为了获得访问"阿拉丁铁蛋"实时聊天框的流畅支持体验,建议您使用Chrome浏览器或选择360浏览器极速模式(如何切换极速模式?),感谢您选择我们!

2,6-二氯-1,4-苯醌

规格或纯度: >98.0%
有货

库存信息

关闭

库存信息

关闭

库存信息

关闭

库存信息

关闭
货号 (SKU) 包装规格 是否现货 价格 数量
D154940-250mg
250mg 现货 Stock Image
D154940-1g
1g 现货 Stock Image
D154940-5g
5g 现货 Stock Image
D154940-25g
25g 现货 Stock Image
查看相关系列
非杂环砌块

基本描述

别名 2,6一二氯-p-苯醌|2,6-二氯对苯醌
英文别名 2,6-Dichloro-1,4-benzoquinone|697-91-6|2,6-Dichloro-p-benzoquinone|2,6-Dichlorobenzoquinone|2,6-dichlorocyclohexa-2,5-diene-1,4-dione|2,6-Dichloroquinone|2,6-Dichloquinone|2,5-Cyclohexadiene-1,4-dione, 2,6-dichloro-|NSC 6211|p-Quinone, 2,6-dichloro-|p-BEN
规格或纯度 >98.0%
英文名称 2,6-Dichloro-1,4-benzoquinone
储存温度 -20°C储存,充氩
运输条件 超低温冰袋运输
产品介绍

2,6-Dichloro-1,4-benzoquinone (DCBQ, 2,6-DCBQ) is a halobenzoquinone. Halobenzoquinones are disinfection byproducts (DBPs) found in drinking water. They are capable of producing reactive oxygen species and causing oxidative damage to proteins and DNA in T24 human bladder carcinoma cells. UV-induced transformation of DCBQ in drinking water has been reported.Detection of DCBQ in drinking water by liquid chromatography-ESI tandem mass spectrometry has been reported.2,6-Dichloro-1,4-benzoquinone is the suitable reagent used to in a study to evaluate the diffusion coefficients (D) for a family of quinones, nitroaromatics, ferrocenes and aromatic hydrocarbon compounds, in acetonitrile by single potential step chronoamperometry. It may be used in the preparation of : · 2,3,5-Trichloro-1,4-dihydroquinone · 2,3,5-trichloro-1,4-benzoquinone · 2,6-Dichloro-1,4-dihydroquinone

2,6-Dichloro-1,4-benzoquinone (DCBQ, 2,6-DCBQ) is a halobenzoquinone. Halobenzoquinones are disinfection byproducts (DBPs) found in drinking water. They are capable of producing reactive oxygen species and causing oxidative damage to proteins and DNA in T24 human bladder carcinoma cells. UV-induced transformation of DCBQ in drinking water has been reported.Detection of DCBQ in drinking water by liquid chromatography-ESI tandem mass spectrometry has been reported.
2,6-Dichloro-1,4-benzoquinone is the suitable reagent used to in a study to evaluate the diffusion coefficients (D) for a family of quinones, nitroaromatics, ferrocenes and aromatic hydrocarbon compounds, in acetonitrile by single potential step chronoamperometry. It may be used in the preparation of : · 2,3,5-Trichloro-1,4-dihydroquinone · 2,3,5-trichloro-1,4-benzoquinone · 2,6-Dichloro-1,4-dihydroquinone

名称和标识符

IUPAC Name 2,6-dichlorocyclohexa-2,5-diene-1,4-dione
INCHI InChI=1S/C6H2Cl2O2/c7-4-1-3(9)2-5(8)6(4)10/h1-2H
InChi Key JCARTGJGWCGSSU-UHFFFAOYSA-N
Canonical SMILES C1=C(C(=O)C(=CC1=O)Cl)Cl
Isomeric SMILES C1=C(C(=O)C(=CC1=O)Cl)Cl
WGK Germany 3
RTECS DK4000000
PubChem CID 12771
分子量 176.98
Beilstein号 7(3)3376
Reaxy-Rn 2044125

化学和物理性质

溶解性 Insoluble in water. Solubility in methanol (almost transparency);
敏感性 对湿度和空气敏感
熔点 120-123℃

安全和危险性(GHS)

象形图
ghs07

Harmful

信号词 Warning
危险声明 H315: Causes skin irritation
H319: Causes serious eye irritation
H335: May cause respiratory irritation
H302: Harmful if swallowed
预防措施声明 P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P271,P270,P304+P340,P403+P233,P362+P364,P330,P264+P265,P301+P317,P337+P317,P332+P317,P319
WGK Germany 3
RTECS DK4000000
Reaxy-Rn 2044125
个人防护装备 dust mask type N95 (US), Eyeshields, Gloves

质检证书(COA)

质检报告(COA)

输入批号以搜索COA:

相关文档

质检报告COA

请输入批号:


产品问答

产品问答

登录提交问题 Hover me 请先登录再提交问题
您提交该产品问题后,我们会在1-2个工作日内给您答复,您可以登录"我的账号",然后点击"我的产品问答"查看答案

参考文献

1. I Yruela,G Montoya,P J Alonso,R Picorel.  (1991-12-05)  Identification of the pheophytin-QA-Fe domain of the reducing side of the photosystem II as the Cu(II)-inhibitory binding site..  The Journal of biological chemistry,  266  ((34)):  (22847-22850).  [PMID:1744077]
2. A Magnuson,L E Andréasson.  (1997-03-18)  Different manganese binding sites in photosystem II probed by selective chemical modification of histidyl and carboxylic acid residues..  Biochemistry,  36  ((11)):  (3254-3261).  [PMID:9116003]
3. A A Leontievsky,N M Myasoedova,B P Baskunov,C S Evans,L A Golovleva.  (2001-08-07)  Transformation of 2,4,6-trichlorophenol by the white rot fungi Panus tigrinus and Coriolus versicolor..  Biodegradation,  11  ((5)):  (331-340).  [PMID:11487063]
4. Yasuhiro Kashino,Wendy M Lauber,James A Carroll,Qingjun Wang,John Whitmarsh,Kazuhiko Satoh,Himadri B Pakrasi.  (2002-06-19)  Proteomic analysis of a highly active photosystem II preparation from the cyanobacterium Synechocystis sp. PCC 6803 reveals the presence of novel polypeptides..  Biochemistry,  41  ((25)):  (8004-8012).  [PMID:12069591]
5. Nikolai G Bukhov,Govindachary Sridharan,Elena A Egorova,Robert Carpentier.  (2003-05-27)  Interaction of exogenous quinones with membranes of higher plant chloroplasts: modulation of quinone capacities as photochemical and non-photochemical quenchers of energy in Photosystem II during light-dark transitions..  Biochimica et biophysica acta,  1604  ((2)):  (115-123).  [PMID:12765768]
6. C E Milliken,G P Meier,J E M Watts,K R Sowers,H D May.  (2004-01-09)  Microbial anaerobic demethylation and dechlorination of chlorinated hydroquinone metabolites synthesized by basidiomycete fungi..  Applied and environmental microbiology,  70  ((1)):  (385-392).  [PMID:14711667]
7. Pedro Heredia,Javier De Las Rivas.  (2004-01-14)  Fluorescence induction of Photosystem II membranes shows the steps till reduction and protonation of the quinone pool..  Journal of plant physiology,  160  ((12)):  (1499-1506).  [PMID:14717444]
8. A Pawlukojć,I Natkaniec,G Bator,E Grech,L Sobczyk.  (2004-09-08)  Inelastic neutron scattering studies on dichloro-1,4-benzoquinones..  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy,  60  ((12)):  (2875-2882).  [PMID:15350924]
9. Hong Jin Hwang,Robert L Burnap.  (2005-07-13)  Multiflash experiments reveal a new kinetic phase of photosystem II manganese cluster assembly in Synechocystis sp. PCC6803 in vivo..  Biochemistry,  44  ((28)):  (9766-9774).  [PMID:16008361]
10. Feng Qin,Yuan-Yuan Zhao,Yuli Zhao,Jessica M Boyd,Wenjun Zhou,Xing-Fang Li.  (2009-12-22)  A toxic disinfection by-product, 2,6-dichloro-1,4-benzoquinone, identified in drinking water..  Angewandte Chemie (International ed. in English),  49  ((4)):  (790-792).  [PMID:20025006]
11. Denis V Yanykin,Andrei A Khorobrykh,Sergey A Khorobrykh,Vyacheslav V Klimov.  (2010-01-26)  Photoconsumption of molecular oxygen on both donor and acceptor sides of photosystem II in Mn-depleted subchloroplast membrane fragments..  Biochimica et biophysica acta,  1797  ((4)):  (516-523).  [PMID:20097156]
12. Yichao Qian,Wei Wang,Jessica M Boyd,Minghuo Wu,Steve E Hrudey,Xing-Fang Li.  (2013-04-09)  UV-induced transformation of four halobenzoquinones in drinking water..  Environmental science & technology,  47  ((9)):  (4426-4433).  [PMID:23560392]
13. Håkan Nilsson,Tomasz Krupnik,Joanna Kargul,Johannes Messinger.  (2014-04-15)  Substrate water exchange in photosystem II core complexes of the extremophilic red alga Cyanidioschyzon merolae..  Biochimica et biophysica acta,  1837  ((8)):  (1257-1262).  [PMID:24726350]
14. Breanne E Holmes,Lisa Smeester,Rebecca C Fry,Howard S Weinberg.  (2017-08-27)  Identification of endocrine active disinfection by-products (DBPs) that bind to the androgen receptor..  Chemosphere,  187  ():  (114-122).  [PMID:28843117]
15. Kai He,Erika Okuta,José Andres Cordero,Shinya Echigo,Yasuhiro Asada,Sadahiko Itoh.  (2018-03-10)  Formation of chlorinated haloacetic acids by chlorination of low molecular weight compounds listed on pollutant release and transfer registers (PRTRs)..  Journal of hazardous materials,  351  ():  (98-107).  [PMID:29522930]
16. Jinhua Li,Birget Moe,Yanming Liu,Xing-Fang Li.  (2018-05-09)  Halobenzoquinone-Induced Alteration of Gene Expression Associated with Oxidative Stress Signaling Pathways..  Environmental science & technology,  52  ((11)):  (6576-6584).  [PMID:29737854]
17. Lin-Na Xie,Jie Shao,Chun-Hua Huang,Feng Li,Dan Xu,Balaraman Kalyanaraman,Ben-Zhan Zhu.  (2018-10-24)  An unusual double radical homolysis mechanism for the unexpected activation of the aldoxime nerve-agent antidotes by polyhalogenated quinoid carcinogens under normal physiological conditions..  Free radical biology & medicine,  130  ():  (1-7).  [PMID:30352302]
18. Kenichi Nakamura,Shu Zhu,Katsuko Komatsu,Masao Hattori,Makoto Iwashima.  (2019-01-11)  Expression and Characterization of the Human Intestinal Bacterial Enzyme Which Cleaves the C-Glycosidic Bond in 3″-Oxo-puerarin..  Biological & pharmaceutical bulletin,  42  ((3)):  (417-423).  [PMID:30626800]
19. Breanne E Holmes,Lisa Smeester,Rebecca C Fry,Howard S Weinberg.  (2019-01-31)  Disinfection Byproducts Bind Human Estrogen Receptor-α..  Environmental toxicology and chemistry,  38  ((5)):  (956-964).  [PMID:30698843]
20. Amy A Cuthbertson,Cristina Bach,Susan D Richardson,Xavier Dauchy.  (2019-11-17)  A novel automated method for the quantification of ten halobenzoquinones in drinking water using online solid-phase extraction coupled with liquid chromatography tandem mass spectrometry..  Journal of chromatography. A,  1612  ():  (460642-460642).  [PMID:31732155]
21. H S Misra,T S Desai.  (1993-08-16)  Involvement of acceptor side components of PSII in the regulatory mechanism of Plectonema boryanum grown photoautotrophically under diazotrophic condition..  Biochemical and biophysical research communications,  194  ((3)):  (1001-1007).  [PMID:8352756]
22. N Knoepfle,T M Bricker,C Putnam-Evans.  (1999-02-04)  Site-directed mutagenesis of basic arginine residues 305 and 342 in the CP 43 protein of photosystem II affects oxygen-evolving activity in Synechocystis 6803..  Biochemistry,  38  ((5)):  (1582-1588).  [PMID:9931025]
23. Y I Park,J Karlsson,I Rojdestvenski,N Pronina,V Klimov,G Oquist,G Samuelsson.  (1999-02-26)  Role of a novel photosystem II-associated carbonic anhydrase in photosynthetic carbon assimilation in Chlamydomonas reinhardtii..  FEBS letters,  444  ((1)):  (102-105).  [PMID:10037156]
24. Masako Iwai,Mitsunori Katayama,Masahiko Ikeuchi.  (2006-05-16)  Absence of the psbH gene product destabilizes the Photosystem II complex and prevents association of the Photosystem II-X protein in the thermophilic cyanobacterium Thermosynechococcus elongatus BP-1..  Photosynthesis research,  87  ((3)):  (313-322).  [PMID:16699922]
25. S Dudekula,M Fragata.  (2006-08-29)  Investigation of the electron transfer site of p-benzoquinone in isolated photosystem II particles and thylakoid membranes using alpha- and beta-cyclodextrins..  Journal of photochemistry and photobiology. B, Biology,  85  ((3)):  (177-183).  [PMID:16934484]
26. Ben-Zhan Zhu,Hong-Tao Zhao,Balaraman Kalyanaraman,Jun Liu,Guo-Qiang Shan,Yu-Guo Du,Balz Frei.  (2007-03-16)  Mechanism of metal-independent decomposition of organic hydroperoxides and formation of alkoxyl radicals by halogenated quinones..  Proceedings of the National Academy of Sciences of the United States of America,  104  ((10)):  (3698-3702).  [PMID:17360415]
27. Ben-Zhan Zhu,Guo-Qiang Shan,Chun-Hua Huang,Balaraman Kalyanaraman,Li Mao,Yu-Guo Du.  (2009-06-27)  Metal-independent decomposition of hydroperoxides by halogenated quinones: detection and identification of a quinone ketoxy radical..  Proceedings of the National Academy of Sciences of the United States of America,  106  ((28)):  (11466-11471).  [PMID:19556549]
28. Sabrina Diemert,Wei Wang,Robert C Andrews,Xing-Fang Li.  (2013-02-06)  Removal of halo-benzoquinone (emerging disinfection by-product) precursor material from three surface waters using coagulation..  Water research,  47  ((5)):  (1773-1782).  [PMID:23379973]
29. Jinhua Li,Wei Wang,Hongquan Zhang,X Chris Le,Xing-Fang Li.  (2014-05-09)  Glutathione-mediated detoxification of halobenzoquinone drinking water disinfection byproducts in T24 cells..  Toxicological sciences : an official journal of the Society of Toxicology,  141  ((2)):  (335-343).  [PMID:24812012]
30. Xuefeng Sun,Dongbin Wei,Wei Liu,Jialin Geng,Jun Liu,Yuguo Du.  (2019-01-28)  Formation of novel disinfection by-products chlorinated benzoquinone, phenyl benzoquinones and polycyclic aromatic hydrocarbons during chlorination treatment on UV filter 2,4-dihydroxybenzophenone in swimming pool water..  Journal of hazardous materials,  367  ():  (725-733).  [PMID:30685680]