英文别名
Phosphomolybdic acid hydrate | 51429-74-4 | dodecamolybdophosphoric acid | RN225F04V1 | Phosphomolybdic acid [MI] | Molybdenumphosphorus hydroxide oxide | UNII-RN225F04V1 | Phosphoric acid, anhydride with molybdic acid | Molybdenum phosphorus hydroxide oxide | phosphoric a
规格或纯度
工业级, MO:30%
英文名称
Phosphomolybdic acid hydrate
储存条件
室温,充氩
运输条件
常规运输
名称和识别符
PubChem SID
EC号
234-713-5
分子类型
小分子
IUPAC Name
phosphoric acid;trioxomolybdenum;hydrate
INCHI
1S/12Mo.H3O4P.H2O.36O/c;;;;;;;;;;;;1-5(2,3)4;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;/h;;;;;;;;;;;;(H3,1,2,3,4);1H2;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;
InChi Key
PDDXOPNEMCREGN-UHFFFAOYSA-N
Smiles
O.OP(=O)(O)O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O
Isomeric SMILES
O.OP(=O)(O)O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O
UN Number
Packing Group
III
分子量
1825.25 (anhydrous basis)

技术文档

📋 安全数据表 (SDS)

全面的危险、操作、储存及法规合规文件。

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该级别的完整质量属性和验收标准。

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高级数据

系统学分类

分类树(Taxonomy Tree)

界(kingdom) 无机化合物
超类(Superclass) 混合金属/非金属化合物
类(Class) 过渡金属含氧阴离子化合物
亚类(Subclass) 过渡金属磷酸盐
中间层级节点(Intermediate Tree Nodes) 暂无
直接上位类(Direct Parent) 过渡金属磷酸盐
其他上位类(Alternative Parents) 无机盐  无机氧化物  
分子骨架(Molecular Framework) 暂无
取代基(Substituents) 无机氧化物 - 无机盐 - 钼酸盐
描述(Description) 该化合物属于过渡金属磷酸盐类无机化合物。这类化合物中最大的氧阴离子为磷酸根,且非氧阴离子中的最重原子为过渡金属。
外部描述符(External Descriptors) 暂无
三维结构
交互式化学结构模型





化学和物理性质
密度
1.62
敏感性
易吸潮
熔点
90℃
分子量
1843.400 g/mol
XLogP3
氢键供体数Hydrogen Bond Donor Count
4
氢键受体数Hydrogen Bond Acceptor Count
41
可旋转键计数Rotatable Bond Count
0
精确质量Exact Mass
1841.67 Da
单同位素质量Monoisotopic Mass
1866.67 Da
拓扑极表面积Topological Polar Surface Area
693.000 Ų
重原子数Heavy Atom Count
54
形式电荷Formal Charge
0
复杂度Complexity
112.000
同位素原子数Isotope Atom Count
0
定义的原子立体中心计数Defined Atom Stereocenter Count
0
未定义的原子立体中心计数Undefined Atom Stereocenter Count
0
定义的键立体中心计数Defined Bond Stereocenter Count
0
未定义的键立体中心计数Undefined Bond Stereocenter Count
0
所有立体化学键的总数The total count of all stereochemical bonds
0
共价键合单元计数Covalently-Bonded Unit Count
14
安全和危险性(GHS)
象形图
GHS03,   GHS05
信号词
危险
危险声明

H272: 可能加剧火灾; 氧化剂

H290: 可能腐蚀金属

H314: 造成严重的皮肤灼伤和眼睛损伤

预防措施声明

P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。

P264: 处理后要彻底洗手。

P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。

P363: 再次使用之前,请清洗受污染的衣物。

P301+P330+P331: 如误吞咽:漱口。不要诱导呕吐。

P304+P340: 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。

P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。

P405: 密闭存放

P501: 将内容物/容器处理到。。。

P302+P361+P354: 如果接触皮肤:立即脱掉所有被污染的衣服。立即用水冲洗几分钟。

WGK Germany
3
Class
5.1 / 8
个人防护装备
Eyeshields,Faceshields,full-face particle respirator type N100 (US),Gloves,respirator cartridge type N100 (US),type P1 (EN143) respirator filter,type P3 (EN 143) respirator cartridges
质检证书(CoA,COO,BSE/TSE 和分析图谱)
C of A & Other Certificates(BSE/TSE, COO):
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批号(Lot Number) 证书类型 货号
D2515481 分析证书 P598898
D2515482 分析证书 P598898
D2515585 分析证书 P598898
G2523067 分析证书 P598898
C2521493 分析证书 P598898
C2521492 分析证书 P598898
A2605103 分析证书 P598898
A2613123 分析证书 P598898
E2606115 分析证书 P598898
G2523064 分析证书 P598898
G2523065 分析证书 P598898
H2603071 分析证书 P598898
I2321959 分析证书 P598898
I2321960 分析证书 P598898
I2321961 分析证书 P598898
L2526004 分析证书 P598898

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技术文档和文章
此产品的引用文献
引用文献
1. Jinbo Zhu, Xu Chen, Xiangge Sang, Gang Yang.  (2023)  Synthesis of a phosphomolybdic acid-modified AlPO4-5/SAPO-34 composite catalyst and its catalytic performance in the MTO reaction.  APPLIED CATALYSIS A-GENERAL,  [10.1016/j.apcata.2023.119486]
2. Jiawang Xiang, Bing Zhang, Yani Shi, Yanfei Wen, Yuan Yuan, Jianying Lin, Zhihuan Zhao, Jing Li, Yan Cheng.  (2023)  Isoniazide modified Ag nanoparticles triggered photothermal immunoassay for carcinoembryonic antigen detection.  ANALYTICAL BIOCHEMISTRY,  [PMID:37890548] [10.1016/j.ab.2023.115370]
3. Weiwei Han, Yang Qian, Fan Zhang, Yi He, Ping Li, Xingwang Zhang.  (2023)  Ultrasmall IrO2 nanoparticles anchored on hollow Co-Mo multi-oxide heterostructure nanocages for efficient oxygen evolution in acid.  CHEMICAL ENGINEERING JOURNAL,  [10.1016/j.cej.2023.145353]
4. Wenting Li, Xinai Zhang, Yongqiang Shi, Xuetao Hu, Xin Wang, Nini Liang, Tingting Shen, Xiaobo Zou, Jiyong Shi.  (2023)  A dual-modal biosensor coupling cooperative catalysis strategy for sensitive detection of AFB1 in agri-products.  FOOD CHEMISTRY,  [PMID:37354581] [10.1016/j.foodchem.2023.136553]
5. Zhenchao Tao, Jingguo Wang, Haitao Wu, Jiaru Hu, Lu Li, Yuhang Zhou, Qi Zheng, Lisha Zha, Zhengbao Zha.  (2023)  Renal Clearable Mo-Based Polyoxometalate Nanoclusters: A Promising Radioprotectant against Ionizing Irradiation.  ACS Applied Materials & Interfaces,  [PMID:36702809] [10.1021/acsami.2c19282]
6. Yu Xiaoxia, Zhou Qi, Bi Lihua.  (2023)  Ultrasensitive Electrochemical Sensor Based on β-Cyclodextrin–Polyaniline–Phosphomolybdic Acid Matrix for the Detection of Ascorbic Acid.  RUSSIAN JOURNAL OF APPLIED CHEMISTRY,  95  (7): (1036-1047).  [10.1134/S1070427222070163]
7. Yisheng Xu, Yaoheng Liang, Zeng Yuai, Hangyu Long, Qizhi He, Kaijin Guo, Yuyuan Zhang, Dongchu Chen, Xuejun Xu, Huawen Hu.  (2022)  Co-doping g-C3N4 with P and Mo for efficient photocatalytic tetracycline degradation under visible light.  CERAMICS INTERNATIONAL,  [10.1016/j.ceramint.2022.05.114]
8. Xingyu Luo, Fengjiao Li, Fei Peng, Lizhen Huang, Xiaoling Lang, Meiqin Shi.  (2021)  Strategies for Perfect Confinement of POM@MOF and Its Applications in Producing Defect-Rich Electrocatalyst.  ACS Applied Materials & Interfaces,  [PMID:34797968] [10.1021/acsami.1c17808]
9. Junxian Hu, Chaohong Guan, Huangxu Li, Yangyang Xie, Liuyun Zhang, Jingqiang Zheng, Yanqing Lai, Zhian Zhang.  (2021)  Boosting potassium-storage performance via confining highly dispersed molybdenum dioxide nanoparticles within N-doped porous carbon nano-octahedrons.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,  [PMID:34571298] [10.1016/j.jcis.2021.09.068]
10. Shiqiang Wang, Yali Cao, Wei Jia, Zhenjiang Lu, Dianzeng Jia.  (2021)  A cage-confinement strategy to fabricate Pt-Mo6Co6C heterojunction for highly efficient PH-universal hydrogen evolution.  APPLIED CATALYSIS B-ENVIRONMENTAL,  [10.1016/j.apcatb.2021.120579]
11. Man Qi, Xi Chen, Heng Zhong, Jingwei Wu, Fangming Jin.  (2020)  Base-Free, Vanadium-Catalyzed Conversion of Chitin into Acetic Acid under Low Oxygen Pressure.  ACS Sustainable Chemistry & Engineering,  [10.1021/acssuschemeng.0c07147]
12. Zhihao Si, Miao Zuo, Wenlong Jia, Gaofeng Chen, Xing Tang, Xianhai Zeng, Lu Lin.  (2020)  Effective Synthesis of a Biodiesel Precursor from Furan Derivatives at Room Temperature with NaHSO4 as a Recyclable Catalyst.  ENERGY & FUELS,  [10.1021/acs.energyfuels.0c03018]
13. Shifu Wang, Zuoyi Xiao, Shangru Zhai, Guoxiang Wang, Wensha Niu, Longfei Qin, Zhongcheng Li, Qingda An.  (2020)  Construction of Sn–Mo bimetallic oxide nanoparticle-encapsulated P-doped 3D hierarchical porous carbon through an in-situ reduction and competitive cross-linking strategy for efficient pseudocapacitive energy storage.  ELECTROCHIMICA ACTA,  [10.1016/j.electacta.2020.136106]
14. Hui Wang, Meiyin Wang, Jining Shang, Yuanhang Ren, Bin Yue, Heyong He.  (2020)  H3PMo12O40 Immobilized on Amine Functionalized SBA-15 as a Catalyst for Aldose Epimerization.  Materials,  13  (3): (507).  [PMID:31973194] [10.3390/ma13030507]
15. Di Yin, Ming-Liang Wang, Ying-Zi Wang, Xun Hu, Bo Liu, Hong Liu, Lulu Ma, Guang-Gang Gao.  (2019)  A ternary ZnO/ZnS/MoS2 composite as a reusable SERS substrate derived from the polyoxomolybdate/ZIF-8 host–guest framework.  Journal of Materials Chemistry C,  7  (32): (9856-9864).  [10.1039/C9TC02967B]
16. Yueling Cao, Hepeng Zhang, Kangkai Liu, Qiuyu Zhang, Kai-Jie Chen.  (2019)  Biowaste-Derived Bimetallic Ru–MoOx Catalyst for the Direct Hydrogenation of Furfural to Tetrahydrofurfuryl Alcohol.  ACS Sustainable Chemistry & Engineering,  [10.1021/acssuschemeng.9b01765]
17. Menglei Yuan, Sobia Dipazir, Meng Wang, Yu Sun, Denglei Gao, Yiling Bai, Min Zhang, Peilong Lu, Hongyan He, Xiangyang Zhu, Shuwei Li, Zhanjun Liu, Zhaopeng Luo, Guangjin Zhang.  (2019)  Polyoxometalate-assisted formation of CoSe/MoSe2 heterostructures with enhanced oxygen evolution activity.  Journal of Materials Chemistry A,  7  (7): (3317-3326).  [10.1039/C8TA11976G]
18. Cong Wang, Ming Zhou, Yuanyuan Ma, Huaqiao Tan, Yonghui Wang, Yangguang Li.  (2018)  Hybridized Polyoxometalate-Based Metal–Organic Framework with Ketjenblack for the Nonenzymatic Detection of H2O2.  Chemistry-An Asian Journal,  13  (16): (2054-2059).  [PMID:29920940] [10.1002/asia.201800758]
19. Wang Hongzhi, Zhou Haibin, Zhang Weiguo, Yao Suwei.  (2018)  Urea-assisted synthesis of amorphous molybdenum sulfide on P-doped carbon nanotubes for enhanced hydrogen evolution.  JOURNAL OF MATERIALS SCIENCE,  53  (12): (8951-8962).  [10.1007/s10853-018-2226-3]
20. Sheng Zhu, Xiaoxin Yang, Lan Li, Xiao Wang, Gaoyi Han.  (2024)  Confined grotthuss proton-conduction along polyoxometalate chains inside carbon nanotubes for high-rate charge storage.  CHEMICAL ENGINEERING JOURNAL,  [10.1016/j.cej.2024.150744]
21. Xujing Ji, Jiayang Zhang, Guoqing Zhang, Na Li, Ruixin Wang, Haiqiang Lin, Xinping Duan.  (2024)  Dual interfacing with metallic cobalt boosts the electron shuttle of CdS-carbide nanoassemblies.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,  [PMID:38277838] [10.1016/j.jcis.2024.01.142]
22. Xinlun Song, Junshuo Cui, Zhenning Lou, Weijun Shan, Haibiao Yu, Xiaogeng Feng, Yuejiao Wang, Ying Xiong.  (2024)  Enhancement of oxygen evolution reaction by in situ growth PMo12@ZIF-67 on MWCNTs via perylene bisimide-based dispersant.  JOURNAL OF ALLOYS AND COMPOUNDS,  [10.1016/j.jallcom.2024.174762]
23. Sheng Zhu, Yating Wu, Lingtong Ding, Xuehuan Zhang, Lan Li, Xiao Wang, Gaoyi Han.  (2024)  Heightening polyoxometalate encapsulation efficiency for biaxial strain-induced catalytic activity boosting.  Energy Storage Materials,  [10.1016/j.ensm.2024.103777]
24. Xuanhua Zhang, Chao Wang, Chao Luan, Mengyin Liao, Wenyuan Xu.  (2024)  Preparation of MOF-derived molybdenum-carbide-modified PtCu nano-alloy catalysts and their methanol oxidation performance.  NEW JOURNAL OF CHEMISTRY,  48  (17): (7964-7971).  [10.1039/D3NJ05511F]
25. Xinming Ye, Xinyi Jing, Yunlan Liu, Zhiqing Han, Fan Yang, Liang Qiao, Jie Ren, Linggong Meng, Zhimao Li, Wensheng Wang, Jie Li, Yingchun Li.  (2024)  Simultaneously Flame Retarding and Toughening of Epoxy Resin Composites Based on Two-Dimensional Polyhedral Oligomeric Silsesquioxane/Polyoxometalate Supramolecular Nanocrystals with Ultralow Loading.  ACS Applied Materials & Interfaces,  [PMID:39240053] [10.1021/acsami.4c09639]
26. Taiwen Zhang, Jun Guo, Yiju Zhang, Dan Zhang, Lin Lu, Shuangyan Qiu, Jiangqin Zhong.  (2023)  Synthesis, Characterization, and Catalytic Performance of Modified Keggin-type Calix[6]arene-like Polyoxometalates.  ChemistrySelect,  8  (26): (e202204971).  [10.1002/slct.202204971]
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28. Dai Li, Huajie Chen, Yutao Zheng, Sheng Zhou, Fengyuan Yong, Xiangbo Zhang, Kui Wang, Huiyun Wen, Jiyong Wu, Weiming Xue, Saipeng Huang.  (2024)  Mo-doped carbon-dots nanozyme with peroxide-like activity for sensitive and selective smartphone-assisted colorimetric S2− ion detection and antibacterial application.  SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,  [PMID:39426130] [10.1016/j.saa.2024.125274]
29. Zhang Fenghua, Shi Wenxiong, Liu Qingda, Wang Xun.  (2025)  Modular assembly of polyoxometalate clusters at the sub-1 nm scale.  Nature Protocols,  [PMID:40696073] [10.1038/s41596-025-01212-1]
30. Jiachen Sun, Baofeng Zhao, Sen Lin, Minghao Ge, Shuai Cheng, Dan Li, Xifan Mei, Shurui Chen.  (2025)  DNase1 Mimic TMNCs Disrupt Neutrophil Extracellular Traps and Free Radical Circulation for Ischemic Stroke Therapy.  Advanced Healthcare Materials,  [PMID:40741682] [10.1002/adhm.202500693]
31. Xueting Li, Guimin Wang, Chunmei Lv, Xiuwen Wang, Yue Liu, Haijing Yan, Zilin Zhang, Yanqing Jiao.  (2025)  Interface Engineering and Heteroatom Doping Trigger Multisite Synergism in V-Incorporated MoP/Cu3P to Accelerate Alkaline Hydrogen Evolution.  ACS Sustainable Chemistry & Engineering,  [10.1021/acssuschemeng.5c02007]
32. Sheng Zhu, Lan Li, Wenyan Zan, Xuehuan Zhang, Xinrui Zhang, Bing Deng, Gaoyi Han, Yan Li.  (2025)  Strong Interactions between Flash Subnanometer Carbide Nanowires and Single-Walled Carbon Nanotubes for Catalysis.  ACS Nano,  [PMID:40754809] [10.1021/acsnano.5c11080]
33. Xie Wenhe, Huang Xin-Yu, Zhu Chengcheng, Li Jichun, Deng Yu, Rong Youwen, Chen Keyu, Deng Yonghui.  (2025)  Synthesis of ordered mesoporous metal oxides by solvent evaporation-induced cooperative assembly.  Nature Protocols,  [PMID:40835793] [10.1038/s41596-025-01225-w]
34. Jinxiu Qian, Fan Yang, Hongchen Liu, Guohua Li, Siyuan Sun, Xiaoyun Zhang, Guang Ma, Jiating Cheng, Mingjie Li, Ni Wu, Xi Li, Yongfeng Li.  (2024)  Interfacial engineering of CoP-MoO2/NF heterojunction for high-efficient hydrogen evolution reaction coupled with 5-hydroxymethylfuran electrooxidation.  SEPARATION AND PURIFICATION TECHNOLOGY,  [10.1016/j.seppur.2024.127601]
35. Qian-Wen Lu, Qing He, Qing-Shuai Zhang, Da Sheng, Song-Hai Wu, Yong Liu, Xu Han.  (2025)  Highly Selective Oxidation of 5-Hydroxymethylfurfural to 2,5-Formylfuran Mediated by Surface Superoxo and Peroxo on Mo3Cu1/NH2-SBA-15.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,  [10.1021/acs.iecr.5c00580]
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