MeCpPtMe3 is a commonly used organometallic precursor for platinum.
MeCpPtMe3 was used for the deposition of ultrathin metallic layers of platinum by electron beam induced deposition, atomic sputtering.These deposits find application in microelectronics, catalysis, photonics and chemical sensing.
Application
MeCpPtMe3
is a homogeneous catalyst useful for hydrosilylation reactions.
Storage and Stability
Do not store above 4°C (39°F). Store in a tightly closed original container under dry inert gas protected from direct sunlight in a dry, cool and well-ventilated area.
Product class
M-C, Homogeneous Catalysts, Electronic Materials, PGM based Electronic Materials, Alkyl Ligands, Arene/Aryl Ligands
Reaction type
Hydrosilylation, Oxidation
Chemical properties
Theoretical metal content
Applications & references
Platinum nanoparticles are formed by gas phase loading of the volatile platinum compounds on metal-organic frameworks and by subsequent reduction with 100 bar hydrogen. For instance, the Pt component shows high catalytic activity in solvent-free and base-free oxidation of alcohols in air at room temperature.
Reference: Chem. Eur. J. 2008, 14, 8204 (DOI: 10.1002/chem.200801043)
Trimethyl(methylcyclopentadienyl)platinum(IV) as an effective photoinitiator for hydrosilylation reactions.
Reference: Inorg. Chem. 2004, 43, 6869 (DOI: 10.1021/ic0496222)
Trimethyl(methylcyclopentadienyl)platinum(IV) is often used as ALD and CVD precursor.
Reference: WO2010 033318 ; Electrochimica Acta 2012, 75, 101 (10.1016/j.electacta.2012.04.084)
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