三丁基氯化锡

  • ≥96%
有货

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货号 (SKU) 包装规格 是否现货 价格 数量
T104678-25g
25g 现货 Stock Image
T104678-100g
100g 现货 Stock Image
T104678-500g
500g 现货 Stock Image
T104678-2.5kg
2.5kg 现货 Stock Image

基本描述

别名 三丁基氯化锡 | 氯化三丁基锡
英文别名 CCRIS 6319 | Tri(n-butyl) tin chloride | TRIBUTYL TIN CHLORIDE | Tri-butyl tin chloride | Tributylchlorotin | Tri-n-butylchlorotin | C12H27ClSn | DTXSID3027403 | tri-n-butyltinchloride | F0001-0521 | MFCD00000521 | tributylstannanylium;chloride | TBTC, PE
规格或纯度 ≥96%
英文名称 Tributyltin chloride
应用 催化剂。合成中导入三丁基锡基团。前列腺素合成。具有防腐、杀菌、防霉等作用。广泛用于木材防腐,船舶油漆等。同时作为医药中间体广泛应用於医药行业。
储存温度 充氩,干燥,阴凉
运输条件 常规运输
产品介绍

溶于乙醇、庚烷、苯和甲苯,不溶于冷水。遇热水水解。有毒。有腐蚀性。


名称和识别符

PubChem SID 504752633
EC号 215-958-7
IUPAC Name tributyl(chloro)stannane
INCHI InChI=1S/3C4H9.ClH.Sn/c3*1-3-4-2;;/h3*1,3-4H2,2H3;1H;/q;;;;+1/p-1
InChi Key GCTFWCDSFPMHHS-UHFFFAOYSA-M
Canonical SMILES CCCC[Sn](CCCC)(CCCC)Cl
Isomeric SMILES CCCC[Sn](CCCC)(CCCC)Cl
WGK Germany 3
RTECS WH6820000
PubChem CID 15096
UN Number 2788
分子量 325.51
Beilstein号 3535715

化学和物理性质

溶解性 Miscible with alcohol, heptane, benzene and toluene. Immiscible with water.
密度 1.2
敏感性 对湿度敏感;易吸潮
折光率 1.4903
闪点(℉) >112℃
闪点(℃) >112℃
沸点 145-147°C
熔点 -9°C
分子量 325.500 g/mol
XLogP3
氢键供体数Hydrogen Bond Donor Count 0
氢键受体数Hydrogen Bond Acceptor Count 0
可旋转键计数Rotatable Bond Count 9
精确质量Exact Mass 326.082 Da
单同位素质量Monoisotopic Mass 326.082 Da
拓扑极表面积Topological Polar Surface Area 0.000 Ų
重原子数Heavy Atom Count 14
形式电荷Formal Charge 0
复杂度Complexity 104.000
同位素原子数Isotope Atom Count 0
定义的原子立体中心计数Defined Atom Stereocenter Count 0
未定义的原子立体中心计数Undefined Atom Stereocenter Count 0
定义的键立体中心计数Defined Bond Stereocenter Count 0
未定义的键立体中心计数Undefined Bond Stereocenter Count 0
所有立体化学键的总数The total count of all stereochemical bonds 0
共价键合单元计数Covalently-Bonded Unit Count 1

安全和危险性(GHS)

一般危化品 一般危化品
象形图 GHS06,   GHS08,   GHS09
信号词 Danger
危险声明

H315: 引起皮肤刺激

H319: 引起严重眼睛刺激

H301: 吞咽会中毒

H317: 可能引起皮肤过敏反应

H312: 皮肤接触有害

H400: 对水生生物有剧毒

H410: 对水生生物有剧毒并具有长期持续影响

H372: 通过长时间或反复暴露对器官造成损害

预防措施声明

P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾

P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。

P273: 避免释放到环境中。

P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。

P302+P352: 如皮肤沾染:用水充分清洗。

P321: 特殊处理(请参阅此标签上的...)。

P405: 密闭存放

P501: 将内容物/容器处理到。。。

P264: 处理后要彻底洗手。

P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。

P270: 使用本产品时,请勿进食、饮水或吸烟。

P272: 被污染的工作服不允许离开工作场所

P333+P313: 如发生皮肤刺激或皮疹:求医/就诊。

P362+P364: 脱掉沾污的衣服,清洗后方可重新使用。

P391: 收集溢出物

P330: 漱口

P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。

P301+P316: 如果吞咽:立即寻求紧急医疗救助。

P317: 寻求紧急医疗救助。

P337+P317: 如果眼睛刺激持续:寻求医疗帮助。

P332+P317: 如果出现皮肤刺激:请寻求医疗帮助。

P319: 如果你感到不适,请寻求医疗帮助。

WGK Germany 3
RTECS WH6820000
个人防护装备 Eyeshields,Faceshields,full-face respirator (US),Gloves,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter

技术规格说明书

Purity(GC) 96-100(%)
Density (20°C) 1.198-1.21
Refractive index n20/D 1.488-1.493
Appearance(T104678) colorless to pale yellow liquid
Proton NMR spectrum Conforms to Structure

质检证书(CoA,COO,BSE/TSE 和分析图谱)

C of A & Other Certificates(BSE/TSE, COO):
输入批号以搜索分析图谱:

通过匹配包装上的批号来查找并下载产品的 COA,每批产品都进行了严格的验证,您可放心使用!

找到18个结果

批号(Lot Number) 证书类型 日期 货号
H2529684 分析证书 25-06-19 T104678
H2529683 分析证书 25-06-19 T104678
H2529682 分析证书 25-06-19 T104678
H2529681 分析证书 25-06-19 T104678
F2223409 分析证书 25-04-02 T104678
C2525809 分析证书 24-07-13 T104678
C2525803 分析证书 24-07-13 T104678
C2127137 分析证书 24-01-10 T104678
C2526041 分析证书 23-05-31 T104678
B2515039 分析证书 23-05-31 T104678
F2315943 分析证书 23-05-31 T104678
F2315948 分析证书 23-05-31 T104678
F2315949 分析证书 23-05-31 T104678
F2315953 分析证书 23-05-31 T104678
C2127139 分析证书 23-05-17 T104678
C2024027 分析证书 23-01-26 T104678
F2223399 分析证书 22-06-05 T104678
F2223400 分析证书 22-06-05 T104678

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此产品的引用文献

1. Shaowen Pei, Xiuping Ju, Jinsheng Zhao, Hongmei Du.  (2019)  Synthesis and Electrochromic Properties of Two Random Copolymers Containing Benzotriazole, Benzothiadiazole as Electron Acceptors and Benzodithiophene or Indacenodithiophene as Electron Donors.  International Journal of Electrochemical Science,  14  (6643).  [10.20964/2019.07.23]
2. Lanlan Shen, Zhiru Bai, Yu Jiang, Liying Li, Fengxing Jiang, Jingkun Xu, Huanhuan Qiu, Huixuan Liu, Rongri Tan.  (2020)  Electrosynthesis and Spectroelectrochemistry Properties of Copolymers Based on 3,4-Ethylenedioxythiophene and Quaterthiophenen Derivatives.  International Journal of Electrochemical Science,  15  (8363).  [10.20964/2020.09.73]
3. Shuang Chen, Lingqian Kong, Chaolei Ban, Jinsheng Zhao, Hongmei Du.  (2018)  Synthesis and Characterization of Four Random copolymers Containing Fluorene as Electron Donors and Benzotriazole, Benzothiadiazole, Pyrido[3,4-b]pyrazine as Electron Acceptors.  International Journal of Electrochemical Science,  13  (9964).  [10.20964/2018.10.16]
4. Qiaoqiao Wang, Jingjing Miao, Anran Zhao, Manni Wu, Luqing Pan.  (2022)  Use of GAL4 factor-based yeast assay to quantify the effects of xenobiotics on RXR homodimer and RXR/PPAR heterodimer in scallop Chlamys farreri.  SCIENCE OF THE TOTAL ENVIRONMENT,  852  (158526).  [PMID:36063929] [10.1016/j.scitotenv.2022.158526]
5. Xiaochong Song, Qing Luo, Xiaojia Huang.  (2022)  Speciation of organotin compounds in water and seafood samples by online hyphenation of porous polymer-based magnetism-enhanced in-tube solid phase microextraction and HPLC.  ANALYTICA CHIMICA ACTA,  1223  (340175).  [PMID:35998999] [10.1016/j.aca.2022.340175]
6. Rui Li, Haoran Xu, Yuhang Zhang, Lijing Chang, Yang Ma, Yanjun Hou, Shoulei Miao, Cheng Wang.  (2021)  Electrochromic properties of pyrene conductive polymers modified by chemical polymerization.  RSC Advances,  11  (62): (39291-39305).  [PMID:35492490] [10.1039/D1RA07977H]
7. Yuhang Zhang, Rui Li, Lijing Chang, Yang Ma, Yanjun Hou, Haijun Niu.  (2021)  Electropolymerization of Thiophene-Based Monomers with Different Spatial Structures: The Impact of Monomer Structure on Electrochromic Properties.  MACROMOLECULAR CHEMISTRY AND PHYSICS,  223  (2): (2100341).  [10.1002/macp.202100341]
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12. Zhen Xu, Yuling Zhang, Bozhen Wang, Zhi Liu, Jinsheng Zhao, Yu Xie.  (2019)  Yellow-to-blue switching of indole[3,2-b]carbazole-based electrochromic polymers and the corresponding electrochromic devices with outstanding photopic contrast, fast switching speed, and satisfactory cycling stability.  ELECTROCHIMICA ACTA,  302  (373).  [10.1016/j.electacta.2019.02.054]
13. Yan Zhang, Lingqian Kong, Hongmei Du, Jinsheng Zhao, Yu Xie.  (2018)  Three novel donor-acceptor type electrochromic polymers containing 2,3-bis(5-methylfuran-2-yl)thieno[3,4-b]pyrazine acceptor and different thiophene donors: Low-band-gap, neutral green-colored, fast-switching materials.  JOURNAL OF ELECTROANALYTICAL CHEMISTRY,  830-831  (7).  [10.1016/j.jelechem.2018.10.020]
14. Jianzhong Xu, Qi Ji, Lingqian Kong, Hongmei Du, Xiuping Ju, Jinsheng Zhao.  (2018)  Soluble Electrochromic Polymers Incorporating Benzoselenadiazole and Electron Donor Units (Carbazole or Fluorene): Synthesis and Electronic-Optical Properties.  Polymers,  10  (4): (450).  [PMID:30966485] [10.3390/polym10040450]
15. Shuai Li, Guoliang Liu, Xiuping Ju, Yan Zhang, Jinsheng Zhao.  (2017)  Synthesis, Characterization and Application of Four Novel Electrochromic Materials Employing Nitrotriphenylamine Unit as the Acceptor and Different Thiophene Derivatives as the Donor.  Polymers,  (5): (173).  [PMID:30970853] [10.3390/polym9050173]
16. Zhen Liu, Le Wang, Weiwei Bian, Min Zhang, Jinhua Zhan.  (2017)  Porous silver coating fiber for rapidly screening organotin compounds by solid phase microextraction coupled with surface enhanced Raman spectroscopy.  RSC Advances,  (6): (3117-3124).  [10.1039/C6RA25491H]
17. Yan Zhang, Lingqian Kong, Xuezhong Liu, Chunlei Wang, Jinsheng Zhao.  (2016)  Two New Bithiophenes Derivatives Multielectrochromic Copolymer Based on Triphenylamine Unit and Their Application for Electrochromic Devices.  BULLETIN OF THE KOREAN CHEMICAL SOCIETY,  37  (8): (1234-1243).  [10.1002/bkcs.10844]
18. Shuang Chen, Di Zhang, Min Wang, Lingqian Kong, Jinsheng Zhao.  (2016)  Donor–acceptor type polymers containing the 2,3-bis(2-pyridyl)-5,8-dibromoquinoxaline acceptor and different thiophene donors: electrochemical, spectroelectrochemistry and electrochromic properties.  NEW JOURNAL OF CHEMISTRY,  40  (3): (2178-2188).  [10.1039/C5NJ02651B]
19. Huang Yuanyuan, Yang Qingwei, Song Ling, Ran Hongjie, Jiang Hui, Sun Da.  (2024)  Efficient eradication of organotin utilizing K2FeO4 augmented by nZVI: revelations on influential factors, kinetic dynamics, and mechanistic insights.  Frontiers in Environmental Science,  12  [10.3389/fenvs.2024.1358297]
20. Songlin Wang, Chi Chen, Peng Yang, Yu Guo, Bingxing Wang, Hongying Niu, Qiying Zhang, Jianji Wang.  (2024)  Facile One-Pot Preparation of Organotin-Oxometalate Polymers for Efficient Synthesis of Dimethyl Carbonate from CO2.  INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,  63  (23): (10151-10161).  [10.1021/acs.iecr.4c00937]
21. Yiren Xiong, Guoqiang Guo, Hongyi Xian, Zuqing Hu, Di Ouyang, Jiayi He, Shanshan He, Renyi Liu, Zhenjie Gao, Meilin Tang, Ying Chen, Suqin Tan, Xiaoqi Zhu, Abudumijiti Abulimiti, Sujin Zheng, Hehai Huang, Dalin Hu.  (2024)  MCF-7 cell - derived exosomes were involved in protecting source cells from the damage caused by tributyltin chloride via transport function.  TOXICOLOGY,  505  (153844).  [PMID:38801937] [10.1016/j.tox.2024.153844]
22. Jiao Wang, Zhiyuan Mi, Caihong Lu, Zhenhua Han, Yuxin Wu, Xiaolong Fu, Guofang Zhang.  (2024)  Preparation of carbon nanotube-filled bismuth/tin green nanocomposites and their efficient catalytic activity in the thermal decomposition of ammonium perchlorate.  Surfaces and Interfaces,  45  (103866).  [10.1016/j.surfin.2024.103866]
23. Binhua Mei, Ju Bai, Yuhang Zhang, Yang Ma, Yanjun Hou, Shuhong Wang, Cheng Wang.  (2024)  Synthesis of thienopyrazine- and cyclofluorene–thiophene-based donor–acceptor low-band gap polymers and their application in memory devices.  JOURNAL OF APPLIED POLYMER SCIENCE,  (e55998).  [10.1002/app.55998]

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