三正丁基氢化锡

5篇引用文献

≥97%
含0.05% BHT 稳定剂

CAS编号: 688-73-3
分子式: C₁₂H₂₈Sn
分子量: 291.06
Beilstein号: 3587329
EC号: 211-704-4
MDL号: MFCD00009416
PubChem编号: 3032732

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货号 (SKU)	包装规格	是否现货
T106234-10g	10g	现货
T106234-50g	50g	现货
T106234-250g	250g	现货
T106234-500g	500g	现货

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Organotin Reagents (2) Reducing Agents (21)

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基本描述

别名	三丁基氢化锡 \| 氢化三丁锡 \| 三丁基锡烷
英文别名	T1473 \| A836269 \| DTXSID0040709 \| MFCD00009416 \| Tributlytin \| Tributyltin \| tributyl-tin \| PIILXFBHQILWPS-UHFFFAOYSA-N \| TRIBUTYLTIN HYDRIDE [MI] \| AKOS032949789 \| FT-0636016 \| TBY \| TRIBUTYL TIN \| EINECS 211-704-4 \| GS-6317 \| UNII-4XDX163P3D \| AKOS01590
规格或纯度	≥97%, 含0.05% BHT 稳定剂
英文名称	Tributyltin hydride
储存温度	2-8°C储存,充氩
运输条件	冰袋运输
产品介绍	和水反应，溶于大多数有机溶剂。广泛使用的自由基试剂，可用于还原裂解、自由基脱卤以及分子内自由基环化。 A widely used radical reagent used in reductive cleavage, radical dehalogenation, and intramolecular radical cyclization. Radical promoted intramolecular cyclization leading to isoxazolo-benzaulene ring system. Vinyl tin fragment used in a synthesis of (+)-panepophenanthrin via biomimetic Diels-Alder dimerization. application： Tri-n-butyltin hydride is used as a radical reagent in reductive cleavage, radical dehalogenation and intramolecular radical cyclization. It also promotes intramolecular cyclization leading to isoxazolo-benzaulene ring system. Further, it acts as a reducing agent for the conversion of alkyl halides to hydrocarbons. In addition to this, it is used in a veterinary anthelmintic for poultry and an intermediate to make other butyltin compounds.

名称和识别符

EC号	211-704-4
分子类型	小分子
INCHI	InChI=1S/3C4H9.Sn/c31-3-4-2;/h31,3-4H2,2H3;
InChi Key	PIILXFBHQILWPS-UHFFFAOYSA-N
Canonical SMILES	CCCC[Sn](CCCC)CCCC
Isomeric SMILES	CCCC[Sn](CCCC)CCCC
WGK Germany	3
PubChem CID	3032732
UN Number	2788
Packing Group	III
分子量	291.06
Beilstein号	3587329

化学和物理性质

溶解性	Immiscible with water.
密度	1.11
敏感性	对空气, 湿度和热敏感
折光率	1.473
闪点(℉)	104 °F
闪点(℃)	40℃
沸点	80°C
熔点	0-1℃
分子量	290.050 g/mol
XLogP3
氢键供体数Hydrogen Bond Donor Count	0
氢键受体数Hydrogen Bond Acceptor Count	0
可旋转键计数Rotatable Bond Count	9
精确质量Exact Mass	291.113 Da
单同位素质量Monoisotopic Mass	291.113 Da
拓扑极表面积Topological Polar Surface Area	0.000 Å²
重原子数Heavy Atom Count	13
形式电荷Formal Charge	0
复杂度Complexity	72.100
同位素原子数Isotope Atom Count	0
定义的原子立体中心计数Defined Atom Stereocenter Count	0
未定义的原子立体中心计数Undefined Atom Stereocenter Count	0
定义的键立体中心计数Defined Bond Stereocenter Count	0
未定义的键立体中心计数Undefined Bond Stereocenter Count	0
所有立体化学键的总数The total count of all stereochemical bonds	0
共价键合单元计数Covalently-Bonded Unit Count	1

安全和危险性（GHS）

一般危化品	一般危化品
象形图	GHS06, GHS08, GHS09, GHS02
信号词	Danger
危险声明	H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H301: 吞咽会中毒 H302: 吞食有害 H225: 高度易燃的液体和蒸气 H336: 可能引起嗜睡或头晕 H312: 皮肤接触有害 H226: 易燃液体和蒸气 H410: 对水生生物有剧毒并具有长期持续影响 H372: 通过长时间或反复暴露对器官造成损害 H360: 可能损害生育力或未出生的孩子 H304: 吞咽并进入呼吸道可能致命 H313: 接触皮肤可能有害
预防措施声明	P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P273: 避免释放到环境中。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P301+P310: 如误吞咽：立即呼叫急救中心/医生。 P370+P378: 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P210: 远离热源，热表面，火花，明火和其他点火源。 - 禁止抽烟。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P233: 保持容器密闭。 P240: 地面/粘结容器和接收设备 P264: 处理后要彻底洗手。 P403+P235: 存放在通风良好的地方。保持低温。 P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。 P303+P361+P353: 如皮肤（或头发）沾染：立即脱掉所有沾染的衣服。用水清洗皮肤/淋浴。 P201: 使用前获取特殊说明 P308+P313: 如接触到或有疑虑：求医/就诊。 P241: 使用防爆的[电气/通风/照明/.../]设备。 P270: 使用本产品时，请勿进食、饮水或吸烟。 P337+P313: 如仍觉眼刺激：求医/就诊。 P314: 如果你感到不适，请就医。 P332+P313: 如发生皮肤刺激：求医/就诊。 P391: 收集溢出物 P202: 在阅读并理解所有安全预防措施之前，不要进行操作。 P330: 漱口 P242: 仅使用无火花的工具。 P243: 采取防静电措施
WGK Germany	3
Class	3(6.1)
个人防护装备	Eyeshields， Faceshields， full-face respirator (US)， Gloves， multi-purpose combination respirator cartridge (US)， type ABEK (EN14387) respirator filter

SDS英文版

技术规格说明书

Purity(GC)	97-100（%）
Refractive index n20/D	1.471-1.474
Density (20°C)	1.1-1.106
Appearance（T106234)	Colorless to light yellow liquid
Infrared spectrum	Conforms to Structure
Stabilizer(~0.05% BHT)	Conforms

技术规格说明书

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找到26个结果

批号(Lot Number)	证书类型	日期	货号
I2321322	分析证书	25-06-11	T106234
B2514026	分析证书	24-06-21	T106234
J2417817	分析证书	24-06-21	T106234
J2417809	分析证书	24-06-21	T106234
J2417796	分析证书	24-06-21	T106234
J2417792	分析证书	24-06-21	T106234
D2516078	分析证书	24-06-21	T106234
C2407160	分析证书	24-02-22	T106234
C2407158	分析证书	24-02-22	T106234
C2407159	分析证书	24-02-22	T106234
C2407157	分析证书	24-02-22	T106234
F2523044	分析证书	24-02-22	T106234
A2203108	分析证书	23-10-10	T106234
I2321323	分析证书	23-08-31	T106234
I2321329	分析证书	23-08-31	T106234
C2303013	分析证书	23-02-17	T106234
C23021245	分析证书	23-02-17	T106234
C23021239	分析证书	23-02-17	T106234
H2209727	分析证书	22-07-27	T106234
H2209728	分析证书	22-07-27	T106234
H2209729	分析证书	22-07-27	T106234
H2209730	分析证书	22-07-27	T106234
F2125251	分析证书	21-06-29	T106234
F2125246	分析证书	21-06-29	T106234
F2125245	分析证书	21-06-29	T106234
F2125244	分析证书	21-06-29	T106234

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1. Shanshan Zhu,Futao Hu,Ting Yang,Ning Gan,Daodong Pan,Yuting Cao,Dazhen Wu. (2013-02-19) Synthesis and characterization of a molecularly imprinted polymer for the determination of trace tributyltin in seawater and seafood by liquid chromatography-tandem mass spectroscopy.. Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 921-922 (21-26). [PMID:23416291]
2. Zhe Xu, Wang Yin, Yong Guan, Meidong Lang. (2023) The “De−Re Polymerization” Strategy: From Nondegradable Pet to Degradable Peat. MACROMOLECULAR CHEMISTRY AND PHYSICS, (29): (2300149). [PMID:10439047] [10.1002/macp.202300149]
3. Enjie He, Kai Tu, Jiannan Cheng, Huanjun Lu, Lifen Zhang, Zhenping Cheng, Xiulin Zhu. (2021) Multimesophase transitions of main-chain liquid crystalline copolymers with strictly alternating fluorocarbon chains. Polymer Chemistry, 12 (5): (736-743). [10.1039/D0PY01644F]
4. Changchao Jia, Ping Yang, Hsueh-Shih Chen, Junpeng Wang. (2015) Template-free synthesis of mesoporous anatase titania hollow spheres and their enhanced photocatalysis. CRYSTENGCOMM, 17 (15): (2940-2948). [10.1039/C4CE02358G]
5. Peng Liu, Jiexing Liang, Shen Chen, Hailiang Zhang. (2014) Bulk and solution properties of a thermo-responsive rod–coil block polymer based on poly(N-isopropylacrylamide). RSC Advances, 4 (90): (49028-49039). [10.1039/C4RA07179D]

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溶液计算器

摩尔浓度计算器

计算溶液所需的质量、体积或浓度。

质量

浓度

体积

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g/mol

稀释计算器

计算配制储备溶液所需的稀释度。

浓度1（C1）

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浓度 2 (C2)

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复溶计算器

复溶计算器允许您快速计算试剂的体积，以复溶小瓶。只需输入试剂的质量和目标浓度，计算器将确定其余部分。

体积（添加到小瓶中）

质量（小瓶）

所需的复溶浓度