基本描述

别名	亚乙基双(三乙氧基硅烷) \| 4,4,7,7-四乙氧基-3,8-二氧杂-4,7-disiladecane \| 1,2-双(三乙氧基硅烷)乙烷 \| 双苯基磷酸乙烯(三乙氧基硅烷), 1,2-(三乙氧基硅烷)乙烷
英文别名	Ethylenebis(triethoxysilane) \| 4,4,7,7-Tetraethoxy-3,8-dioxa-4,7-disiladecane \| 1,2-Bis(triethoxysilyl)ethane \| 1,2-(Triethoxysilyl)ethane
规格或纯度	≥96%
英文名称	1,2-Bis(triethoxysilyl)ethane
储存温度	充氩
运输条件	常规运输
产品介绍	1,2-二(三乙氧基硅基)乙烷是一种非官能化硅烷，也是一种双三烷氧基甲硅烷基前体。 1,2-双(三乙氧基硅基)乙烷(BTESE)是一种硅氧烷前驱体，主要用于制备介孔有机材料。它可以调整二氧化硅网络，适合分子分离相关的应用。应用 1,2-双(三乙氧基硅基)乙烷可用于制备介孔有机硅材料。介孔二氧化硅的胺功能化可以由这种硅烷完成。它可以与聚(乙烯醇)形成无机杂化膜。已经研究了该交联硅烷对双-GMA（双酚-A-二缩水甘油基二甲基丙烯酸酯）树脂与硅化钛键合的影响。 BTESE可作为铝镁合金(Al93Mg7)的防腐涂层，在核和食品加工业具有潜在应用。BTESE膜耐氯，100℃下热稳定。可用于气体渗透(GS)和反渗透(RO)应用。还可以通过溶胶-凝胶缩合法与四甲氧基硅烷形成具有增强化学稳定性的肽分离介孔杂化整体。 1,2-Bis(triethoxysilyl)ethane (BTESE) is a silsesquioxane precursor which is mainly used in the preparation of mesoporous organic materials. It can tune silica networks which makes them useful in applications related to molecular separation. 1,2-bis(triethoxysilyl)ethane is a non-functional silane and a double trialkoxysilyl precursor.

AI解读

名称和识别符

PubChem SID	488186308
EC号	240-212-2
IUPAC Name	triethoxy(2-triethoxysilylethyl)silane
INCHI	InChI=1S/C14H34O6Si2/c1-7-15-21(16-8-2,17-9-3)13-14-22(18-10-4,19-11-5)20-12-6/h7-14H2,1-6H3
InChi Key	IZRJPHXTEXTLHY-UHFFFAOYSA-N
Canonical SMILES	CCO[Si](CC[Si](OCC)(OCC)OCC)(OCC)OCC
Isomeric SMILES	CCO[Si](CC[Si](OCC)(OCC)OCC)(OCC)OCC
WGK Germany	3
RTECS	JG7755000
PubChem CID	85266
分子量	354.59

化学和物理性质

溶解性	Soluble in alcohol, aromatic and aliphatic hydrocarbons. Hydrolyzes with water.
密度	0.958
敏感性	易吸潮
折光率	1.41
比旋光度	1.41
闪点(℉)	235.4 °F
闪点(℃)	113 °C
沸点	119 °C
分子量	354.590 g/mol
XLogP3
氢键供体数Hydrogen Bond Donor Count	0
氢键受体数Hydrogen Bond Acceptor Count	6
可旋转键计数Rotatable Bond Count	15
精确质量Exact Mass	354.189 Da
单同位素质量Monoisotopic Mass	354.189 Da
拓扑极表面积Topological Polar Surface Area	55.400 Å²
重原子数Heavy Atom Count	22
形式电荷Formal Charge	0
复杂度Complexity	208.000
同位素原子数Isotope Atom Count	0
定义的原子立体中心计数Defined Atom Stereocenter Count	0
未定义的原子立体中心计数Undefined Atom Stereocenter Count	0
定义的键立体中心计数Defined Bond Stereocenter Count	0
未定义的键立体中心计数Undefined Bond Stereocenter Count	0
所有立体化学键的总数The total count of all stereochemical bonds	0
共价键合单元计数Covalently-Bonded Unit Count	1

安全和危险性（GHS）

象形图	GHS06, GHS08, GHS05, GHS07
信号词	Danger
危险声明	H315: 引起皮肤刺激 H335: 可能引起呼吸道刺激 H301: 吞咽会中毒 H412: 对水生生物有害并具有长期持续影响 H318: 造成严重的眼睛损伤 H312: 皮肤接触有害 H372: 通过长时间或反复暴露对器官造成损害
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WGK Germany	3
RTECS	JG7755000
个人防护装备	Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

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1. Wei Wang, Jiaru Zhougu, Chunlai Liu, Na Wang, Songlin Shi, Zelong Liu, Peihang Shen, Fengwei Shi, Jianglei Hu. (2024) Facile synthesis of H3PW12O40-functionalized organosilicon nanotubes using singlemicelle templates: High catalytic activity for biodiesel methyl oleate. FUEL, 361 (130693). [10.1016/j.fuel.2023.130693]
2. Huaying Zhong, Yi Zhang, Yangmin Gong, Chuyun Wan, Yufei Zhang, Mingming Zheng. (2023) Ultraviolet/Visible Light-Responsive Pickering Interfacial Biocatalysis: Efficient and Robust Platform for Bioconversions. ACS Sustainable Chemistry & Engineering, [10.1021/acssuschemeng.3c05438]
3. Shichun Gu, Ruyi Wang, Junxiong Zhang, Hairong Dong, Liping Deng, Xue Wang, Yapeng He. (2024) One-step synthesis of hollow and yolk-shell mesoporous organosilica nanospheres for efficient separation of lead ions. MICROPOROUS AND MESOPOROUS MATERIALS, 364 (112884). [PMID:17984221] [10.1016/j.micromeso.2023.112884]
4. Cuicui Wu, Pan Feng, Xuan Guo, Yunming Fang. (2023) Purification of artemisinin precursor amorphadiene from microbial metabolites containing isomeride farnesene: Solid-Pd chemocatalysis of farnesene to squalene with high boiling point. CATALYSIS COMMUNICATIONS, 183 (15): (106770). [PMID:16393996] [10.1016/j.catcom.2023.106770]
5. Jia Tan, Binbin Ding, Hao Chen, Qi Meng, Jing Li, Chunzheng Yang, Wenying Zhang, Xinyang Li, Di Han, Pan Zheng, Ping'an Ma, Jun Lin. (2023) Effects of Skeleton Structure of Mesoporous Silica Nanoadjuvants on Cancer Immunotherapy. Small, (2305567). [PMID:37702141] [10.1002/smll.202305567]
6. Bei Liu, Kaijun Quan, Xiaoming Yang, Jia Chen, Hongdeng Qiu. (2023) Clickable periodic mesoporous organosilicas core-shell particles with radially-oriented mesopores for high-performance liquid chromatography. MICROPOROUS AND MESOPOROUS MATERIALS, 362 (112785). [10.1016/j.micromeso.2023.112785]
7. Daohong Chen, Suxin Zhou, Yixin Kuang, Jiajia Han, Yalan Hu, Yuefan Liu, Juan Zheng, Gangfeng Ouyang. (2023) Etched hollow periodic mesoporous organosilica with enlarged pore size for high-performance solid phase microextraction of polybrominated biphenyls. MICROCHEMICAL JOURNAL, 191 (108841). [10.1016/j.microc.2023.108841]
8. Yang Ling, Yan Peng, Shiyou Guan. (2023) Facile Synthesis of SiOx/C Composite with Homogeneous Distribution of SiOx and Carbon as Anodes for Superior Lithium-Ion Batteries. ChemistrySelect, 8 (16): (e202300233). [10.1002/slct.202300233]
9. Yan Gao, Yu Chen, Cuiying Wang, Aiping Yin, Hailong Li, Jianshe Zhao. (2023) Polyoxometalates Encapsulated into Hollow Periodic Mesoporous Organosilica as Nanoreactors for Extraction Oxidation Desulfurization. Catalysts, 13 (4): (747). [10.3390/catal13040747]
10. Feng Gao, Zheming Tong, Weiqiang Xiao, Quan Liu, Jianguo Lu, Yang Hou, Qinggang He, Xiang Gao, Dangguo Cheng, Xiaoli Zhan, Yaoguang Ma, Qinghua Zhang. (2023) Structural Engineering of Hierarchical Aerogels Hybrid Networks for Efficient Thermal Comfort Management and Versatile Protection. Small, 19 (25): (2301164). [PMID:36919943] [10.1002/smll.202301164]
11. Wu Hongdan, Liu Xiaodi, Yang Xiaoyu, Hu Chuanzhi, Zhou Zhihui. (2023) Pervaporation performance of BTESE/TEOS-derived organosilica membrane and its stability in isopropanol aqueous solutions. KOREAN JOURNAL OF CHEMICAL ENGINEERING, 40 (1): (195-204). [10.1007/s11814-022-1245-6]
12. Tao Yang, Yufei Zhang, Liujia Xu, Hao Zhu, Juntao Zhang, Zheng Guo, Fenghong Huang, Mingming Zheng. (2022) pH-Switchable Pickering Interfacial Biocatalysis: One-Pot Enzymatic Synthesis of Phytosterol Esters with Low-Value Rice Bran Oil. ACS Sustainable Chemistry & Engineering, 10 (21): (6963–6972). [10.1021/acssuschemeng.1c08719]
13. Ze-Yu Liu, Xiao-Yue Tang, Chuan-Qing Huang, Jin Zhang, Wen-Qian Huang, Yong Ye. (2022) 808 nm NIR-triggered Camellia sapogein/curcumin-based antibacterial upconversion nanoparticles for synergistic photodynamic-chemical combined therapy. Inorganic Chemistry Frontiers, 9 (8): (1836-1846). [10.1039/D1QI01569A]
14. Yang Wu, Guiyun Deng, Zhiyong Song, Kai Zhang, Jiamin Deng, Kai Jiang, Heyou Han. (2022) Enhancing antibacterial immunotherapy for bacterial pneumonia via nanovaccines coated with outer membrane vesicles. CHEMICAL ENGINEERING JOURNAL, 436 (135040). [10.1016/j.cej.2022.135040]
15. Yin Hu, Yongyuan Ren, Rongwei Shi, Jiangtao Yu, Zhe Sun, Siyu Guo, Jiangna Guo, Feng Yan. (2021) Robust and High-Temperature-Resistant Nanofiber Membrane Separators for Li–Metal, Li–Sulfur, and Aqueous Li-Ion Batteries. ACS Applied Materials & Interfaces, 13 (14): (16289–16299). [PMID:33784815] [10.1021/acsami.1c00207]
16. Sun Yangyi, Mao Yijing, Zhang Chengyu, Di Ningyu, Qi Dongming, Shentu Baoqing. (2021) Thermodynamics and kinetics of Cu2+ adsorption of organic-inorganic hybrid hollow mesoporous silica spheres. JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 98 (2): (310-318). [10.1007/s10971-020-05459-w]
17. Chao Wang, Guolong Sang, Yedong Rong, Boran Zhang, Yi Zhao, Jinlong Yang. (2021) Unexpected phenomenon in a conventional system: synthesis of raspberry-like hollow periodic mesoporous organosilica with controlled structure in one continuous step. NEW JOURNAL OF CHEMISTRY, 45 (15): (6651-6660). [10.1039/D0NJ05917J]
18. Yalei Miao, Yecheng Feng, Jie Bai, Zhongyi Liu, Xubo Zhao. (2021) Optimized mesoporous silica nanoparticle-based drug delivery system with removable manganese oxide gatekeeper for controlled delivery of doxorubicin. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 592 (227). [PMID:33662827] [10.1016/j.jcis.2021.02.054]
19. Tianyao Li, Fei He, Bin Liu, Tao Jia, Boyang Shao, Ruoxi Zhao, Hui Zhu, Dan Yang, Shili Gai, Piaoping Yang. (2020) In Situ Synthesis of FeOCl in Hollow Dendritic Mesoporous Organosilicon for Ascorbic Acid-Enhanced and MR Imaging-Guided Chemodynamic Therapy in Neutral pH Conditions. ACS Applied Materials & Interfaces, 12 (51): (56886–56897). [PMID:33290033] [10.1021/acsami.0c19330]
20. Yue Wei, Gang Li, Cong Wang, Hongchen Guo. (2021) Integrated fast-mass transfer and high Ti-sites utilization into hybrid amphiphilic TS@PMO catalyst towards efficient solvent-free methyl oleate epoxidation. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 586 (233). [PMID:33176930] [10.1016/j.jcis.2020.10.087]
21. Yangyi Sun, Yijing Mao, Ningyu Di, Xiaolong Chen, Dongming Qi, Baoqing Shentu. (2020) Core-template-free synthesis of molecularly ethane-bridged hollow mesoporous silica spheres from acid-hydrolyzed precursor. NEW JOURNAL OF CHEMISTRY, 44 (33): (13997-14004). [10.1039/D0NJ01221A]
22. Wang Hongning, Yang Qinqin, Zhang Zhihui, Song Fujiao, Zhong Jing, Huang Weiqiu, Chen Ruoyu. (2020) Organosiliceous nanotubes with enhanced hydrophobicity and VOCs adsorption performance under dry and humid conditions. JOURNAL OF POROUS MATERIALS, 27 (4): (1179-1190). [10.1007/s10934-020-00891-3]
23. Bao Shidong, Li Ye, Fei Zhengfu, Mei Heng, Zhou Yuzhi, Wang Xiaoli, Liu Dongxue. (2020) Effective adsorption of uranium(VI) from aqueous solution using ethylene-bridged mesoporous silica functionalized with ureido groups. JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 324 (1): (385-394). [10.1007/s10967-020-07063-2]
24. Kun Zeng, Li Ma, Wenxiu Yang, Shan Lei, Mozhen Wang, Yezi You, Yu Zhao, Xuewu Ge. (2020) Biodegradable nano-organosilica gene carrier for high-efficiency gene transfection. Journal of Materials Chemistry B, 8 (12): (2483-2494). [PMID:32110782] [10.1039/D0TB00108B]
25. Xiaoxiao Wang, Lizhu Chen, Zhaogang Teng, Zhi-Fei Wang. (2019) Facile Method To Efficiently Fabricate Large-Size Mesoporous Organosilica Nanosheets with Uniform Tunable Pore Size for Robust Separation Membranes. CHEMISTRY OF MATERIALS, 31 (10): (3823–3830). [10.1021/acs.chemmater.9b01102]
26. Yanjun Jiang, Huan Liu, Lihui Wang, Liya Zhou, Zhihong Huang, Li Ma, Ying He, Lujing Shi, Jing Gao. (2019) Virus-like organosilica nanoparticles for lipase immobilization: Characterization and biocatalytic applications. BIOCHEMICAL ENGINEERING JOURNAL, 144 (125). [10.1016/j.bej.2019.01.022]
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28. Yuan Gao, Kunmei Su, Zhenhuan Li, Bowen Cheng. (2018) Graphene oxide hybrid poly(p-phenylene sulfide) nanofiltration membrane intercalated by bis(triethoxysilyl) ethane. CHEMICAL ENGINEERING JOURNAL, 352 (10). [10.1016/j.cej.2018.06.180]
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参考文献

1. Wei Wang, Jiaru Zhougu, Chunlai Liu, Na Wang, Songlin Shi, Zelong Liu, Peihang Shen, Fengwei Shi, Jianglei Hu. (2024) Facile synthesis of H3PW12O40-functionalized organosilicon nanotubes using singlemicelle templates: High catalytic activity for biodiesel methyl oleate. FUEL, 361 (130693). [10.1016/j.fuel.2023.130693]
2. Huaying Zhong, Yi Zhang, Yangmin Gong, Chuyun Wan, Yufei Zhang, Mingming Zheng. (2023) Ultraviolet/Visible Light-Responsive Pickering Interfacial Biocatalysis: Efficient and Robust Platform for Bioconversions. ACS Sustainable Chemistry & Engineering, [10.1021/acssuschemeng.3c05438]
3. Shichun Gu, Ruyi Wang, Junxiong Zhang, Hairong Dong, Liping Deng, Xue Wang, Yapeng He. (2024) One-step synthesis of hollow and yolk-shell mesoporous organosilica nanospheres for efficient separation of lead ions. MICROPOROUS AND MESOPOROUS MATERIALS, 364 (112884). [PMID:17984221] [10.1016/j.micromeso.2023.112884]
4. Cuicui Wu, Pan Feng, Xuan Guo, Yunming Fang. (2023) Purification of artemisinin precursor amorphadiene from microbial metabolites containing isomeride farnesene: Solid-Pd chemocatalysis of farnesene to squalene with high boiling point. CATALYSIS COMMUNICATIONS, 183 (15): (106770). [PMID:16393996] [10.1016/j.catcom.2023.106770]
5. Jia Tan, Binbin Ding, Hao Chen, Qi Meng, Jing Li, Chunzheng Yang, Wenying Zhang, Xinyang Li, Di Han, Pan Zheng, Ping'an Ma, Jun Lin. (2023) Effects of Skeleton Structure of Mesoporous Silica Nanoadjuvants on Cancer Immunotherapy. Small, (2305567). [PMID:37702141] [10.1002/smll.202305567]
6. Bei Liu, Kaijun Quan, Xiaoming Yang, Jia Chen, Hongdeng Qiu. (2023) Clickable periodic mesoporous organosilicas core-shell particles with radially-oriented mesopores for high-performance liquid chromatography. MICROPOROUS AND MESOPOROUS MATERIALS, 362 (112785). [10.1016/j.micromeso.2023.112785]
7. Daohong Chen, Suxin Zhou, Yixin Kuang, Jiajia Han, Yalan Hu, Yuefan Liu, Juan Zheng, Gangfeng Ouyang. (2023) Etched hollow periodic mesoporous organosilica with enlarged pore size for high-performance solid phase microextraction of polybrominated biphenyls. MICROCHEMICAL JOURNAL, 191 (108841). [10.1016/j.microc.2023.108841]
8. Yang Ling, Yan Peng, Shiyou Guan. (2023) Facile Synthesis of SiOx/C Composite with Homogeneous Distribution of SiOx and Carbon as Anodes for Superior Lithium-Ion Batteries. ChemistrySelect, 8 (16): (e202300233). [10.1002/slct.202300233]
9. Yan Gao, Yu Chen, Cuiying Wang, Aiping Yin, Hailong Li, Jianshe Zhao. (2023) Polyoxometalates Encapsulated into Hollow Periodic Mesoporous Organosilica as Nanoreactors for Extraction Oxidation Desulfurization. Catalysts, 13 (4): (747). [10.3390/catal13040747]
10. Feng Gao, Zheming Tong, Weiqiang Xiao, Quan Liu, Jianguo Lu, Yang Hou, Qinggang He, Xiang Gao, Dangguo Cheng, Xiaoli Zhan, Yaoguang Ma, Qinghua Zhang. (2023) Structural Engineering of Hierarchical Aerogels Hybrid Networks for Efficient Thermal Comfort Management and Versatile Protection. Small, 19 (25): (2301164). [PMID:36919943] [10.1002/smll.202301164]
11. Wu Hongdan, Liu Xiaodi, Yang Xiaoyu, Hu Chuanzhi, Zhou Zhihui. (2023) Pervaporation performance of BTESE/TEOS-derived organosilica membrane and its stability in isopropanol aqueous solutions. KOREAN JOURNAL OF CHEMICAL ENGINEERING, 40 (1): (195-204). [10.1007/s11814-022-1245-6]
12. Tao Yang, Yufei Zhang, Liujia Xu, Hao Zhu, Juntao Zhang, Zheng Guo, Fenghong Huang, Mingming Zheng. (2022) pH-Switchable Pickering Interfacial Biocatalysis: One-Pot Enzymatic Synthesis of Phytosterol Esters with Low-Value Rice Bran Oil. ACS Sustainable Chemistry & Engineering, 10 (21): (6963–6972). [10.1021/acssuschemeng.1c08719]
13. Ze-Yu Liu, Xiao-Yue Tang, Chuan-Qing Huang, Jin Zhang, Wen-Qian Huang, Yong Ye. (2022) 808 nm NIR-triggered Camellia sapogein/curcumin-based antibacterial upconversion nanoparticles for synergistic photodynamic-chemical combined therapy. Inorganic Chemistry Frontiers, 9 (8): (1836-1846). [10.1039/D1QI01569A]
14. Yang Wu, Guiyun Deng, Zhiyong Song, Kai Zhang, Jiamin Deng, Kai Jiang, Heyou Han. (2022) Enhancing antibacterial immunotherapy for bacterial pneumonia via nanovaccines coated with outer membrane vesicles. CHEMICAL ENGINEERING JOURNAL, 436 (135040). [10.1016/j.cej.2022.135040]
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