CAS(16872-11-0),氟硼酸,四氟硼酸 | 氢氟硼酸 | CHEBI:38902 | Fluoboric acid, 48% | fluorboric acid | MFCD00011345 | HBF4 | Borate(1-), tetrafluoro-, hydrogen | Fluoboric acid (H(BF4)) | CAS-16872-11-0 | H429WZ9FBQ | AKOS015971394

概述规格名称和识别符技术文档高级数据系统学分类三维结构质检证书（CoA,COO,BSE/TSE 和分析图谱) 化学和物理性质安全和危险性（GHS）此产品的引用文献技术文档和文章引用文献溶液计算器常见问题

🧪

为什么选择此级别

，适用于对基线干扰要求严格的色谱和分析工作流程。

🌡

储存与运输

室温。DG运输。请查阅批次 COA 获取详细规格。

📋

质量文档

SDS、COA、产品数据表及规格说明书均可下载。可通过批号查询获取批次 COA。

📚

文献证明

在色谱分析、有机合成和交叉偶联反应领域已被 65 篇同行评审文献引用。

概述

呈强酸性，有毒，能与水及醇混和，对皮肤和粘膜有强腐蚀性，并能刺激眼和呼吸道。常温下不腐蚀玻璃，但其浓溶液不能长期贮存于玻璃瓶中。制备稳定的重氮盐类，制造缩醛催化，在镁离子和钾离子存在下测定钠的试剂有机合成的催化剂，还用于海棉钛及其合金的--溶解和印刷线路板工业。

Tetrafluoroboric acid is used as a catalyst for the protection and deprotection reactions of various carbohydrates. It participates in the synthesis of 4-sulfonic acid phenyl diazonium tetrafluoroborate, which was required for the preparation of sulfonated graphene (SG).
Tetrafluoroboric acid solution may be used as a catalyst for the hydration of aromatic haloalkynes to α-halomethyl ketones in the absence of metal catalysts. It may also be used the epoxidized soybean oil (ESBO) ring opening step of fatty acids preparation.

规格

别名

四氟硼酸 | 氢氟硼酸

英文别名

规格或纯度

50 wt. % in H2O

英文名称

Tetrafluoroboric acid

应用

制备稳定的重氮盐类，制造缩醛催化，在镁离子和钾离子存在下测定钠的试剂有机合成的催化剂，还用于海棉钛及其合金的--溶解和印刷线路板工业。

储存条件

室温

运输条件

DG运输

名称和识别符

PubChem SID

504753378

EC号

240-898-3

分子类型

小分子

IUPAC Name

hydron;tetrafluoroborate

INCHI

1S/BF4/c2-1(3,4)5/q-1/p+1

InChi Key

ODGCEQLVLXJUCC-UHFFFAOYSA-O

Smiles

[H+].[B-](F)(F)(F)F

Isomeric SMILES

[H+].[B-](F)(F)(F)F

UN Number

1775

Packing Group

分子量

87.81

Reaxy-Rn

11548281

Reaxys-RN link address

https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=11548281&ln=

技术文档

📋 安全数据表 (SDS)

全面的危险、操作、储存及法规合规文件。

下载 SDS →

✅ 分析证书 (COA)

批次质量数据。输入批号以获取对应 COA。

查询 COA →

📊 产品数据表

产品规格和应用的快速参考摘要。

查看数据表 →

🔬 规格说明书

该级别的完整质量属性和验收标准。

查看规格说明 →

高级数据

系统学分类

分类树（Taxonomy Tree）

界（kingdom) 无机化合物
- 超类（Superclass) 混合金属/非金属化合物
  - 类（Class) 准金属盐
    - 亚类（Subclass）类金属氟化物

界（kingdom)	无机化合物
超类（Superclass)	混合金属/非金属化合物
类（Class)	准金属盐
亚类（Subclass）	类金属氟化物
中间层级节点（Intermediate Tree Nodes）	暂无
直接上位类(Direct Parent)	类金属氟化物
其他上位类（Alternative Parents）	无机盐
分子骨架（Molecular Framework)	暂无
取代基（Substituents）	无机盐 - 类金属氟化物
描述（Description）	该化合物属于无机化合物中的类金属氟化物。这类无机化合物中，最大的卤素原子为氟，而最重的金属原子为类金属。
外部描述符（External Descriptors）	boron fluoride

三维结构

交互式化学结构模型

球棍
棍棒
线框模型
空间填充
显示氢气
动画

化学和物理性质

溶解性

Miscible with water.

密度

1.4

沸点

130°C

熔点

-90°C

分子量

87.820 g/mol

XLogP3

氢键供体数Hydrogen Bond Donor Count

氢键受体数Hydrogen Bond Acceptor Count

可旋转键计数Rotatable Bond Count

精确质量Exact Mass

88.0107 Da

单同位素质量Monoisotopic Mass

88.0107 Da

拓扑极表面积Topological Polar Surface Area

0.000 Å²

重原子数Heavy Atom Count

形式电荷Formal Charge

复杂度Complexity

19.100

同位素原子数Isotope Atom Count

定义的原子立体中心计数Defined Atom Stereocenter Count

未定义的原子立体中心计数Undefined Atom Stereocenter Count

定义的键立体中心计数Defined Bond Stereocenter Count

未定义的键立体中心计数Undefined Bond Stereocenter Count

所有立体化学键的总数The total count of all stereochemical bonds

共价键合单元计数Covalently-Bonded Unit Count

安全和危险性（GHS）

一般危化品

象形图

GHS05

信号词

危险

危险声明

H314: 造成严重的皮肤灼伤和眼睛损伤

预防措施声明

P264: 处理后要彻底洗手。

P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。

P310: 立即致电解毒中心或医生。

P363: 再次使用之前，请清洗受污染的衣物。

P301+P330+P331: 如误吞咽：漱口。不要诱导呕吐。

P303+P361+P353: 如皮肤（或头发）沾染：立即脱掉所有沾染的衣服。用水清洗皮肤/淋浴。

P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。

P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。

P405: 密闭存放

P501: 将内容物/容器处理到。。。

WGK Germany

Class

个人防护装备

Faceshields,full-face respirator (US),Gloves,Goggles,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter

质检证书（CoA,COO,BSE/TSE 和分析图谱)

C of A & Other Certificates(BSE/TSE, COO):

输入批号以搜索分析图谱:

通过匹配包装上的批号来查找并下载产品的 COA，每批产品都进行了严格的验证，您可放心使用！

找到52个结果

批号(Lot Number)	证书类型	货号
I2609260	分析证书	T110577
I2609259	分析证书	T110577
I2609258	分析证书	T110577
I2609256	分析证书	T110577
C2630525	分析证书	T110577
C2630530	分析证书	T110577
C2630551	分析证书	T110577
C2630585	分析证书	T110577
I2518513	分析证书	T110577
I2518512	分析证书	T110577
I2518511	分析证书	T110577
I2518429	分析证书	T110577
L2509123	分析证书	T110577
A2507443	分析证书	T110577
A2507444	分析证书	T110577
A2507457	分析证书	T110577
A2507458	分析证书	T110577
L2405539	分析证书	T110577
L2405549	分析证书	T110577
L2405547	分析证书	T110577
L2405548	分析证书	T110577
K2412682	分析证书	T110577
K2412683	分析证书	T110577
J2423157	分析证书	T110577
J2422832	分析证书	T110577
L2413733	分析证书	T110577
L2413721	分析证书	T110577
D2402475	分析证书	T110577
J2418147	分析证书	T110577
D2402476	分析证书	T110577
D2402474	分析证书	T110577
J2313521	分析证书	T110577
J2313522	分析证书	T110577
I2305514	分析证书	T110577
I2305513	分析证书	T110577
I2305512	分析证书	T110577
I2305515	分析证书	T110577
C23241425	分析证书	T110577
H2304164	分析证书	T110577
C23241438	分析证书	T110577
C23241439	分析证书	T110577
C23241442	分析证书	T110577
J2211067	分析证书	T110577
K2222389	分析证书	T110577
K2222385	分析证书	T110577
J2211070	分析证书	T110577
J2211069	分析证书	T110577
J2211066	分析证书	T110577
F2225480	分析证书	T110577
F2225478	分析证书	T110577
F2225477	分析证书	T110577
F2225466	分析证书	T110577

显示更多⌵

技术文档和文章

无机酸怎么选：用 pH 与“生成盐去向”把除垢、除锈和表面处理做可控（附表1–表3）

目录：技术文章

探索主题:

酸无机酸

How to Choose Inorganic Acids: Making Descaling, Derusting, and Surface Treatment Controllable via pH and the “Fate of the Salts Formed” (with Tables 1–3)

目录：技术文章

探索主题:

Acids Inorganic Acids

含间氟吡啶基序为什么难做？从 Balz–Schiemann 风险看稳定烯胺砌块的合成逻辑

目录：技术文章

探索主题:

药物化学卤素

Why Is the meta-Fluoropyridine Motif Difficult to Make? Understanding the Synthetic Logic of Stable Enamine Building Blocks from the Risks of the Balz–Schiemann Reaction

目录：技术文章

探索主题:

Field of synthetic chemistry Halogen Bond Medicinal Chemistry

此产品的引用文献

如何在您的发表作品中引用阿拉丁的产品和网站? 引用文献检索

引用文献

1. Yangfeng Xia, Changbo Lu, Yaohui Wang, Jinmao Chen, Wanli Xu, Gaojun An, Yanqiang Zhang. (2023) Brønsted ionic liquids as catalysts for synthesis of 2-pyrazoline derivatives from ketazines: A combined experimental and theoretical approach. JOURNAL OF MOLECULAR STRUCTURE, [10.1016/j.molstruc.2023.137065]
2. Wei Chen, Zewen Wu, Xingyang He, Ying Su, Sang-Keun Oh, Shaolin Zhang. (2023) Mussel-bionic composite coatings based on biomass polyurethane and its adhesive mechanisms of humid interface with cementitious materials. PROGRESS IN ORGANIC COATINGS, [10.1016/j.porgcoat.2023.108001]
3. Di-Ming Chen, Xue-Jing Zhang. (2023) Immobilization of open O-donor sites within a double-walled metal-organic framework for efficient C2H2/CO2 separation. JOURNAL OF MOLECULAR STRUCTURE, [10.1016/j.molstruc.2023.136560]
4. Tong Su, Meiqiao Wei, Hanqing Liu, Yunshan Fang, Qiong Wu, Zhehui Weng, Jie Ling, Renjie Chen, Yulan Wang, Xiusha Zhao, Haidong Ju. (2023) Two Purely Inorganic Cationic Tellurite Materials Based on Group IB Metal Tetrafluoroborates with Similar Lamellar Cationic Layers: [Cu2F(Te2O5)](BF4) and [Ag18O2(Te4O9)4(Te3O8)(BF4)2]·2HBF4. INORGANIC CHEMISTRY, [PMID:37314892] [10.1021/acs.inorgchem.3c00856]
5. Mutailipu Miriding, Han Jian, Li Zhi, Li Fuming, Li Junjie, Zhang Fangfang, Long Xifa, Yang Zhihua, Pan Shilie. (2023) Achieving the full-wavelength phase-matching for efficient nonlinear optical frequency conversion in C(NH2)3BF4. Nature Photonics, 17 (8): (694-701). [10.1038/s41566-023-01228-7]
6. Peng Cai, Hefeng Zhang, Yifu Huang. (2023) A facile strategy to achieve room-temperature organic long afterglow from melt processible, new two-dimensional polyamide doped γ-polyamide 6. POLYMERS FOR ADVANCED TECHNOLOGIES, 34 (7): (2312-2321). [10.1002/pat.6052]
7. Cun Gao, Xiao-Bing Mu, Wen-Yu Yuan, Peng Zhang, Ying Wang, Quan-Guo Zhai. (2023) Construction of new multi-cage-based MOFs using flexible triangular ligands for efficient gas adsorption and separation. JOURNAL OF SOLID STATE CHEMISTRY, [10.1016/j.jssc.2023.123994]
8. Tuohetijiang Baiheti, Abudukadi Tudi, Minqiang Gai, Xuping Wang, Shujuan Han. (2023) Na2BaB12O18F4: A Mixed Alkali/Alkaline-Earth Metal Fluorooxoborate with Two Unprecedented Interpenetrating Three-Dimensional B–O/F Anionic Networks and a Short Ultraviolet Cutoff Edge. INORGANIC CHEMISTRY, [PMID:36926852] [10.1021/acs.inorgchem.3c00203]
9. Danxia Lin, Shi Tu, Liang Yu, Yinuo Yuan, Ying Wu, Xin Zhou, Zhong Li, Qibin Xia. (2023) Highly Efficient Separation of CH4/C2H6/C3H8 from Natural Gas on a Novel Copper-Based Metal–Organic Framework. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, [10.1021/acs.iecr.2c04286]
10. Wei Chen, Zewen Wu, Yuxuan Xie, Xingyang He, Ying Su, Yiliang Qin, Dingding Tang, Sang-Keun Oh. (2023) Fabrication of silane and nano-silica composite modified Bio-based WPU and its interfacial bonding mechanism with cementitious materials. CONSTRUCTION AND BUILDING MATERIALS, [10.1016/j.conbuildmat.2023.130819]
11. Guangjian Liao, Fuming Mei, Zhuqi Chen, Guochuan Yin. (2022) Lewis acid improved dioxygen activation by a non-heme iron(II) complex towards tryptophan 2,3-dioxygenase activity for olefin oxygenation. DALTON TRANSACTIONS, 51 (47): (18024-18032). [PMID:36373374] [10.1039/D2DT02769K]
12. Wen-Feng Zhou, Yi-Min Wei, Zhi-Wei Xiao, Yan Jiang, Yan-Kai Zhang, Zhen-Wei Zhang, Hui Hu, Longlong Geng, Da-Shuai Zhang, Yong-Zheng Zhang, Xiuling Zhang, Shujuan Zhuang. (2022) Construction of a dual-cage-based MOF with uncoordinated nitrogen sites for CO2 adsorption and fixation. JOURNAL OF SOLID STATE CHEMISTRY, [10.1016/j.jssc.2022.123699]
13. S. Zhang, Q. Yang, T. Wang, S. Li, X. Lv, J. Su, J. Chen, S. Ni, Y. Lai, J. Zhan. (2022) On-demand fabrication of porous silver nanostructures by chloride ions inspired galvanic replacement reaction. Materials Today Chemistry, [10.1016/j.mtchem.2022.100995]
14. Xin Qi, Yu Guo, Qianlin Chen, Xiaohan Zhao, Xianquan Ao. (2021) Preparation and performance of a kitchen waste oil-modified polyvinyl alcohol-grafted urea slow-release fertilizer. JOURNAL OF APPLIED POLYMER SCIENCE, 139 (2): (51484). [10.1002/app.51484]
15. Xue Shuqing, Wu Guanhong, Li Mingzhong, Liu Zihan, Deng Yuwei, Han Wenqian, Lv Xuanyu, Wan Siyu, Xi Xiangyun, Yang Dong, Dong Angang. (2021) Generalized assembly of sandwich-like 0D/2D/0D heterostructures with highly exposed surfaces toward superior electrochemical performances. Nano Research, 15 (1): (255-263). [10.1007/s12274-021-3468-y]
16. Hao-Jing Ding, Ying Zhang, Xi Wang, Qiu-Ying Lin, Shu-Ming Zhang, Mei-Hui Yu, Ze Chang, Xian-He Bu. (2021) Defective Hierarchical Pore Engineering of a Zn–Ni MOF by Labile Coordination Bonding Modulation. INORGANIC CHEMISTRY, [PMID:33769042] [10.1021/acs.inorgchem.1c00164]
17. Guangxu Bo, Xiaoling Xu, Xiaoke Tian, Jiao Wu, Xin He, Li Xu, Yunjun Yan. (2021) Synthesis and characterization of flame-retardant rigid polyurethane foams derived from gutter oil biodiesel. EUROPEAN POLYMER JOURNAL, [10.1016/j.eurpolymj.2021.110329]
18. Xuyang Chen, Yu Wei, Wenxuan Sun, Xiangfen Meng, Shengjie Hao, Yan Gao. (2020) Turning off hydrogen evolution via an organic dye photosensitizer in aqueous acetonitrile solution during photocatalytic CO2 reduction to CO. Molecular Catalysis, [10.1016/j.mcat.2020.111299]
19. Daofei Lv, Zewei Liu, Feng Xu, Houxiao Wu, Wenbing Yuan, Jian Yan, Hongxia Xi, Xin Chen, Qibin Xia. (2020) A Ni-based metal-organic framework with super-high C3H8 uptake for adsorptive separation of light alkanes. SEPARATION AND PURIFICATION TECHNOLOGY, [10.1016/j.seppur.2020.118198]
20. Chenyang Wei, Zhengping Liu, Hongwei Tan, Liyan Huang, Jun Li. (2020) A non-metal route to realize the bio-based polyester of poly(hexylene succinate): preparation conditions, side-reactions and mechanism in sulfonic acid-functionalized Brønsted acidic ionic liquids. RSC Advances, 10 (58): (35381-35388). [PMID:35515662] [10.1039/D0RA07157A]
21. Haoran Song, Yuwei Wang, Zheng Ling, Daoyuan Zu, Zhuo Li, Yongming Shen, Changping Li. (2020) Enhanced photocatalytic degradation of perfluorooctanoic acid by Ti3C2 MXene-derived heterojunction photocatalyst: Application of intercalation strategy in DESs. SCIENCE OF THE TOTAL ENVIRONMENT, [PMID:32758985] [10.1016/j.scitotenv.2020.141009]
22. Xiu Chen, Haidong Li, Linzhou Zhang, Quan Shi, Suoqi Zhao, Chunming Xu. (2020) Direct sulfur-containing compounds analysis in petroleum via (+) ESI FT-ICR MS using HBF4 as ionization promoter. FUEL, [10.1016/j.fuel.2020.118334]
23. Minqiang Gai, Tinghao Tong, Ying Wang, Zhihua Yang, Shilie Pan. (2020) New Alkaline-Earth Metal Fluoroiodates Exhibiting Large Birefringence and Short Ultraviolet Cutoff Edge with Highly Polarizable (IO3F)2– Units. CHEMISTRY OF MATERIALS, [10.1021/acs.chemmater.0c01452]
24. Anlian Zhu, Wanlu Feng, Zhiyong Li, Shuang Cheng, Qianhan Chen, Dongshuang Fan, Yuanyang Guo, Lingjun Li, Jianji Wang. (2020) Cleaner enzymatic production of biodiesel with easy separation procedures triggered by a biocompatible hydrophilic ionic liquid. GREEN CHEMISTRY, 22 (6): (1944-1951). [10.1039/C9GC03796A]
25. Yeyun Meng, Peng Lv, Qi Liu, Bing Liao, Hao Pang, Weiqu Liu. (2019) Preparation and characterization of soybean oil-based waterborne polyurethane/acrylate hybrid emulsions for self-matting coatings. NEW JOURNAL OF CHEMISTRY, 43 (48): (19193-19199). [10.1039/C9NJ04538D]
26. Ruoqian Zhang, Yuanyuan Liu, Jiajia Wang, Zeyan Wang, Peng Wang, Zhaoke Zheng, Xiaoyan Qin, Xiaoyang Zhang, Ying Dai, Baibiao Huang. (2019) Post-synthetic platinum complex modification of a triazine based metal organic frameworks for enhanced photocatalytic H2 evolution. JOURNAL OF SOLID STATE CHEMISTRY, [10.1016/j.jssc.2019.01.006]
27. Hengjun Gai, Lin Qiao, Caiyun Zhong, Xiaowei Zhang, Meng Xiao, Hongbing Song. (2018) Designing Ionic Liquids with Dual Lewis Basic Sites to Efficiently Separate Phenolic Compounds from Low-Temperature Coal Tar. ACS Sustainable Chemistry & Engineering, [10.1021/acssuschemeng.8b02119]
28. Han Dandan, Yan Yancui, Wei Jishi, Wang Biwei, Li Tongtao, Guo Guannan, Yang Dong, Xie Songhai, Dong Angang. (2017) Fine-Tuning the Wall Thickness of Ordered Mesoporous Graphene by Exploiting Ligand Exchange of Colloidal Nanocrystals. Frontiers in Chemistry, [PMID:29322042] [10.3389/fchem.2017.00117]
29. Jianjun Du, Hong Du, Xiangyu Li, Jiangli Fan, Xiaojun Peng. (2017) In-situ colorimetric recognition of arylamine based on chemodosimeter-functionalized gold nanoparticle. SENSORS AND ACTUATORS B-CHEMICAL, [10.1016/j.snb.2017.03.067]
30. Cong Li, Tingting Zhang, Jingyu Zhao, He Liu, Bo Zheng, Yue Gu, Xiaoyi Yan, Yaru Li, Nannan Lu, Zhiquan Zhang, Guodong Feng. (2017) Boosted Sensor Performance by Surface Modification of Bifunctional rht-Type Metal–Organic Framework with Nanosized Electrochemically Reduced Graphene Oxide. ACS Applied Materials & Interfaces, [PMID:28030766] [10.1021/acsami.6b13788]
31. Duan-Jian Tao, Yan Dong, Zhi-Jun Cao, Feng-Feng Chen, Xiang-Shu Chen, Kuan Huang. (2016) Tuning the acidity of sulfonic functionalized ionic liquids for highly efficient and selective synthesis of terpene esters. JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, [10.1016/j.jiec.2016.07.014]
32. Pengcheng Hu, Rui Zhang, Zhichang Liu, Haiyan Liu, Chunming Xu, Xianghai Meng, Meng Liang, Shuangshuang Liang. (2015) Absorption Performance and Mechanism of CO2 in Aqueous Solutions of Amine-Based Ionic Liquids. ENERGY & FUELS, [10.1021/acs.energyfuels.5b01062]
33. Ya Fu, Jiaan Wu, Hongan Zhou, Guanping Jin. (2015) Removal of nickel(II) from aqueous solutions using iminodiacetic acid functionalized polyglycidyl methacrylate grafted-carbon fibers. CHINESE JOURNAL OF CHEMICAL ENGINEERING, [10.1016/j.cjche.2013.08.004]
34. Hui Hu, Fang Li, Qi Xia, Xiaodan Li, Li Liao, Maohong Fan. (2014) Research on influencing factors and mechanism of CO2 absorption by poly-amino-based ionic liquids. International Journal of Greenhouse Gas Control, [10.1016/j.ijggc.2014.09.021]
35. Kaisheng Yao, Weiwei Lu, Xinying Li, Jianji Wang. (2014) Tailoring the properties of aqueous–ionic liquid interfaces for tunable synthesis and self-assembly of ZnS nanoparticles. Journal of Materials Chemistry A, 2 (14): (5140-5148). [10.1039/C3TA15006B]
36. Qiaohong Peng, Khalid Mahmood, Ying Wu, Leli Wang, Yanyan Liang, Jianan Shen, Zhengping Liu. (2014) A facile route to realize the copolymerization of L-lactic acid and ε-caprolactone: sulfonic acid-functionalized Brønsted acidic ionic liquids as both solvents and catalysts. GREEN CHEMISTRY, 16 (4): (2234-2241). [10.1039/C3GC42477D]
37. Kaisheng Yao, Weiwei Lu, Xinying Li, Jianji Wang. (2012) Ionic liquids-modulated two-phase thermal synthesis of three-dimensional CuS nanostructures. JOURNAL OF SOLID STATE CHEMISTRY, [10.1016/j.jssc.2012.07.023]
38. Xiaoyu Mu, Li Qi, Haizhi Zhang, Ying Shen, Juan Qiao, Huimin Ma. (2012) Ionic liquids with amino acids as cations: Novel chiral ligands in chiral ligand-exchange capillary electrophoresis. TALANTA, [PMID:22841091] [10.1016/j.talanta.2012.04.044]
39. Di-Ming Chen, Han-Dong Qiao, Meng-Yao Sun, Shao-Ming Fang. (2024) A polyhedron-based metal-organic framework with electronegative donor sites for efficient C2H6/C2H4 separation. JOURNAL OF MOLECULAR STRUCTURE, [10.1016/j.molstruc.2024.140166]
40. Rou-Yu Li, Wenyu Yuan, Shuo Wang, Peng Zhang, Heng Wu, Yi-Min Su, En-Lei Wen, Xiaolin Zhu, Quan-Guo Zhai. (2024) Controllable Regulation of CO2 Adsorption Behavior via Precise Charge Donation Modulation for Highly Selective CO2 Electroreduction to Formic Acid. Small, [PMID:39449203] [10.1002/smll.202408351]
41. Wang Hui-Hui, Yin He-Liang, Yin Wei-Wei, Song Yong-Li, Chen Hong. (2024) Cu(II)-based complex loaded with drug paclitaxel hydrogels against thyroid cancer and optimizing novel derivatives. Scientific Reports, 14 (1): (1-12). [PMID:38844812] [10.1038/s41598-024-63940-w]
42. Di-Ming Chen, Han-Dong Qiao, Pei-Feng Wang, Zi-Jun Zhao, Shao-Ming Fang. (2025) Experimental and computational study on a dual structural cage-based Ni-MOF for efficient C2H2/CO2 separation. JOURNAL OF MOLECULAR STRUCTURE, [10.1016/j.molstruc.2025.142042]
43. Lina Jiang, Yanan Ding, Aimei Zhu, Qiugen Zhang, Qinglin Liu. (2024) High permeance of polyamide nanofiltration membranes with porous organic polymers interlayers based on diazo coupling reaction. JOURNAL OF MEMBRANE SCIENCE, [10.1016/j.memsci.2024.123344]
44. Qiu Xiong, Xiaofeng Huang, Can Wang, Qin Zhou, Yong Gang, Tinghao Li, Chongzhu Hu, Ni Zhang, Xiaobing Wang, Jihuai Wu, Zhenhuang Su, Xingyu Gao, Xin Li, Nanfeng Zheng, Peng Gao. (2024) Managed spatial strain uniformity for efficient perovskite photovoltaics enables minimized energy deficit. Joule, [10.1016/j.joule.2024.01.016]
45. Hao Yuan, Hanxiang Guo, Zhaosheng Huang, Ping Zhang, Zhe Wang, Chunde Jin. (2025) Synthesis of multifunctional polyurethane wood coating from epoxidized soybean oil and CO2-based polyol. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, [10.1016/j.colsurfa.2025.136162]
46. Yinhui Zhang, Wenshuo Zhang, Junjie Deng, Yuye Zhong, Pingping Zhao, Houbin Li, Tao Zhang. (2024) Synthesis of waste soybean oil-based waterborne polyurethane for exploration of its green and various application. INDUSTRIAL CROPS AND PRODUCTS, [10.1016/j.indcrop.2024.118733]
47. Lei Yutian, Yin Mengying, Shi Chang, Wu Lingxi, Peng Guoqiang, Xu Youkui, Wang Haoxu, Tang Rongbing, Li ZhenHua, Jin Zhiwen. (2024) Tailored molecular for ultra-stability and biocompatible pseudohalide metal-free perovskite towards X-ray detectors with record sensitivity. npj Flexible Electronics, 8 (1): (1-10). [10.1038/s41528-024-00330-2]
48. Kang Wang, Yao Jiang, Mingming Xu, Dongdong Zheng, Shaojun Jia, Peng Cui. (2024) Tailoring a MOF-based adsorbent with partitioned aliphatic pore spaces for efficient CH4 purification from natural gas. AICHE JOURNAL, 70 (7): (e18443). [10.1002/aic.18443]
49. Muhammad Arif, Xu Liu, Zijian Li, Hangwei Jia, Yansheng Jiang, Zhihua Yang, Xueling Hou, Shilie Pan. (2024) Unveiling Charge Dependent Law to Enhance Birefringence in 2-Aminopyrimidine Family. Advanced Optical Materials, [10.1002/adom.202402327]
50. Rui-Li Yu, Qian-Fan Li, Zhen-Le Li, Xiao-Yu Wang, Liang-Zhi Xia. (2023) Analysis of Radioactive Iodine Trapping Mechanism by Zinc-Based Metal–Organic Frameworks with Various N-Containing Carboxylate Ligands. ACS Applied Materials & Interfaces, [PMID:37458304] [10.1021/acsami.3c07032]
51. Xiaoxing Lu, Zhizhuo Lu, Rong Zhang, Lijiang Zhao, Hujun Xie. (2021) Distribution of pigments in the aqueous two-phase system formed with piperazinium-based ionic liquid and anionic surfactant. JOURNAL OF MOLECULAR LIQUIDS, [10.1016/j.molliq.2021.115677]
52. Shaohua Liu, Li-Li Zhang, Ke Li, Xiaotian Ma, Xifa Long, Yun Yang. (2025) Coordinated assembly of alkali and alkaline earth metals with perfluorinated [AlF6] group to design deep-ultraviolet zero-order waveplate materials. DALTON TRANSACTIONS, [PMID:40208202] [10.1039/D5DT00356C]
53. Meiling Li, ShanShan Mao, Xin Zhou, Hao Wang. (2024) One-step purification of ethylene from ethane/ethylene mixtures by a stable vanadium-based metal-organic framework. SEPARATION AND PURIFICATION TECHNOLOGY, [10.1016/j.seppur.2024.131049]
54. Qianqian Peng, Chengxuan Zhou, Shucan Qin, Jinbiao Liang, Shengyun Xu, Jiaming Mao, Jianming Shi, Yanrong Liu, Yunqian Ma. (2025) Efficient capture and conversion of H2S into H2 and sulfur in guanidinium ionic liquid–NaOH aqueous solution. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, [PMID:40843547] [10.1039/D5CP01911G]
55. Yaoguo Shen, Jiajia Xiong, Mengqing Wu, Mengcai Li, Yingwu Zhou, Yanjie Zhang. (2025) Enhancing Birefringence via a Planar-Conformation-Locking Strategy. Laser & Photonics Reviews, [10.1002/lpor.202501545]
56. Long Yao, Guixuan Shan, Abrar Laiba, Yu Zhao, Yujiao Zhang, Ru’an Chi, Bingwen Long, Wei Li, Jinli Zhang. (2025) Fluoride species conversion-enhanced selective extraction: A green and safe strategy for fluorine recovery in wet-process phosphoric acid production. Journal of Environmental Chemical Engineering, [10.1016/j.jece.2025.119345]
57. Xinbin Liu, Juangang Zhao, Tiansheng Li, Zhengbing Meng, Jinbiao Qing, Wen Xu, Youxuan Ouyang, Yuanyuan Zeng. (2025) Effects of WC Addition on Microstructure and Properties of Plasma-Cladded AlCoCrFeNi High-Entropy Alloy Coatings. Lubricants, 13 (9): (407). [10.3390/lubricants13090407]
58. Hong-Juan Lv, Yunhui Zhai, Ying-Ying Xue, Jiao Lei, Wenyu Yuan, Quan-Guo Zhai. (2025) Distortable functionalized ligand implantation in ultra-microporous MOFs for efficient C2H2 purification. Inorganic Chemistry Frontiers, 12 (12): (4007-4018). [10.1039/D5QI00475F]
59. Mu-Lan Yao, Si-Lu Wang, Si-Mian Liu, Xiao Wang, Ji-Jiang Wang, Xiang-Yang Hou. (2025) MOFs-based dual-emission stable fluorescent/colorimetric probe for efficient identification and screening of trace Hg2+, In3+, Zr4+. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, [PMID:41115404] [10.1016/j.saa.2025.127068]
60. Zhipeng Luo, Peng Cai, Wenhui Chen, Jiaxing Chen, Silong Cai, Haochen Huang, Zixin Liu, Hefeng Zhang, Yifu Huang. (2025) Ultra-Low Doping of Frozen/Thawed Polyvinyl Alcohol Ionogels With Benzimidazole-Linked 2D Polymer Nanosheets for Enhanced Photoluminescence. JOURNAL OF APPLIED POLYMER SCIENCE, [10.1002/app.58091]
61. Yuan Li, Lei Tang, Xiaomin Li, Xiaoqing Wang, Qi Shi, Jiangfeng Yang, Jinping Li. (2025) Synergistic adsorption sites within a novel zeolitic imidazolate framework for low-concentration CH4 enrichment. CHEMICAL ENGINEERING JOURNAL, [10.1016/j.cej.2025.171264]
62. Xue Bai, Li-Ping Liu, Yi-Fei Xu, Yu Sun, Wan-Hong Sun, Zhe-Peng Deng, Yin-Xia Sun, Li Xu. (2025) Synergy between interface-induced dual active sites ZIF-67@Co-TCTB for enhanced visible-light photocatalytic nitrogen fixation. APPLIED SURFACE SCIENCE, [10.1016/j.apsusc.2025.165545]
63. Di-Ming Chen, Xue-Jing Zhang, Dong-Ying Shi, Lin Han. (2025) A bifunctional ligand-based metal-organic framework with rich aromatic pores and open O donor sites for selective C2H6/C2H4 separation. JOURNAL OF MOLECULAR STRUCTURE, [10.1016/j.molstruc.2025.145095]
64. Wei Chen, Zhirui Zhu, Xingyang He, Ying Su, Chao Yang, Zihao Jin, Huahui Qi, Cong Tian, Zewen Wu, Shiyu Guan, Dakun Tang. (2025) Enhanced wet Interface bonding and protective properties of dopamine and PDA@MXene composite modified biomass polyurethane coatings. PROGRESS IN ORGANIC COATINGS, [10.1016/j.porgcoat.2025.109759]
65. Yuqi Zhang, Yuan Yao, Peihao Dou, Qing Cheng, Yanqiang Zhang. (2026) Catalytic ignition of the [BMIM]DCA-H2O2 propellant with the Cu(vim)2(DCA)2 complex. RSC Advances, 16 (18): (16748-16755). [10.1039/D6RA00294C]