L-(-)樟脑磺酸

1篇引用文献

≥99%

CAS编号: 35963-20-3
分子式: C₁₀H₁₆O₄S
分子量: 232.3
Beilstein号: 2809676
EC号: 252-817-9
MDL号: MFCD00064158
PubChem编号: 5771688
PubChem SID: 504763967

有货

库存信息

关闭

库存信息

关闭

库存信息

关闭

库存信息

关闭

库存信息

关闭

库存信息

关闭

货号 (SKU)	包装规格	是否现货
C100499-5g	5g	现货
C100499-25g	25g	现货
C100499-100g	100g	现货
C100499-250g	250g	现货
C100499-500g	500g	现货
C100499-2.5kg	2.5kg	期货

查看相关系列

不对称合成 (592) 手性非杂环砌块 (285)

Skip to the end of the images gallery

Skip to the beginning of the images gallery

基本描述

别名	(-)-樟脑-10-磺酸, (1R)-(-)-樟脑-10-磺酸, (1R)-樟脑-10-磺酸 \| (-)-10-樟脑磺酸 \| 樟脑磺酸
英文别名	((1R,4S)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonic acid \| Camphorsulfonic acid, (-)- \| (-)-camphorsulfonic acid \| L(-)-Camphorsulfonic acid \| (-)-10-Camphorsulfonic Acid \| (1R)-(-)-Camphor-10-sulfonic acid \| (1R)-(-)-10-Camphorsulfonic
规格或纯度	≥99%
英文名称	(1R)-(-)-10-Camphorsulfonic acid
应用	有机合成中间体，拆分剂。
储存温度	充氩
运输条件	常规运输
产品介绍	不溶于醚，微溶于冰醋酸、乙酸乙酯，在潮湿的空气中易潮解。 (1R)-(-)-10-樟脑磺酸是一种用于紫外/可见检测的高效液相色谱衍生试剂。它主要用于基底的解析。 (1R)-(-)-10-樟脑磺酸可作为手性构件用于通过对映选择性碳芳基化合成五价有机铋衍生物。基于光学活性聚苯胺膜的电位传感器可以将它作为手性单体用于手性氨基酸的对映选择性传感。应用 (1R)-(−)-10-樟脑磺酸可作为合成砌块，用于通过对映选择性C-芳基化反应合成5价有机铋衍生物。它可作为手性单体，用于基于光学活性聚苯胺薄膜的电位传感器介导的手性氨基酸的对映选择性感应。 Insoluble in ether, slightly soluble in glacial acetic acid and ethyl acetate, and easily deliquescent in humid air. (1R)-(−)-10-Camphorsulfonic acid is an HPLC derivatization reagent for UV/Vis detection. It is mainly employed for the resolution of bases. (1R)-(−)-10-Camphorsulfonic acid may be used as a chiral building block for the synthesis of pentavalent organo-bismuth derivatives by enantioselective C-arylation. It may be used as a chiral monomer in the enantioselective sensing of chiral amino acids by potentiometric sensors based on optical active polyaniline films.

AI解读

名称和识别符

PubChem SID	504763967
EC号	252-817-9
IUPAC Name	[(1R,4S)-7,7-dimethyl-2-oxo-1-bicyclo[2.2.1]heptanyl]methanesulfonic acid
INCHI	InChI=1S/C10H16O4S/c1-9(2)7-3-4-10(9,8(11)5-7)6-15(12,13)14/h7H,3-6H2,1-2H3,(H,12,13,14)/t7-,10-/m0/s1
InChi Key	MIOPJNTWMNEORI-XVKPBYJWSA-N
Canonical SMILES	CC1(C2CCC1(C(=O)C2)CS(=O)(=O)O)C
Isomeric SMILES	CC1([C@H]2CC[C@@]1(C(=O)C2)CS(=O)(=O)O)C
WGK Germany	3
PubChem CID	5771688
UN Number	3261
分子量	232.3
Beilstein号	2809676
Reaxy-Rn	2809676

化学和物理性质

溶解性	Soluble in water, and a wide variety of organic substances.
密度	1.331
敏感性	对湿度敏感
比旋光度	-21.5 ° (C=5, H2O)
熔点	198°C
分子量	232.300 g/mol
XLogP3	0.500
氢键供体数Hydrogen Bond Donor Count	1
氢键受体数Hydrogen Bond Acceptor Count	4
可旋转键计数Rotatable Bond Count	2
精确质量Exact Mass	232.077 Da
单同位素质量Monoisotopic Mass	232.077 Da
拓扑极表面积Topological Polar Surface Area	79.800 Å²
重原子数Heavy Atom Count	15
形式电荷Formal Charge	0
复杂度Complexity	404.000
同位素原子数Isotope Atom Count	0
定义的原子立体中心计数Defined Atom Stereocenter Count	2
未定义的原子立体中心计数Undefined Atom Stereocenter Count	0
定义的键立体中心计数Defined Bond Stereocenter Count	0
未定义的键立体中心计数Undefined Bond Stereocenter Count	0
所有立体化学键的总数The total count of all stereochemical bonds	0
共价键合单元计数Covalently-Bonded Unit Count	1

安全和危险性（GHS）

象形图	GHS05
信号词	Danger
危险声明	H314: 造成严重的皮肤灼伤和眼睛损伤 H318: 造成严重的眼睛损伤
预防措施声明	P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P321: 特殊处理（请参阅此标签上的...）。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P264: 处理后要彻底洗手。 P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。 P301+P330+P331: 如误吞咽：漱口。不要诱导呕吐。 P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。 P363: 再次使用之前，请清洗受污染的衣物。 P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。 P305+P354+P338: 如果进入眼睛：立即用水冲洗几分钟。取下隐形眼镜（如果有的话），并且操作简单。继续冲洗。 P317: 寻求紧急医疗救助。 P302+P361+P354: 如果接触皮肤：立即脱掉所有被污染的衣服。立即用水冲洗几分钟。 P316: 立即寻求紧急医疗救助。
WGK Germany	3
Reaxy-Rn	2809676
个人防护装备	Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

技术规格说明书

Purity(Neutralization titration)	98.5-101.5（%）
Specific Rotation [a]20/D(c=5 in H2O)	-23--20（°）
Appearance（C100499)	white to light brown to beige powder crystal solid
Proton NMR spectrum	Conforms to Structure
Solubility in H2O	Almost transparency

技术规格说明书

质检证书（CoA,COO,BSE/TSE 和分析图谱)

C of A & Other Certificates(BSE/TSE, COO):

输入批号以搜索分析图谱:

通过匹配包装上的批号来查找并下载产品的 COA，每批产品都进行了严格的验证，您可放心使用！

找到18个结果

批号(Lot Number)	证书类型	日期	货号
G2402169	分析证书	24-06-20	C100499
G2402166	分析证书	24-06-20	C100499
G2402165	分析证书	24-06-20	C100499
G2402164	分析证书	24-06-20	C100499
G2402163	分析证书	24-06-20	C100499
G2402161	分析证书	24-06-20	C100499
G2402162	分析证书	24-06-20	C100499
D2424127	分析证书	24-03-12	C100499
D2416176	分析证书	24-03-11	C100499
G2412107	分析证书	24-03-11	C100499
D2424128	分析证书	24-03-11	C100499
F2010021	分析证书	24-03-06	C100499
B2215133	分析证书	21-12-15	C100499
B2506093	分析证书	21-12-15	C100499
B2215151	分析证书	21-12-15	C100499
B2215150	分析证书	21-12-15	C100499
B2215141	分析证书	21-12-15	C100499
B2215134	分析证书	21-12-15	C100499

显示更多⌵

可替换产品

此产品的引用文献

如何在您的发表作品中引用阿拉丁的产品和网站?

1. Zhiyi Huang, Huan Wang, Jiahao Du, Xiaochun Liu, Guoyi Pan, Xingshan Yin, Wenjing Lin, Xiaofeng Lin, Yingjuan Sun, Guobin Yi, Li Niu. (2023) High-strength, self-reinforcing and recyclable multifunctional lignin-based polyurethanes based on multi-level dynamic cross-linking. CHEMICAL ENGINEERING JOURNAL, 473 (145423). [10.1016/j.cej.2023.145423]

参考文献

1. C Pierron,J M Panas,M F Etcheverry,G Ledouble. (1990-07-06) Determination of 10-camphorsulphonates in pharmaceutical formulations by high-performance liquid chromatography.. Journal of chromatography, 511 (367-372). [PMID:2211919]
2. X R Xu,Q M Tang,Y H Yao. (1987-03-01) [D-camphor-beta-sulfonic acid as an ion-pair reagent for the determination of biogenic amines and their metabolites in the rat brain by reverse phase high performance liquid chromatography].. Zhongguo yao li xue bao = Acta pharmacologica Sinica, 8 ((2)): (113-117). [PMID:2958994]
3. J A Nakhosteen,J Vieira. (1983-03-31) [The expectorant Solucampher: effect on the tracheal clearing velocity in chronic bronchitis].. ZFA. Zeitschrift fur Allgemeinmedizin, 59 ((9)): (36-38). [PMID:6858351]
4. Per J Garegg,Karl-Jonas Johansson,Peter Konradsson,Bengt Lindberg,Zygmunt Trumpakaj. (2002-03-14) Transglucosidation of methyl and ethyl D-glucopyranosides by alcoholysis.. Carbohydrate research, 337 ((6)): (517-521). [PMID:11890889]
5. G Li,M Huang,G Yang,G Wu,A Du,Y Su. (2003-01-29) [The enantiomeric separation of aromatic alcohol amino drugs by thin-layer chromatography].. Se pu = Chinese journal of chromatography, 17 ((2)): (215-216). [PMID:12549175]
6. Anne-Catherine Servais,Marianne Fillet,Patrice Chiap,Walthère Dewé,Philippe Hubert,Jacques Crommen. (2004-09-08) Enantiomeric separation of basic compounds using heptakis(2,3-di-O-methyl-6-O-sulfo)-beta-cyclodextrin in combination with potassium camphorsulfonate in nonaqueous capillary electrophoresis: optimization by means of an experimental design.. Electrophoresis, 25 ((16)): (2701-2710). [PMID:15352001]
7. Andrew J Miles,Frank Wien,B A Wallace. (2004-11-24) Redetermination of the extinction coefficient of camphor-10-sulfonic acid, a calibration standard for circular dichroism spectroscopy.. Analytical biochemistry, 335 ((2)): (338-339). [PMID:15556575]
8. A Bielejewska,K Duszczyk,J Zukowski. (2005-08-05) Effect of (+) or (-) camphorsulfonic acid additives to the mobile phase on enantioseparations of some basic drugs on a Chiralcel OD column.. Journal of chromatography. A, 1083 ((1-2)): (133-140). [PMID:16078699]
9. Alexei V Caramyshev,Vladimir M Lobachov,Daniel V Selivanov,Eugene V Sheval,Andrei Kh Vorobiev,Olesja N Katasova,Vladimir Y Polyakov,Alexander A Makarov,Ivan Yu Sakharov. (2007-07-17) Micellar peroxidase-catalyzed synthesis of chiral polyaniline.. Biomacromolecules, 8 ((8)): (2549-2555). [PMID:17630690]
10. Kaoru Nobuoka,Satoshi Kitaoka,Masashi Iio,Thomas Harran,Yuichi Ishikawa. (2007-11-09) Solute-solvent interactions in imidazolium camphorsulfonate ionic liquids.. Physical chemistry chemical physics : PCCP, 9 ((44)): (5891-5896). [PMID:17989797]
11. Bala Kishan Gorityala,Shuting Cai,Jimei Ma,Xue-Wei Liu. (2009-04-29) (S)-Camphorsulfonic acid catalyzed highly stereoselective synthesis of pseudoglycosides.. Bioorganic & medicinal chemistry letters, 19 ((11)): (3093-3095). [PMID:19398332]
12. A Kumar,Somik Banerjee,Jyoti P Saikia,B K Konwar. (2010-04-02) Swift heavy ion irradiation induced enhancement in the antioxidant activity and biocompatibility of polyaniline nanofibers.. Nanotechnology, 21 ((17)): (175102-175102). [PMID:20357408]
13. Chen Liu,Yixin Lu. (2010-04-24) Primary amine/(+)-CSA salt-promoted organocatalytic conjugate addition of nitro esters to enones.. Organic letters, 12 ((10)): (2278-2281). [PMID:20411973]
14. Szu Heng Liu,Yi Hung Lin,Liang Jen Huang,Shiang Wen Luo,Wan Lin Tsai,Su Yu Chiang,Hok Sum Fung. (2010-10-27) Design and construction of a compact end-station at NSRRC for circular-dichroism spectra in the vacuum-ultraviolet region.. Journal of synchrotron radiation, 17 ((6)): (761-768). [PMID:20975221]
15. Yimin Hua,Shai Dagan,Samanthi Wickramasekara,Dylan J Boday,Vicki H Wysocki. (2010-11-03) Analysis of deprotonated acids with silicon nanoparticle-assisted laser desorption/ ionization mass spectrometry.. Journal of mass spectrometry : JMS, 45 ((12)): (1394-1401). [PMID:21038364]
16. Suh-Jen Jane Tsai,Yao-Shen Zhong,Jen-Feng Weng,Hsiu-Hua Huang,Pei-Yin Hsieh. (2010-12-24) Determination of bile acids in pig liver, pig kidney and bovine liver by gas chromatography-chemical ionization tandem mass spectrometry with total ion chromatograms and extraction ion chromatograms.. Journal of chromatography. A, 1218 ((3)): (524-533). [PMID:21176836]
17. Chen Liu,Qiang Zhu,Kuo-Wei Huang,Yixin Lu. (2011-04-23) Primary amine/CSA ion pair: a powerful catalytic system for the asymmetric enamine catalysis.. Organic letters, 13 ((10)): (2638-2641). [PMID:21510614]
18. Nidhin Paul,Muthuchamy Murugavel,Shanmugam Muthusubramanian,Dharmarajan Sriram. (2012-01-27) Camphorsulfonic acid catalysed facile tandem double Friedlander annulation protocol for the synthesis of phenoxy linked bisquinoline derivatives and discovery of antitubercular agents.. Bioorganic & medicinal chemistry letters, 22 ((4)): (1643-1648). [PMID:22277278]
19. Ruizhi Pang,Kaisong Zhang. (2017-09-25) Fabrication of hydrophobic fluorinated silica-polyamide thin film nanocomposite reverse osmosis membranes with dramatically improved salt rejection.. Journal of colloid and interface science, 510 (127-132). [PMID:28942162]
20. Katarzyna Jankowska,Jakub Zdarta,Adam Grzywaczyk,Ewa Kijeńska-Gawrońska,Andrzej Biadasz,Teofil Jesionowski. (2020-03-11) Electrospun poly(methyl methacrylate)/polyaniline fibres as a support for laccase immobilisation and use in dye decolourisation.. Environmental research, 184 (109332-109332). [PMID:32151845]
21. Soyoung Noh,Hye Yeon Gong,Hyun Jong Lee,Won-Gun Koh. (2021-01-14) Electrically Conductive Micropatterned Polyaniline-Poly(ethylene glycol) Composite Hydrogel.. Materials (Basel, Switzerland), 14 ((2)): [PMID:33435614]
22. Zhiyi Huang, Huan Wang, Jiahao Du, Xiaochun Liu, Guoyi Pan, Xingshan Yin, Wenjing Lin, Xiaofeng Lin, Yingjuan Sun, Guobin Yi, Li Niu. (2023) High-strength, self-reinforcing and recyclable multifunctional lignin-based polyurethanes based on multi-level dynamic cross-linking. CHEMICAL ENGINEERING JOURNAL, 473 (145423). [10.1016/j.cej.2023.145423]

溶液计算器

摩尔浓度计算器

计算溶液所需的质量、体积或浓度。

质量

浓度

体积

分子量

g/mol

稀释计算器

计算配制储备溶液所需的稀释度。

浓度1（C1）

体积 1 (V1)

浓度 2 (C2)

体积 2 (V2)

复溶计算器

复溶计算器允许您快速计算试剂的体积，以复溶小瓶。只需输入试剂的质量和目标浓度，计算器将确定其余部分。

体积（添加到小瓶中）

质量（小瓶）

所需的复溶浓度

L-(-)樟脑磺酸

库存信息

库存信息

库存信息

库存信息

库存信息

库存信息

基本描述

AI解读

名称和识别符

化学和物理性质

安全和危险性（GHS）

技术规格说明书

质检证书（CoA,COO,BSE/TSE 和分析图谱)

显示更多⌵

相关文档

可替换产品

此产品的引用文献

参考文献

溶液计算器

摩尔浓度计算器

稀释计算器

复溶计算器

相关技术文章